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Multiple Dolomitization and Fluid Flow Events in the Precambrian Dengying Formation of Sichuan Basin, Southwestern China 被引量:7
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作者 PENG Bo LI Zongxing +6 位作者 LI Guorong LIU Chenglin ZHU Shifa ZHANG Wang ZUO Yinhui GUO Yingchun WEI Xiaojie 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2018年第1期311-332,共22页
The Precambrian Dengying Formation is a set of large-scale, extensively dolomitized, carbonate reservoirs occurring within the Sichuan Basin. Petrographic and geochemical studies reveal dolomitization was a direct res... The Precambrian Dengying Formation is a set of large-scale, extensively dolomitized, carbonate reservoirs occurring within the Sichuan Basin. Petrographic and geochemical studies reveal dolomitization was a direct result of precipitation by chemically distinct fluids occurring at different times and at different intensities. Based on this evidence, dolomitization and multiple fluid flow events are analyzed, and three types of fluid evolution models are proposed. Results of analysis show that Precambrian Dengying Formation carbonates were deposited in a restricted peritidal environment (630- 542 Ma). A high temperature and high Mg2+ concentration seawater was a direct result of dolomitization for the micrite matrix, and for fibrous aragonite in primary pores. Geochemical evidence shows low δ18O values of micritic dolomite varying from -1.29%o to -4.52%o PDB, abundant light rare earth elements (REEs), and low dolomite order degrees. Microbes and meteoric water significantly altered dolomite original chemical signatures, resulting in algal micritic dolomite and the fine-grained, granular, dolosparite dolomite having very negative δ18O values. Finely crystalline cement dolomite (536.3-280 Ma) and coarsely crystalline cement dolomite have a higher crystallization degree and higher order degree. The diagenetic sequence and fluid inclusion evidence imply a linear correlation between their burial depth and homogenization temperatures, which closely resemble the temperature of generated hydrocarbon. Compared with finely crystalline dolomite, precipitation of coarsely crystalline dolomite was more affected by restricted basinal fluids. In addition, there is a trend toward a more negative δ18O value, higher salinity, higher Fe and Mn concentrations, REE-rich. Two periods of hydrothermal fluids are identified, as the exceptionally high temperatures as opposed to the temperatures of burial history, in addition to the presence of high salinity fluid inclusions. The early hydrothermal fluid flow event was characterized by hot magnesium- and silicon-rich fluids, as demonstrated by the recrystallized matrix dolomite that is intimately associated with flint, opal, and microcrystalline quartz in intergranular or intercrystalline pores. This event was likely the result of a seafloor hydrothermal chimney eruption during Episode I of the Tongwan Movement (536.3-5.5 Ma). In contrast, later hydrothermal fluids, which caused precipitation of saddle dolomite, were characterized by high salinity (15-16.05wt% NaCI equivalent) and homogenization temperatures (250 to 265℃), δ18O values that were more enriched, and REE signatures. Geochemical data and the paragenetic sequence indicate that this hydrothermal fluid was related to extensive Permian large igneous province activity (360-280 Ma). This study demonstrates the presence of complicated dolomitization processes occurring during various paleoclimates, tectonic cycles, and basinal fluids flow; results are a useful reference for these dolomitized Precambrian carbonates reservoirs. 展开更多
关键词 PRECAMBRIAN dolomitE geological fluid flow meteoric water hydrothermal activity SichuanBasin
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Characteristics and Dolomitization of Upper Cambrian to Lower Ordovician Dolomite from Outcrop in Keping Uplift, Western Tarim Basin, Northwest China 被引量:4
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作者 JI Congwei QING Hairuo +3 位作者 CHEN Daizhao LUO Ping JIN Zhijun SHAO Longyi 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2013年第4期1005-1018,共14页
Late Cambrian to Early Ordovician sedimentary rocks in the western Tarim Basin, Northwest China, are composed of shallow-marine platform carbonates. The Keping Uplift is located in the northwest region of this basin. ... Late Cambrian to Early Ordovician sedimentary rocks in the western Tarim Basin, Northwest China, are composed of shallow-marine platform carbonates. The Keping Uplift is located in the northwest region of this basin. On the basis of petrographic and geochemical features, four matrix replacement dolomites and one type of cement dolomite are identified. Matrix replacement dolomites include (1) micritic dolomites (MD1); (2) fine-coarse euhedral floating dolomites (MD2); (3) fine-coarse euhedral dolomites (MD3); and (4) medium-very coarse anhedral mosaic dolomites (MD4). Dolomite cement occurs in minor amounts as coarse saddle dolomite cement (CD1) that mostly fills vugs and fractures in the matrix dolomites. These matrix dolomites have δ18O values of ?9.7‰ to ?3.0‰ VPDB (Vienna Pee Dee Belemnite); δ13C values of ?0.8‰ to 3.5‰ VPDB; 87Sr/86Sr ratios of 0.708516 to 0.709643; Sr concentrations of 50 to 257 ppm; Fe contents of 425 to 16878 ppm; and Mn contents of 28 to 144 ppm. Petrographic and geochemical data suggest that the matrix replacement dolomites were likely formed by normal and evaporative seawater in early stages prior to chemical compaction at shallow burial depths. Compared with matrix dolomites, dolomite cement yields lower δ18O values (?12.9‰ to ?9.1‰ VPDB); slightly lower δ13C values (?1.6‰-0.6‰ VPDB); higher 87Sr/86Sr ratios (0.709165-0.709764); and high homogenization temperature (Th) values (98°C-225°C) and salinities (6 wt%-24 wt% NaCl equivalent). Limited data from dolomite cement shows a low Sr concentration (58.6 ppm) and high Fe and Mn contents (1233 and 1250 ppm, respectively). These data imply that the dolomite cement precipitated from higher temperature hydrothermal salinity fluids. These fluids could be related to widespread igneous activities in the Tarim Basin occurring during Permian time when the host dolostones were deeply buried. Faults likely acted as important conduits that channeled dolomitizing fluids from the underlying strata into the basal carbonates, leading to intense dolomitization. Therefore, dolomitization, in the Keping Uplift area is likely related to evaporated seawater via seepage reflux in addition to burial processes and hydrothermal fluids. 展开更多
关键词 dolomitization lithologic characteristics geochemical characteristics Upper Cambrian-Lower Ordovician Keping Uplift
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Dolomitization evolution and its effects on hydrocarbon reservoir formation from penecontemporaneous to deep burial environment 被引量:5
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作者 SHEN Anjiang LUO Xianying +2 位作者 HU Anping QIAO Zhanfeng ZHANG Jie 《Petroleum Exploration and Development》 CSCD 2022年第4期731-743,共13页
Aiming at the scientific problem that only part of dolomite acts as dolomite reservoir,this paper takes the multiple dolomite-bearing formations in the Tarim and Ordos basins,NW China and Sichuan Basin,SW China as the... Aiming at the scientific problem that only part of dolomite acts as dolomite reservoir,this paper takes the multiple dolomite-bearing formations in the Tarim and Ordos basins,NW China and Sichuan Basin,SW China as the study object,by means of mineral petrological analysis and geochemical methods including carbonate clumped isotope,U-Pb isotopic dating,etc.,to rebuild the dolomitization pathway and evaluate its effects on reservoir formation.On the basis of detailed rock thin section observation,five dolomitic structural components are identified,including original fabric-retained dolomite(microbial and/or micrite structure),buried metasomatic dolomite I(subhedral-euhedral fine,medium and coarse crystalline structure),buried metasomatic dolomite II(allotriomorphic-subhedral fine,medium and coarse crystalline structure),buried precipitation dolomite and coarse crystalline saddle dolomite.Among them,the first three exist in the form of rocks,the latter two occur as dolomite minerals filling in pores and fractures.The corresponding petrological and geochemical identification templates for them are established.Based on the identification of the five dolomitic structural components,six dolomitization pathways for three types of reservoirs(preserved dolomite,reworked dolomite and limestone buried dolomitization)are distinguished.The initial porosity of the original rock before dolomitization and the dolomitization pathway are the main factors controlling the development of dolomite reservoirs.The preserved dolomite and reworked dolomite types have the most favorable dolomitization pathway for reservoir formation,and are large scale and controlled by sedimentary facies in development and distribution,making them the first choices for oil and gas exploration in deep carbonate formations. 展开更多
关键词 dolomitization dolomitization pathway dolomite reservoir CARBONATES penecontemporaneous environment burial environment dolomite genesis identification template
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Dolomitization and the causes of dolomitization dolomite reservoir 被引量:2
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作者 FAN Bojiang ZHANG Xiaoming +2 位作者 ZHANG Jian PANG Xiongqi LIU Chenglin 《Chinese Journal Of Geochemistry》 EI CAS 2012年第2期147-154,共8页
This paper utilizes multi-methods,such as core observation,slice identification,isotope analysis,trace element analysis,fluid inclusion technique and so on,to study the causes of the dolomite in the Nanpu Sag and the ... This paper utilizes multi-methods,such as core observation,slice identification,isotope analysis,trace element analysis,fluid inclusion technique and so on,to study the causes of the dolomite in the Nanpu Sag and the origins of the dolomite reservoir.The study results show that the forming environment of dolomite in the Nanpu Sag is a fresh-water lake environment,and the dolomite is the product of dolomitization which is caused by volcanic thermal fluids in the Early Dongying period.With the development of intergranular pores in the dolomitization process,a lot of dissolved pores/vugs and fractures were formed by denudation in the later periods because of the influence of thermal fluids including the associated fluids of volcanic activities and the expelled hydrocarbon fluids of the source rocks.On the whole,these secondary dissolution spaces greatly enhance the reservoir ability of the dolomite,and there are enough reservoir spaces in the dolomite in the Nanpu Sag. 展开更多
关键词 白云岩储层 成因 南堡凹陷 湖泊环境 地热流体 火山活动 储集空间 同位素分析
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Dolomitization of the lower cretaceous carbonate reservoir in the Euphrates Graben,Syria 被引量:1
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作者 Yousef Ibrahem V.P.Morozov V.Sudakov 《Petroleum Science》 SCIE CAS CSCD 2021年第5期1342-1356,共15页
Results of this study are based on core materials description,thin sections,Cathodoluminescence(CL),and Scanning Electron Microscope(SEM)examinations.The Lower Cretaceous over the Euphrates Graben area was characteriz... Results of this study are based on core materials description,thin sections,Cathodoluminescence(CL),and Scanning Electron Microscope(SEM)examinations.The Lower Cretaceous over the Euphrates Graben area was characterized by carbonate sedimentation in shallow marine environments.The low energy lagoonal to inner shelf sediments of the Judea Formation includes micritic mudstone to wackestone texture,dolomitic limestones and dolostones.Two types of dolomites recognized in the carbonates of the Judea Formation,the preserving microcrystalline dolomites which commonly founded in the partially dolomitized micritic limestones,and the destructive coarsely crystalline dolomites which commonly founded in the dolostones and dolomitic limestones.Petrographic examinations indicate that the preserving microcrystalline dolomites represent subtidal cycles developed in a shoal to open marine depositional environments,they probably formed under conditions of the shallow burial diagenesis.The destructive coarsely crystalline dolomites may develop in more basinward,open marine environments under conditions of the deep burial diagenesis that accompanied by rising in temperature,pressure,and burial depth.It is believed that evolution of the diagenetic history of the Judean Formation sediments occurred in two diagenetic stages;the shallow burial diagenesis,and the deep burial diagenesis.Compaction processes,early fracturing,micritization,early calcite,and the early phase of dolomitization were part of the multiple diagenetic alterations during the shallow burial diagenesis.The deep burial diagenesis was marked by dissolution,late stage of dolomitization and replacement,mechanical and chemical compaction,and the late calcite precipitation.It is believed that dolomitization of the Judea Formation carbonates in the Euphrates Graben has contributed to improving the reservoir properties by increasing the porosity and thus the permeability. 展开更多
关键词 dolomitization CARBONATE DIAGENESIS Burial history Euphrates graben SYRIA
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Characteristics and Dolomitization of Dolostones in Nenjiang Formation Unit 1,Northern Songliao Basin
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作者 Yuan Gao China University of Geosciences(Beijing),Beijing 100083,China. 《地学前缘》 EI CAS CSCD 北大核心 2009年第S1期99-99,共1页
Songliao Basin is a large-scale Cretaceous continental sedimentary basin in northeastern China. In the northern Songliao Basin Nenjiang Formation Unit 1 are mainly dark mudstones with dolostone interbeds.Understanding... Songliao Basin is a large-scale Cretaceous continental sedimentary basin in northeastern China. In the northern Songliao Basin Nenjiang Formation Unit 1 are mainly dark mudstones with dolostone interbeds.Understanding the sedimentary characteristics and dolomitization of the dolostones is of great significance to the paleoenvironment and paleoc- 展开更多
关键词 Songliao Basin Nenjiang Formation dolomitE SEDIMENTARY CHARACTERISTICS REPLACEMENT marine TRANSGRESSION
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Dolomitization of the Ordovician subsalt Majiagou Formation in the central Ordos Basin,China:fluid origins and dolomites evolution
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作者 Ying Xiong Li-Chao Wang +3 位作者 Xiu-Cheng Tan Yun Liu Ming-Jie Liu Zhan-Feng Qiao 《Petroleum Science》 SCIE CAS CSCD 2021年第2期362-379,共18页
The Middle Ordovician subsalt Majiagou Formation in the Ordos Basin comprises pervasively dolomitized shallow marine limestone and is a major reservoir rich in natural gas resources.Four types of dolomite matrix and c... The Middle Ordovician subsalt Majiagou Formation in the Ordos Basin comprises pervasively dolomitized shallow marine limestone and is a major reservoir rich in natural gas resources.Four types of dolomite matrix and cement were identified based on petrographic textures:(very)finely crystalline,non-planar to planar-s matrix dolomite(Md1);finely to medium crystalline,planar-s to planar-e matrix dolomite(Md2);microbialites comprising dolomite microcrystals(Md3);and finely to coarsely crystalline dolomite cement(Cd).The Md1 and Md2 dolomites were controlled by alternating lagoon-shoal facies and haveδ13C values(−1.89 to+1.45‰VPDB for Md1,−1.35 to+0.42‰VPDB for Md2)that fall within or are slightly higher than the coeval seawater,suggesting the dolomitizing fluid of evaporated seawater.Md2 dolomite was then subjected to penecontemporaneous karstification by meteoric water and burial recrystallization by sealed brines during diagenesis,as indicated by its relatively lowerδ18O values(−8.89 to−5.73‰VPDB)and higher 87Sr/86Sr ratios(0.708920–0.710199).Md3 dolomite comprises thrombolite and stromatolite and is interpreted to form by a combination of initial microbial mediation and later replacive dolomitization related to evaporated seawater.Cd dolomite was associated with early-formed karst system in the Md2 host dolomite.The lowestδ18O values(−11.78 to−10.18‰VPDB)and 87Sr/86Sr ratios(0.708688–0.708725)and fluid inclusion data(Th:123–175°C)indicate involvement of hydrothermal fluid from which the Cd dolomite precipitated during deep burial.These results reveal the multi-stage dolomitization history of the Majiagou Formation and provide new constraints on fluid origins and dolomites evolution during deep burial in old superimposed basins,such as the Ordos Basin and elsewhere. 展开更多
关键词 dolomitization Fluid origin dolomite reservoir Hydrothermal alteration Ordos Basin
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Dolomitization in Campanian Oil Shale Rocks from South-Western Jordan
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作者 Hani M. Alnawafleh Khalid E. Tarawneh +4 位作者 Hani N. Khoury Nafeth A. Abdelhadi Osama Y. Shakkoury Reyad A. Dwairi Mazen N. Amaireh 《Open Journal of Geology》 2015年第10期689-700,共12页
This work represents the first detailed study of an oil shale (OS) section from the Upper Campanian Amman Silicified Limestone (ASL) Formation in south-western part of Jordan. More than five meters of oil shale have b... This work represents the first detailed study of an oil shale (OS) section from the Upper Campanian Amman Silicified Limestone (ASL) Formation in south-western part of Jordan. More than five meters of oil shale have been recorded. Using the petrography and geochemistry, this study aims to focus on such non-conventional types of oil shale rocks in Jordan and to shed some light on their composition and formational environment. Unlike oil shale from Maastrichtian to early Tertiary, this type of oil shale is highly dolomitized. The dolomite is diagenetic in origin. This oil shale type contains considerable amount of OM and remarkably enriched in some trace elements and shows quite low sulfur content. Results suggest that the formation of dolomite appears to be limited by the rate of organic matter oxidation. 展开更多
关键词 JORDAN Oil SHALE dolomitization CAMPANIAN
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Role of tannin pretreatment in flotation separation of magnesite and dolomite 被引量:1
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作者 Xiufeng Gong Jin Yao +5 位作者 Jun Guo Bin Yang Haoran Sun Wanzhong Yin Yulian Wang Yafeng Fu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第3期452-461,共10页
Flotation separation of magnesite and its calcium-containing carbonate minerals is a difficult problem.Recently,new regulat-ors have been proposed for magnesite flotation decalcification,although traditional regulator... Flotation separation of magnesite and its calcium-containing carbonate minerals is a difficult problem.Recently,new regulat-ors have been proposed for magnesite flotation decalcification,although traditional regulators such as tannin,water glass,sodium carbon-ate,and sodium hexametaphosphate are more widely used in industry.However,they are rarely used as the main regulators in research because they perform poorly in magnesite and dolomite single-mineral flotation tests.Inspired by the limonite presedimentation method and the addition of a regulator to magnesite slurry mixing,we used a tannin pretreatment method for separating magnesite and dolomite.Microflotation experiments confirmed that the tannin pretreatment method selectively and largely reduces the flotation recovery rate of dolomite without affecting the flotation recovery rate of magnesite.Moreover,the contact angles of the tannin-pretreated magnesite and dolomite increased and decreased,respectively,in the presence of NaOl.Zeta potential and Fourier transform infrared analyses showed that the tannin pretreatment method efficiently hinders NaOl adsorption on the dolomite surface but does not affect NaOl adsorption on the magnesite surface.X-ray photoelectron spectroscopy and density functional theory calculations confirmed that tannin interacts more strongly with dolomite than with magnesite. 展开更多
关键词 tannin pretreatment selective inhibition flotation separation MAGNESITE dolomitE
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Autochthonous Dolomitization and Dissolution in the Microbial Carbonate Rocks of the Fengjiawan Formation in the Ordos Basin
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作者 ZHANG Jing ZHANG Baomin +1 位作者 ZHANG Shuichang WANG Huajian 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2022年第4期1376-1387,共12页
Many euhedral dolomite crystals and related pores are found in the microbial siliceous stromatolite dolomite and siliceous oolitic dolomite in the Fengjiawan Formation of the Mesoproterozoic Jixian System in the south... Many euhedral dolomite crystals and related pores are found in the microbial siliceous stromatolite dolomite and siliceous oolitic dolomite in the Fengjiawan Formation of the Mesoproterozoic Jixian System in the southern Ordos Basin.With the application of the microscope,scanning electron microscope,cathodoluminescence and in-situ trace element imaging,it can be seen that different from the phase I dolomite that was damaged by silicification,the intact euhedral phase II dolomite occurred through dolomitization after silicification,concentrated mainly in the organic-rich dark laminae of the stromatolite and the dark spheres and cores of the ooids.A considerable number of phase II dolomite crystals were dissolved,giving rise to mold pores and vugs which constituted the matrix pores and also the major pore space of the Fengjiawan Formation.The formation and dissolution of the dolomite were controlled by the microenvironment favorable,respectively,for carbonate precipitation and dissolution under the influence of microbial biological activities and related biochemical reactions.The driving force and material supply of dolomitization and dissolution were confined to the fabrics enriched with microorganisms,which are highly autochthonous.This mechanism may be a key factor for the development of Precambrian dolomite and related reservoirs,in the context of the domination of microbial rocks. 展开更多
关键词 microbial carbonate rock AUTOCHTHONOUS dolomitization DISSOLUTION Fengjiawan Formation Ordos Basin
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Dolomitization Mechanism Based on Petrography and Geochemistry in the Shotori Formation (Middle Triassic), Central Iran
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作者 A. Rahimi M. H. Adabi +2 位作者 A. Aghanabati M. R. Majidifard A. M. Jamali 《Open Journal of Geology》 2016年第9期1149-1168,共20页
Middle Triassic carbonate sequences of Shotori Formation have a thickness of 70 m and are deposited Robat-e-Kalmard region of Tabas city in Central Iran basin. Gradationally and conformably overlying Sorkh shale Forma... Middle Triassic carbonate sequences of Shotori Formation have a thickness of 70 m and are deposited Robat-e-Kalmard region of Tabas city in Central Iran basin. Gradationally and conformably overlying Sorkh shale Formation, Shotori Formation, mostly composed of medium to thick dolomites (50 m), interbeded with thin lime and sandstones, is disconformable by a laterite horizon at its upper boundary. This Formation mainly consists of fine-to-coarsely crystalline dolomites. According to petrographic (fabric and grain size) and geochemical (elemental analysis of Ca, Mg, Na, Sr, Fe, Mn) evidence, five various types of dolomites were recognized in Shotori Formation. This variety results from early and late diagenetic processes, triggering a change in dolomitizing fluids and thereby forming various dolomites. Geochemical studies have revealed that the dolomites of Shotori Formation have formed under meteoric diagenesis and reducing conditions. Various dolomitization mechanisms are proposed for various types of dolomites;that is to say, Sabkha model is considered for type 1 dolomite, mixing zone model for type 2 and 3 dolomites and burial model for type 4 and 5 dolomites. 展开更多
关键词 dolomitization PETROGRAPHY GEOCHEMISTRY Shotori Formation Central Iran
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Episodic dolomitization of Paleozoic limestones in the Kinta Valley,Malaysia:Implications on porosity evolution and reservoir properties
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作者 Poon Xin Hui Mu.Ramkumar +2 位作者 R.Nagarajan Manoj J.Mathew T.F.Ng 《Energy Geoscience》 2021年第4期298-307,共10页
Carbonates undergo a variety of physical,mineralogical,chemical changes during depositional and postdepositional stages that are of interest to exploration geologists and sedimentologists.World over,about 60%of hydroc... Carbonates undergo a variety of physical,mineralogical,chemical changes during depositional and postdepositional stages that are of interest to exploration geologists and sedimentologists.World over,about 60%of hydrocarbon reserves occur in carbonates with the dominant proportion associated with dolomitic reservoirs,in particular fault-associated dolomites which appear to be proven hydrocarbon reservoirs.Dolomitization as the critical diagenetic process thus plays an important role in determining reservoir characteristics and in designing exploration strategies.The buried Paleozoic dolomites exhibit relatively higher porosity than their counterparts,Paleozoic limestones.Fault-associated dolomites are usually targets of hydrocarbon exploration due to their good reservoir quality.High heterogeneity in carbonate reservoirs due to varied porosity types and distribution makes reservoir characterization a daunting task.However,the key elements that control porosity development and evolution in these dolomites remain debatable.Studying the influence of multiphase dolomitization,associated diagenetic events,hydrothermal alteration and their causative thermo-tectonic events on porosity evolution and reservoir quality is essential to understanding the critical processes and controlling factors that result in diverse impacts on reservoir quality.In this paper,an attempt is made to characterize dolomitization in homogeneous carbonate mud and its relationship with porosity evolution and reservoir property.In the field,six facies types excluding host limestone are recognized,which are in turn characterized into seven petrographically recognizable phases,namely the host limestone,early replacement dolomite,sucrosic dolomite,metamorphosed dolomite,late replacement dolomite,brecciated limestone and dolomite and late stage calcite.Mineralogical analyses reveal the dominance of stoichiometric dolomites,followed by calcareous dolomites and magnesium calcites.Among all the field-based facies and petrographic phases,the sucrosic dolomites show appreciable porosity within a range from 4%to 8%,whereas the other phases show either nil or insignificant porosity under megascopic and petrographic observations.Our study confirms that in the process of dolomitization that substantially modifies porosity,dolomitic crystal morphologies play a significant role in enhancing or reducing the porosity. 展开更多
关键词 dolomitization Porosity evolution PALEOZOIC Kinta Valley MALAYSIA
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Origin of Dolomitization in Demirkazik Formation(Adana-Turkey)
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作者 Cengiz Yetis Bayram Ali Mert Meryem Yesilot Kaplan 《Journal of Geoscience and Environment Protection》 2017年第6期135-146,共12页
Demirkaz&#305k formation consisting of the limestones and dolomites is common in the Adana, Turkey. In this study, it is aimed to find the origin of dolomitization by preparing a detailed geological map. For this ... Demirkaz&#305k formation consisting of the limestones and dolomites is common in the Adana, Turkey. In this study, it is aimed to find the origin of dolomitization by preparing a detailed geological map. For this purpose, firstly, thin section/polished section and, chemical analysis of the twenty-one samples characterizing dolomitization of the field were prepared and examined. In the chemical analyzes, 21 samples were determined MgO-CaO ratio. Geological map was prepared by field study and MgO contents of the samples that are known coordinates in the chemical data, and the regions where dolomitization was effective were determined. Dolomitization in these carbonates occurs at early stages and late stages. Two dolomite types are petrographically determined;(1) fine crystalline dolomite (TD-1) with 10 - 25 μm crystal size and (2) coarse crystalline dolomite (TD-2) with 50 - 120 μm crystal size. TD-1 is formed by synsedimentary replacement and TD-2 derived from TD-1. The evidence of dolomitization due to pressure changes in the TD-2 dolomites is evidence of late diagenetic. There are three types of carbonate by chemical data;limestone, dolomitic limestone, calcitic dolomite and MgCO3 ratio of these is increased respectively. The rate of dolomitization is very variable and at the fracture regions, the Mg ratio increases, indicating that tectonism is the cause of dolomitization. 展开更多
关键词 dolomitE LIMESTONE REPLACEMENT dolomitization
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Impact and mechanism of bisphosphonate depressant 1-hydroxypropane-1,1-diphosphonic acid on flotation decalcification of dolomite-rich magnesite ore
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作者 Wengang Liu Xudong Chen +3 位作者 Wenbao Liu Naixu Zhang Yong Mao Ying Guo 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第7期1017-1032,共16页
Given the depletion of high-quality magnesite deposits and the rising demand for high-end magnesium materials,the separation and utilization of high-calcium magnesite ores have become essential.However,the similar sur... Given the depletion of high-quality magnesite deposits and the rising demand for high-end magnesium materials,the separation and utilization of high-calcium magnesite ores have become essential.However,the similar surface properties and solubility of semi-soluble salt-type minerals,pose significant challenges for the utilization of dolomite-rich magnesite resources.In this study,1-hydroxypropane-1,1-di phosphonic acid(HPDP)was identified for the first time as a high-performance depressant for dolomite.Various tests,including contact angle measurements,ζ potential analysis,X-ray photoelectron spectroscopy,and atomic force microscopy,were conducted to elucidate the interfacial interaction mechanisms of HPDP on the surfaces of the two minerals at different scales.Additionally,molecular modeling calculations were used to detail the spatial matching relationship between HPDP and the crystal faces of the two minerals.It was emphasized that HPDP specifically adsorbed onto the dolomite surface by forming calcium phosphonate,ensuring that the dolomite surface remained hydrophilic and sank.Moreover,it was found that the adsorption strength of HPDP on the mineral surfaces depended on the activity of the metal sites and their spatial distribution.These findings provide a theoretical foundation for the molecular design of flotation reagents for high-calcium magnesite ores. 展开更多
关键词 Depressant Interfacial mechanism MAGNESITE dolomitE DFT DECALCIFICATION
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Origin of facies-controlled dolomite and exploration significance of the Middle Permian Qixia Formation in central Sichuan Basin, Western China
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作者 Xiao-Liang Bai Long Wen +8 位作者 Yong-Mei Zhang Xi-Hua Zhang Jing Wang Yan-Gui Chen Si-Qiao Peng Wei Wang Jia-Yi Zhong Ya Li Ping Gao 《Petroleum Science》 SCIE EI CAS CSCD 2024年第5期2927-2945,共19页
The intraplatform shoal dolomite of the Middle Permian Qixia Formation is currently considered the key target of hydrocarbon exploration in the central Sichuan Basin. To systematically investigate the origin of the st... The intraplatform shoal dolomite of the Middle Permian Qixia Formation is currently considered the key target of hydrocarbon exploration in the central Sichuan Basin. To systematically investigate the origin of the stratabound facies-controlled porous dolomites of the Qixia Formation, integrated petrography,logging and seismic analysis were carried out in this work. The results are as following:(1) the dolomite reservoir is universal in the central Sichuan Basin, and its distribution is controlled by intraplatform shoals, with multilayer superposition vertically. Thick massive dolostone may also develop along with the fault.(2) Three replaced dolomites and one dolomite cement were identified: very finely to finely crystalline, anhedral to subhedral dolomite(Rd1);finely to medium crystalline, anhedral to subhedral dolomite(Rd2);coarsely crystalline, subhedral to euhedral dolomite(Rd3) and coarsely crystalline saddle dolomite cement(Sd). Rd2 and Rd3 are partly fabric-retentive, and preserve the original bioclastic ghosts. Sd shows wavy extinction, filled in the breccia veins.(3) The U-Pb dating and homogenization temperatures results indicate that the dolomite and Sd cement are associated with hydrothermal event during the Emeishan large igneous province. The δ^(13)C,^(87)Sr/^(86)Sr, and seawater-like REEY patterns suggest that the dolomitization and Sd precipitation fluids originate from connate seawater heated by elevated heat-flow.(4) The ELIP triggered large scale thermal anomalies in the basin during the Dongwu movement period. The increased temperature and pressure drove the formation water in the intra-platform shoal facies and overcame the binding effect of Mg^(2+) hydrate. Moreover, the deep hydrothermal fluid preferentially penetrated into the porous strata of shoal facies along the faults and fractures, mixed with formation water to some extent, and extensive dolomitization occurred. The facies-controlled dolomite reservoir and the underlying Cambrian source rock form a good source-reservoir assemblage, which can be a key replacement option. 展开更多
关键词 Central sichuan basin Qiaxia formation Facies-controlled dolomite Hydrothermal fluids Connate seawater
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Reactive transport modeling constraints on the complex genesis of a lacustrine dolomite reservoir:A case from the Eocene Qaidam Basin,China
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作者 Ying Xiong Bo Liu +5 位作者 Xiu-Cheng Tan Zheng-Meng Hou Jia-Shun Luo Ya-Chen Xie Kai-Bo Shi Kun-Yu Wu 《Petroleum Science》 SCIE EI CAS CSCD 2024年第4期2240-2256,共17页
Reactive transport modeling(RTM)is an emerging method used to address geological issues in diagenesis research.However,the extrapolation of RTM results to practical reservoir prediction is not sufficiently understood.... Reactive transport modeling(RTM)is an emerging method used to address geological issues in diagenesis research.However,the extrapolation of RTM results to practical reservoir prediction is not sufficiently understood.This paper presents a case study of the Eocene Qaidam Basin that combines RTM results with petrological and mineralogical evidence.The results show that the Eocene Xiaganchaigou Formation is characterized by mixed siliciclastic-carbonate-evaporite sedimentation in a semiclosed saline lacustrine environment.Periodic evaporation and salinization processes during the syngeneticpenecontemporaneous stage gave rise to the replacive genesis of dolomites and the cyclic enrichment of dolomite in the middle-upper parts of the meter-scale depositional sequences.The successive change in mineral paragenesis from terrigenous clastics to carbonates to evaporites was reconstructed using RTM simulations.Parametric uncertainty analyses further suggest that the evaporation intensity(brine salinity)and particle size of sediments(reactive surface area)were important rate-determining factors in the dolomitization,as shown by the relatively higher reaction rates under conditions of higher brine salinity and fine-grained sediments.Combining the simulation results with measured mineralogical and reservoir physical property data indicates that the preservation of original intergranular pores and the generation of porosity via replacive dolomitization were the major formation mechanisms of the distinctive lacustrine dolomite reservoirs(widespread submicron intercrystalline micropores)in the Eocene Qaidam Basin.The results confirm that RTM can be effectively used in geological studies,can provide a better general understanding of the dolomitizing fluid-rock interactions,and can shed light on the spatiotemporal evolution of mineralogy and porosity during dolomitization and the formation of lacustrine dolomite reservoirs. 展开更多
关键词 Reactive transport modeling Lacustrine dolomite Mineralogy and porosity evolution Reservoir genesis
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Dominance of rock exposure and soil depth in leaf trait networks outweighs soil quality in karst limestone and dolomite habitats
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作者 Min Jiao Jiawei Yan +3 位作者 Ying Zhao Tingting Xia Kaiping Shen Yuejun He 《Forest Ecosystems》 SCIE CSCD 2024年第5期632-641,共10页
Leaf trait networks(LTNs)visualize the intricate linkages reflecting plant trait-functional coordination.Typical karst vegetation,developed from lithological dolomite and limestone,generally exhibits differential comm... Leaf trait networks(LTNs)visualize the intricate linkages reflecting plant trait-functional coordination.Typical karst vegetation,developed from lithological dolomite and limestone,generally exhibits differential communities,possibly due to habitat rock exposure,soil depth,and soil physicochemical properties variations,leading to a shift from plant trait variation to functional linkages.However,how soil and habitat quality affect the differentiation of leaf trait networks remains unclear.LTNs were constructed for typical dolomite and limestone habitats by analyzing twenty-one woody plant leaf traits across fifty-six forest subplots in karst mountains.The differences between dolomite and limestone LTNs were compared using network parameters.The network association of soil and habitat quality was analyzed using redundancy analysis(RDA),Mantle's test,and a random forest model.The limestone LTN exhibited significantly higher edge density with lower diameter and average path length when compared to the dolomite LTN.It indicates LTN differentiation,with the limestone network displaying a more compact architecture and higher connectivity than the dolomite network.The specific leaf phosphorus and leaf nitrogen contents of dolomite LTN,as well as the leaf mass and leaf carbon contents of limestone LTN,significantly contributed to network degree and closeness,serving as crucial node traits regulating LTN connectedness.Additionally,both habitat LTNs significantly correlated with soil nitrogen and phosphorus,stoichiometric ratios,pH,and organic carbon,as well as soil depth and rock exposure rates,with soil depth and rock exposure showing greater relative importance.Soil depth and rock exposure dominate trait network differentiation,with the limestone habitat exhibiting a more compact network architecture than the dolomite habitat. 展开更多
关键词 Leaf trait networks Functional traits Woody plant community KARST dolomitE LIMESTONE
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Characteristics and main controlling factors of intra-platform shoal thin-layer dolomite reservoirs:A case study of Middle Permian Qixia Formation in Gaoshiti-Moxi area of Sichuan Basin,SW China
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作者 HE Jiang LIAN Zhihua +5 位作者 LUO Wenjun ZHOU Hui XU Huilin HE Puwei Yang Yi LAN Xuemei 《Petroleum Exploration and Development》 SCIE 2024年第1期69-80,共12页
Based on the study of the distribution of intra-platform shoals and the characteristics of dolomite reservoirs in the Middle Permian Qixia Formation in the Gaoshiti–Moxi area of the Sichuan Basin,SW China,the control... Based on the study of the distribution of intra-platform shoals and the characteristics of dolomite reservoirs in the Middle Permian Qixia Formation in the Gaoshiti–Moxi area of the Sichuan Basin,SW China,the controlling factors of reservoir development were analyzed,and the formation model of“intra-platform shoal thin-layer dolomite reservoir”was established.The Qixia Formation is a regressive cycle from bottom to top,in which the first member(Qi1 Member)develops low-energy open sea microfacies,and the second member(Qi2 Member)evolves into intra-platform shoal and inter-shoal sea with decreases in sea level.The intra-platform shoal is mainly distributed near the top of two secondary shallowing cycles of the Qi2 Member.The most important reservoir rock of the Qixia Formation is thin-layer fractured-vuggy dolomite,followed by vuggy dolomite.The semi-filled saddle dolomite is common in fracture-vug,and intercrystalline pores and residual dissolution pores combined with fractures to form the effective pore-fracture network.Based on the coupling analysis of sedimentary and diagenesis characteristics,the reservoir formation model of“pre-depositional micro-paleogeomorphology controlling shoal,sedimentary shoal controlling dolomite,penecontemporaneous dolomite benefiting preservation of pores,and late hydrothermal action effectively improving reservoir quality”was systematically established.The“first-order high zone”micro-paleogeomorphology before the deposition of the Qixia Formation controlled the development of large area of intra-platform shoals in Gaoshiti area during the deposition of the Qi2 Member.Shoal facies is the basic condition of early dolomitization,and the distribution range of intra-platform shoal and dolomite reservoir is highly consistent.The grain limestone of shoal facies is transformed by two stages of dolomitization.The penecontemporaneous dolomitization is conducive to the preservation of primary pores and secondary dissolved pores.The burial hydrothermal fluid enters the early dolomite body along the fractures associated with the Emeishan basalt event,makes it recrystallized into medium–coarse crystal dolomite.With the intercrystalline pores and the residual vugs after the hydrothermal dissolution along the fractures,the high-quality intra-platform shoal-type thin-layer dolomite reservoirs are formed.The establishment of this reservoir formation model can provide important theoretical support for the sustainable development of Permian gas reservoirs in the Sichuan Basin. 展开更多
关键词 Middle Permian Qixia Formation intra-platform shoal thin-layer dolomite paleogeomorphology diagenesis Gaoshiti-Moxi area Sichuan Basin
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Facies-controlled prediction of dolomite reservoirs in the Middle Permian Qixia Formation in Shuangyushi,northwestern Sichuan Basin
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作者 Chao Zheng Benjian Zhang +11 位作者 Rongrong Li Hong Yin Yufeng Wang Xin Hu Xiao Chen Ran Liu Qi Zeng Zhiyun Sun Rui Zhang Xingyu Zhang Weidong Yin Kun Zhang 《Energy Geoscience》 EI 2024年第2期21-30,共10页
The Middle Permian Qixia Formation in the Shuangyushi area,northwestern Sichuan Basin,develops shoal-facies dolomite reservoirs.To pinpoint promising reservoirs in the Qixia Formation,deep thin shoal-facies dolomite r... The Middle Permian Qixia Formation in the Shuangyushi area,northwestern Sichuan Basin,develops shoal-facies dolomite reservoirs.To pinpoint promising reservoirs in the Qixia Formation,deep thin shoal-facies dolomite reservoirs were predicted using the techniques of pre-stack Kirchhoff-Q compensation for absorption,inverse Q filtering,low-to high-frequency compensation,forward modeling,and facies-controlled seismic meme inversion.The results are obtained in six aspects.First,the dolomite reservoirs mainly exist in the middle and lower parts of the second member of Qixia Formation(Qi2 Member),which coincide with the zones shoal cores are developed.Second,the forward modeling shows that the trough energy at the top and bottom of shoal core increases with increasing shoal-core thickness,and weak peak reflections are associated in the middle of shoal core.Third,five types of seismic waveform are identified through waveform analysis of seismic facies.Type-Ⅰ and Type-Ⅱ waveforms correspond to promising facies(shoal core microfacies).Fourth,vertically,two packages of thin dolomite reservoirs turn up in the sedimentary cycle of intraplatform shoal in the Qi2 Member,and the lower package is superior to the upper package in dolomite thickness,scale and lateral connectivity.Fifth,in plane,significantly controlled by sedimentary facies,dolomite reservoirs laterally distribute with consistent thickness in shoal cores at topographical highs and extend toward the break.Sixth,the promising prospects are the zones with thick dolomite reservoirs and superimposition of horstegraben structural traps. 展开更多
关键词 Reservoir prediction Seismic facies Shoal-facies dolomite Qixia formation Shuangyushi Sichuan basin
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Rock physical characteristics of deep dolomite under complex geological conditions:A case study of 4th Member of Sinian Dengying Formation in the Sichuan Basin,China
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作者 Chuang Li Shu-Xin Pan +4 位作者 Hong-Bin Wang Ji-Xin Deng Jian-Guo Zhao Zhi Li Yu Zhang 《Petroleum Science》 SCIE EI CAS CSCD 2024年第4期2370-2382,共13页
The deep-ultra deep carbonate reservoir in China,commonly subjected to modification of multi-stage diagenesis,has extremely high heterogeneity.Conventional rock physics analysis cannot accurately identify the elastic ... The deep-ultra deep carbonate reservoir in China,commonly subjected to modification of multi-stage diagenesis,has extremely high heterogeneity.Conventional rock physics analysis cannot accurately identify the elastic responses of reservoir.Here,the rock physics properties of the dolomite from the 4th Member of the Sinian Dengying Formation are experimentally measured,and the change law of rock physics characteristics is investigated within the framework of the diagenetic processes by the analysis of the elastic and petrologic characteristics,pore structure,and sedimentary environments.The results show that the differentiated diagenesis results in different pore structure characteristics and microtexture characteristics of the rock.The microbial dolomite of the algal mound-grain beach facies is subjected to the contemporaneous microbial dolomitization and seepage-reflux dolomitization,penecontemporaneous selective dissolution,burial dolomitization,and hydrothermal dolomitization.The resultant crystalline dolomite is found with one main type of the dolomite crystal contact boundaries,and the dissolution pore is extensive development.The siliceous,muddy,and limy dolomite of the interbeach sea environment mainly experiences the weak capillary concentration dolomitization,intensive mechanical compaction-induced densification,and burial dolomitization.Such crystalline dolomite is observed with four types of contact boundaries,namely the dolomite contact,clay contact,quartz contact,and calcite contact boundaries,and porosity mostly attributed to residual primary inter-granular or crystalline pores.The samples with the same crystal boundary condition have consistent correlations between the compressional-and shear-wave velocities,and between the compressional-wave velocity and the velocity ratio.Additionally,the variation of the acoustic velocity with effective pressure and the intensity of pore-scale fluid-related dispersion are controlled by the differentiation of pore structure types of the samples.The varied effects of soft pores like micro-cracks on the compressional-and shearwave velocity causes considerable changes in the relationships between the compressional-and shearwave velocities,compressional-wave velocity and velocity ratio,and porosity and acoustic velocity.This research is an attempt to demonstrate a novel method for investigating the rock physics variation of rock during the geological process,and the obtained findings can provide the rock physics basis for seismic prediction of the characteristics of deep carbonate reservoirs. 展开更多
关键词 Deep-ultra deep carbonate reservoirs Rock physics properties dolomitE Seismic elastic properties MICRO-CRACK Pore structure types
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