CMOS image sensors produced by the existing CMOS manufacturing process usually have difficulty achieving complete charge transfer owing to the introduction of potential barriers or Si/SiO_(2)interface state traps in t...CMOS image sensors produced by the existing CMOS manufacturing process usually have difficulty achieving complete charge transfer owing to the introduction of potential barriers or Si/SiO_(2)interface state traps in the charge transfer path,which reduces the charge transfer efficiency and image quality.Until now,scholars have only considered mechanisms that limit charge transfer from the perspectives of potential barriers and spill back effect under high illumination condition.However,the existing models have thus far ignored the charge transfer limitation due to Si/SiO_(2)interface state traps in the transfer gate channel,particularly under low illumination.Therefore,this paper proposes,for the first time,an analytical model for quantifying the incomplete charge transfer caused by Si/SiO_(2)interface state traps in the transfer gate channel under low illumination.This model can predict the variation rules of the number of untransferred charges and charge transfer efficiency when the trap energy level follows Gaussian distribution,exponential distribution and measured distribution.The model was verified with technology computer-aided design simulations,and the results showed that the simulation results exhibit the consistency with the proposed model.展开更多
The color-tunable white organic light-emitting diode (CT-WOLED) with wide correlation color temperature (CCT) has many advantages in optimizing the artificial light source to adapt to the human physiological cycle. Th...The color-tunable white organic light-emitting diode (CT-WOLED) with wide correlation color temperature (CCT) has many advantages in optimizing the artificial light source to adapt to the human physiological cycle. The research on the change trend of CCT and the law of extending the change range of CCT will help to further improve the performance of this kind of device. The present work fabricated a series of CT-WOLED devices with a simple structure, which are all composed of two ultra-thin phosphor layers (PO-01 and Flrpic) and a spacer interlayer. The yellow interface exciplex (TCTA/PO-T2T) formed between the spacer layer (PO-T2T) and transmission material (TCTA) in EML will decrease the CCT value at low voltage. The relationship between the energy transfer in EML and CCT change trend is investigated by adjusting the interface exciplexes and the thickness of the interlayer or the phosphor layer in devices A, B and C, respectively. The results demonstrate that a simple OLED device with an interlayer inserted between two ultra-thin phosphor layers can achieve a wider CCT span from 3359 K to 6451 K at voltage increases from 2.75 V to 8.25 V. .展开更多
The regulation of interface electron-transfer and catalytic kinetics is very important to design the efficient electrocatalyst for alkaline hydrogen oxidation reaction(HOR).Here,we show the Pt-Ni alloy nanoparticles(P...The regulation of interface electron-transfer and catalytic kinetics is very important to design the efficient electrocatalyst for alkaline hydrogen oxidation reaction(HOR).Here,we show the Pt-Ni alloy nanoparticles(PtNi_(2))have an enhanced HOR activity compared with single component Pt catalyst.While,the interface electron-transfer kinetics of PtNi_(2)catalyst exhibits a very wide electron-transfer speed distribution.When combined with carbon dots(CDs),the interface charge transfer of PtNi_(2)-CDs composite is optimized,and then the PtNi_(2)-5 mg CDs exhibits about 2.67 times and 4.04 times higher mass and specific activity in 0.1 M KOH than that of 20%commercial Pt/C.In this system,CDs also contribute to trapping H^(+)and H_(2)O generated during HOR,tuning hydrogen binding energy(HBE),and regulating interface electron transfer.This work provides a deep understanding of the interface catalytic kinetics of Pt-based alloys towards highly efficient HOR catalysts design.展开更多
As well known in the petroleum industry and academia,Ni/ZnO catalysts have excellent desulfurization performance.However,the sulfur transfer mechanism of reactive adsorption desulfurization(RADS)that occurs on Ni/ZnO ...As well known in the petroleum industry and academia,Ni/ZnO catalysts have excellent desulfurization performance.However,the sulfur transfer mechanism of reactive adsorption desulfurization(RADS)that occurs on Ni/ZnO catalysts remains controversial.Herein,a periodic Ni nanorod supported on ZnO slab was built to represent the Ni/ZnO system,and density functional theory calculations were performed to study the sulfur transfer process and the role of H_(2)within the process.The results elucidate that the direct solid-state diffusion of S from Ni to interfacial oxygen vacancies(Ov)is more favorable than the hydrogenation of S to SH/H_(2)S on Ni and the subsequent H_(2)S desorption,and accordingly,H_(2)O is produced on Ni rather than on ZnO.Ab initio thermodynamics analysis shows that the hydrogen atmosphere applied in preparing Ni/ZnO catalysts greatly promotes the O_(v)formation on ZnO surface,which accounts for the presence of interfacial O_(v)in freshly prepared catalysts.Under RADS condition,hydrogenation of interfacial O atoms to form O-H groups facilitates the reverse spillover of these lattice O atoms from ZnO to Ni,accompanied with the interfacial O_(v)generation.In contrast to the classic S transfer mechanism via H_(2)S,the present work clearly demonstrates that the interfacial S transfer is a feasible reaction pathway in the RADS mechanism.More importantly,the existence of interfacial O_(v)is an essential prerequisite for this interfacial S diffusion,and H_(2)plays a key role in facilitating the O_(v)formation.展开更多
On the basis of experimental studies, a program dealing with the boundary condition in the quenching process has been developed. In this program the method of Beck nonlinear estimation (inverse heat conduction method)...On the basis of experimental studies, a program dealing with the boundary condition in the quenching process has been developed. In this program the method of Beck nonlinear estimation (inverse heat conduction method) was adopted so that the problem of the heat transfer coefficient varying significantly and complicatedly in the quenching process, has been effectively solved. Calculation result shows that the heat transfer coefficient between quenching workpiece and media boundary has a peak value, and this value and the temperature interval in which the peak value occurs vary with the cross section dimensions of workpiece, the types of the quenching media, the temperature and the surface position.展开更多
The effect of an adsorbed anionic surfactant sodium dodecyl benzene sulfonate (SDBS) on electron transfer (ET) reaction between ferricyanide aqueous solution and decamethylferrocene (DMFc) located on the adjacen...The effect of an adsorbed anionic surfactant sodium dodecyl benzene sulfonate (SDBS) on electron transfer (ET) reaction between ferricyanide aqueous solution and decamethylferrocene (DMFc) located on the adjacent organic phase was investigated for the first time by thin layer method. The adsorption of SDBS at the interface resulted in a decay in the cathodic plateau current of bimolecular reaction with increasing concentrations of SDBS in aqueous phase. However, the rate constant of electron transfer (ket) increased monotonically as the SDBS concentrations increased from 0 to 200 p, moFL. The experimental results showed that SDBS formed patches on the interface and influenced the structure of electrical double layer. 2009 Xiao Quan Lu. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.展开更多
Experiments have been done on mass transfer to a liquid-liquid interface on which inert gas bubbles are sparged.To simulate the pyrometallurgy system of melten slag-metal(or matte),aqueous solution-mercury(or zinc ama...Experiments have been done on mass transfer to a liquid-liquid interface on which inert gas bubbles are sparged.To simulate the pyrometallurgy system of melten slag-metal(or matte),aqueous solution-mercury(or zinc amalgam) system was used.The mass transfer coefficients of indicator ions as a function of bubble parameters have been determined.The experimental results show satisfactory agreement with the mass transfer model proposed Previously.展开更多
A transient three-dimensional coupling model based on the compressible volume of fluid (VOF) method was developed to simulate the transport of volatile pollutants at the air-water interface. VOF is a numerical techn...A transient three-dimensional coupling model based on the compressible volume of fluid (VOF) method was developed to simulate the transport of volatile pollutants at the air-water interface. VOF is a numerical technique for locating and tracking the free surface of water flow. The relationships between Henry's constant, thermodynamics parameters, and the enlarged topological index were proposed for nonstandard conditions. A series of experiments and numerical simulations were performed to study the transport of benzene and carbinol. The simulation results agreed with the experimental results. Temperature had no effect on mass transfer of pollutants with low transfer free energy and high Henry's constant. The temporal and spatial distribution of pollutants with high transfer free energy and low Henry's constant was affected by temperature. The total enthalpy and total transfer free energy increased significantly with temperature, with significant fluctuations at low temperatures. The total enthalpy and total transfer free energy increased steadily without fluctuation at high temperatures.展开更多
The ion transfer reaction of 2-benzoylpyridine-thiosemicarbazone (HL), which has antimicrobial and antifungal properties and anticancer activity, has been studied to determine its lipophilicity by cyclic voltammetry a...The ion transfer reaction of 2-benzoylpyridine-thiosemicarbazone (HL), which has antimicrobial and antifungal properties and anticancer activity, has been studied to determine its lipophilicity by cyclic voltammetry at the water/1,2-dichloroethane (1,2-DCE) interface. The physicochemical parameters such as standard partition coefficient (lgPI)andthestandardGibbsenergyoftransfer("G0tr,,wI "o)oftheprotonatedformoftheligandwere measured asa function of pH in aqueous phase. The protonated form of the ligand exhibited reversible or quasi-reversible voltammograms at the1,2-DCEintherangeofpH1-5.Theprotonationconstantsoftheligand,pKa1andpKa2,weredeterminedspectrophotometrically and were found to be 12.14 and 3.24, respectively. The standard Gibbs energy of transfer ("G0tr,,wN" o) and the partition coefficient of neutral species (lgPN) were also determined by the shake-flask method. The standard Gibbs energy of transfer of this compound across the water/1,2-DCE interface was evaluated as the quantitative measure of its lipophilicity. The difference between lgPI and lgPN was related to the degree of charge delocalization and was used to evaluate qualitatively the lipophilicity of the ligand.展开更多
A similarity analysis for Marangoni convection induced flow over a vapor-liquid interface due to an imposed temperature gradient was carried out. The analysis assumes that the surface tension varies linearly with temp...A similarity analysis for Marangoni convection induced flow over a vapor-liquid interface due to an imposed temperature gradient was carried out. The analysis assumes that the surface tension varies linearly with temperature but the temperature variation is a power law function of the location. The similarity solutions are presented numerically and the associated transfer characteristics are discussed.展开更多
In this paper, the effects of interface properties on the stress transfer between matrix and fiber in short fiber reinforced metal matrix composites (SFRMMCs) is studied with the method of the elasto plastic finite ...In this paper, the effects of interface properties on the stress transfer between matrix and fiber in short fiber reinforced metal matrix composites (SFRMMCs) is studied with the method of the elasto plastic finite element. The interface properties include Young’s modulus, thickness and elasto plastic performances. In the calculation an interfacial layer with given thickness is introduced into the single fiber model. It is shown that, for a soft interface, the variation in interfacial properties influences the stress transfer greatly.展开更多
The non-stationary of the motor imagery electroencephalography(MI-EEG)signal is one of the main limitations for the development of motor imagery brain-computer interfaces(MI-BCI).The nonstationary of the MI-EEG signal...The non-stationary of the motor imagery electroencephalography(MI-EEG)signal is one of the main limitations for the development of motor imagery brain-computer interfaces(MI-BCI).The nonstationary of the MI-EEG signal and the changes of the experimental environment make the feature distribution of the testing set and training set deviates,which reduces the classification accuracy of MI-BCI.In this paper,we propose a Kullback–Leibler divergence(KL)-based transfer learning algorithm to solve the problem of feature transfer,the proposed algorithm uses KL to measure the similarity between the training set and the testing set,adds support vector machine(SVM)classification probability to classify and weight the covariance,and discards the poorly performing samples.The results show that the proposed algorithm can significantly improve the classification accuracy of the testing set compared with the traditional algorithms,especially for subjects with medium classification accuracy.Moreover,the algorithm based on transfer learning has the potential to improve the consistency of feature distribution that the traditional algorithms do not have,which is significant for the application of MI-BCI.展开更多
Transferring the contralateral C7 nerve root to the median or radial nerve has become an important means of repairing brachial plexus nerve injury.However,outcomes have been disappointing.Electroencephalography(EEG)-b...Transferring the contralateral C7 nerve root to the median or radial nerve has become an important means of repairing brachial plexus nerve injury.However,outcomes have been disappointing.Electroencephalography(EEG)-based human-machine interfaces have achieved promising results in promoting neurological recovery by controlling a distal exoskeleton to perform functional limb exercises early after nerve injury,which maintains target muscle activity and promotes the neurological rehabilitation effect.This review summarizes the progress of research in EEG-based human-machine interface combined with contralateral C7 transfer repair of brachial plexus nerve injury.Nerve transfer may result in loss of nerve function in the donor area,so only nerves with minimal impact on the donor area,such as the C7 nerve,should be selected as the donor.Single tendon transfer does not fully restore optimal joint function,so multiple functions often need to be reestablished simultaneously.Compared with traditional manual rehabilitation,EEG-based human-machine interfaces have the potential to maximize patient initiative and promote nerve regeneration and cortical remodeling,which facilitates neurological recovery.In the early stages of brachial plexus injury treatment,the use of an EEG-based human-machine interface combined with contralateral C7 transfer can facilitate postoperative neurological recovery by making full use of the brain’s computational capabilities and actively controlling functional exercise with the aid of external machinery.It can also prevent disuse atrophy of muscles and target organs and maintain neuromuscular junction effectiveness.Promoting cortical remodeling is also particularly important for neurological recovery after contralateral C7 transfer.Future studies are needed to investigate the mechanism by which early movement delays neuromuscular junction damage and promotes cortical remodeling.Understanding this mechanism should help guide the development of neurological rehabilitation strategies for patients with brachial plexus injury.展开更多
One-dimensional nanowire is an important candidate for lead-halide perovskite-based photonic detectors and solar cells. Its surface population, diameter, and growth direction, etc., are critical for device performance...One-dimensional nanowire is an important candidate for lead-halide perovskite-based photonic detectors and solar cells. Its surface population, diameter, and growth direction, etc., are critical for device performance. In this research,we carried out a detailed study on electron transfer process at the interface of nanowire CH_(3) NH_(3) PbI_(3)(N-MAPbI_(3))/Phenyl C61 butyric acid methyl-ester synonym(PCBM), as well as the interface of compact CH_(3) NH_(3) PbI_(3)(C-MAPbI_(3))/PCBM by transient absorption spectroscopy. By comparing the carrier recombination dynamics of N-MAPbI_(3), N-MAPbI_(3)/PCBM,C-MAPbI_(3), and C-MAPbI_(3)/PCBM from picosecond(ps) to hundred nanosecond(ns) time scale, it is demonstrated that electron transfer at N-MAPbI_(3)/PCBM interface is less efficient than that at C-MAPbI_(3)/PCBM interface. In addition, electron transfer efficiency at C-MAPbI_(3)/PCBM interface was found to be excitation density-dependent, and it reduces with photo-generation carrier concentration increasing in a range from 1.0 × 1018 cm^(-3)–4.0 × 1018 cm^(-3). Hot electron transfer,which leads to acceleration of electron transfer between the interfaces, was also visualized as carrier concentration increases from 1.0 × 10^(18) cm^(-3)–2.2 × 10^(18) cm^(-3).展开更多
We develop a design of a hybrid quantum interface for quantum information transfer (QIT), adopting a nanome- chanical resonator as the intermedium, which is magnetically coupled with individual nitrogen-vacancy cent...We develop a design of a hybrid quantum interface for quantum information transfer (QIT), adopting a nanome- chanical resonator as the intermedium, which is magnetically coupled with individual nitrogen-vacancy centers as the solid qubits, while eapacitively coupled with a coplanar waveguide resonator as the quantum data bus. We describe the Hamiltonian of the model, and analytically demonstrate the QIT for both the resonant interaction and large detuning cases. The hybrid quantum interface allows for QIT between arbitrarily selected individual nitrogen-vacancy centers, and has advantages of the sealability and controllability. Our methods open an alter- native perspective for implementing QIT, which is important during quantum storing or processing procedures in quantum computing.展开更多
We propose a scheme to implement quantum state transfer between two distant quantum nodes via a hybrid solid–optomechanical interface. The quantum state is encoded on the native superconducting qubit, and transferred...We propose a scheme to implement quantum state transfer between two distant quantum nodes via a hybrid solid–optomechanical interface. The quantum state is encoded on the native superconducting qubit, and transferred to the microwave photon, then the optical photon successively, which afterwards is transmitted to the remote node by cavity leaking,and finally the quantum state is transferred to the remote superconducting qubit. The high efficiency of the state transfer is achieved by controllable Gaussian pulses sequence and numerically demonstrated with theoretically feasible parameters.Our scheme has the potential to implement unified quantum computing–communication–computing, and high fidelity of the microwave–optics–microwave transfer process of the quantum state.展开更多
The boundary slip condition is pivotal for nanoscale fluid motion.Recent research has primarily focused on simulating the interaction mechanism between the electronic structure of two-dimensional materials and slip of...The boundary slip condition is pivotal for nanoscale fluid motion.Recent research has primarily focused on simulating the interaction mechanism between the electronic structure of two-dimensional materials and slip of water at the nanoscale,raising the possibility for ultralow friction flow of water at the nanoscale.However,experimentally elucidating electronic interactions at the dynamic solid–liquid interface to control boundary slip poses a significant challenge.In this study,the crucial role of electron structures at the dynamic solid–liquid interface in regulating slip length was revealed.Notably,the slip length of water on the molybdenum disulfide/graphene(MoS_(2)/G)heterostructure(100.9±3.6 nm)significantly exceeded that of either graphene(27.7±2.2 nm)or MoS_(2)(5.7±3.1 nm)alone.It was also analyzed how electron transfer significantly affected interface interactions.Excess electrons played a crucial role in determining the type and proportion of excitons at both MoS_(2)–water and MoS_(2)/G–water interfaces.Additionally,by applying voltage,distinct photoluminescence(PL)responses at static and dynamic interfaces were discovered,achieving a 5-fold modulation in PL intensity and a 2-fold modulation in the trion to exciton intensity ratio.More electrons transfer from the top graphene to the bottom MoS_(2)at the MoS_(2)/G–water interface,reducing surface charge density.Thus,the reduction of electrostatic interactions between the solid and water leads to an increased slip length of water on the MoS_(2)/G heterostructure.The process aids in comprehending the origin of frictional resistance at the subatomic scale.This work establishes a foundation for actively controlling and designing of fluid transport at the nanoscale.展开更多
Transfer learning,as a new machine learning methodology,may solve problems in related but different domains by using existing knowledge,and it is often applied to transfer training data from another domain for model t...Transfer learning,as a new machine learning methodology,may solve problems in related but different domains by using existing knowledge,and it is often applied to transfer training data from another domain for model training in the case of insuficient training data.In recent years,an increasing number of researchers who engage in brain-computer interface(BCI),have focused on using transfer learning to make most of the available electroencephalogram data from different subjects,effectively reducing the cost of expensive data acquisition and labeling as well as greatly improving the learning performance of the model.This paper surveys the development of transfer learning and reviews the transfer learning approaches in BCI.In addition,according to the"what to transfer"question in transfer learning,this review is organized into three contexts:instance-based transfer learning,parameter-based transfer learning,and feature-based transfer learning.Furthermore,the current transfer learning applications in BCI research are summarized in terms of the transfer learning methods,datasets,evaluation performance,etc.At the end of the paper,the questions to be solved in future research are put forward,laying the foundation for the popularization and in-depth research of transfer learning in BCI.展开更多
Heat transfer at the metal-die interface has a great influence on the solidification process and casting structure. As thin-wall components are extensively produced by high pressure die casting process(HPDC), the B390...Heat transfer at the metal-die interface has a great influence on the solidification process and casting structure. As thin-wall components are extensively produced by high pressure die casting process(HPDC), the B390 alloy finger-plate casting was cast against an H13 steel die on a cold-chamber HPDC machine. The interfacial heat transfer behavior at different positions of the die was carefully studied using an inverse approach based on the temperature measurements inside the die. Furthermore, the filling process and the solidification rate in different finger-plates were also given to explain the distribution of interfacial heat flux(q) and interfacial heat transfer coefficient(h). Measurement results at the side of sprue indicates that qmax and hmax could reach 9.2 MW·m^(-2) and 64.3 kW ·m^(-2)·K^(-1), respectively. The simulation of melt flow in the die reveals that the thinnest(T_1) finger plate could accelerate the melt flow from 50 m·s^(-1) to 110 m·s^(-1). Due to this high velocity, the interfacial heat flux at the end of T_1 could firstly reach a highest value 7.92 MW·m^(-2) among the ends of T_n(n=2,3,4,5). In addition, the q_(max) and h_(max) values of T_2, T_4 and T_5 finger-plates increase with the increasing thickness of the finger plate. Finally, at the rapid decreasing stage of interfacial heat transfer coefficient(h), the decreasing rate of h has an exponential relationship with the increasing rate of solid fraction(f).展开更多
基金supported by the National Natural Science Foundation of China(62171172).
文摘CMOS image sensors produced by the existing CMOS manufacturing process usually have difficulty achieving complete charge transfer owing to the introduction of potential barriers or Si/SiO_(2)interface state traps in the charge transfer path,which reduces the charge transfer efficiency and image quality.Until now,scholars have only considered mechanisms that limit charge transfer from the perspectives of potential barriers and spill back effect under high illumination condition.However,the existing models have thus far ignored the charge transfer limitation due to Si/SiO_(2)interface state traps in the transfer gate channel,particularly under low illumination.Therefore,this paper proposes,for the first time,an analytical model for quantifying the incomplete charge transfer caused by Si/SiO_(2)interface state traps in the transfer gate channel under low illumination.This model can predict the variation rules of the number of untransferred charges and charge transfer efficiency when the trap energy level follows Gaussian distribution,exponential distribution and measured distribution.The model was verified with technology computer-aided design simulations,and the results showed that the simulation results exhibit the consistency with the proposed model.
文摘The color-tunable white organic light-emitting diode (CT-WOLED) with wide correlation color temperature (CCT) has many advantages in optimizing the artificial light source to adapt to the human physiological cycle. The research on the change trend of CCT and the law of extending the change range of CCT will help to further improve the performance of this kind of device. The present work fabricated a series of CT-WOLED devices with a simple structure, which are all composed of two ultra-thin phosphor layers (PO-01 and Flrpic) and a spacer interlayer. The yellow interface exciplex (TCTA/PO-T2T) formed between the spacer layer (PO-T2T) and transmission material (TCTA) in EML will decrease the CCT value at low voltage. The relationship between the energy transfer in EML and CCT change trend is investigated by adjusting the interface exciplexes and the thickness of the interlayer or the phosphor layer in devices A, B and C, respectively. The results demonstrate that a simple OLED device with an interlayer inserted between two ultra-thin phosphor layers can achieve a wider CCT span from 3359 K to 6451 K at voltage increases from 2.75 V to 8.25 V. .
基金supported by the National Key R&D Program of China(2020YFA0406104,2020YFA0406101)the National MCF Energy R&D Program of China(2018YFE0306105)+5 种基金the Innovative Research Group Project of the National Natural Science Foundation of China(51821002)the National Natural Science Foundation of China(51725204,21771132,51972216,52041202)the Natural Science Foundation of Jiangsu Province(BK20190041)the Key-Area Research and Development Program of Guang Dong Province(2019B010933001)the Collaborative Innovation Center of Suzhou Nano Science&Technologythe 111 Project。
文摘The regulation of interface electron-transfer and catalytic kinetics is very important to design the efficient electrocatalyst for alkaline hydrogen oxidation reaction(HOR).Here,we show the Pt-Ni alloy nanoparticles(PtNi_(2))have an enhanced HOR activity compared with single component Pt catalyst.While,the interface electron-transfer kinetics of PtNi_(2)catalyst exhibits a very wide electron-transfer speed distribution.When combined with carbon dots(CDs),the interface charge transfer of PtNi_(2)-CDs composite is optimized,and then the PtNi_(2)-5 mg CDs exhibits about 2.67 times and 4.04 times higher mass and specific activity in 0.1 M KOH than that of 20%commercial Pt/C.In this system,CDs also contribute to trapping H^(+)and H_(2)O generated during HOR,tuning hydrogen binding energy(HBE),and regulating interface electron transfer.This work provides a deep understanding of the interface catalytic kinetics of Pt-based alloys towards highly efficient HOR catalysts design.
基金supported by the National Natural Science Foundation of China(22178388,21776315)the Taishan Scholars Program of Shandong Province(tsqn201909065)the Fundamental Research Funds for the Central Universities(19CX05001A).
文摘As well known in the petroleum industry and academia,Ni/ZnO catalysts have excellent desulfurization performance.However,the sulfur transfer mechanism of reactive adsorption desulfurization(RADS)that occurs on Ni/ZnO catalysts remains controversial.Herein,a periodic Ni nanorod supported on ZnO slab was built to represent the Ni/ZnO system,and density functional theory calculations were performed to study the sulfur transfer process and the role of H_(2)within the process.The results elucidate that the direct solid-state diffusion of S from Ni to interfacial oxygen vacancies(Ov)is more favorable than the hydrogenation of S to SH/H_(2)S on Ni and the subsequent H_(2)S desorption,and accordingly,H_(2)O is produced on Ni rather than on ZnO.Ab initio thermodynamics analysis shows that the hydrogen atmosphere applied in preparing Ni/ZnO catalysts greatly promotes the O_(v)formation on ZnO surface,which accounts for the presence of interfacial O_(v)in freshly prepared catalysts.Under RADS condition,hydrogenation of interfacial O atoms to form O-H groups facilitates the reverse spillover of these lattice O atoms from ZnO to Ni,accompanied with the interfacial O_(v)generation.In contrast to the classic S transfer mechanism via H_(2)S,the present work clearly demonstrates that the interfacial S transfer is a feasible reaction pathway in the RADS mechanism.More importantly,the existence of interfacial O_(v)is an essential prerequisite for this interfacial S diffusion,and H_(2)plays a key role in facilitating the O_(v)formation.
文摘On the basis of experimental studies, a program dealing with the boundary condition in the quenching process has been developed. In this program the method of Beck nonlinear estimation (inverse heat conduction method) was adopted so that the problem of the heat transfer coefficient varying significantly and complicatedly in the quenching process, has been effectively solved. Calculation result shows that the heat transfer coefficient between quenching workpiece and media boundary has a peak value, and this value and the temperature interval in which the peak value occurs vary with the cross section dimensions of workpiece, the types of the quenching media, the temperature and the surface position.
基金supported by the National Science Foundation of China(No.20775060 and No.20875077)the National Science Foundation of Gansu(No.0701RJZA109 and No.0803RJZA105)and the Key Laboratory of Polymer Materials of Gansu Province
文摘The effect of an adsorbed anionic surfactant sodium dodecyl benzene sulfonate (SDBS) on electron transfer (ET) reaction between ferricyanide aqueous solution and decamethylferrocene (DMFc) located on the adjacent organic phase was investigated for the first time by thin layer method. The adsorption of SDBS at the interface resulted in a decay in the cathodic plateau current of bimolecular reaction with increasing concentrations of SDBS in aqueous phase. However, the rate constant of electron transfer (ket) increased monotonically as the SDBS concentrations increased from 0 to 200 p, moFL. The experimental results showed that SDBS formed patches on the interface and influenced the structure of electrical double layer. 2009 Xiao Quan Lu. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
文摘Experiments have been done on mass transfer to a liquid-liquid interface on which inert gas bubbles are sparged.To simulate the pyrometallurgy system of melten slag-metal(or matte),aqueous solution-mercury(or zinc amalgam) system was used.The mass transfer coefficients of indicator ions as a function of bubble parameters have been determined.The experimental results show satisfactory agreement with the mass transfer model proposed Previously.
基金supported by the National Natural Science Foundation of China(Grant No.51109106)the Natural Science Foundation of Jiangsu Province(Grant No.BK20130946)the Qing Lan Project of Jiangsu Province
文摘A transient three-dimensional coupling model based on the compressible volume of fluid (VOF) method was developed to simulate the transport of volatile pollutants at the air-water interface. VOF is a numerical technique for locating and tracking the free surface of water flow. The relationships between Henry's constant, thermodynamics parameters, and the enlarged topological index were proposed for nonstandard conditions. A series of experiments and numerical simulations were performed to study the transport of benzene and carbinol. The simulation results agreed with the experimental results. Temperature had no effect on mass transfer of pollutants with low transfer free energy and high Henry's constant. The temporal and spatial distribution of pollutants with high transfer free energy and low Henry's constant was affected by temperature. The total enthalpy and total transfer free energy increased significantly with temperature, with significant fluctuations at low temperatures. The total enthalpy and total transfer free energy increased steadily without fluctuation at high temperatures.
基金the Scientific Research Projects (BAP) of Selcuk University, Turkey (2003/151).
文摘The ion transfer reaction of 2-benzoylpyridine-thiosemicarbazone (HL), which has antimicrobial and antifungal properties and anticancer activity, has been studied to determine its lipophilicity by cyclic voltammetry at the water/1,2-dichloroethane (1,2-DCE) interface. The physicochemical parameters such as standard partition coefficient (lgPI)andthestandardGibbsenergyoftransfer("G0tr,,wI "o)oftheprotonatedformoftheligandwere measured asa function of pH in aqueous phase. The protonated form of the ligand exhibited reversible or quasi-reversible voltammograms at the1,2-DCEintherangeofpH1-5.Theprotonationconstantsoftheligand,pKa1andpKa2,weredeterminedspectrophotometrically and were found to be 12.14 and 3.24, respectively. The standard Gibbs energy of transfer ("G0tr,,wN" o) and the partition coefficient of neutral species (lgPN) were also determined by the shake-flask method. The standard Gibbs energy of transfer of this compound across the water/1,2-DCE interface was evaluated as the quantitative measure of its lipophilicity. The difference between lgPI and lgPN was related to the degree of charge delocalization and was used to evaluate qualitatively the lipophilicity of the ligand.
基金The work was financially supported by the National Natural Science Foundations of China (No.50476083).
文摘A similarity analysis for Marangoni convection induced flow over a vapor-liquid interface due to an imposed temperature gradient was carried out. The analysis assumes that the surface tension varies linearly with temperature but the temperature variation is a power law function of the location. The similarity solutions are presented numerically and the associated transfer characteristics are discussed.
文摘In this paper, the effects of interface properties on the stress transfer between matrix and fiber in short fiber reinforced metal matrix composites (SFRMMCs) is studied with the method of the elasto plastic finite element. The interface properties include Young’s modulus, thickness and elasto plastic performances. In the calculation an interfacial layer with given thickness is introduced into the single fiber model. It is shown that, for a soft interface, the variation in interfacial properties influences the stress transfer greatly.
文摘The non-stationary of the motor imagery electroencephalography(MI-EEG)signal is one of the main limitations for the development of motor imagery brain-computer interfaces(MI-BCI).The nonstationary of the MI-EEG signal and the changes of the experimental environment make the feature distribution of the testing set and training set deviates,which reduces the classification accuracy of MI-BCI.In this paper,we propose a Kullback–Leibler divergence(KL)-based transfer learning algorithm to solve the problem of feature transfer,the proposed algorithm uses KL to measure the similarity between the training set and the testing set,adds support vector machine(SVM)classification probability to classify and weight the covariance,and discards the poorly performing samples.The results show that the proposed algorithm can significantly improve the classification accuracy of the testing set compared with the traditional algorithms,especially for subjects with medium classification accuracy.Moreover,the algorithm based on transfer learning has the potential to improve the consistency of feature distribution that the traditional algorithms do not have,which is significant for the application of MI-BCI.
基金supported by the National Natural Science Foundation of China, No.31771322(to PXZ)the Natural Science Foundation of Beijing, No.7212121(to PXZ)+2 种基金Shenzhen Science and Technology Plan Project, No.JCYJ20190806162205278(to PXZ)Funds for Severe Trauma Standardized Treatment, No.SZSM202011001(to PXZ)a grant from National Center for Trauma Medicine, Beijing, China, No.BMU2020 XY005-01(to PXZ)
文摘Transferring the contralateral C7 nerve root to the median or radial nerve has become an important means of repairing brachial plexus nerve injury.However,outcomes have been disappointing.Electroencephalography(EEG)-based human-machine interfaces have achieved promising results in promoting neurological recovery by controlling a distal exoskeleton to perform functional limb exercises early after nerve injury,which maintains target muscle activity and promotes the neurological rehabilitation effect.This review summarizes the progress of research in EEG-based human-machine interface combined with contralateral C7 transfer repair of brachial plexus nerve injury.Nerve transfer may result in loss of nerve function in the donor area,so only nerves with minimal impact on the donor area,such as the C7 nerve,should be selected as the donor.Single tendon transfer does not fully restore optimal joint function,so multiple functions often need to be reestablished simultaneously.Compared with traditional manual rehabilitation,EEG-based human-machine interfaces have the potential to maximize patient initiative and promote nerve regeneration and cortical remodeling,which facilitates neurological recovery.In the early stages of brachial plexus injury treatment,the use of an EEG-based human-machine interface combined with contralateral C7 transfer can facilitate postoperative neurological recovery by making full use of the brain’s computational capabilities and actively controlling functional exercise with the aid of external machinery.It can also prevent disuse atrophy of muscles and target organs and maintain neuromuscular junction effectiveness.Promoting cortical remodeling is also particularly important for neurological recovery after contralateral C7 transfer.Future studies are needed to investigate the mechanism by which early movement delays neuromuscular junction damage and promotes cortical remodeling.Understanding this mechanism should help guide the development of neurological rehabilitation strategies for patients with brachial plexus injury.
基金supported by the National Natural Science Foundation of China (Grant Nos. 21503066 and 61904048)the Fundamental Research Project from Shenzhen Science and Technology Innovation Committee (Grant No. JCYJ20180302174021198)+2 种基金the Natural Science Foundation of Hebei ProvinceChina(Grant No. F2017201136)the Foundation of Hebei Educational Committee (Grant No. ZC2016003)。
文摘One-dimensional nanowire is an important candidate for lead-halide perovskite-based photonic detectors and solar cells. Its surface population, diameter, and growth direction, etc., are critical for device performance. In this research,we carried out a detailed study on electron transfer process at the interface of nanowire CH_(3) NH_(3) PbI_(3)(N-MAPbI_(3))/Phenyl C61 butyric acid methyl-ester synonym(PCBM), as well as the interface of compact CH_(3) NH_(3) PbI_(3)(C-MAPbI_(3))/PCBM by transient absorption spectroscopy. By comparing the carrier recombination dynamics of N-MAPbI_(3), N-MAPbI_(3)/PCBM,C-MAPbI_(3), and C-MAPbI_(3)/PCBM from picosecond(ps) to hundred nanosecond(ns) time scale, it is demonstrated that electron transfer at N-MAPbI_(3)/PCBM interface is less efficient than that at C-MAPbI_(3)/PCBM interface. In addition, electron transfer efficiency at C-MAPbI_(3)/PCBM interface was found to be excitation density-dependent, and it reduces with photo-generation carrier concentration increasing in a range from 1.0 × 1018 cm^(-3)–4.0 × 1018 cm^(-3). Hot electron transfer,which leads to acceleration of electron transfer between the interfaces, was also visualized as carrier concentration increases from 1.0 × 10^(18) cm^(-3)–2.2 × 10^(18) cm^(-3).
基金Supported by the National Natural Science Foundation of China under Grant No 11305021the Fundamental Research Funds for the Central Universities of China under Grants Nos 3132014229 and 3132014328
文摘We develop a design of a hybrid quantum interface for quantum information transfer (QIT), adopting a nanome- chanical resonator as the intermedium, which is magnetically coupled with individual nitrogen-vacancy centers as the solid qubits, while eapacitively coupled with a coplanar waveguide resonator as the quantum data bus. We describe the Hamiltonian of the model, and analytically demonstrate the QIT for both the resonant interaction and large detuning cases. The hybrid quantum interface allows for QIT between arbitrarily selected individual nitrogen-vacancy centers, and has advantages of the sealability and controllability. Our methods open an alter- native perspective for implementing QIT, which is important during quantum storing or processing procedures in quantum computing.
基金Project supported by the National Natural Science Foundation of China(Grant No.11305021)the Fundamental Research Funds for the Central Universities of China(Grants Nos.3132017072 and 3132015149)
文摘We propose a scheme to implement quantum state transfer between two distant quantum nodes via a hybrid solid–optomechanical interface. The quantum state is encoded on the native superconducting qubit, and transferred to the microwave photon, then the optical photon successively, which afterwards is transmitted to the remote node by cavity leaking,and finally the quantum state is transferred to the remote superconducting qubit. The high efficiency of the state transfer is achieved by controllable Gaussian pulses sequence and numerically demonstrated with theoretically feasible parameters.Our scheme has the potential to implement unified quantum computing–communication–computing, and high fidelity of the microwave–optics–microwave transfer process of the quantum state.
基金supported by the National Natural Science Foundation of China(Nos.52075284,52105195,and 11890672)the Postdoctoral Research Foundation of China(Nos.2020M680528,BX2021151,and 2022M711805).
文摘The boundary slip condition is pivotal for nanoscale fluid motion.Recent research has primarily focused on simulating the interaction mechanism between the electronic structure of two-dimensional materials and slip of water at the nanoscale,raising the possibility for ultralow friction flow of water at the nanoscale.However,experimentally elucidating electronic interactions at the dynamic solid–liquid interface to control boundary slip poses a significant challenge.In this study,the crucial role of electron structures at the dynamic solid–liquid interface in regulating slip length was revealed.Notably,the slip length of water on the molybdenum disulfide/graphene(MoS_(2)/G)heterostructure(100.9±3.6 nm)significantly exceeded that of either graphene(27.7±2.2 nm)or MoS_(2)(5.7±3.1 nm)alone.It was also analyzed how electron transfer significantly affected interface interactions.Excess electrons played a crucial role in determining the type and proportion of excitons at both MoS_(2)–water and MoS_(2)/G–water interfaces.Additionally,by applying voltage,distinct photoluminescence(PL)responses at static and dynamic interfaces were discovered,achieving a 5-fold modulation in PL intensity and a 2-fold modulation in the trion to exciton intensity ratio.More electrons transfer from the top graphene to the bottom MoS_(2)at the MoS_(2)/G–water interface,reducing surface charge density.Thus,the reduction of electrostatic interactions between the solid and water leads to an increased slip length of water on the MoS_(2)/G heterostructure.The process aids in comprehending the origin of frictional resistance at the subatomic scale.This work establishes a foundation for actively controlling and designing of fluid transport at the nanoscale.
基金the National Natural Science Foundation of China(Nos.11832003 and 81471770)the Natural Science Foundation of Beijing(No.4182009)。
文摘Transfer learning,as a new machine learning methodology,may solve problems in related but different domains by using existing knowledge,and it is often applied to transfer training data from another domain for model training in the case of insuficient training data.In recent years,an increasing number of researchers who engage in brain-computer interface(BCI),have focused on using transfer learning to make most of the available electroencephalogram data from different subjects,effectively reducing the cost of expensive data acquisition and labeling as well as greatly improving the learning performance of the model.This paper surveys the development of transfer learning and reviews the transfer learning approaches in BCI.In addition,according to the"what to transfer"question in transfer learning,this review is organized into three contexts:instance-based transfer learning,parameter-based transfer learning,and feature-based transfer learning.Furthermore,the current transfer learning applications in BCI research are summarized in terms of the transfer learning methods,datasets,evaluation performance,etc.At the end of the paper,the questions to be solved in future research are put forward,laying the foundation for the popularization and in-depth research of transfer learning in BCI.
基金financially supported by the class General Financial Grant from the China Postdoctoral Science Foundation(No.2015M580093)the National Nature Science Foundation of China(No.20151301587)the National Major Science and Technology Program of China(No.2012ZX04012011)
文摘Heat transfer at the metal-die interface has a great influence on the solidification process and casting structure. As thin-wall components are extensively produced by high pressure die casting process(HPDC), the B390 alloy finger-plate casting was cast against an H13 steel die on a cold-chamber HPDC machine. The interfacial heat transfer behavior at different positions of the die was carefully studied using an inverse approach based on the temperature measurements inside the die. Furthermore, the filling process and the solidification rate in different finger-plates were also given to explain the distribution of interfacial heat flux(q) and interfacial heat transfer coefficient(h). Measurement results at the side of sprue indicates that qmax and hmax could reach 9.2 MW·m^(-2) and 64.3 kW ·m^(-2)·K^(-1), respectively. The simulation of melt flow in the die reveals that the thinnest(T_1) finger plate could accelerate the melt flow from 50 m·s^(-1) to 110 m·s^(-1). Due to this high velocity, the interfacial heat flux at the end of T_1 could firstly reach a highest value 7.92 MW·m^(-2) among the ends of T_n(n=2,3,4,5). In addition, the q_(max) and h_(max) values of T_2, T_4 and T_5 finger-plates increase with the increasing thickness of the finger plate. Finally, at the rapid decreasing stage of interfacial heat transfer coefficient(h), the decreasing rate of h has an exponential relationship with the increasing rate of solid fraction(f).