The effect of rare earth compound of CeCl3 on the kinetic process, composition, microstructure and mechanical properties of co-permeating of solid powder boron-vanadium (B-V) was investigated. The results indicate tha...The effect of rare earth compound of CeCl3 on the kinetic process, composition, microstructure and mechanical properties of co-permeating of solid powder boron-vanadium (B-V) was investigated. The results indicate that the addition of CeCl3 to permeating agent not only has obviously catalytic effect on permeating rate, which increases by more than 40%, hut also greatly improves the hardness and abrasion resistant of the permeating layer owing to the formation of new phase of CeFe2 after Ce permeates into the layer of the part as an alloying ingredient. It is believed that rare earth elements accelerate the permeating rate of B and V by increasing the potentials of B and V of the agent, activating the surface of the workpiece, and decreasing the activation energy of diffusion of the B and V atoms.展开更多
The title compound was synthesized by means of direction. Its composition was determined by TG and ICP. The studies of IR and XRD indicate that the compound has the Keggin structure. The rare earth chemical thermal di...The title compound was synthesized by means of direction. Its composition was determined by TG and ICP. The studies of IR and XRD indicate that the compound has the Keggin structure. The rare earth chemical thermal diffusion of the complex also was studied. The results show that the rare earth element Gd can permeate into the surface, interface and the body cavity of the prepared material. The results of TG-DTA show that the stable temperature is improved and the conductivity of the permeated sample is 3.05 S·cm -1, which is 4.67×106 times higher than that of the parent K_7[BNi(OH_2)W_ 11O_ 39]·11H_2O.展开更多
In layered optimization scheme and solid state cathodoluminescence, silicon oxide plays a very important role in obtaining high energy hot electrons to excite luminescent centers or organic luminescent ma terials. The...In layered optimization scheme and solid state cathodoluminescence, silicon oxide plays a very important role in obtaining high energy hot electrons to excite luminescent centers or organic luminescent ma terials. The acceleration ability of electrons of SiO2 and ZnS was compared through the variation of emission intensity based on ZnS：Er phosphor during the reverse of polarity of sinusoidal voltage. The ratio of maximum emission intensity under positive and negative half period is 2.18. This result not only demonstrates that parts of primary electron comes from electrode, but electrons in conduction band of SiO2 can be heated to higher energy than that of ZnS.展开更多
The acceleration ability of electrons in SiO2 and ZnS was compared through the variation of emission intensity based on ZnS ： Er electroluminescence during the reverse of polarity of sinusoidal voltage. In order to a...The acceleration ability of electrons in SiO2 and ZnS was compared through the variation of emission intensity based on ZnS ： Er electroluminescence during the reverse of polarity of sinusoidal voltage. In order to avoid the influence of work function of electrode, cathodal and anodal materials were ITO （indium tin oxide）. The ratio of maximum emission intensity under positive and negative half period is 2.18. This result demonstrates that the electron acceleration ability of SiO2 is 2.18 times stronger than that of ZnS.展开更多
文摘The effect of rare earth compound of CeCl3 on the kinetic process, composition, microstructure and mechanical properties of co-permeating of solid powder boron-vanadium (B-V) was investigated. The results indicate that the addition of CeCl3 to permeating agent not only has obviously catalytic effect on permeating rate, which increases by more than 40%, hut also greatly improves the hardness and abrasion resistant of the permeating layer owing to the formation of new phase of CeFe2 after Ce permeates into the layer of the part as an alloying ingredient. It is believed that rare earth elements accelerate the permeating rate of B and V by increasing the potentials of B and V of the agent, activating the surface of the workpiece, and decreasing the activation energy of diffusion of the B and V atoms.
文摘The title compound was synthesized by means of direction. Its composition was determined by TG and ICP. The studies of IR and XRD indicate that the compound has the Keggin structure. The rare earth chemical thermal diffusion of the complex also was studied. The results show that the rare earth element Gd can permeate into the surface, interface and the body cavity of the prepared material. The results of TG-DTA show that the stable temperature is improved and the conductivity of the permeated sample is 3.05 S·cm -1, which is 4.67×106 times higher than that of the parent K_7[BNi(OH_2)W_ 11O_ 39]·11H_2O.
文摘In layered optimization scheme and solid state cathodoluminescence, silicon oxide plays a very important role in obtaining high energy hot electrons to excite luminescent centers or organic luminescent ma terials. The acceleration ability of electrons of SiO2 and ZnS was compared through the variation of emission intensity based on ZnS：Er phosphor during the reverse of polarity of sinusoidal voltage. The ratio of maximum emission intensity under positive and negative half period is 2.18. This result not only demonstrates that parts of primary electron comes from electrode, but electrons in conduction band of SiO2 can be heated to higher energy than that of ZnS.
文摘The acceleration ability of electrons in SiO2 and ZnS was compared through the variation of emission intensity based on ZnS ： Er electroluminescence during the reverse of polarity of sinusoidal voltage. In order to avoid the influence of work function of electrode, cathodal and anodal materials were ITO （indium tin oxide）. The ratio of maximum emission intensity under positive and negative half period is 2.18. This result demonstrates that the electron acceleration ability of SiO2 is 2.18 times stronger than that of ZnS.
