Phase Homogeneity and Crystal Structure of Sb_(88)Te_(12) Synthesized by Melt-quench Method

Phase homogeneity and crystal structure of SbsaTe12 alloy synthesized by melt-quench method have been analyzed using X-ray diffraction （XRD） and Raman spectroscopy. Rietveld refinement of crystal structure of Sb8sTe12 has revealed the formation of SbsTe3 and Sb phases respectively with 11R and A7 structures （space group is R3m）. Phase fractions of the phases SbsTe3 and Sb have been determined to be 44.44% and 55.56% respectively. Raman spectrum of SbssTe12 has showed a highest intensity peak at 156 cm-1 and another peak at 151.1 cm-1, which correspond to Alg modes of SbsTe3 and element Sb, respectively. Analysis of Raman spectrum has substantiated the results obtained from structure refinement regarding the presence of two different phases.

Synthesis and Characterization of High-purity Aluminum Titanate with Water Quenching Method

High-purity aluminum titanate was synthesized via a water quenching method with waste-residue in the aluminum factory and industrial TiO2 as the main raw materials, which belongs to the comprehensive utilization of solid wastes. Compared with the conventional method, it can reduce synthesis temperature, effectively inhibit decomposition and raise the content of AT; the addition of tiny silicon powder can improve the sintering and optimize the properties of AT. The crystalline phase structure and microstructure of each sample were characterized with XRD and SEM methods; the content of each crystalline phase in each sample was confirmed with Rietveld Quantification method; the properties of each sample were also tested. The experimental results showed that No. 4 is the optimum specimen, with the corresponding mass ratio of Al2O3/TiO2 to be 1.27 and the content of AT of 97.2 wt%. The addition of optimum tiny silicon powder is confirmed to be 8wt%; its corresponding bulk density is 2.63 g/cm^3, bending strength is 46.34 MPa, and the retention of one thermal vibration bending strength is 71.5%.

Determination of trace arsenic(V) by catalytic solid substrate-room temperature phosphorescence quenching method

In the H2SO4 medium and in the presence of dodecylbenzene sulfonic acid sodiumsalt (DBS), dimethyl yellow (R) could emit strong and stable solid substrate room temperature phosphorescence (RTP) on filter paper. And NaIO4 could oxidize R to cause the RTP quenching. Arsenic(V) could catalyze the reaction of NaIO4 oxidizing R, which caused the RTP sharply quenching. The reducing value of phosphorescence intensity (ΔIp) for the system with DBS is 3.3 times higher than that without DBS. Moreover, the ΔIp is proportional to the concentration of As(V). Based on the facts above, a new RTP quenching method for the determination of trace As(V) has been established.

Improved Nonlinear Equation Method for Numerical Prediction of Jominy End-Quench Curves

Without considering the effects of alloying interaction on the Jominy end-quench curves, the prediction resuits obtained by YU Bai-hai＇s nonlinear equation method for multi-alloying steels were different from those experimental ones reported in literature. Some alloying elements have marked influence on Jominy end-quench curves of steels. An improved mathematical model for simulating the Jominy end-quench curves is proposed by introducing a parameter named alloying interactions equivalent （Le）. With the improved model, the Jominy end-quench curves of steels so obtained agree very well with the experimental ones.

Finite Differential Method Simulation on Temperature Field in Process of Laser Quenching

Laser Quenching is one of main contents in laser heat treatment. At present, computer simulation on cooling course of laser quenching is the main research field and the foundation of calculating inner thermal stresses in object. It also provides theoretical basis for optimizing and controlling the course of laser quenching technology. In this paper, the difference between finite element method and finite differential method, which are two methods to calculate the laser quenching temperature field and calculation precision are studied. The unstable temperature field is solved and the configure and time are discretizcd simultaneously. About time discrete, two kinds of differential pattern are discussed. Compared the calculation results with measurement values, it shows that the differential method adopting in the paper is feasible and the calculation precision and calculation velocity can be increased to use variable step-size about time. Also, the result testifies that different calculation methods can be employed in case of variable application situation and calculation precision.

Preparation of micro-nano hollow multiphase ceramic microspheres containing MnFe_2O_4 absorbent by self-reactive quenching method

Fe–Fe2O3–MnO2–sucrose–epoxy resin and O2 as reaction system and feed gas,separately,were used to prepare micro-nano hollow multiphase ceramic microspheres containing MnFe2O4absorbent by self-reactive quenching method which is integrated with flame jet,selfpropagating high-temperature synthesis(SHS),and rapidly solidification.The morphologies and phase compositions of hollow microspheres were studied by scanning electron microscope(SEM),transmission electron microscope(TEM),X-ray diffraction(XRD),and energy dispersive spectroscopy.The results show that the quenching products are regular spherical substantially with hollow structure,particle size is between few hundreds nanometers and 5 lm.Phase compositions are diphase of Fe3O4,Mn3O4,and MnFe2O4,and the spinel soft magnetic ferrite MnFe2O4 with microwave magnetic properties is in majority.Collisions with each other,burst as well as‘‘refinement’’of agglomerate powders in flame field may be the main reasons for the formation of micro-nano hollow multiphase ceramic microspheres containing MnFeOabsorbent.

Study on State of Terbium Ion in Liposome by One order Derivative Fluorescence Quenching Method

The state of Tb3+ is investigated in liposome. When the concentration of PC is below CMC (critical micell concentration), most of Tb3+ is associated with PC, the binding constant is about 3.35×103 L/mol. When the concentration of PC is beyond CMC, most of Tb3+ is dimerized, the dimerization constant is about 3.92×104L/mol. In PC?CH?H2O system, the binding constant of Tb3+?CH complex 2.93×104L/mol is obtained.

A Reproducible Approach of Preparing High-Quality Overdoped Bi_2Sr_2CaCu_2O_(8+δ) Single Crystals by Oxygen Annealing and Quenching Method

We report a reproducible approach in preparing high-quality overdoped Bi2 Sr2 CaCu2 08＋δ （Bi2212） single crystals by annealing Bi2212 crystals in high oxygen pressure followed by a fast quenching. In this way, high-quality overdoped and heavily overdoped Bi2212 single crystals are obtained by controlling the annealing oxygen pressure. We find that, beyond a limit of oxygen pressure that can achieve most heavily overdoped Bi2212 with a Tc N63 K, the annealed Bi2212 begins to decompose. This accounts for the existence of the hole-doping limit and thus the Tc limit in the heavily overdoped region of Bi2212 by the oxygen annealing process. These results provide a reliable way in preparing high-quality overdoped and heavily overdoped Bi2212 crystals that are important for studies of the physical properties, electronic structure and superconductivity mechanism of the cuprate superconductors.

A FLUORESCENCE QUENCHING IMNUNOASSAY METHOD FOR DETERMINATION OF TRACE ALBUMIN USING UNLABELED EUROPIUM CHELATE

A fluoroimmunoassay method using unlabeled europium chelate is described.The principle is similar to that of fluoroimmunoassay method using lanthanide chelate as labels.The procedure is simple because labeling process is omitted.The detection limit is about 10^(10) mol/L antigen.The relative standard deviation of immunoassay is less than 10%.The recoveries of human serum albumin and estradiol protein conjugate are 96-105% and 111% respectively.

Determination of heavy metal ion in landfill leachate with solvent extracting ＆ fluorescence quenching method

Add the masking agent and biscyclohexanoneoxalyldihydraone into the diluted clarificd liquid of the landfill leachate which was treatmented by digestion and centrifugal filtration to complexate all heavy metal ion in the trcatmented liquid, and extracted using CHCl3 many time, then it were demasking and decomposing respectively, and adjusted different pH and formed Me^n＋-PAN coordination compound when these metal ion reaction with PAN. The Fluoresence quenching of Rh6G （λex/λem=543mn/558nm） when the metal ion coordination compound was add into the Rh6G solution step by step, the quenching intensity was directly proportional to the concentration of the metal ion in the certain range. So a new method of fast and simple for determination of trace metal ion in landfill lcachate was established to determine metal ion in sample of different landfill leachate in Three Gorge Water Reservoir, and comparison the classic assay method with satisfactory results.

Determination of Chlorobenzene by Hydroxypropyl-β- Cyclodextrin Sensitized Fluorescence Quenching Method with Neutral Red as a Fluorescence Probe

The fluorescence quenching of inclusion complex of neutral red （NR） and hydroxypropyl-β-cyclodextrin （HP-β-CD） carried by chlorobenzene was investigated. The fluorescence intensity of NR increased due to the formed inclusion complex of HP-β-CD and NR. But the fluorescence intensity of NR-HP-β-CD diminished when chlorobenzene was added, and there was a linear relationship between the fluorescence quenching value of the system （△IF = IF, NR-HP-β-CD - IF, CB-NB-NR-HP-β-CD） and the concentration of chlorobenzene. Based on this, a novel fluorescence quenching method for the determination of chlorobenzene with NR as a fluorescence probe has been developed. Under the optimal conditions, the linear range of calibration curve for the determination of chlorobenzene was 5.0 × 10^-8 - 8.0 × 10^-6 mol/L and the detection limit was 1.0 × 10^-8 mol/L. It has been applied to determination ofchlorobenzene in synthetic waste water samples with satisfactory results.

A QUENCHING FLUORESCENCE IMMUNOASSAY METHOD FOR DETERMINATION OF TRACE ALBUMIN USING UNLABELED TERBIUM CHELATE

A fluoroimmunoassay method using unlabeled Terbium chelate is described.The principle is similar to that of fluoroimmunoassay method using lanthanide chelate as labels.The procedure is simpte because labeling process is unnecessary.The recovery of HSA and albumin in urine is 107% and 95% respectively.The standard deviation is tess than 10%.

掺氮碳量子点用于柳氮磺吡啶的快速检测

以微波法一步合成制备出荧光性能强、荧光量子产率为89.38%的掺氮碳量子点(N-CDs),并通过荧光猝灭法建立了快速准确测定柳氮磺吡啶(SSZ)的新方法。通过透射电子显微镜、傅里叶红外光谱对碳量子点进行表征,结果显示N-CDs的平均粒径为2.91 nm,主要由C、O、N元素组成,大量羰基、羟基和羧基存在于N-CDs表面。在最佳条件下,柳氮磺吡啶浓度在0.1~2μmol/L和3~200μmol/L范围内线性良好,检出限为0.2μmol/L。将所建方法用于柳氮磺吡啶肠溶片中柳氮磺吡啶含量的测定,回收率为97.3%~102%。

旋流法熔渣水淬余热回收数值模拟研究

热炉渣及其余热的利用是钢铁工业面临的巨大挑战。如何回收熔渣中的余热,进行余热发电是节能减排、环保的重要内容。熔渣余热回收包括机械破碎法、鼓风法和离心法等,但热回收技术不成熟,均有缺点。为提高水淬法的热能回收利用、降低回收装置的占地面积、提高熔渣的冷却效率,本文通过Fluent数值模拟的方法,对旋流法熔渣余热回收装置进行研究,主要探究熔渣的放热情况、流动情况以及装置蒸汽产出。模拟结果显示,熔渣在旋流法反应器内停留时间可达约15 s,换热时间充分。捕渣网的设计可以加速熔渣在反应器内的沉降。同时由于水的比热和潜热巨大,对熔渣的降温速率可以达到水泥生产的玻璃态炉渣产品的需求。通过使用旋流法对50 t/h、1550℃熔渣余热进行回收利用,可以产生高达40 t/h、209.9℃过热蒸汽用以发电,产生的年收益可达51082万元,具有非常大的应用潜力。

2195铝锂合金浸入式末端淬火实验与温度场有限元模拟

通过浸入式末端淬火实验和有限元模拟研究了2195铝锂合金的淬火温度场,获得不同位置的冷却曲线和硬度,结合微观组织分析2195铝锂合金的淬火敏感性机理。结果表明:2195铝锂合金板材的界面传热系数与表面温度之间存在非线性关系,当样品表面温度降低时,界面传热系数先升高后降低,在101℃左右达到最大值28.3 kW/(m^(2)∙℃);2195铝锂合金采用浸入式末端淬火时,淬火速率随着距离浸入端距离的增加而减小;随着淬火速率的减小,淬火析出相的尺寸和面积分数均增加,硬度随之降低;当淬火速率从402.5℃/s下降至3.9℃/s时,硬度下降率为25.6%。同时,分别建立了硬度值H和硬度下降率ΔH与淬火析出相的面积分数A的关系曲线。在慢速淬火过程中,由于大量淬火析出相的析出,影响后续时效过程中T1相的析出和长大,导致强化效果显著降低,合金的硬度大幅下降。

铝锂合金淬火敏感性的研究进展

铝锂合金具有低密度、高比强度、高比刚度及优良耐腐蚀性能,在航空航天领域获得了广泛的应用,但铝锂合金存在的淬火敏感性限制了其在大规格结构件上的应用。本文概括了国内外关于铝锂合金淬火敏感性的研究情况,介绍了淬火敏感性的研究方法,围绕合金元素、塑性变形和热处理工艺分析了影响淬火敏感性的因素,最后阐述了淬火过程中的组织演变及析出行为对铝锂合金时效后组织和性能的影响,并提出未来研究中值得进一步探索的难点、重点问题。

淬火冷却方式对7A52铝合金方管材组织与性能的影响

通过金相组织观察和室温力学性能测试,研究了在线风冷淬火、在线水罐淬火和离线淬火对壁厚为5 mm的7A52铝合金方管材显微组织与力学性能的影响。结果表明,7A52铝合金方管材采用在线水罐淬火冷却方式时,其抗拉强度为483 MPa,屈服强度为431 MPa,断后伸长率为13%,既可满足产品的强度要求,又能降低生产成本。

反常热猝灭Sr_(2)Ga_(2)SiO_(7)∶Sm^(3)+红色荧光粉的合成及发光性能

采用高温固相法合成了系列Sr_(2-x)Ga_(2)SiO_(7)∶xSm^(3)+红色荧光粉,通过X射线衍射(XRD)、扫描电子显微镜(SEM)、光致发光(PL)光谱、高温荧光光谱、荧光量子效率和荧光衰减寿命等一系列表征手段对合成荧光粉的物相及晶体结构、发光性能和热稳定性进行研究。一系列结果表明,在404 nm紫外光激发下,Sr_(2-x)Ga_(2)SiO_(7)∶xSm^(3)+荧光粉在598 nm处发出明亮的红色光。Sr_(2-x)Ga_(2)SiO_(7)∶xSm^(3)+荧光粉发光强度随Sm^(3)+离子浓度变化,在x=0.03时发生浓度猝灭,是由电偶极-电偶极相互作用导致的。随着温度逐渐上升,系列荧光粉表现出反常的热猝灭现象,在393 K时发光强度达到最大,强度为室温下的102.5%;在473 K时,发光强度仍可以保持室温下的101.3%。此外,最佳样品的荧光量子效率可达72.5%。研究表明,Sr_(2-x)Ga_(2)SiO_(7)∶xSm^(3)+红色荧光粉是一种具有高热稳定性、高量子效率可用于WLED的发光材料。

6061T6超高硬度扁棒淬火工艺开发

6061T6铝合金材料用途广泛,市场对该合金硬度要求越来越高,实际生产急需攻克此难关。本次研究认为:材料硬度与淬火方式密切相关,离线淬火优于在线淬火;当挤压机出口距离淬火区域较远时,材料淬火转移时间较长,固溶体过饱和度降低,导致材料表面硬度偏低;表面粗晶是导致材料表面硬度偏低的次要原因。通过550℃高温固溶热处理能获得超高硬度的6061T6铝材,标准推荐的529℃可作为普通硬度材料的固溶温度。

基于溴酸钾氧化酚藏花红的荧光猝灭法测定柠檬酸

在稀H_(2)SO_(4)介质中,用柠檬酸活化钒(V)可催化溴酸钾氧化酚藏花红,导致酚藏花红的荧光猝灭,由此建立了荧光猝灭法测定柠檬酸的新方法。探讨了硫酸、溴酸钾、偏钒酸铵、酚藏花红用量、反应温度、反应时间对体系的影响,优化了测定条件。在最佳实验条件下,方法的线性范围为0.833~3.750μg·mL^(-1),线性方程为ΔF=-2.359+67.483ρ,相关系数R^(2)为0.9929,检出限为0.42μg·mL^(-1)。该方法用于饮料中柠檬酸的测定,测定结果的回收率为95.5%~108%,RSD为3.5%~4.1%,表明本分析方法可行。