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团结就是力量,独立才能发光——关于AIE和ACQ效应的科普实验
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作者 贾艳媛 荣融 +3 位作者 刘洁 郭晶 姜国玉 郭硕 《大学化学》 CAS 2024年第9期349-358,共10页
发光材料在生活中具有诸多的应用,但目前面向公众的有关发光材料尤其是ACQ和AIE分子的发光现象及其光学性能研究的普及实验仍有欠缺。本实验是以科普为目的,分别针对各个年龄段的受众设计了特色性普及实验;同时,本实验也是一个多场景适... 发光材料在生活中具有诸多的应用,但目前面向公众的有关发光材料尤其是ACQ和AIE分子的发光现象及其光学性能研究的普及实验仍有欠缺。本实验是以科普为目的,分别针对各个年龄段的受众设计了特色性普及实验;同时,本实验也是一个多场景适用性科普实验,分别于线上线下多渠道进行展示。实验步骤简单易行,色彩丰富,发光效果明显。既便于操作,又能极大地让公众了解生活中的发光分子,更重要的是本实验可以有效引导青少年发现、提出并解决科学问题,更有利于实现对青少年一定程度上的研究性思维与方法的培养,具有一定创新性。 展开更多
关键词 发光材料 acq效应 AIE效应 荧光 梯度科普
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An Experimental Artificial Neural Network Model:Investigating and Predicting Effects of Quenching Process on Residual Stresses of AISI 1035 Steel Alloy
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作者 Salman Khayoon Aldriasawi Nihayat Hussein Ameen +3 位作者 Kareem Idan Fadheel Ashham Muhammed Anead Hakeem Emad Mhabes Barhm Mohamad 《Journal of Harbin Institute of Technology(New Series)》 CAS 2024年第5期78-92,共15页
The present study establishes a new estimation model using an artificial neural network(ANN) to predict the mechanical properties of the AISI 1035 alloy.The experiments were designed based on the L16 orthogonal array ... The present study establishes a new estimation model using an artificial neural network(ANN) to predict the mechanical properties of the AISI 1035 alloy.The experiments were designed based on the L16 orthogonal array of the Taguchi method.A proposed numerical model for predicting the correlation of mechanical properties was supplemented with experimental data.The quenching process was conducted using a cooling medium called “nanofluids”.Nanoparticles were dissolved in a liquid phase at various concentrations(0.5%,1%,2.5%,and 5% vf) to prepare the nanofluids.Experimental investigations were done to assess the impact of temperature,base fluid,volume fraction,and soaking time on the mechanical properties.The outcomes showed that all conditions led to a noticeable improvement in the alloy's hardness which reached 100%,the grain size was refined about 80%,and unwanted residual stresses were removed from 50 to 150 MPa.Adding 5% of CuO nanoparticles to oil led to the best grain size refinement,while adding 2.5% of Al_(2)O_(3) nanoparticles to engine oil resulted in the greatest compressive residual stress.The experimental variables were used as the input data for the established numerical ANN model,and the mechanical properties were the output.Upwards of 99% of the training network's correlations seemed to be positive.The estimated result,nevertheless,matched the experimental dataset exactly.Thus,the ANN model is an effective tool for reflecting the effects of quenching conditions on the mechanical properties of AISI 1035. 展开更多
关键词 quenching nanofluids residual stresses steel alloy artificial neural network MANOVA
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Analysis of Quenching Resistor Effect to Improve Stability of TIA Circuit for APD-A Secondary Publication
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作者 Dong-Han Ki Yu-Rin Jin +1 位作者 Sung-Mi Kim Seong-Ik Cho 《Journal of Electronic Research and Application》 2024年第2期54-61,共8页
In this paper,since the Avalanche Photo Diode(APD)for Light-to-Voltage LTV conversion uses a high voltage in the operating range unlike other Photo Diodes(PD),the quenching resistor must be connected in series to prev... In this paper,since the Avalanche Photo Diode(APD)for Light-to-Voltage LTV conversion uses a high voltage in the operating range unlike other Photo Diodes(PD),the quenching resistor must be connected in series to prevent overcurrent when using the Transimpedance Amplifier(TIA).In such a case,quenching resistance may affect the transfer function of the TIA circuit,resulting in serious stability.Therefore,in this paper,by analyzing the effect of APD quenching resistance on the voltage and current loop transfer function of TIA,we proposed a loop analysis and a method for determining the quenching resistance value to improve stability.A TIA circuit with quenching resistance was designed by the proposed method and its operational stability was verified through simulation and chip fabrication. 展开更多
关键词 APD TIA quenching resistor STABILITY Transfer function
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Discussion on the Free Quenching Heat Treatment Process of Automotive Leaf Springs
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作者 Xianfeng Xu 《Frontiers of Metallurgical Industry》 2024年第1期9-11,共3页
Free quenching of automotive leaf springs is a new technology that has gradually started to be applied in the industry in China in recent years.Only a few manufacturers are applying it in the industry.Through more tha... Free quenching of automotive leaf springs is a new technology that has gradually started to be applied in the industry in China in recent years.Only a few manufacturers are applying it in the industry.Through more than half a year of on-site practice,the changes in the hot forming of spring plates before free quenching have been explored,and finally a heat treatment process that meets the production requirements of our company has been developed,achieving normal production. 展开更多
关键词 automotive leaf springs free quenching heat treatment TECHNOLOGY
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ACQ、AIE聚合物纳米粒子发光性能及其在喷墨印花中的应用
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作者 梁小琴 梁梨花 +1 位作者 朱尽顺 马明月 《现代纺织技术》 北大核心 2024年第4期84-92,共9页
为探究聚集诱导猝灭(ACQ)型和聚集诱导发光(AIE)型聚合物纳米粒子(PNPs)的发光性能,以及二者在喷墨印花中的应用效果,采用细乳液聚合技术原位包覆ACQ染料尼罗红(NR)和AIE染料四苯基乙烯(TPE),制得ACQ-PNPs和AIE-PNPs。采用重量法、动态... 为探究聚集诱导猝灭(ACQ)型和聚集诱导发光(AIE)型聚合物纳米粒子(PNPs)的发光性能,以及二者在喷墨印花中的应用效果,采用细乳液聚合技术原位包覆ACQ染料尼罗红(NR)和AIE染料四苯基乙烯(TPE),制得ACQ-PNPs和AIE-PNPs。采用重量法、动态光散射、扫描电镜、紫外-可见分光光度法和荧光光谱法等研究了染料用量对PMMA/NR NPs和PMMA/TPE NPs的最终转化率、颗粒特征和发光性能的影响;将poly(MMA-co-20%BA)/NR NPs和poly(MMA-co-20%BA)/TPE NPs乳液配制成墨水,用于棉织物的喷墨打印,探究两类墨水在棉织物上的喷墨印花效果。结果表明:当染料质量分数低于1.5%时,NR和TPE染料对PMMA/NR NPs和PMMA/TPE NPs体系聚合反应最终转化率和纳米粒子尺寸影响均较小,PMMA/NR NPs荧光强度随NR染料质量分数的增加呈现先增加后趋于稳定的趋势,而PMMA/TPE NPs荧光强度与TPE染料近乎呈线性正相关。此外,经poly(MMA-co-20%BA)/NR和poly(MMA-co-20%BA)/TPE NPs墨水喷墨打印后的棉织物,其图案分别呈现出明亮的红色和蓝色荧光。研究表明,在合适的染料浓度范围内,采用细乳液聚合法制得的ACQ和AIE聚合物纳米粒子乳液在喷墨印花领域中均有良好的应用前景。 展开更多
关键词 聚集诱导发光 聚集荧光猝灭 聚合物纳米粒子 细乳液聚合 发光性能 喷墨印花
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ACQ对尾巨桉表面颜色及耐腐性能的影响研究 被引量:1
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作者 岑晓倩 张亚庆 +1 位作者 王亮 卢翠香 《林产工业》 北大核心 2023年第7期7-11,33,共6页
研究了氨溶性季铵铜(ACQ)防腐剂对尾巨桉表面颜色及防腐性能的影响。结果表明:经ACQ浸渍后,尾巨桉木材的明度L^(*)、红绿轴色品指数a^(*)、黄蓝轴色品指数b^(*)和色度值C均显著降低。经浓度为2%、4%和8%的ACQ浸渍处理后,尾巨桉对绵腐卧... 研究了氨溶性季铵铜(ACQ)防腐剂对尾巨桉表面颜色及防腐性能的影响。结果表明:经ACQ浸渍后,尾巨桉木材的明度L^(*)、红绿轴色品指数a^(*)、黄蓝轴色品指数b^(*)和色度值C均显著降低。经浓度为2%、4%和8%的ACQ浸渍处理后,尾巨桉对绵腐卧孔菌(PV)均达到了Ⅰ级耐腐水平。经8%的ACQ浸渍处理后,尾巨桉对彩绒革盖菌(CV)也达到Ⅰ级耐腐水平。SEM测试进一步确认了较高浓度的ACQ更有利于提高尾巨桉的耐腐性。FT-IR结果表明,ACQ与尾巨桉木材中的木质素和半纤维素发生了结合。该研究对尾巨桉的耐腐性改良具有重要意义。 展开更多
关键词 acq防腐处理 尾巨桉 木材腐朽菌 色差指标 耐腐性能
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Influence of quenching medium on the dendrite morphology,hardness,and tribological behaviour of cast Cu-Ni-Sn spinodal alloy for defence application 被引量:1
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作者 Bipin Sankar Karthik V Shankar +4 位作者 Vamu Sunil Hemanth Kashyap S Nikhil Nair Adarsh A.Nair Abhinav P M 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2023年第12期83-100,共18页
Cu-Ni-Sn spinodal alloys(Spinodal bronze)are potential materials with robust applications in components associated with defence applications like bearings,propellers,bushes,and shafts of heavily loaded aircraft,off-ro... Cu-Ni-Sn spinodal alloys(Spinodal bronze)are potential materials with robust applications in components associated with defence applications like bearings,propellers,bushes,and shafts of heavily loaded aircraft,off-road vehicles,and warships.This paper presents a comparative study using water,Brine solution,and SAE 40 oil as the quenching media in regular bronze(Cu-6Sn)and spinodal bronze(Cu-9Ni-6Sn)alloys.Morphological analysis was conducted by optical microscopy,transmission electron microscopy(TEM),and X-ray diffraction technique(XRD)on bronze and spinodal bronze samples immersed in the three different quenching media to understand the grain size and hardness values better.Tribological analysis was performed to analyze the effect of quenching media on the wear aspects of bronze and spinodal bronze samples.The hardness value of the brine-aged spinodal bronze samples was as high as 320 Hv,and the grain size was very low in the range of 60μm.A quantitative comparison between brine-aged regular bronze and brine-aged spinodal bronze showed that the hardness(Hv)was almost 80%higher for brine-aged spinodal bronze.Further,the grain size was approximately 30%finer for spinodal bronze when compared with regular bronze.When the load was increased in spinodal bronze samples,there was an initial dip in wear rate followed by a marginal increase.There was a steady increase in friction coefficient with a rise in load for brine-aged regular bronze and spinodal bronze samples.These results indicate that brine solution is the most effective quenching medium for cast Cu-Ni-Sn spinodal alloys. 展开更多
关键词 quenching Water BRINE SAE 40 oil Grain size HARDNESS Wear rate Spinodal decomposition CuSn Spinodal alloy CuNiSn
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Influence of two distinct quenching end-temperatures on phase development and mechanical properties in QP980 steel
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作者 XIE Shuang ZHONG Yong WANG Li 《Baosteel Technical Research》 CAS 2023年第1期22-31,共10页
Bainite microstructures have become increasingly attractive for the development of advanced high-strength steel owing to their balanced strength-plasticity properties.In this study, the final microstructure and mechan... Bainite microstructures have become increasingly attractive for the development of advanced high-strength steel owing to their balanced strength-plasticity properties.In this study, the final microstructure and mechanical properties of a quenching and partitioning(QP) steel sample after two distinct QP processes were analyzed.The results reveal that martensite transformation after quenching resulted in a lathed morphology with higher yield strength and hole expansion ratio.In contrast, bainite transformation after quenching resulted in the formation of a blocky microstructure composed of bainitic ferrite retained austenite and nanoscale precipitates during the subsequent phase transformation at a higher temperature.This kind of final microstructure is beneficial to the elongation of QP steel but detrimental to the hole expansion ratio. 展开更多
关键词 QP steel BAINITE hole expansion quenching temperature
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Residual stress with asymmetric spray quenching for thick aluminum alloy plates
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作者 Ning Fan Zhihui Li +3 位作者 Yanan Li Xiwu Li Yongan Zhang Baiqing Xiong 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第11期2200-2211,共12页
Solution and quenching heat treatments are generally carried out in a roller hearth furnace for large-scale thick aluminum alloy plates.However,the asymmetric or uneven spray water flow rate is inevitable under indust... Solution and quenching heat treatments are generally carried out in a roller hearth furnace for large-scale thick aluminum alloy plates.However,the asymmetric or uneven spray water flow rate is inevitable under industrial production conditions,which leads to an asymmetric residual stress distribution.The spray quenching treatment was conducted on self-designed spray equipment,and the residual stress along the thickness direction was measured by a layer removal method based on deflections.Under the asymmetric spray quenching condition,the subsurface stress of the high-flow rate surface was lower than that of the low-flow rate surface,and the difference between the two subsurface stresses increased with the increase in the difference in water flow rates.The subsurface stress underneath the surface with a water flow rate of 0.60 m^(3)/h was 15.38 MPa less than that of 0.15 m^(3)/h.The simulated residual stress by finite element(FE)method of the high heat transfer coefficient(HTC)surface was less than that of the low HTC surface,which is consistent with the experimental results.The FE model can be used to analyze the strain and stress evolution and predict the quenched stress magnitude and distribution. 展开更多
关键词 aluminum alloy spray quenching residual stress layer removal method finite element method
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Effect of quenching and tempering processes on properties and microstructure of G115 steel
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作者 WANG Tingting XU Songqian 《Baosteel Technical Research》 CAS 2023年第4期17-21,共5页
The novel martensitic heat-resistant steel G115 was designed for thick-section boiler components of ultra-supercritical(USC) power plants at 630-650 ℃.The impact of the quenching and tempering processes on the proper... The novel martensitic heat-resistant steel G115 was designed for thick-section boiler components of ultra-supercritical(USC) power plants at 630-650 ℃.The impact of the quenching and tempering processes on the properties and microstructure of G115 steel was explored.The samples that were quenched and tempered twice had a higher tensile strength at room temperature and 650 ℃,and the impact energy was significantly improved.The strength and impact energy increased in proportion to the increase in the first quenching temperature.The microstructure differences between the single and double quenched and tempered samples were examined using metallographic microscopy and scanning electron microscopy.The grain size of the double quenched and tempered samples was finer than that of the single quenched and tempered samples, and the tempered martensite lath is more visible, as are the carbides and other precipitates, which are finer and more uniformly distributed.As the first quenching temperature increased, the grains became coarser but more uniform. 展开更多
关键词 G115 quenching and tempering tensile properties MICROSTRUCTURE
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Development and Application of Multi-phase Nitrides Bonded Silicon Carbide Lintel Blocks for Dry Quenching Furnaces
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作者 CAO Huiyan FENG Yanbin +4 位作者 ZHANG Xinhua HUANG Zhigang LI Jie WANG Xinhui WU Jiguang 《China's Refractories》 CAS 2023年第2期7-11,共5页
Multi-phase nitrides bonded silicon carbide lintel blocks were prepared using industrial SiC(SiC≥98 mass%,3-0.5,≤0.5 and≤0.044 mm),Si powder(Si≥98 mass%,≤0.044 mm),and SiO2 micropowder(SiO2≥96 mass%,d50=0.15 pm)... Multi-phase nitrides bonded silicon carbide lintel blocks were prepared using industrial SiC(SiC≥98 mass%,3-0.5,≤0.5 and≤0.044 mm),Si powder(Si≥98 mass%,≤0.044 mm),and SiO2 micropowder(SiO2≥96 mass%,d50=0.15 pm)as raw materials,and calcium lignosulfonate as the additive,batching,mixing,and molding on a vibration pressure molding machine,drying and then firing at 1420℃for 10 h in high-purity N2.The apparent porosity,the bulk density,the cold modulus of rupture,the hot modulus of rupture,and the linear expansion coefficient of the samples were tested.The phase composition and the microstructure of the samples at different nitriding depths(50,100,and 150 mm)were analyzed by XRD and SEM.The field application effects of the blocks were studied.The results show that:(1)the multi-phase nitrides bonded silicon carbide refractories can dynamically adjust their own phase composition and minimize structural and thermal stresses,improving the service life of key parts of dry quenching furnaces;(2)calcium lignosulfonate can improve the nitriding micro-environment of multi-phase nitrides bonded silicon carbide lintel blocks,successfully increasing the effective nitriding thickness of the blocks to 300 mm;(3)Sinosteel LI RR provides a unique concept in the design of materials and block types as well as the stable and scientific overall structure,promoting the industrialization process of dry quenching furnaces with long service life in China. 展开更多
关键词 inclined channel area dry quenching furnaces silicon carbide multi-phase nitrides lintel blocks
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ACQ防腐木检测试验及分析研究
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作者 郭艳梅 《呼伦贝尔学院学报》 2023年第3期98-103,共6页
通过对国内华北、华东、东北、华南等不同地区购买的同一级别的ACQ防腐木材以及实验室自制的ACQ-3防腐木材进行透入度、载药量、失重率的检测试验,测试其耐腐蚀性能,分析得出载药量高透入度低比载药量低透入度高的耐腐效果好,二者同时... 通过对国内华北、华东、东北、华南等不同地区购买的同一级别的ACQ防腐木材以及实验室自制的ACQ-3防腐木材进行透入度、载药量、失重率的检测试验,测试其耐腐蚀性能,分析得出载药量高透入度低比载药量低透入度高的耐腐效果好,二者同时具备效果最佳。对比《防腐木材使用分类和要求》(GB/T27651-2011),结合我国目前防腐木使用的影响因素,主要包括地域、使用环境、使用领域、使用年限等,提出对现有ACQ防腐木材质量评价体系的改进意见。 展开更多
关键词 acq防腐木 质量检测 性能检测
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环氧虫啶与人血清白蛋白的相互作用 被引量:2
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作者 刘晓娟 邓培渊 +1 位作者 范春丽 田云芳 《农药学学报》 CAS CSCD 北大核心 2024年第1期160-167,共8页
新烟碱类杀虫剂环氧虫啶对非靶标生物具有潜在危害,但对其毒理机理、其在人体内的运输机制等方面缺乏研究。本研究运用荧光光谱法、分子对接、分子动力学、结合自由能计算和丙氨酸扫描等方法,研究了环氧虫啶与人血清白蛋白(HSA)的结合... 新烟碱类杀虫剂环氧虫啶对非靶标生物具有潜在危害,但对其毒理机理、其在人体内的运输机制等方面缺乏研究。本研究运用荧光光谱法、分子对接、分子动力学、结合自由能计算和丙氨酸扫描等方法,研究了环氧虫啶与人血清白蛋白(HSA)的结合模式。结果表明:1)环氧虫啶能有效猝灭HSA荧光,不同温度下环氧虫啶与HSA的结合常数在0.76×10^(5)~1.57×10^(5)L/mol之间,具有较强的结合能力;2)环氧虫啶结合在HSA的IIA疏水腔内,有1个结合位点;3)结合自由能分析和热力学参数计算显示,环氧虫啶和HSA结合的主要作用力是范德华力和氢键作用;4)分子动力学模拟结果显示,二者结合自由能为-25.90 kJ/mol,形成了相对稳定的复合物;5)丙氨酸突变扫描结果显示,氨基酸残基Gln459是环氧虫啶与HSA结合的关键氨基酸。该研究结果可为阐明环氧虫啶在人体内的毒性机理提供理论依据。 展开更多
关键词 环氧虫啶 人血清白蛋白 相互作用 荧光猝灭 分子对接 分子动力学
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Visualization of Vapor Film Collapse Behavior with Complexity on Quenching Process by Cellular Automaton
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作者 Tsuyoshi Sugimoto 《Journal of Mechanics Engineering and Automation》 2023年第1期7-15,共9页
The vapor film collapse that occurs in the quenching process is complicated and affects the heat treatment quality and its distortion.In order to incorporate it into the MBD(Model Based Development)technology required... The vapor film collapse that occurs in the quenching process is complicated and affects the heat treatment quality and its distortion.In order to incorporate it into the MBD(Model Based Development)technology required these days,it is necessary to predict the quality of heat treatment by CAE(Computer Added Engineering),shorten the product development period.The calculation of the vapor film collapses in a simple and practical time in order to improve the product performance.However,in the past,in order to formulate the vapor film collapse on a simulation,it was necessary to perform a very large amount of computational calculation CFD(computational fluid dynamics),which was a problem in terms of computer resources and the model of vapor film collapse.In addition,this phenomenon has a complexity behavior of the phenomenon in iterative processing,which also complicates the calculation.In this study,the vapor film collapse phenomenon is easily visualized using self-organized cellular automaton simulation which includes the phenomena of“vapor film thickness and its fluctuation”,“flow disturbance”,“surface step of workpiece”,and“decrease of cooling due to r shape of surface”.The average cooling state and repeated fluctuations of the cooling state were reproduced by this method. 展开更多
关键词 quenching cellular automaton vapor film collapse complexity.
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不同工艺渗碳淬火和深冷处理后20CrNi2Mo轴承钢的组织与性能 被引量:1
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作者 姚国林 王合闯 《机械工程材料》 CAS CSCD 北大核心 2024年第1期79-84,共6页
对正火态20CrNi2Mo轴承钢分别进行渗碳油淬+回火、二次渗碳油淬+回火、渗碳气淬+渗碳油淬+回火等3种渗碳淬火+回火处理以及在上述工艺的回火前增加深冷处理的渗碳淬火+深冷+回火处理,研究了不同工艺处理后轴承钢的显微组织、力学性能和... 对正火态20CrNi2Mo轴承钢分别进行渗碳油淬+回火、二次渗碳油淬+回火、渗碳气淬+渗碳油淬+回火等3种渗碳淬火+回火处理以及在上述工艺的回火前增加深冷处理的渗碳淬火+深冷+回火处理,研究了不同工艺处理后轴承钢的显微组织、力学性能和耐磨性能。结果表明:渗碳淬火+回火后轴承钢的组织均为针状马氏体+残余奥氏体+碳化物,渗碳气淬+渗碳油淬+回火后的马氏体更细小,残余奥氏体更少,此工艺下轴承钢的硬度、抗拉强度和断后伸长率均高于其他2种渗碳淬火+回火工艺,磨痕宽度和深度较小;与渗碳淬火+回火相比,渗碳淬火+深冷+回火处理后轴承钢中奥氏体含量减少,硬度提高,磨痕宽度和深度减小,并且在200 N载荷下的磨损质量损失明显减少;较优的工艺是渗碳气淬+渗碳油淬+深冷+回火。 展开更多
关键词 轴承钢 渗碳淬火 深冷处理 组织 性能
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基于AIE效应的内源性硫化氢荧光探针的研究进展
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作者 刘冰弥 宫达诚 +1 位作者 田璐 生慧 《辽宁大学学报(自然科学版)》 CAS 2024年第2期130-140,共11页
合理设计监测内源性硫化氢的荧光探针分子有助于充分了解其生理和病理功能.目前,在研的检测硫化氢的小分子荧光探针多存在聚集诱导猝灭效应,因此克服此缺陷的聚集诱导发光效应荧光探针的研究受到越来越多的关注.本文结合研究实践简要综... 合理设计监测内源性硫化氢的荧光探针分子有助于充分了解其生理和病理功能.目前,在研的检测硫化氢的小分子荧光探针多存在聚集诱导猝灭效应,因此克服此缺陷的聚集诱导发光效应荧光探针的研究受到越来越多的关注.本文结合研究实践简要综述了近几年具有聚集诱导发光效应的化学反应型硫化氢活体成像荧光探针的研究进展及设计思想并进行展望,以期对该领域研究提供一些借鉴和思考. 展开更多
关键词 内源性硫化氢 聚集诱导发光效应 聚集诱导猝灭效应 荧光探针 活体成像
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激光硬化与渗氮复合处理H13钢组织与性能
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作者 曹驰 骆卫东 +2 位作者 陈志林 罗丽萍 陈贤武 《兰州理工大学学报》 CAS 北大核心 2024年第1期10-18,共9页
通过激光淬火/离子渗氮复合方法对H13钢进行表面改性处理,从而提高其表面的性能.利用X射线衍射技术、光学显微观察、扫描电子显微观察、能谱分析技术、显微硬度和纳米测试系统以及高频往复磨损试验,分别研究了离子渗氮、激光淬火、以及... 通过激光淬火/离子渗氮复合方法对H13钢进行表面改性处理,从而提高其表面的性能.利用X射线衍射技术、光学显微观察、扫描电子显微观察、能谱分析技术、显微硬度和纳米测试系统以及高频往复磨损试验,分别研究了离子渗氮、激光淬火、以及激光淬火与离子渗氮复合处理对H13钢改性层组织结构、力学性能、摩擦磨损性能的影响过程和影响机理.结果表明:复合处理工艺可以显著改善改性层的综合性能.和单一渗氮处理相比,复合处理改性层硬度和有效硬化层深度分别从1180 HV和80μm提高至1360 HV和550μm,摩擦系数和磨损率分别从0.68和5.78×10^(-8)mm^(3)·N^(-1)·m^(-1)降低至0.59和1.35×10^(-8)mm^(3)·N^(-1)·m^(-1).试样的硬度和耐磨性显著增加,平均摩擦系数明显降低. 展开更多
关键词 H13钢 激光淬火 离子渗氮 复合处理
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离子氮碳氧三元共渗对45钢耐蚀耐磨性能的影响与机理研究
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作者 胡静 梁硕 +4 位作者 卢阳阳 王海强 陈立立 安旭龙 魏伟 《常州大学学报(自然科学版)》 CAS 2024年第3期1-9,共9页
研究选择45钢为原材料,分别采用绿色环保离子氮碳氧三元共渗技术(Plasma oxynitrocarburising,PNCO)和传统淬火-抛光-淬火技术(Quench-polish-quench,QPQ)进行表面改性,并利用SEM,XRD,摩擦磨损试验机,浸泡腐蚀实验对比分析2种方法的改... 研究选择45钢为原材料,分别采用绿色环保离子氮碳氧三元共渗技术(Plasma oxynitrocarburising,PNCO)和传统淬火-抛光-淬火技术(Quench-polish-quench,QPQ)进行表面改性,并利用SEM,XRD,摩擦磨损试验机,浸泡腐蚀实验对比分析2种方法的改性效果,包括截面显微组织、表面形貌、物相、耐磨性和耐蚀性。结果表明,PNCO处理后,获得了与QPQ处理相同的多层次渗层结构,由表层1~2μm氧化膜及次表层化合物层和有效硬化层构成,且PNCO处理后表面氧化膜成纳米结构,化合物层比QPQ更加致密。同时,PNCO处理后,磨损率和腐蚀失重率分别为1.39 mg/(N·m)和0.39%,耐磨耐蚀性均略优于QPQ,为研究绿色高效高性能表面改性技术提供了可行的研究方向。 展开更多
关键词 离子氮碳氧三元共渗技术 QPQ技术 氧化膜 耐磨性 耐蚀性
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基于磁性纳米材料Fe_(3)O_(4)@PPy和聚集诱导发光材料(TTAPE)检测肝素药品中的多硫酸软骨素残留
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作者 王玥婷 焦哲 曾燕艳 《现代化工》 CAS CSCD 北大核心 2024年第2期246-251,共6页
合成了一种聚吡咯修饰的磁性纳米颗粒(Fe_(3)O_(4)@PPy),通过结合AIE荧光探针四苯基乙烯衍生物(TTAPE)建立了一种检测肝素药品中多硫酸软骨素的检测方法。肝素和多硫酸软骨素与TTAPE结合导致运动受限,进而释放荧光,而Fe_(3)O_(4)@PPy加... 合成了一种聚吡咯修饰的磁性纳米颗粒(Fe_(3)O_(4)@PPy),通过结合AIE荧光探针四苯基乙烯衍生物(TTAPE)建立了一种检测肝素药品中多硫酸软骨素的检测方法。肝素和多硫酸软骨素与TTAPE结合导致运动受限,进而释放荧光,而Fe_(3)O_(4)@PPy加入后可以猝灭其荧光。研究了肝素和多硫酸软骨素与TTAPE结合后荧光增强规律和Fe_(3)O_(4)@PPy对它们的荧光猝灭规律,建立了不同的猝灭曲线,进而同时检测肝素和多硫酸软骨素。实验确定了肝素和多硫酸软骨素的最佳荧光检测波长为482 nm,Fe_(3)O_(4)@PPy的使用量为5 mg,检测浓度的线性范围为0~3.5 mg/L,肝素浓度的相对偏差在0.5%以下。肝素实际样品中多硫酸软骨素的回收率为90%和96.67%,相对标准偏差为4.4%和4.1%。 展开更多
关键词 肝素 多硫酸软骨素 聚集诱导发光 磁性纳米材料 淬灭 荧光探针
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掺氮碳量子点用于柳氮磺吡啶的快速检测
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作者 赵艳 孙雪花 《分析测试学报》 CAS CSCD 北大核心 2024年第7期1052-1057,共6页
以微波法一步合成制备出荧光性能强、荧光量子产率为89.38%的掺氮碳量子点(N-CDs),并通过荧光猝灭法建立了快速准确测定柳氮磺吡啶(SSZ)的新方法。通过透射电子显微镜、傅里叶红外光谱对碳量子点进行表征,结果显示N-CDs的平均粒径为2.91... 以微波法一步合成制备出荧光性能强、荧光量子产率为89.38%的掺氮碳量子点(N-CDs),并通过荧光猝灭法建立了快速准确测定柳氮磺吡啶(SSZ)的新方法。通过透射电子显微镜、傅里叶红外光谱对碳量子点进行表征,结果显示N-CDs的平均粒径为2.91 nm,主要由C、O、N元素组成,大量羰基、羟基和羧基存在于N-CDs表面。在最佳条件下,柳氮磺吡啶浓度在0.1~2μmol/L和3~200μmol/L范围内线性良好,检出限为0.2μmol/L。将所建方法用于柳氮磺吡啶肠溶片中柳氮磺吡啶含量的测定,回收率为97.3%~102%。 展开更多
关键词 微波法 掺氮碳量子点 荧光猝灭 柳氮磺吡啶
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