Phosphinoylazidation of alkenes is a direct method to build nitrogen-and phosphorus-containing compounds from feed-stock chemicals.Notwithstanding the advances in other phosphinyl radical related difunctionalization o...Phosphinoylazidation of alkenes is a direct method to build nitrogen-and phosphorus-containing compounds from feed-stock chemicals.Notwithstanding the advances in other phosphinyl radical related difunctionalization of alkenes,catalytic phosphinoylazidation of alkenes has not yet been reported.Here,we describe the first iron-catalyzed intermolecular phosphinoylazidation of styrenes and unactivated alkenes.The method is practically useful and requires a relatively low loading of catalyst.Mechanistic studies confirmed the radical nature of the reaction and disclosed the unusually low activation energy 4.8 kcal/mol of radical azido group transfer from the azidyl iron(III)phthalocyanine species(PcFeulN3)to a benzylic radical.This work may help to clarify the mechanism of iron-catalyzed azidation,inspire other mechanism studies and spur further synthetic applications.展开更多
In this paper, we prove that if a torsion nilpotent group G is a weak semi-radicable group, then every Sylow p-group Gp is a central-by-finite p-group, and moreover Gp's center ζ(GP) satisfies |ζ(GP) : (ζ(GP))P...In this paper, we prove that if a torsion nilpotent group G is a weak semi-radicable group, then every Sylow p-group Gp is a central-by-finite p-group, and moreover Gp's center ζ(GP) satisfies |ζ(GP) : (ζ(GP))P| <∞, that is, ζ(GP) = D×F, where D is a divisible Abelian group, and F is a finite Abelian group.展开更多
文摘Phosphinoylazidation of alkenes is a direct method to build nitrogen-and phosphorus-containing compounds from feed-stock chemicals.Notwithstanding the advances in other phosphinyl radical related difunctionalization of alkenes,catalytic phosphinoylazidation of alkenes has not yet been reported.Here,we describe the first iron-catalyzed intermolecular phosphinoylazidation of styrenes and unactivated alkenes.The method is practically useful and requires a relatively low loading of catalyst.Mechanistic studies confirmed the radical nature of the reaction and disclosed the unusually low activation energy 4.8 kcal/mol of radical azido group transfer from the azidyl iron(III)phthalocyanine species(PcFeulN3)to a benzylic radical.This work may help to clarify the mechanism of iron-catalyzed azidation,inspire other mechanism studies and spur further synthetic applications.
文摘In this paper, we prove that if a torsion nilpotent group G is a weak semi-radicable group, then every Sylow p-group Gp is a central-by-finite p-group, and moreover Gp's center ζ(GP) satisfies |ζ(GP) : (ζ(GP))P| <∞, that is, ζ(GP) = D×F, where D is a divisible Abelian group, and F is a finite Abelian group.
