Roles of rare earth oxide （RE2O3） additives in millimeter-wave（MM） sintering of AIN were investigated from the standpoints of phase diagram, heating characteristics of rare earth oxides, and morphology of intergra...Roles of rare earth oxide （RE2O3） additives in millimeter-wave（MM） sintering of AIN were investigated from the standpoints of phase diagram, heating characteristics of rare earth oxides, and morphology of intergranular oxide phase. In the millimeter-wave sintering of AIN, densification temperature decreased with the decrease of the ionic radius of rare earth ion and was closely related with the eutectic temperature in the RE2Oa-Al2O3 binary system. The lowest densification temperature in the millimeter-wave sintering of AIN with Yb2O3 additive was attributed to the largest heating rate of Yb2O3-Al2O3 binary oxide under millimeter-wave radiation. Furthermore, the lowest densification temperature could be attained while selecting the Yb2O3 content so as to form the intergranular phase with the eutectic composition in the Yb2O3-Al2O3 binary system. The result showed good agreement with the above mentioned during the sintering of Si3N4 with Yb2O3-Al2O3 additive. From TEM observation, it was verified that film-like intergranular oxide phase formed under millimeter-wave radiation was favorable for attaining high thermal conductivity in the Yb2O3 added AINs.展开更多
Cerium contained conversion films were deposited on LC4 aluminum alloy usingsquare wave pulse (SWP) in a CeCl_3 solution with KMnO_4 as the oxidant. Energy dispersivespectroscopy (EDS) and scanning electron microscopy...Cerium contained conversion films were deposited on LC4 aluminum alloy usingsquare wave pulse (SWP) in a CeCl_3 solution with KMnO_4 as the oxidant. Energy dispersivespectroscopy (EDS) and scanning electron microscopy (SEM) were adopted to study the composition andthe morphology of the film. It is found that the film is composed of Al, Zn, Cu, and small amount ofcerium. The polarization curves of the specimens treated with SWP technique measured in 3.5% (massfraction) NaCl solution reveal that the film thus formed inhibits both the anodic and cathodicprocess of the corrosion of the specimen. The immersion tests of treated specimens in 3.5% NaClsolution indicate that the corrosion resistance of the SWP treated specimen is better than that ofthe untreated and is equivalent to or even better than that of the traditionally electro-chemicallytreated specimens.展开更多
基金the Grant-in-Aid for Scientific Research on Priority Area (18070004) of MEXT, Japan
文摘Roles of rare earth oxide （RE2O3） additives in millimeter-wave（MM） sintering of AIN were investigated from the standpoints of phase diagram, heating characteristics of rare earth oxides, and morphology of intergranular oxide phase. In the millimeter-wave sintering of AIN, densification temperature decreased with the decrease of the ionic radius of rare earth ion and was closely related with the eutectic temperature in the RE2Oa-Al2O3 binary system. The lowest densification temperature in the millimeter-wave sintering of AIN with Yb2O3 additive was attributed to the largest heating rate of Yb2O3-Al2O3 binary oxide under millimeter-wave radiation. Furthermore, the lowest densification temperature could be attained while selecting the Yb2O3 content so as to form the intergranular phase with the eutectic composition in the Yb2O3-Al2O3 binary system. The result showed good agreement with the above mentioned during the sintering of Si3N4 with Yb2O3-Al2O3 additive. From TEM observation, it was verified that film-like intergranular oxide phase formed under millimeter-wave radiation was favorable for attaining high thermal conductivity in the Yb2O3 added AINs.
基金This work was financially supported by the National Natural Science Foundation of China (No. 59771067) and the National Key Laboratory of New Metal Materials.
文摘Cerium contained conversion films were deposited on LC4 aluminum alloy usingsquare wave pulse (SWP) in a CeCl_3 solution with KMnO_4 as the oxidant. Energy dispersivespectroscopy (EDS) and scanning electron microscopy (SEM) were adopted to study the composition andthe morphology of the film. It is found that the film is composed of Al, Zn, Cu, and small amount ofcerium. The polarization curves of the specimens treated with SWP technique measured in 3.5% (massfraction) NaCl solution reveal that the film thus formed inhibits both the anodic and cathodicprocess of the corrosion of the specimen. The immersion tests of treated specimens in 3.5% NaClsolution indicate that the corrosion resistance of the SWP treated specimen is better than that ofthe untreated and is equivalent to or even better than that of the traditionally electro-chemicallytreated specimens.
