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Optimization of the Pretreatment of the Mixture of Cassava Peelings and Pineapple Fibers Using Response Surface Methodology and a Process Simulator for the Bioethanol Production
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作者 Paul Nestor Djomou Djonga George Elambo Nkeng +2 位作者 Madjoyogo Hervé Sirma Ahmat Tom Thierry Tchamba Tchuidjang 《Energy and Power Engineering》 2024年第2期79-96,共18页
The increase in oil prices and greenhouse gas emissions has led to the search for substitutes for fossil fuels. In Cameroon, the abundance of lignocellulosic resources is inherent to agricultural activity. Production ... The increase in oil prices and greenhouse gas emissions has led to the search for substitutes for fossil fuels. In Cameroon, the abundance of lignocellulosic resources is inherent to agricultural activity. Production of bioethanol remains a challenge given the crystallinity of cellulose and the presence of the complex. The pretreatment aimed to solubilize the lignin fraction and to make cellulose more accessible to the hydrolytic enzymes, was done using the organosolv process. A mathematical modeling was performed to point out the effect of the temperature on the kinetics of the release of the reducing sugars during the pretreatment. Two mathematical model was used, SAEMAN’s model and Response surface methodology. The first show that the kinetic parameters of the hydrolysis of the cellulose and reducing sugar are: 0.05089 min<sup>-1</sup>, 5358.1461 J·mol<sup>-1</sup>, 1383.03691 min<sup>-1</sup>, 51577.6100 J·mol<sup>-1</sup> respectively. The second model was used. Temperature is the factor having the most positive influence whereas, ethanol concentration is not an essential factor. To release the maximum, an organosolv pre-treatment of this sub-strate should be carried out at 209.08°C for 47.60 min with an ethanol-water ratio of 24.02%. Organosolv pre-treatment is an effective process for delignification of the lignocellulosic structure. 展开更多
关键词 BIOETHANOL Cassava Peeling Pineapple fibers Organosolv Process and Optimization
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Demineralized Bone Matrix Fibers plus Allograft Bone for Multilevel Posterolateral Spine Fusion: A Game Changer?
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作者 Bodin Arnaud Barnouin Laurence +2 位作者 Coulomb Remy Haignere Vincent Kouyoumdjian Pascal 《Open Journal of Orthopedics》 2024年第2期105-113,共9页
Introduction: While autograft bone is the gold standard for multilevel posterolateral lumbar fusion, bone substitutes and graft extenders such as allograft bone, ceramics and demineralized bone matrix (DBM) have been ... Introduction: While autograft bone is the gold standard for multilevel posterolateral lumbar fusion, bone substitutes and graft extenders such as allograft bone, ceramics and demineralized bone matrix (DBM) have been used to avoid the morbidity and insufficient quantity associated with harvesting autologous bone. The primary objective of this retrospective study was to determine whether, in patients with increased risk of operative nonunion related to multilevel fusion, adding DBM fibers to mineralized bone allograft resulted in better fusion than using allograft alone. The secondary objectives were to evaluate how adding DBM fibers affects functional disability, low back pain, intraoperative blood loss and the nonunion rate. Methods: This retrospective study involved a chart review of consecutive patients who underwent multilevel lumbar spinal fusion and were operated on by a single surgeon. The patients were divided into two groups: 14 patients received mineralized bone allograft (control group) and 14 patients received a combination of mineralized bone allograft and DBM (experimental group). Patients were reviewed at a mean of 16.4 ± 2.2 months after surgery at which point CT scans were analyzed to determine whether fusion had occurred;Oswestry disability index (ODI) and pain were also evaluated. Results: A mean of 5 levels [min 2, max 13] were fused in these patients. Posterolateral fusion as defined by the Lenke classification was not significantly different between groups. The experimental DBM group had a significantly better composite fusion score than the control group (P Discussion: Adding DBM fibers to allograft bone during multilevel posterolateral spinal fusion was safe and produced better composite fusion than using allograft only as an autograft extender. 展开更多
关键词 Spine Surgery Demineralized Bone fibers Bone Substitutes Retrospective Study
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Coaxial Wet Spinning of Boron Nitride Nanosheet‑Based Composite Fibers with Enhanced Thermal Conductivity and Mechanical Strength
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作者 Wenjiang Lu Qixuan Deng +3 位作者 Minsu Liu Baofu Ding Zhiyuan Xiong Ling Qiu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第2期126-138,共13页
Hexagonal boron nitride nanosheets(BNNSs)exhibit remarkable thermal and dielectric properties.However,their self-assembly and alignment in macroscopic forms remain challenging due to the chemical inertness of boron ni... Hexagonal boron nitride nanosheets(BNNSs)exhibit remarkable thermal and dielectric properties.However,their self-assembly and alignment in macroscopic forms remain challenging due to the chemical inertness of boron nitride,thereby limiting their performance in applications such as thermal management.In this study,we present a coaxial wet spinning approach for the fabrication of BNNSs/polymer composite fibers with high nanosheet orientation.The composite fibers were prepared using a superacid-based solvent system and showed a layered structure comprising an aramid core and an aramid/BNNSs sheath.Notably,the coaxial fibers exhibited significantly higher BNNSs alignment compared to uniaxial aramid/BNNSs fibers,primarily due to the additional compressive forces exerted at the core-sheath interface during the hot drawing process.With a BNNSs loading of 60 wt%,the resulting coaxial fibers showed exceptional properties,including an ultrahigh Herman orientation parameter of 0.81,thermal conductivity of 17.2 W m^(-1)K^(-1),and tensile strength of 192.5 MPa.These results surpassed those of uniaxial fibers and previously reported BNNSs composite fibers,making them highly suitable for applications such as wearable thermal management textiles.Our findings present a promising strategy for fabricating high-performance composite fibers based on BNNSs. 展开更多
关键词 Boron nitride nanosheets Coaxial fiber Interfacial compression Nanosheet aligning Wearable thermal management
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Progress in the application of polymer fibers in solid electrolytes for lithium metal batteries
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作者 Junbao Kang Nanping Deng +1 位作者 Bowen Cheng Weimin Kang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第5期26-42,共17页
Solid state lithium metal batteries(SSLMBs)are considered to be one of the most promising battery systems for achieving high energy density and excellent safety for energy storage in the future.However,current existed... Solid state lithium metal batteries(SSLMBs)are considered to be one of the most promising battery systems for achieving high energy density and excellent safety for energy storage in the future.However,current existed solid-state electrolytes(SSEs)are still difficult to meet the practical application requirements of SSLMBs.In this review,based on the analysis of main problems and challenges faced by the development of SSEs,the ingenious application and latest progresses including specific suggestions of various polymer fibers and their membrane products in solving these issues are emphatically reviewed.Firstly,the inherent defects of inorganic and organic electrolytes are pointed out.Then,the application strategies of polymer fibers/fiber membranes in strengthening strength,reducing thickness,enhancing thermal stability,increasing the film formability,improving ion conductivity and optimizing interface stability are discussed in detail from two aspects of improving physical structure properties and electrochemical performances.Finally,the researches and development trends of the intelligent applications of high-performance polymer fibers in SSEs is prospected.This review intends to provide timely and important guidance for the design and development of polymer fiber composite SSEs for SSLMBs. 展开更多
关键词 Composite solide lectrolytes Polymer fibers Solid-state lithium metal batteries Solid-stateel ectrolytes Nanofiber membranes
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Carbon Fiber Breakage Mechanism in Aluminum(Al)/Carbon Fibers(CFs) Composite Sheet during Accumulative Roll Bonding(ARB) Process
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作者 胡淑芬 SUN Zhenzhong +3 位作者 SHEN Fanghua DENG Jun 杨卫平 杨浩坤 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第1期167-173,共7页
We put forward a method of fabricating Aluminum(Al)/carbon fibers(CFs) composite sheets by the accumulative roll bonding(ARB) method. The finished Al/CFs composite sheet has CFs and pure Al sheets as sandwich and surf... We put forward a method of fabricating Aluminum(Al)/carbon fibers(CFs) composite sheets by the accumulative roll bonding(ARB) method. The finished Al/CFs composite sheet has CFs and pure Al sheets as sandwich and surface layers. After cross-section observation of the Al/CFs composite sheet, we found that the CFs discretely distributed within the sandwich layer. Besides, the tensile test showed that the contribution of the sandwich CFs layer to tensile strength was less than 11% compared with annealed pure Al sheet. With ex-situ observation of the CFs breakage evolution with-16%,-32%, and-45% rolling reduction during the ARB process, the plastic instability of the Al layer was found to bring shear damages to the CFs. At last, the bridging strengthening mechanism introduced by CFs was sacrificed. We provide new insight into and instruction on Al/CFs composite sheet preparation method and processing parameters. 展开更多
关键词 Al/CFs composite sheet accumulative roll bonding tensile strength plastic instability carbon fiber breakage
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Analysis of piezoelectric semiconductor fibers under gradient temperature changes
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作者 Shuangpeng LI Ruoran CHENG +1 位作者 Nannan MA Chunli ZHANG 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第2期311-320,共10页
Piezoelectric semiconductors(PSs)possess both semiconducting properties and piezoelectric coupling effects,making them optimal building blocks for semiconductor devices.PS fiber-like structures have wide applications ... Piezoelectric semiconductors(PSs)possess both semiconducting properties and piezoelectric coupling effects,making them optimal building blocks for semiconductor devices.PS fiber-like structures have wide applications in multi-functional semiconductor devices.In this paper,a one-dimensional(1D)theoretical model is established to describe the piezotronic responses of a PS fiber under gradient temperature changes.The theoretical model aims to explain the mechanism behind the resistance change caused by such gradient temperature changes.Numerical results demonstrate that a gradient temperature change significantly affects the physical fields within the PS fiber,and can induce changes in its surface resistance.It provides important theoretical guidance on the development of piezotronic devices that are sensitive to temperature effects. 展开更多
关键词 piezoelectric semiconductor(PS)fiber one-dimensional(1D)model piezotronic effect gradient temperature change
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Preserving glacier mass:Cellulosic LENZING^(TM) fibers provide snow and ice protection solution
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《China Textile》 2024年第1期10-11,共2页
In field trials on Austrian glaciers,nonwovens made of ce u osic LENZING^(TM) fibers are being used to cover glacier mass.They are showing promising results and offer a sustainable solution for glacier protection.Nonw... In field trials on Austrian glaciers,nonwovens made of ce u osic LENZING^(TM) fibers are being used to cover glacier mass.They are showing promising results and offer a sustainable solution for glacier protection.Nonwovens containing fossilbased synthetic fibers might cause negative environmental consequences such as microplastics on glaciers.Geotextiles with ce u osic LENZINGTMfibers won the prestigious Swiss BIO TOP,an award for wood and material innovations.Geotextiles are already widely used to protect snow and ice on glaciers frommelting. 展开更多
关键词 fibers GLACIER NONWOVEN
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The structural characteristics of dietary fibers from Tremella fuciformis and their hypolipidemic effects in mice 被引量:4
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作者 Shanshan Zhang Xinle Xu +1 位作者 Xu Cao Tingting Liu 《Food Science and Human Wellness》 SCIE CSCD 2023年第2期503-511,共9页
In this study,Tremella fuciformis residues as raw material,dietary fibers from tremella were prepared by multiple enzymes.The structure of dietary fibers from tremella was studied by Fourier transform infrared(FTIR),X... In this study,Tremella fuciformis residues as raw material,dietary fibers from tremella were prepared by multiple enzymes.The structure of dietary fibers from tremella was studied by Fourier transform infrared(FTIR),X-ray diffraction analysis(XRD)and scanning electron microscopy(SEM).We analyzed their lipidlowering properties in vitro(water holding,oil holding swelling cholesterol and sodium cholate binding capacitises)and the hypolipidemic effects in mice.The results showed that tremella dietary fibers presented the infrared absorption spectrum characteristics of polysaccharides and the characteristic diffraction peaks of cellulose type I.SEM results indicated that the surface of insoluble dietary fiber(IDF)was porous,while the soluble dietary fiber(SDF)was relatively compact and spongy.IDF exhibited significantly higher water holding,oil holding,and swelling binding capacities than the corresponding SDF.However,SDF exhibited significantly higher viscosity than IDF.The results showed tremella dietary fibers were significant in swelling,water holding and oil holding,cholesterol and bile acids.In vivo experiment results in mice indicated that SDF has the best effect on hyperlipidemia mice than IDF and total dietary fiber(TDF).SDF showed that the total cholesterol(TC),triglyceride(TG)and low density lipoprotein cholesterol(LDL-C)contents dropped by 28.33%,18.65%,and 48.97%,respectively,while high density lipoprotein cholesterol(HDL-C)content increased by 43.80%.Compared with the high-fat control(HCM)group,the arteriosclerosis index(AI)and liver index(LI)of the SDF group mice showed significant differences,indicating that SDF has a good auxiliary effect of lowering blood lipids.The administration of tremella fibers improved the lipid metabolism disorderly situation of hyperlipidemia mice.These results provide a reference for further research and rational development of T.fuciformis. 展开更多
关键词 Tremella fuciformis Dietary fiber Structural characterization Hypolipidemic effects
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Fabrication of ZIF-8 membranes on dual-layer ZnO-PES/PES organic hollow fibers by in-situ crystallization 被引量:2
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作者 Zhengchi Yin Xiaoke Wu +5 位作者 Yanwei Yang Huayu Zhang Wangtao Li Ruimin Zhu Qiancheng Zheng Zhengbao Wang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第3期101-110,共10页
Compared to inorganic supports, polymeric supports can offer additional benefits, e.g., easier processing and cheaper. However, the organic surface has weak adhesion to the zeolitic imidazolate frameworks(ZIFs) membra... Compared to inorganic supports, polymeric supports can offer additional benefits, e.g., easier processing and cheaper. However, the organic surface has weak adhesion to the zeolitic imidazolate frameworks(ZIFs) membrane layer, which usually requires complex surface modification or seeding. Herein, we demonstrate that a dual-layer asymmetric polymer support prepared by a simple spinning process is a good candidate for the preparation of ZIF-8 membrane. The inner layer of the support is an organic hollow fiber(PES) with finger-like pores, and the outer layer is a ZnO-PES composite layer with finger-like pores also. The ZnO-PES composite layer is expected to contain uniform ZnO crystals in the polymer matrix, i.e., the ZnO particles in the skin layer of the support are not easy to fall off. Under the induction of ZnO particles in the outer layers, continuous ZIF-8 membranes can be prepared by single in-situ crystallization, showing good adhesion to the supports. The obtained ZIF-8 membranes show a H_(2) permeance of 8.7 × 10^(-8)mol·m^(-2)·s^(-1)·Pa^(-1) with a H_(2)/N_(2) ideal separation selectivity of 18.0. The design and preparation of this dual-layer polymer support is expected to promote the large-scale application of MOF membranes on polymer supports. 展开更多
关键词 Dual-layer PES hollow fiber In-situ crystallization ZIF-8 membrane Gas separation ZNO
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Boosting Capacitive Deionization Performance of Commercial Carbon Fibers Cloth via Structural Regulation Based on Catalytic-Etching Effect 被引量:1
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作者 Chunjie Zhang Dong Wang +5 位作者 Zhen Wang Guangshuai Zhang Zhichao Liu Jie Wu Jin Hu Guangwu Wen 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2023年第1期242-252,共11页
Monolithic carbon electrodes with robust mechanical integrity and porous architecture are highly desired for capacitive deionization but remain challenging.Owing to the excellent mechanical strength and electroconduct... Monolithic carbon electrodes with robust mechanical integrity and porous architecture are highly desired for capacitive deionization but remain challenging.Owing to the excellent mechanical strength and electroconductivity,commercial carbon fibers cloth demonstrates great potential as high-performance electrodes for ions storage.Despite this,its direct application on capacitive deionization is rarely reported in terms of limited pore structure and natural hydrophobicity.Herein,a powerful metal-organic framework-engaged structural regulation strategy is developed to boost the desalination properties of carbon fibers.The obtained porous carbon fibers features hierarchical porous structure and hydrophilic surface providing abundant ions-accessible sites,and continuous graphitized carbon core ensuring rapid electrons transport.The catalytic-etching mechanism involving oxidation of Co and subsequent carbonthermal reduction is proposed and highly relies on annealing temperature and holding time.When directly evaluated as a current collector-free capacitive deionization electrode,the porous carbon fibers demonstrates much superior desalination capability than pristine carbon fibers,and remarkable cyclic stability up to 20 h with negligible degeneration.Particularly,the PCF-1000 showcases the highest areal salt adsorption capacity of 0.037 mg cm^(−2) among carbon microfibers.Moreover,monolithic porous carbon fibers-carbon nanotubes with increased active sites and good structural integrity by in-situ growth of carbon nanotubes are further fabricated to enhance the desalination performance(0.051 mg cm^(−2)).This work demonstrates the great potential of carbon fibers in constructing high-efficient and robust monolithic electrode for capacitive deionization. 展开更多
关键词 capacitive deionization carbon fibers cloth catalytic-etching monolithic electrodes
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Dietary fibers with low hydration properties exacerbate diarrhea and impair intestinal health and nutrient digestibility in weaned piglets 被引量:1
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作者 Shuangbo Huang Zhijuan Cui +6 位作者 Xiangyu Hao Chuanhui Cheng Jianzhao Chen Deyuan Wu Hefeng Luo Jinping Deng Chengquan Tan 《Journal of Animal Science and Biotechnology》 SCIE CAS CSCD 2023年第2期771-791,共21页
Background:This study aimed to investigate the hydration properties of different-source fibrous materials by com-paring their water-binding capacity(WBC),water swelling capacity(WSC),viscosity,and in vivo effects of s... Background:This study aimed to investigate the hydration properties of different-source fibrous materials by com-paring their water-binding capacity(WBC),water swelling capacity(WSC),viscosity,and in vivo effects of selected samples on growth performance,nutrient digestibility,diarrhea,and intestinal health in weaned piglets.Methods:A total of 13 commercially available fibrous materials were first compared in chemical composition and in vitro hydration property.Subsequently,40 weaned piglets were randomized to five experimental dietary groups(8 piglets per group):control diet(a basal diet without dietary fiber,CON),basal diet supplemented with 5%microcrys-talline cellulose(MCC),5%wheat bran(WB),5%Moringa oleifera leaf powder(MOLP),or 5%sugar beet pulp(SBP),fol-lowed by analyzing their growth performance and diarrhea rate in a 28-d experiment.After the feeding experiment,anaesthetized piglets were killed,and their intestinal and colon content or plasma samples were analyzed in nutrient digestibility,intestinal morphology,intestinal barrier,short-chain fatty acids(SCFAs),and bacterial population.Results:In vitro studies showed low hydration properties for WB and MCC,while medium hydration properties for MOLP and SBP.In vivo studies indicated that compared with medium hydration property groups,low hydration prop-erty groups showed(1)exacerbated diarrhea,impaired intestinal health,and reduced apparent fecal digestibility of dry matter,gross energy,acid detergent fiber,and neutral detergent fiber;(2)decreased SCFAs concentration and rela-tive levels of Lactobacillus and Bifidobacterium,but increased levels of Escherichia coli and Brachyspira hyodysenteriae in colon contents.Additionally,SBP showed optimal performance in reducing diarrhea and increasing SCFAs produc-tion.Correlation analysis revealed a positive correlation of fiber hydration properties with in vitro SCFAs production,and diarrhea index and nutrient digestibility were negatively and positively correlated with SCFAs levels in the colon contents of weaned piglets,respectively.Conclusions:Different-source dietary fibers varied in their hydration properties and impacts on diarrhea,microbial composition and SCFAs production in weaned piglets.WB and MCC could exacerbate diarrhea and impair nutrient digestibility,probably because their low hydration properties were detrimental to gut microbial homeostasis and fermentation.Our findings provide new ideas for rational use of fiber resources in weaned piglets. 展开更多
关键词 DIARRHEA Dietary fiber Hydration property Intestinal health Nutrient digestibility Weaned piglet
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Specialty optical fibers for advanced sensing applications 被引量:1
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作者 Huanhuan Liu Dora Juan Juan Hu +10 位作者 Qizhen Sun Lei Wei Kaiwei Li Changrui Liao Bozhe Li Cong Zhao Xinyong Dong Yuhan Tang Yihong Xiao Gerd Keiser Perry Ping Shum 《Opto-Electronic Science》 2023年第2期1-26,共26页
Optical fiber technology has changed the world by enabling extraordinary growth in world-wide communications and sensing.The rapid development and wide deployment of optical fiber sensors are driven by their excellent... Optical fiber technology has changed the world by enabling extraordinary growth in world-wide communications and sensing.The rapid development and wide deployment of optical fiber sensors are driven by their excellent sensing performance with outstanding flexibility,functionality,and versatility.Notably,the research on specialty optical fibers is playing a critical role in enabling and proliferating the optical fiber sensing applications.This paper overviews recent developments in specialty optical fibers and their sensing applications.The specialty optical fibers are reviewed based on their innovations in special structures,special materials,and technologies to realize lab in/on a fiber.An overview of sensing applications in various fields is presented.The prospects and emerging research areas of specialty optical fibers are also discussed. 展开更多
关键词 specialty optical fibers photonic crystal fiber MULTIFUNCTIONAL multi-material fibers lab in/on fiber
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Analysis of Ethylene Glycol Degumming Process and Characterization of Hemp Fibers 被引量:1
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作者 池虹 秦智慧 +3 位作者 赵树元 刘柳 张瑞云 程隆棣 《Journal of Donghua University(English Edition)》 CAS 2023年第3期255-260,共6页
To overcome the shortcomings of traditional degumming process,an efficient and environmentally friendly ethylene glycol(EG) degumming process was adopted to degum hemp fibers.The surface morphology,chemical compositio... To overcome the shortcomings of traditional degumming process,an efficient and environmentally friendly ethylene glycol(EG) degumming process was adopted to degum hemp fibers.The surface morphology,chemical composition,chemical structures,and mechanical properties of the fiber samples were analyzed to explore the mechanism of the degumming process.It was found that the EG degumming process could be divided into the main degumming stage(heating) and the supplementary degumming stage(insulation).The removal rates of hemicellulose and lignin in the main degumming stage were 70.56% and 60.17%,respectively.In the supplementary degumming stage,9.95% hemicellulose and 25.39% lignin were removed.It is confirmed that EG can separate hemp fibers effectively with less damage,which holds great potential for the biomass fiber separation technology. 展开更多
关键词 hemp fiber degumming process ethylene glycol(EG) HEMICELLULOSE LIGNIN
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Design optimization of plastic scintillators with wavelength-shifting fibers and silicon photomultiplier readouts in the top veto tracker of the JUNO-TAO experiment 被引量:1
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作者 Guang Luo Y.K.Hor +10 位作者 Pei-Zhi Lu Zhi-Min Wang Ru-Hui Li Min Li Yi-Chen Li Liang Zhan Wei Wang Yue-Huan Wei Yu Chen Xiang Xiao Feng-Peng An 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2023年第7期99-112,共14页
Plastic scintillators(PSs)embedded with wavelength-shifting fibers are widely used in high-energy particle physics,such as in muon taggers,as well as in medical physics and other applications.In this study,a simulatio... Plastic scintillators(PSs)embedded with wavelength-shifting fibers are widely used in high-energy particle physics,such as in muon taggers,as well as in medical physics and other applications.In this study,a simulation package was built to evaluate the effects of the diameter and layout of optical fibers on the light yield with different configurations.The optimal optical configuration was designed based on simulations and validated using two PS prototypes under certain experimental condi-tions.A top veto tracker(TVT)for the JUNO-TAO experiment,comprising four layers of 160 strips of PS,was designed and evaluated.The threshold was evaluated when the muon tagging efficiency of a PS strip was>99%.The efficiency of three layer out of four layer of TVT is>99%,even with a tagging efficiency of a single strip as low as 97%,using a threshold of 10 photoelectrons and assuming a 40%silicon PM photon detection efficiency. 展开更多
关键词 Plastic scintillator WLS fiber Light yield Optical transmission performance Muon tagging efficiency JUNO-TAO
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Temperature‑Arousing Self‑Powered Fire Warning E‑Textile Based on p-n Segment Coaxial Aerogel Fibers for Active Fire Protection in Firefighting Clothing 被引量:1
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作者 Hualing He Yi Qin +6 位作者 Zhenyu Zhu Qing Jiang Shengnan Ouyang Yuhang Wan Xueru Qu Jie Xu Zhicai Yu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第12期141-160,共20页
Firefighting protective clothing is a crucial protective equipment for firefighters to minimize skin burn and ensure safety firefighting operation and rescue mission.A recent increasing concern is to develop self-powe... Firefighting protective clothing is a crucial protective equipment for firefighters to minimize skin burn and ensure safety firefighting operation and rescue mission.A recent increasing concern is to develop self-powered fire warning materials that can be incorporated into the firefighting clothing to achieve active fire protection for firefighters before the protective clothing catches fire on fireground.However,it is still a challenge to facilely design and manufacture thermoelectric(TE)textile(TET)-based fire warning electronics with dynamic surface conformability and breathability.Here,we develop an alternate coaxial wet-spinning strategy to continuously produce alternating p/n-type TE aerogel fibers involving n-type Ti_(3)C_(2)T_(x)MXene and p-type MXene/SWCNT-COOH as core materials,and tough aramid nanofiber as protective shell,which simultaneously ensure the flexibility and high-efficiency TE power generation.With such alternating p/n-type TE fibers,TET-based self-powered fire warning sensors with high mechanical stability and wearability are successfully fabricated through stitching the alternating p-n segment TE fibers into aramid fabric.The results indicate that TET-based fire warning electronics containing 50 p-n pairs produce the open-circuit voltage of 7.5 mV with a power density of 119.79 nW cm-2 at a temperature difference of 300℃.The output voltage signal is then calculated as corresponding surface temperature of firefighting clothing based on a linear relationship between TE voltage and temperature.The fire alarm response time and flame-retardant properties are further displayed.Such self-powered fire warning electronics are true textiles that offer breathability and compatibility with body movement,demonstrating their potential application in firefighting clothing. 展开更多
关键词 Self-powered fire warning Coaxial wet spinning P-n segment thermoelectric fiber Thermoelectric textiles Active fire protection
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Research on Infrared Emissivity and Laser Reflectivity of Sn_(1−x)Er_(x)O_(2)Micro/Nanofibers Based on First-Principles 被引量:1
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作者 Yuanjia Xia Fang Zhao +2 位作者 Zhizun Li Zhaogang Cheng Jianwei Hu 《Journal of Renewable Materials》 SCIE EI 2023年第2期921-936,共16页
Sn_(1−x)Er_(x)O_(2)(x=0%,8%,16%,24%)micro/nanofibers were prepared by electrospinning combined with heat treatment using erbium nitrate,stannous chloride and polyvinylpyrrolidone(PVP)as raw materials.The target produc... Sn_(1−x)Er_(x)O_(2)(x=0%,8%,16%,24%)micro/nanofibers were prepared by electrospinning combined with heat treatment using erbium nitrate,stannous chloride and polyvinylpyrrolidone(PVP)as raw materials.The target products were characterized by thermogravimetric analyzer,X-ray diffrotometer,fourier transform infrared spectrometer,scanning electron microscope,spectrophotometer and infrared emissivity tester,and the effects of Er^(3+)doping on its infrared and laser emissivity were studied.At the same time,the Sn_(1−x)Er_(x)O_(2)(x=0%,16%)doping models were constructed based on the first principles of density functional theory,and the related optoelectronic properties such as their energy band structure,density of states,reflectivity and dielectric constant were analyzed,and further explained the mechanism of Er^(3+)doping on SnO_(2)infrared emissivity and laser absorption from the point of electronic structure.The results showed that after calcination at 600℃,single rutile type SnO_(2)was formed,and the crystal structure was not changed by doping Er^(3+).The calcined products showed good fiber morphology,and the average fiber diameter was 402 nm.The infrared emissivity and resistivity of the samples both decreased first and then increased with the increase of Er^(3+)doping amount.When x=16%,the infrared emis-sivity of the sample was at least 0.71;and Er^(3+)doping can effectively reduce the reflectivity of SnO_(2)at 1.06μm and 1.55μm,when x=16%,its reflectivity at 1.06μm and 1.55μm are 50.5%and 40%,respectively,when x=24%,the reflectivity at 1.06μm and 1.55μm wavelengths are 47.3%and 42.1%,respectively.At the same time,the change of carrier concentration and electron transition before and after Er^(3+)doping were described by first-principle calculation,and the regulation mechanism of infrared emissivity and laser reflectivity was explained.This study provides a certain experimental and theoretical basis for the development of a single-type,light-weight and easily prepared infrared and laser compatible-stealth material. 展开更多
关键词 Micro/nano fibers Er^(3+)doping SnO_(2) laser and infrared compatible stealth material
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Comparative transcriptome and lipidome reveal that a low K^(+) signal effectively alleviates the effect induced by Ca^(2+) deficiency in cotton fibers
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作者 GUO Kai GAO Wei +11 位作者 ZHANG Tao-rui WANG Zu-ying SUN Xiao-ting YANG Peng LONG Lu LIU Xue-ying WANG Wen-wen TENG Zhong-hua LIU Da-jun LIU De-xin TU Li-li ZHANG Zheng-sheng 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2023年第8期2306-2322,共17页
Calcium(Ca^(2+))plays an important role in determining plant growth and development because it maintains cell wall and membrane integrity.Therefore,understanding the role of Ca^(2+)in carbon and lipid metabolism could... Calcium(Ca^(2+))plays an important role in determining plant growth and development because it maintains cell wall and membrane integrity.Therefore,understanding the role of Ca^(2+)in carbon and lipid metabolism could provide insights into the dynamic changes in cell membranes and cell walls during the rapid elongation of cotton fibers.In the present study,we found that the lack of Ca^(2+)promoted fiber elongation and rapid ovule expansion,but it also caused tissue browning in the ovule culture system.RNA-sequencing revealed that Ca^(2+)deficiency induced cells to be highly oxidized,and the expression of genes related to carbon metabolism and lipid metabolism was activated significantly.All gene members of nine key enzymes involved in glycolysis were up-regulated,and glucose was significantly reduced in Ca^(2+)deficiency-treated tissues.Ca^(2+)deficiency adjusted the flowing of glycolysis metabolic.However,low K^(+)recovered the expression levels of glycolysis genes and glucose content caused by Ca^(2+)deficiency.Electrospray ionizationtandem mass spectrometry technology was applied to uncover the dynamic profile of lipidome under Ca^(2+)and K^(+)interacted conditions.Ca^(2+)deficiency led to the decrease of fatty acid(FA),diacylglycerol(DAG),glycolipid and the significant increase of triacylglycerol(TAG),phospholipid phosphatidylethanolamine(PE),phosphatidylglycerol(PG),and PC(phosphatidylcholine).Low K^(+)restored the contents of FA,phospholipids,and glycolipids,effectively relieved the symptoms caused by Ca^(2+)deficiency,and recovered the development of fiber cells.This study revealed dynamic changes in transcript and metabolic levels and uncovered the signaling interaction of Ca^(2+)deficiency and low K^(+)in glycolysis and lipid metabolism during fiber development. 展开更多
关键词 cotton fiber GLYCOLYSIS LIPIDOME calcium potassium
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Recent Progress on Fabrication of Thermal Conductive Aluminum Nitride Fibers
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作者 沈卓尔 任松 +3 位作者 葛灿 赵浩阅 韩梦瑶 方剑 《Journal of Donghua University(English Edition)》 CAS 2023年第6期622-630,共9页
Among nitride fibers,aluminum nitride(AlN)fibers have been developed for various advanced applications due to their mechanical flexibility,high thermal conductivity,and excellent electrical insulation and chemical sta... Among nitride fibers,aluminum nitride(AlN)fibers have been developed for various advanced applications due to their mechanical flexibility,high thermal conductivity,and excellent electrical insulation and chemical stability.This article presents an overview on the recent progress of AlN fibers.The properties of AlN,particularly the thermal conductivity of AlN in polymer matrix composites are introduced.Afterward,two major approaches,carbothermal reduction and nitriding polycrystalline alumina fiber,for the preparation of AlN fibers are discussed.The carbothermal reduction includes electrospinning,solution blow spinning,and chemical vapor deposition.Furthermore,some perspectives on the future directions for the preparation and application of fibrous AlN are highlighted.This review is expected to provide readers with valuable guidance on the preparation of AlN fibers and inspire researchers to explore more potential applications. 展开更多
关键词 aluminum nitride fiber thermal conductivity carbothermal reduction nitriding polycrystalline alumina fiber
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Freestanding fibers assembled by CoPSe@N-doped carbon heterostructures as an anode for fast potassium storage in hybrid capacitors
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作者 Xueya Liu Jin Wang +5 位作者 Tiantian Tang Caiyun Li Yukun Liu Liang Si Sen Zhang Chao Deng 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第11期587-598,I0013,共13页
Although the fast development of potassium-ion hybrid capacitors(PIHC)recently,the issues such as the slow kinetics and poor durability of potassium ion hosts greatly restric their applications.Herein,a freestanding f... Although the fast development of potassium-ion hybrid capacitors(PIHC)recently,the issues such as the slow kinetics and poor durability of potassium ion hosts greatly restric their applications.Herein,a freestanding fiber(NHF fiber)with necklace-like configuration and CoPSe@N-doped carbon(CoPSe@NCNT)heterostructured units is introduced as the anode in PIHC.The highly porous network of NHF fiber facilitates the fast ion transports and promises the good high-rate property.Additionally,the nanoscle crystallites inside in-situ grown NCNT favor the high adaption to volume expansion/shrinkage and endow good structure stability during ion insertion/deinsertion.Density function theoretical(DFT)calculations disclose the CoPSe@NCNT heterostructure has improved intrinsic conductivity,fast potassium migration,and decreased energy barrier.Meanwhile,the finite element simulation analysis(FEA)reveals the decreased stress inside the NHF architecture during charge/discharge processes.Moreover,the electrochemical tests confirm the fast and durable properties of the CoPSe@NCNT NHF fibers for potassium storage.Furthermore,the PIHC full cell with the anode of CoPSe@NCNT NHF fiber is assembled,which obtains the superior energy/power densities and high capacity retention(89%)after 2000 cycles at 2 A g^(-1).When the polymer electrolyte is incooperated,the flexible PIHC device achieves the good pliability and good adaptation during wide temperature changes from-20 to 25℃.Therefore,this work introduces a novel anode for fast potassium ion storage,and opens a new approach to assemble the power sources for flexible electronics in diverse conditions. 展开更多
关键词 CoPSe@NCNT heterostructure Freestanding fiber Fastkinetics Hybrid capacitor
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Adjusting the interfacial adhesion via surface modification to prepare high-performance fibers
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作者 Ning Han Xiaolin Zhao Vijay Kumar Thakur 《Nano Materials Science》 EI CAS CSCD 2023年第1期1-14,共14页
Ultra-high molecular weight polyethylene(UHMWPE)fiber is a new kind of high-performance fiber.Due to its excellent physical and chemical characteristics,it is widely used in various fields.However,the surface UHMWPE f... Ultra-high molecular weight polyethylene(UHMWPE)fiber is a new kind of high-performance fiber.Due to its excellent physical and chemical characteristics,it is widely used in various fields.However,the surface UHMWPE fiber is smooth and demonstrates no-polar groups.The weak interfacial adhesion between fiber and resin seri-ously restricts the applications of UHMWPE fiber.Therefore,the surface modification treatments of UHMWPE fiber are used to improve the interfacial adhesion strength.The modified method by adding nanomaterials elu-cidates the easy fabrication,advanced equipment and proper technology.Thus,the progress of UHMWPE nanocomposite fibers prepared via adding various nanofillers are reviewed.Meanwhile,the effects of other various methods on surface modification are also reviewed.This work advances the various design strategies about nano technologies on improving interfacial adhesion performance via treatment methodologies. 展开更多
关键词 UHMWPE fiber Surface modification Interfacial adhesion strength NANOCOMPOSITES
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