Granitic pegmatites are commonly thought to form by fractional crystallization or by liquid immiscibility of granitic magma; however, these proposals are based mainly on analyses of fluid and melt inclusions. Here, we...Granitic pegmatites are commonly thought to form by fractional crystallization or by liquid immiscibility of granitic magma; however, these proposals are based mainly on analyses of fluid and melt inclusions. Here, we use the Jiajika pegmatite deposit, the largest spodumene deposit in Asia, as a case study to investigate ore forming processes using isotope dating. Dating of a single granite sample from the Jiajika deposit using multiple methods gave a zircon U-Pb SHRIMP age of 208.4 ~ 3.9 Ma, an 4~Ar/39Ar age for muscovite of 182.9 ~ 1.7 Ma, and an 4~Ar/39Ar age for biotite of 169.9 ＋ 1.6 Ma. Based on these dating results and the 4~Ar/39Ar age of muscovite from the Jiajika pegmatite, a temperature-time cooling track for the Jiajika granite was constructed using closure temperatures of the different isotope systems. This track indicates that the granite cooled over ^-40 m. y., with segregation of the pegmatite fluid from the granitic magma at a temperature of ~700~C. This result suggests that the Jiajika pegmatite formed not by fractional crystallization, but by segregation of an immiscible liquid from the granitic magma. When compared with fractional crystallization, the relatively early timing of segregation of an immiscible liquid from a granitic magma can prevent the precipitation of ore-forming elements during crystallization, and suggests that liquid immiscibility could be an important ore-forming process for rare metal pegmatities. We also conclude that isotope dating is a method that can potentially be used to determine the dominant ore-forming processes that occurred during the formation of granite-related ore deposits, and suggest that this method can be employed to determine the formation history of the W-Sn ore deposits found elsewhere within the Nanling Metallogenic Belt.展开更多
Objective The Huashi Village in Xinglong County of Hebei Province is located in the Yanshan subsidence zone in the central eastern North China Plate, which is 137 km away from Beijing City （Fig. la）. This area has ...Objective The Huashi Village in Xinglong County of Hebei Province is located in the Yanshan subsidence zone in the central eastern North China Plate, which is 137 km away from Beijing City （Fig. la）. This area has undergone large -scale magmatic intrusion affected by the tectonic compression of the Pacific Plate in the Mesozoic （known as the Yanshanian movement） to form many alkaline rocks such as the Wulingshan rock mass. Previous studies have conducted petrological research and reconnaissance survey of rare metal ores in this area （Tian Shuzhang and Guo Zongshan, 1981; Xu Baoling et al., 1996）. In 2016, the Qinhuangdao Mineral and Hydrology Engineering Geological Brigade of Hebei Bureau of Geology and Mineral Resources Exploration implemented the project of Reconnaissance of Rare Metal Ores Including Rubidium in Huashi Village of Xinglong County, Hebei Province, and discovered super-large rare metal deposits of rubidium and biobium in the Madi alkali feldspar granite bodies in the Huashi Village to achieve great breakthrough of rare metal ore prospecting.展开更多
Many rare metal and REE deposits have been found in the Altay orogenic belt,on the northern margin of the Tarim massif and in the Kunlun-Altun orogenic belt, constituting threevery important rare metal-REE mineralizat...Many rare metal and REE deposits have been found in the Altay orogenic belt,on the northern margin of the Tarim massif and in the Kunlun-Altun orogenic belt, constituting threevery important rare metal-REE mineralization belts in western China. These deposits belong tovarious genetic types with complex ore-forming mechanism, and were formed in certain mineralizationepochs. On the basis of a systematic sum-up of geologic and geochemical achievements and^(40)Ar-^(39)Ar ages of potassium-rich minerals as well as whole-rock Rb-Sr dating results, theauthors systematically analyzed the spatial distribution and mineralization epochs of rare metal-REEdeposits in Xinjiang, northwestern China, and concluded that although the Hercynian rare metal-REEmineralizations in this area are very important, pre- and post-Hercynian (especially Indosinian andearly Yanshanian) rare metal-REE mineralizations also have important theoretical and economicsignificance.展开更多
The northern Guangxi region is an important rare metal, rare earth metal and polymetallic metallogenic province. In the region there exist five metallogenic series and two metallogenic subseries, whose metallogenesis ...The northern Guangxi region is an important rare metal, rare earth metal and polymetallic metallogenic province. In the region there exist five metallogenic series and two metallogenic subseries, whose metallogenesis shows features of polycyclic spiral evolution throughout the geological history. As far as various cycles are concerned, mantle-derived ore substances were reduced while crust-derived ore substances increased from early to late timesfin the whole geological evolutionary history, mantle-derived substances decreased gradually while crust-derived ones increased. Meanwhile ore element associations became more and more varied. In terms of space, mineralization migrated from the old basement outwards, i.e. from west to east during the Precambrian, and from north to south during the Phanerozoic, and again from east to west during the Yanshanian.展开更多
Intrusion-related gold deposits(IRGDs)occur in the Eastern Desert(ED)of Egypt within magmatic districts that are exploited for tungsten and tin mineralization.IRGDs and intrusion-related rare metal deposits(IRRMDs)are...Intrusion-related gold deposits(IRGDs)occur in the Eastern Desert(ED)of Egypt within magmatic districts that are exploited for tungsten and tin mineralization.IRGDs and intrusion-related rare metal deposits(IRRMDs)are almost invariably linked with the late to post collisional Younger Granites(YGs)that have three successive phases(Ⅰ,ⅡandⅢ).At~635–630 Ma,the ED underwent a transition in deformation style from compressional to extensional and a switch from subduction with crustal thickening to delamination with crustal thinning.This transition was concurrent with the emplacement of a short magmatic pulse(~635–630 Ma)that represents a transition between orogenic gold deposits and IRGDs.K-rich calc alkaline granites(phaseⅠandⅡof the YGs)hosting IRGDs like the Hangalia deposit were emplaced during the time span 630–610 Ma.Alkaline magmatism began at 610 Ma,coexisting with the K-rich calc-alkaline magmatism over the 610–590 Ma time span,where the Fawakhir(598±3 Ma)and Um Had(596±2 Ma)granites that host the IRGDs were emplaced.In time,the alkaline magmatism became more alkaline giving rise to phaseⅢof the YGs that hosts IRRMDs.A distinct metallogenic epoch comprising both IRGDs and IRRMDs,was undergoing extreme growth at~600 Ma.展开更多
The Zhawulong granitic pegmatite lithium deposit is located in the Ganzi-Songpan orogenic belt.Fluid inclusions in spodumene and coexisting quartz were studied to understand the cooling path and evolution of fluid wit...The Zhawulong granitic pegmatite lithium deposit is located in the Ganzi-Songpan orogenic belt.Fluid inclusions in spodumene and coexisting quartz were studied to understand the cooling path and evolution of fluid within albite–spodumene pegmatite.There are three distinguishable types of fluid inclusions:crystal-rich,CO2–NaCl–H2 O,and NaCl–H2 O.At more than 500°C and 350~480 MPa,crystal-rich fluid inclusions were captured during the pegmatitic magma-hydrothermal transition stage,characterized by a dense hydrous alkali borosilicate fluid with a carbonate component.Between 412°C and 278°C,CO2–Na Cl–H2 Ofluid inclusions developed in spodumene(I)and quartz(II)with a low salinity(3.3–11.9 wt%NaCl equivalent)and a high volatile content,which represent the boundary between the transition stage and the hydrothermal stage.The subsequentNaCl–H2 Ofluid inclusions from the hydrothermal stage,between 189°C and 302°C,have a low salinity(1.1–13.9 wt%NaCl equivalent).The various types of fluid inclusions reveal the P–T conditions of pegmatite formation,which marks the transition process from magmatic to hydrothermal.The oreforming fluids from the Zhawulong deposit have many of the same characteristics as those from the Jiajika lithium deposit.The ore-forming fluid provided not only materials for crystallization of rare metal minerals,such as spodumene and beryl,but also the ideal conditions forthe growth of ore minerals.Therefore,this area has favorable conditions for lithium enrichment and excellent prospecting potential.展开更多
基金supported by grants from the National Natural Science Foundation of China (40702014)the China Postdoctoral Science Foundation (2008044018,200902580)+1 种基金the Chinese SinoProbe Project (SinoProbe-03-01)the National Nonprofit Institute Research Grant of IMR,GAGS(K1001)
文摘Granitic pegmatites are commonly thought to form by fractional crystallization or by liquid immiscibility of granitic magma; however, these proposals are based mainly on analyses of fluid and melt inclusions. Here, we use the Jiajika pegmatite deposit, the largest spodumene deposit in Asia, as a case study to investigate ore forming processes using isotope dating. Dating of a single granite sample from the Jiajika deposit using multiple methods gave a zircon U-Pb SHRIMP age of 208.4 ~ 3.9 Ma, an 4~Ar/39Ar age for muscovite of 182.9 ~ 1.7 Ma, and an 4~Ar/39Ar age for biotite of 169.9 ＋ 1.6 Ma. Based on these dating results and the 4~Ar/39Ar age of muscovite from the Jiajika pegmatite, a temperature-time cooling track for the Jiajika granite was constructed using closure temperatures of the different isotope systems. This track indicates that the granite cooled over ^-40 m. y., with segregation of the pegmatite fluid from the granitic magma at a temperature of ~700~C. This result suggests that the Jiajika pegmatite formed not by fractional crystallization, but by segregation of an immiscible liquid from the granitic magma. When compared with fractional crystallization, the relatively early timing of segregation of an immiscible liquid from a granitic magma can prevent the precipitation of ore-forming elements during crystallization, and suggests that liquid immiscibility could be an important ore-forming process for rare metal pegmatities. We also conclude that isotope dating is a method that can potentially be used to determine the dominant ore-forming processes that occurred during the formation of granite-related ore deposits, and suggest that this method can be employed to determine the formation history of the W-Sn ore deposits found elsewhere within the Nanling Metallogenic Belt.
基金financially supported by the project of Reconnaissance of Rare Metal Ores Including Rubidium in Huashi Village of Xinglong County, Hebei Province from the Hebei Bureau of Geology and Mineral Resources Exploration (grant No.2015017)
文摘Objective The Huashi Village in Xinglong County of Hebei Province is located in the Yanshan subsidence zone in the central eastern North China Plate, which is 137 km away from Beijing City （Fig. la）. This area has undergone large -scale magmatic intrusion affected by the tectonic compression of the Pacific Plate in the Mesozoic （known as the Yanshanian movement） to form many alkaline rocks such as the Wulingshan rock mass. Previous studies have conducted petrological research and reconnaissance survey of rare metal ores in this area （Tian Shuzhang and Guo Zongshan, 1981; Xu Baoling et al., 1996）. In 2016, the Qinhuangdao Mineral and Hydrology Engineering Geological Brigade of Hebei Bureau of Geology and Mineral Resources Exploration implemented the project of Reconnaissance of Rare Metal Ores Including Rubidium in Huashi Village of Xinglong County, Hebei Province, and discovered super-large rare metal deposits of rubidium and biobium in the Madi alkali feldspar granite bodies in the Huashi Village to achieve great breakthrough of rare metal ore prospecting.
基金This study was supported by China's National Key Basic Research Projects“Large-scale metallization and prognostication of large scale metallogenetic concentrated area"(No.G1999043201)“Isotopic Research of Main Metallogenetic Events in Xinjiang”(No.2001CB409810).
文摘Many rare metal and REE deposits have been found in the Altay orogenic belt,on the northern margin of the Tarim massif and in the Kunlun-Altun orogenic belt, constituting threevery important rare metal-REE mineralization belts in western China. These deposits belong tovarious genetic types with complex ore-forming mechanism, and were formed in certain mineralizationepochs. On the basis of a systematic sum-up of geologic and geochemical achievements and^(40)Ar-^(39)Ar ages of potassium-rich minerals as well as whole-rock Rb-Sr dating results, theauthors systematically analyzed the spatial distribution and mineralization epochs of rare metal-REEdeposits in Xinjiang, northwestern China, and concluded that although the Hercynian rare metal-REEmineralizations in this area are very important, pre- and post-Hercynian (especially Indosinian andearly Yanshanian) rare metal-REE mineralizations also have important theoretical and economicsignificance.
基金This research was supported by the Chinese Foundation for Development of Geological Science and Technology (Project 49273162)the National Natural Science Foundation of China(Project 49273162)
文摘The northern Guangxi region is an important rare metal, rare earth metal and polymetallic metallogenic province. In the region there exist five metallogenic series and two metallogenic subseries, whose metallogenesis shows features of polycyclic spiral evolution throughout the geological history. As far as various cycles are concerned, mantle-derived ore substances were reduced while crust-derived ore substances increased from early to late timesfin the whole geological evolutionary history, mantle-derived substances decreased gradually while crust-derived ones increased. Meanwhile ore element associations became more and more varied. In terms of space, mineralization migrated from the old basement outwards, i.e. from west to east during the Precambrian, and from north to south during the Phanerozoic, and again from east to west during the Yanshanian.
文摘Intrusion-related gold deposits(IRGDs)occur in the Eastern Desert(ED)of Egypt within magmatic districts that are exploited for tungsten and tin mineralization.IRGDs and intrusion-related rare metal deposits(IRRMDs)are almost invariably linked with the late to post collisional Younger Granites(YGs)that have three successive phases(Ⅰ,ⅡandⅢ).At~635–630 Ma,the ED underwent a transition in deformation style from compressional to extensional and a switch from subduction with crustal thickening to delamination with crustal thinning.This transition was concurrent with the emplacement of a short magmatic pulse(~635–630 Ma)that represents a transition between orogenic gold deposits and IRGDs.K-rich calc alkaline granites(phaseⅠandⅡof the YGs)hosting IRGDs like the Hangalia deposit were emplaced during the time span 630–610 Ma.Alkaline magmatism began at 610 Ma,coexisting with the K-rich calc-alkaline magmatism over the 610–590 Ma time span,where the Fawakhir(598±3 Ma)and Um Had(596±2 Ma)granites that host the IRGDs were emplaced.In time,the alkaline magmatism became more alkaline giving rise to phaseⅢof the YGs that hosts IRRMDs.A distinct metallogenic epoch comprising both IRGDs and IRRMDs,was undergoing extreme growth at~600 Ma.
基金funded by the National Natural Science Foundation of China(No.41703048,41872096)the Chinese National Nonprofit Institute Research Grant of CAGS,CGS(YYWF201520,JYYWF201814)the China Geological Survey(DD20160055,DD20190173)
文摘The Zhawulong granitic pegmatite lithium deposit is located in the Ganzi-Songpan orogenic belt.Fluid inclusions in spodumene and coexisting quartz were studied to understand the cooling path and evolution of fluid within albite–spodumene pegmatite.There are three distinguishable types of fluid inclusions:crystal-rich,CO2–NaCl–H2 O,and NaCl–H2 O.At more than 500°C and 350~480 MPa,crystal-rich fluid inclusions were captured during the pegmatitic magma-hydrothermal transition stage,characterized by a dense hydrous alkali borosilicate fluid with a carbonate component.Between 412°C and 278°C,CO2–Na Cl–H2 Ofluid inclusions developed in spodumene(I)and quartz(II)with a low salinity(3.3–11.9 wt%NaCl equivalent)and a high volatile content,which represent the boundary between the transition stage and the hydrothermal stage.The subsequentNaCl–H2 Ofluid inclusions from the hydrothermal stage,between 189°C and 302°C,have a low salinity(1.1–13.9 wt%NaCl equivalent).The various types of fluid inclusions reveal the P–T conditions of pegmatite formation,which marks the transition process from magmatic to hydrothermal.The oreforming fluids from the Zhawulong deposit have many of the same characteristics as those from the Jiajika lithium deposit.The ore-forming fluid provided not only materials for crystallization of rare metal minerals,such as spodumene and beryl,but also the ideal conditions forthe growth of ore minerals.Therefore,this area has favorable conditions for lithium enrichment and excellent prospecting potential.
