In the present work, through the path integral of Gaussian type correlation function, a new formalism based on Fermi-Golden Rule for calculating the rate constant of nonradiative decay process with Duschinsky rotation...In the present work, through the path integral of Gaussian type correlation function, a new formalism based on Fermi-Golden Rule for calculating the rate constant of nonradiative decay process with Duschinsky rotation effect in polyatomic molecules is developed. The advantage of the present path-integral formalism is promoting-mode free. In order to get the rate constant, a "transition rate matrix" needs to be calculated. The rate constant calculated previously is only an approximation of diagonal elements of our "transition rate matrix " . The total rate should be the summation over all the matrix elements.展开更多
Near-field plates with the capabilities of modulating the near-field pattern and forcing the incident wave to a subwavelength spot have been experimentally investigated at microwave wavelengths.Their superlensing prop...Near-field plates with the capabilities of modulating the near-field pattern and forcing the incident wave to a subwavelength spot have been experimentally investigated at microwave wavelengths.Their superlensing properties result from the radiationless electromagnetic interference.However, the material's loss and limitations of state-of-the-art nanofabricating technology pose great challenges to scale down the microwave near-field plates to the infrared or optical region.In this paper, a related but alternative approach based on metasurface is introduced which breaks the near-field diffraction limit at mid-infrared region(10.6 μm).The metasurface consists of periodic arrangement of chromium dipolar antennas with the same geometry but spatially varying orientations, which plays the dual roles in achieving the prescribed amplitude modulation and the abrupt π phase change between the subwavelength neighboring elements.As a result, a two dimensional subdiffraction focus as small as 0.037λ~2 at ~0.15λ above the metasurface is presented.In addition, the broadband response and ease fabrication bridge the gap between the theoretical investigation and valuable applications, such as near-field data storage, subdiffraction imaging and nanolithography.展开更多
基金Supported by the National Natural Science Foundation of China (Grant Nos. 10425420, 20433070 and 90503013)
文摘In the present work, through the path integral of Gaussian type correlation function, a new formalism based on Fermi-Golden Rule for calculating the rate constant of nonradiative decay process with Duschinsky rotation effect in polyatomic molecules is developed. The advantage of the present path-integral formalism is promoting-mode free. In order to get the rate constant, a "transition rate matrix" needs to be calculated. The rate constant calculated previously is only an approximation of diagonal elements of our "transition rate matrix " . The total rate should be the summation over all the matrix elements.
基金supported by the National Natural Science Funds (61575032)
文摘Near-field plates with the capabilities of modulating the near-field pattern and forcing the incident wave to a subwavelength spot have been experimentally investigated at microwave wavelengths.Their superlensing properties result from the radiationless electromagnetic interference.However, the material's loss and limitations of state-of-the-art nanofabricating technology pose great challenges to scale down the microwave near-field plates to the infrared or optical region.In this paper, a related but alternative approach based on metasurface is introduced which breaks the near-field diffraction limit at mid-infrared region(10.6 μm).The metasurface consists of periodic arrangement of chromium dipolar antennas with the same geometry but spatially varying orientations, which plays the dual roles in achieving the prescribed amplitude modulation and the abrupt π phase change between the subwavelength neighboring elements.As a result, a two dimensional subdiffraction focus as small as 0.037λ~2 at ~0.15λ above the metasurface is presented.In addition, the broadband response and ease fabrication bridge the gap between the theoretical investigation and valuable applications, such as near-field data storage, subdiffraction imaging and nanolithography.
