New cadmium and rare earth metal tungstates with the formula Cd0.25RE0.50 0.25WO4 (RE=Nd, Sin, Eu, Gd, D-statistical distrib- uted vacancies in cation sublattice) were synthesized by the solid-state reaction between...New cadmium and rare earth metal tungstates with the formula Cd0.25RE0.50 0.25WO4 (RE=Nd, Sin, Eu, Gd, D-statistical distrib- uted vacancies in cation sublattice) were synthesized by the solid-state reaction between CdWO4 and corresponding RE2W209. The obtained phases crystallize in the scheelite type structure. The Cd0.25RE0.5 0.25WO4 compounds were characterized by X-ray diffractometer (XRD), (DTA-TG), infrared (IR) and EPR methods.展开更多
文摘New cadmium and rare earth metal tungstates with the formula Cd0.25RE0.50 0.25WO4 (RE=Nd, Sin, Eu, Gd, D-statistical distrib- uted vacancies in cation sublattice) were synthesized by the solid-state reaction between CdWO4 and corresponding RE2W209. The obtained phases crystallize in the scheelite type structure. The Cd0.25RE0.5 0.25WO4 compounds were characterized by X-ray diffractometer (XRD), (DTA-TG), infrared (IR) and EPR methods.