Syntheses, structures and magnetic properties of two nitrophenyl substituted nitronyl nitroxide radical-lanthanide complexes [Ln（hfac）3（NITmNO2）2] （Ln = Sm（Ⅲ） （1）, Tb（Ⅲ） （2）, hfac = hexafluoroacetylacet...Syntheses, structures and magnetic properties of two nitrophenyl substituted nitronyl nitroxide radical-lanthanide complexes [Ln（hfac）3（NITmNO2）2] （Ln = Sm（Ⅲ） （1）, Tb（Ⅲ） （2）, hfac = hexafluoroacetylacetonate, NITmNO2 = 2-（3-nitrophenyl）-4,4,5,5-tetramethyl-imidazo- line-1-oxyl-3-oxide） have been described in this paper. X-ray analysis shows that the two complexes have similar mononuclear trispin radical-Ln（Ⅲ）-radical structures, in which the central Ln（Ⅲ） ions are all eight coordinated in D2d dodecahedral （DD） geometry formed by six oxygen atoms from three hfac and two oxygen atoms from nitronyl nitroxide. The magnetic study indicates the antiferromagnetic interaction between Sm（Ⅲ） ion and NITmNO2 in complex 1, while weak ferromagnetic interaction between Tb（Ⅲ） ion and NITmNO2 in complex 2.展开更多
基金Supported by the National Natural Science Foundation of China(21471084,21101096,21471083,21371104)National Innovating Experimentation Project 201410055097100 Projects of Creative Research for the Undergraduates of Nankai University in China(No.BX13165)
文摘Syntheses, structures and magnetic properties of two nitrophenyl substituted nitronyl nitroxide radical-lanthanide complexes [Ln（hfac）3（NITmNO2）2] （Ln = Sm（Ⅲ） （1）, Tb（Ⅲ） （2）, hfac = hexafluoroacetylacetonate, NITmNO2 = 2-（3-nitrophenyl）-4,4,5,5-tetramethyl-imidazo- line-1-oxyl-3-oxide） have been described in this paper. X-ray analysis shows that the two complexes have similar mononuclear trispin radical-Ln（Ⅲ）-radical structures, in which the central Ln（Ⅲ） ions are all eight coordinated in D2d dodecahedral （DD） geometry formed by six oxygen atoms from three hfac and two oxygen atoms from nitronyl nitroxide. The magnetic study indicates the antiferromagnetic interaction between Sm（Ⅲ） ion and NITmNO2 in complex 1, while weak ferromagnetic interaction between Tb（Ⅲ） ion and NITmNO2 in complex 2.
