Nano-sized TiO2 doped La^3+ , was used as photocatalysis to degrade polyethylene (PE) film in solid-state reaction. It made PE lose its mass fraction of 14.5%, and formed more quantities of CO2 and more wax yields ...Nano-sized TiO2 doped La^3+ , was used as photocatalysis to degrade polyethylene (PE) film in solid-state reaction. It made PE lose its mass fraction of 14.5%, and formed more quantities of CO2 and more wax yields after UV irradiation for 288 h. SEM imagines displayed more and bigger holes and pits in the PE film. FT-IR spectra showed that there is a lower absorbance of groups of - CH2 and - CH3 in PE/ TiO2 and 0. 1% La2O3/TiO2/PE composite materials than that in PE film sample of photodegradation, and more carbonyl groups in PE/0.1% LaEO3/TiO2. La^3+ doping TiO2 improves TiO2 activities of oxidation and erosion of PE film under UV irradiation.展开更多
文摘Nano-sized TiO2 doped La^3+ , was used as photocatalysis to degrade polyethylene (PE) film in solid-state reaction. It made PE lose its mass fraction of 14.5%, and formed more quantities of CO2 and more wax yields after UV irradiation for 288 h. SEM imagines displayed more and bigger holes and pits in the PE film. FT-IR spectra showed that there is a lower absorbance of groups of - CH2 and - CH3 in PE/ TiO2 and 0. 1% La2O3/TiO2/PE composite materials than that in PE film sample of photodegradation, and more carbonyl groups in PE/0.1% LaEO3/TiO2. La^3+ doping TiO2 improves TiO2 activities of oxidation and erosion of PE film under UV irradiation.