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New Zircon U-Pb Age of the Super-Large Lijiagou Spodumene Deposit in Songpan Garze Fold Belt, Eastern Tibet: Implications for Early Jurassic Rare-Metal Polymetallic Event 被引量:8
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作者 FEI Guangchun TIAN Jingjing +4 位作者 YANG Jiyi GAO Jianguo TANG Wenchun LI Jian GU Chenghui 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2018年第3期1274-1275,共2页
Objective The Songpan-Garze Fold Belt(SGFB),located in the eastern part of the Tibet Plateau and west of the Sichuan Basin,is an important pegmatite province in China.Some famous pegmatite type deposits occur in the S... Objective The Songpan-Garze Fold Belt(SGFB),located in the eastern part of the Tibet Plateau and west of the Sichuan Basin,is an important pegmatite province in China.Some famous pegmatite type deposits occur in the SGFB,including the Xuebaoding,Jiajika,Keeryin rare metal deposits and Danba muscovite deposit(Li Jiankang et al.,2015).The newly discovered super-large Lijiagou 展开更多
关键词 New Zircon U-Pb Age of the Super-Large Lijiagou Jurassic rare-metal Polymetallic Event
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Geochemistry, geochronology and mineralization of the rare-metal granites in the Daping Ta-Nb deposit, Fujian Province, South China 被引量:2
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作者 WANG Jinrong HU Yongbin +4 位作者 HUANG Shufeng CHEN Bin YE Yuansheng LUO Xiaohua Lv Xinbiao 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2017年第S1期289-290,共2页
1 Introduction Rare-metal granites are widely distributed in South China.The Daping porphyritic granitic Ta-Nb deposit,located in the Yongding area of south Fujian province,South China,is a large rare-metal deposit re... 1 Introduction Rare-metal granites are widely distributed in South China.The Daping porphyritic granitic Ta-Nb deposit,located in the Yongding area of south Fujian province,South China,is a large rare-metal deposit recently discovered.Few studies have been made of its petrology,mineralogy,geochemistry,chronology and metallogeny.In recent years,several exploratory drillings have been done in this deposit.These drilling holes,from 380 to 600 展开更多
关键词 area In South China geochronology and mineralization of the rare-metal granites in the Daping Ta-Nb deposit Fujian Province GEOCHEMISTRY Ta
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Geochemistry and Petrogenesis of Late Ediacaran Rare-metal Albite Granites of the Arabian-Nubian Shield 被引量:1
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作者 Bassam A.ABUAMARAH Mokhles K.AZER +2 位作者 Paul D.ASIMOW Habes GHREFAT Heba S.MUBARAK 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2021年第2期459-480,共22页
The Abu Dabbab albite granite(ADAG),in the central Eastern Desert of Egypt,hosts the most significant rare metal ore deposit in the northern part of the Neoproterozoic Arabian-Nubian Shield.Here,we report detailed fie... The Abu Dabbab albite granite(ADAG),in the central Eastern Desert of Egypt,hosts the most significant rare metal ore deposit in the northern part of the Neoproterozoic Arabian-Nubian Shield.Here,we report detailed field,petrographic,mineralogical and geochemical investigation of the ADAG,an isolated stock-like granitic body with sharp intrusive contacts against metamorphic country rocks,probably emplaced at about 600 Ma.The fine-grained porphyritic upper unit is a preserved remnant of the shallowly-emplaced apex of the magma chamber,whereas the medium-grained lower unit crystallized at deeper levels under subvolcanic conditions.The peraluminous leucocratic ADAG shares common geochemical characteristics with post-collisional intraplate A-type magmas.In addition to the conspicuous enrichment in Na2O,the ADAG is remarkable for its anomalous concentrations of Ta,Nb,Li,Hf,Ga,Sn,Zn and heavy rare-earth elements.Nb-Ta minerals in the ADAG are mixed with Fe-Mn oxides,forming black patches that increase in abundance toward of the base of the intrusion.Columbite-tantalite,cassiterite and wolframite are the most important ore minerals.Pronounced negative Eu anomalies(Eu/Eu*=0.10–0.24)reflect extreme magmatic fractionation and perhaps the effects of late fluid-rock interaction.The ADAG was most likely generated by partial melting of the juvenile middle crust of the ANS as the geotherm was elevated by erosional uplift following lithospheric delamination and it was emplaced at the intersection of lineations of structural weakness.Although formation of the ADAG and its primary enrichment in rare metals are essentially due to magmatic processes,late-stage metasomatism caused limited redistribution of rare metals.Fluid-driven subsolidus modification was limited to the apex of the magma chamber and drove development of greisen,amazonite,and quartz veins along fracture systems. 展开更多
关键词 AMAZONITE GREISEN rare-metal bearing granite stockscheider pegmatite tetrad effect post-collisional Arabian-Nubian Shield
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The Petrological and Geochemical Evolution of Ediacaran Rare-Metal Bearing A-type Granites from the Jabal Aja Complex, Northern Arabian Shield, Saudi Arabia 被引量:1
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作者 Shehta E.ABDALLAH Mokhles K.AZER Abdullah S.AL SHAMMARI 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2020年第3期743-762,共20页
New fieldwork, mineralogical and geochemical data and interpretations are presented for the rare-metal bearing A-type granites of the Aja intrusive complex(AIC) in the northern segment of the Arabian Shield. This comp... New fieldwork, mineralogical and geochemical data and interpretations are presented for the rare-metal bearing A-type granites of the Aja intrusive complex(AIC) in the northern segment of the Arabian Shield. This complex is characterized by discontinuous ring-shaped outcrops cut by later faulting. The A-type rocks of the AIC are late Neoproterozoic post-collisional granites, including alkali feldspar granite, alkaline granite and peralkaline granite. They represent the outer zones of the AIC, surrounding a core of older rocks including monzogranite, syenogranite and granophyre granite. The sharp contacts between A-type granites of the outer zone and the different granitic rocks of the inner zone suggest that the AIC was emplaced as different phases over a time interval, following complete crystallization of earlier batches. The A-type granites represent the late intrusive phases of the AIC, which were emplaced during tectonic extension, as shown by the emplacement of dykes synchronous with the granite emplacement and the presence of cataclastic features. The A-type granites consist of K-feldspars, quartz, albite, amphiboles and sodic pyroxene with a wide variety of accessory minerals, including Fe-Ti oxides, zircon, allanite, fluorite, monazite, titanite, apatite, columbite, xenotime and epidote. They are highly evolved(71.3–75.8 wt% SiO2) and display the typical geochemical characteristics of post-collisional, within-plate granites. They are rare-metal granites enriched in total alkalis, Nb, Zr, Y, Ga, Ta, REE with low CaO, MgO, Ba, and Sr. Eu-negative anomalies(Eu/Eu* = 0.17–0.37) of the A-type granites reflect extreme magmatic fractionation and perhaps the effects of late fluid-rock interactions. The chemical characteristics indicate that the A-type granites of the AIC represent products of extreme fractional crystallization involving alkali feldspar, quartz and, to a lesser extent, ferromagnesian minerals. The parent magma was derived from the partial melting of a juvenile crustal protolith with a mantle contribution. Accumulation of residual volatile-rich melt and exsolved fluids in the late stage of the magma evolution produced pegmatite and quartz veins that cut the peripheries of the AIC. Post-magmatic alteration related to the final stages of the evolution of the A-type granitic magma, indicated by alterations of sodic amphibole and sodic pyroxene, hematitization and partial albitization. 展开更多
关键词 ring complex rare-metal bearing granites sodic amphibole sodic pyroxene within-plate Arabian Shield
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Petrogenetic Peculiarities of Rare-Metal Granite of Limu,Guangxi
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作者 Xu Qidong Xia WeihuaChina University of Geosciences , Wuhan 430074 《Journal of Earth Science》 SCIE CAS CSCD 1992年第1期67-74,共8页
Limu granite massif is a rather typical Mesozoic rare-metal granite in South China . Studying Limu granite massif has important petrological significance for understanding the genesis of rare-metal granites .This pape... Limu granite massif is a rather typical Mesozoic rare-metal granite in South China . Studying Limu granite massif has important petrological significance for understanding the genesis of rare-metal granites .This paper deals with the typical petrographic characteristics and peculiarity of REE in massif , and discusses the genesis of Limu granite massif in terms of analysis of these characteristics . It is suggested that Limu granite massif is derivative product of a high ordered superimposed -remelting granitic magma . 展开更多
关键词 rare-metal granite superimposed-remelting magma rimmed texture snowball texture REE Limu .
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Geology and Mineral Chemistry of Uranium-and Thorium-bearing Minerals in Rare-Metal(NYF)Pegmatites of Um Solimate,South Eastern Desert,Egypt
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作者 Mohamed A.ALI Ahmed E.ABDEL GAWAD Mohamed M.GHONEIM 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2021年第5期1568-1582,共15页
The garnet muscovite granitic pegmatite of Um Solimate,in southern Egypt,represents a promising asset for strategic and economic metals,especially Bi-Ni-Ag-Nb-Ta as well as U and Th.The ore bodies occur as large masse... The garnet muscovite granitic pegmatite of Um Solimate,in southern Egypt,represents a promising asset for strategic and economic metals,especially Bi-Ni-Ag-Nb-Ta as well as U and Th.The ore bodies occur as large masses,pockets and/or veins of very coarse-grained pegmatites,which consist mainly of K-feldspar,quartz and albite with subordinate muscovite,garnet,and biotite.Radiometric data revealed that e U-and e Th-contents of the pegmatites reach up to 39 ppm and 82 ppm,respectively.The studied pegmatites are enriched in primary U and Th minerals(uraninite,coffinite,thorianite and uranothorite)as well as Hf-rich zircon and monazite,which give rise to anomalous radioactive zones.Niobium-tantalium-bearing minerals(i.e.ferrocolumbite,microlite and uranopyrochlore),xenotime,barite,galena,fluorite,and apatite are ubiquitous,and,consequently,the studied pegmatites belong tothe Niobium-Yttrium-Fluorine-type(NYF)family.The noble metal mineralization includes argentite(Ag_(2)S),native Ni and Bi as well as bismite and bismoclite.In addition,beryl and tourmaline are observed in pegmatites near the contact with metasediments and ultramafic bodies.The observed compositional variations of Ta/(Ta+Nb)and Mn/(Mn+Fe)ratios in columbite(0.08-0.45 and 0.11-0.57,respectively)and Hf contents in zircon(3.54-6.46 wt%)may reflectan extreme degree of magmatic fractionation leading to formation of the pegmatite orebody. 展开更多
关键词 radioactivity rare-metal mineralization PEGMATITES U/Th-bearing minerals Um Solimate EGYPT
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REE Tetrad Effects in Rare-metal Granites 被引量:9
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作者 赵振华 AKIMASA MASUDA M.B.SHABANI 《Chinese Journal Of Geochemistry》 EI CAS 1993年第3期206-219,共14页
Described in this paper are the characteristics of tetrad effects of REE in rare-metal granites.Based on the analytical data and experimental geochemical data available,it is pointed out that the tetrad effects of REE... Described in this paper are the characteristics of tetrad effects of REE in rare-metal granites.Based on the analytical data and experimental geochemical data available,it is pointed out that the tetrad effects of REE in the granites are produced in the metal-fluid system.Intense fractional crystallization of granitic melt(containing REE accessary minerals)and its interaction with volatile-rich(F,Cl)fluid are the major factors leading to the tetrad effects of REE.From this,this paper presents a composite genetic model for high-degree fractional crystallization-volatile-rich fluid metasomatism of rare-metal granites.With the model,quantitative calculations have been made.Meanwhile,it is pointed out that the tetrad effects of REE can be used as an important indicator to distinguish mineralized granites from barren ones. 展开更多
关键词 花岗岩 稀土元素 成因
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Geology and mineralization of the Songpan-Ganze-West Kunlun pegmatite-type rare-metal metallogenic belt in China:An overview and synthesis 被引量:17
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作者 Jiankang LI Peng LI +3 位作者 Qinggao YAN Denghong WANG Guangli REN Xin DING 《Science China Earth Sciences》 SCIE EI CAS CSCD 2023年第8期1702-1724,共23页
The Songpan-Ganze orogenic belt on the northeastern margin of the Tibetan Plateau extends westward from the Songpan-Ganze terrain in western Sichuan to the Tianshuihai region in West Kunlun,Xinjiang.It hosts numerous ... The Songpan-Ganze orogenic belt on the northeastern margin of the Tibetan Plateau extends westward from the Songpan-Ganze terrain in western Sichuan to the Tianshuihai region in West Kunlun,Xinjiang.It hosts numerous giant spodumene pegmatite deposits and ore fields,including Jiajika and Ke’eryin in western Sichuan Province,Zhawulong on the border between the Sichuan and Qinghai Provinces,and Dahongliutan in Xinjiang Region.These form the Songpan-Ganze-West Kunlun(SP-GZ-WK) pegmatite-type rare-metal metallogenic belt.The pegmatite type rare-metal deposits in this belt are hosted in the metamorphic thermal domes in the metamorphosed flysh of the Triassic Xikang and Bayankalashan Groups.The mineralized pegmatites are intimately related to the Li-and volatile-rich two-mica granites that are peraluminous and have high(Li+Na+K)/(Mn+Fe+Mg+Ca+Ti) ratios.Pegmatites and granites in individual ore field throughout the belt typically form a cogenetic granite-pegmatite system,in which pegmatite dikes commonly surround granites.Spodumene is the predominant ore mineral in most pegmatites with limited hydrothermal alteration.In the granite-pegmatite systems,granitic magmas were emplaced under P-T conditions of 800–850°C and ~550 MPa,while spodumene crystallized in an alkaline environment.The granite-pegmatite systems share similar Sr-Nd-Hf-Li isotopic compositions to the metasediments of the Xikang and Bayankalashan Groups.The δ7Li values tend to increase from the granites to the Li-poor pegmatites,whereas the reverse is observed between the Li-poor and Li-rich pegmatites.These geochronological data suggest that the granite-pegmatite systems formed in the Late Triassic and tend to be progressively younger from the outer to the inner zones of the metallogenic belt.These characteristics show that the granitic-pegmatitic melts were derived from the anatexis of the Xikang and Bayankalashan Groups during the Paleo-Tethyan orogeny in the Late Triassic.The separation of pegmatitic melts from granitic magmas can be best explained using the Jiajika-style “melt-melt immiscibility” or the Ke’eryin-style “fractional crystallization+melt-melt immiscibility” model.High-maturity terrestrial sediments are of key importance for the anatexis that results in the granitepegmatite melts.The bidirectional tectonic stresses in the Songpan-Ganze orogenic belt may have caused the mineralization difference between the Jiajika deposit and the Ke’eryin ore field.These features indicate the controls of the combination of orogenic deformation,metapelites anatexis,and magmatic differentiation on the rare-metal mineralization of pegmatites.We suggest that pegmatites,pegmatite–parental granite,and their protoliths are important indicators for rare-metal mineralization in the SP-GZ-WK pegmatite type rare-metal metallogenic belt.Based on the widespread presence of fertile metasediments and well development of metamorphic thermal dome,highly differentiated granites,and regional zonation of pegmatites,the Zhawulong ore field is the most prospective area for rare metals and thus should be the priority for future exploration. 展开更多
关键词 Songpan-Ganze-West Kunlun metallogenic belt rare-metal deposit Granitic pegmatite SPODUMENE Metallogenic regularity
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A preliminary study of rare-metal mineralization in the Himalayan leucogranite belts, South Tibet 被引量:71
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作者 WANG RuCheng WU FuYuan +5 位作者 XIE Lei LIU XiaoChi WANG JiaMin YANG Lei LAI Wen LIU Chen 《Science China Earth Sciences》 SCIE EI CAS CSCD 2017年第9期1655-1663,共9页
The Himalayan leucogranite occurs as two extensive(>1000 km) E-W trending belts on the Tibetan Plateau with the unique features. The leucogranite comprised biotite granite, two-mica/muscovite granite, tourmaline gr... The Himalayan leucogranite occurs as two extensive(>1000 km) E-W trending belts on the Tibetan Plateau with the unique features. The leucogranite comprised biotite granite, two-mica/muscovite granite, tourmaline granite and garnet granite, which have been identified in previous studies, as well as albite granite and granitic pegmatite that were identified in this investigation. Fifteen leucogranite plutons were studied and 12 were found to contain rare-metal bearing minerals such as beryl(the representative of Be mineralization), columbite-group minerals, tapiolite, pyrochlore-microlite, fergusonite, Nb-Ta rutile(the representative of Nb-Ta mineralization), and cassiterite(the representative of Sn mineralization) mainly based on the field trip,microscope observation and microprobe analysis. The preliminary result shows that the Himalayan leucogranite is commonly related to the rare-metal mineralization and warrants future investigation. Further exploration and intensive research work is important in determining the rare-metal resource potential of this area. 展开更多
关键词 Leucogranite Beryl Columbite-group minerals Cassiterite rare-metal mineralization Himalaya South Tibet
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东昆仑大格勒地区稀有和稀土矿化碱性杂岩体的发现及意义 被引量:10
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作者 李五福 王涛 +16 位作者 王秉璋 张新远 谭运鸿 袁博武 王春涛 韩晓龙 金婷婷 郑英 曹锦山 王泰山 张焜 付长垒 陈健 刘建栋 李青 张启龙 陈丽娟 《大地构造与成矿学》 EI CAS CSCD 北大核心 2024年第1期38-49,共12页
稀有、稀土元素由于其特殊的属性对国民经济、国家安全和科技发展具有重要的战略意义。与碱性岩类相关的稀有、稀土矿产资源储量十分丰富,近年来对其勘探和开发越来越受到重视。青海省地质调查院在东昆仑中段大格勒地区首次发现了稀有... 稀有、稀土元素由于其特殊的属性对国民经济、国家安全和科技发展具有重要的战略意义。与碱性岩类相关的稀有、稀土矿产资源储量十分丰富,近年来对其勘探和开发越来越受到重视。青海省地质调查院在东昆仑中段大格勒地区首次发现了稀有和稀土矿化碱性杂岩体,岩石类型主要为含尖晶石磷灰石蛇纹石化橄榄岩、含磷灰石金云母霞石单斜辉石岩、橄榄辉长岩、含磷灰石金云母角闪石岩、磁铁矿化含橄榄石磷灰石碳酸岩等,其中含矿岩石为碳酸岩、橄榄岩、辉石岩等。矿石矿物主要为烧绿石、铌钽铁矿、磷灰石、独居石、钛铁矿。现初步圈定Nb、P矿体一条,矿体厚3.8~56.56 m,Nb_(2)O_(5)品位最高6.9%,平均0.71%;P_(2)O_(5)品位最高14.5%,平均品位5.6%,Ta和REE也伴有矿化,显示了很好的含矿性。这一发现大大拓展了青藏高原稀有、稀土矿的找矿空间,为发现新的、优质的稀有稀土矿产提供重要启示,具有重要的找矿和战略意义。 展开更多
关键词 碱性杂岩体 稀有金属 稀土矿 大格勒 东昆仑
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喜马拉雅稀有金属伟晶岩的铪超常富集 被引量:1
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作者 谢磊 田恩农 +1 位作者 饶乐 王汝成 《岩石学报》 SCIE EI CAS CSCD 北大核心 2024年第5期1510-1526,共17页
锆-铪(Zr-Hf)是重要的关键金属,锆石是最主要的Zr-Hf载体,因Zr-Hf相似的晶体化学特征形成了锆石-铪石完全固溶体系列,以晶体化学式中Hf/(Zr+Hf)原子比(Hf^(#))<0.1、0.1~0.5、0.5~0.9和>0.9为区间进行划分,包括锆石、铪质锆石、... 锆-铪(Zr-Hf)是重要的关键金属,锆石是最主要的Zr-Hf载体,因Zr-Hf相似的晶体化学特征形成了锆石-铪石完全固溶体系列,以晶体化学式中Hf/(Zr+Hf)原子比(Hf^(#))<0.1、0.1~0.5、0.5~0.9和>0.9为区间进行划分,包括锆石、铪质锆石、锆质铪石和铪石。而自然界形成锆铪分异从而达到铪超常富集的条件非常严苛,已报道的富铪锆石主要出现在高分异花岗岩和伟晶岩中,而铪质锆石和铪石尤其稀少,我国境内仅在阿尔泰可可托海1号脉LCT(Li-Cs-Ta)伟晶岩中发现了锆质铪石。本次研究在位于喜马拉雅造山带中部、吉隆岩体北部扎龙沟的锂电气石锂云母伟晶岩中发现了锆质铪石(Hf#最高达0.67)。依据矿物产状和成分,该伟晶岩中锆石-铪石被分为四类:核部多孔的斑状Zrn-1,为锆石和铪质锆石;成分均匀且具有暗色CL图像的Zrn-2最为常见,生长在Zrn-1外围或颗粒的核部,主要是铪质锆石;而Zrn-3和Zrn-4是具有铪质锆石-锆质铪石连续成分的边部,分别对应于富Y(最高4.9%Y_(2)O_(3))和低Y(<1.6%Y_(2)O_(3))两类。根据它们的稀土元素特征,它们都落在典型岩浆锆石和重结晶锆石的区域。这些锆石至少经历了三个阶段的结晶过程:原生富U锆石结晶;岩浆晚期亚固相条件下流体作用之后锆石发生溶解再沉淀作用;以及助熔剂元素(Li-B-F等)富集和Li-F矿物(锂电气石、锂云母)大量结晶导致锆铪强烈分异,形成铪质锆石-锆质铪石边部,与岩浆-热液过渡阶段紧密相关。同时,扎龙沟绿柱石伟晶岩和锂辉石伟晶岩中发现了铪质锆石(Hf^(#)达0.27),扎龙沟电气石白云母花岗岩和吉隆沟的花岗岩-伟晶岩只含有锆石(Hf^(#)<0.04),这些显示了岩浆分异作用也是导致锆石中Hf含量的增加和Zr/Hf比值降低的重要因素。结合全球不同岩体中铪质锆石和锆质铪石形成过程,以及喜马拉雅不同岩体花岗岩-伟晶岩中的锆石成分,本次研究对喜马拉雅锆石-铪石系列的指示作用和超常富铪体系的研究进行了展望。 展开更多
关键词 伟晶岩 稀有金属 锆铪分异 岩浆-热液过渡
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稀有金属矿物微区同位素定年与示踪
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作者 杨岳衡 吴石头 +6 位作者 车旭东 杨明 黄超 王浩 杨进辉 王汝成 吴福元 《岩石学报》 SCIE EI CAS CSCD 北大核心 2024年第4期1023-1043,共21页
作为战略性关键金属矿产资源,钨、锡、铌、钽、锂、铍、铷、铯、锆、铪、稀土等稀有金属,在国民经济与国家安全方面有着重要的研究意义。稀有金属矿石矿物微区同位素定年与示踪,是开展稀有金属矿床成矿作用研究的最直接手段,具有整体分... 作为战略性关键金属矿产资源,钨、锡、铌、钽、锂、铍、铷、铯、锆、铪、稀土等稀有金属,在国民经济与国家安全方面有着重要的研究意义。稀有金属矿石矿物微区同位素定年与示踪,是开展稀有金属矿床成矿作用研究的最直接手段,具有整体分析无可比拟的优点。近年来,钨锡铌钽锆铪稀土等稀有金属矿物微区U-Pb定年与Sr-Nd-Hf同位素示踪发展迅速,而锂铍铷铯等稀有金属矿物微区Rb-Sr/Lu-Hf定年正蓬勃发展。本文综述了黑钨矿、白钨矿、锡石、铌钽矿(铌钽氧化物类矿物的简称)、独居石、磷钇矿、氟碳铈矿等稀有金属矿物微区U-Pb定年与Sr-Nd-Hf同位素示踪技术主要进展,展望了锂云母、铁锂云母、铯沸石、钾长石(天河石)等微区Rb-Sr定年与磷钇矿、磷灰石、褐帘石、独居石、黑钨矿、白钨矿等微区Sm-Nd和Lu-Hf定年的广阔前景,获得如下认识:(1)低铀矿物U-Pb定年,除了采用高灵敏度磁式等离子质谱外,元素成像技术能很好地揭示微量元素之间相关性,进而快速锁定高U/Pb区域,提高低铀矿物U-Pb定年成功率;(2)铌钽矿-锡石激光微区Hf同位素能够直接示踪花岗岩-伟晶岩稀有金属成岩成矿物质源区,但这方面工作仍需进一步加强;(3)碰撞/反应池等离子质谱的出现,使高Rb/Sr、Sm/Nd或高Lu/Hf比矿物的同位素定年成为现实,是未来稀有金属激光微区同位素年代学发展的新方向;(4)实验方法研发与标准物质研制相辅相成、相互促进,仍是当前迫切需要解决的关键技术难题。随着战略性关键金属日渐成为国内外成矿作用研究的热点,钨锡铌钽锂铍铷铯锆铪稀土等稀有金属矿物微区同位素定年与示踪方法研究,必将为我国新一轮稀有金属矿床学研究做出应有的学术贡献。 展开更多
关键词 稀有金属 微区分析 同位素定年与示踪 U-Pb/Rb-Sr/Lu-Hf年代学
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新疆和田大红柳滩矿田稀有金属矿床的成矿机制
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作者 高景刚 梁婷 +5 位作者 王登红 凤永刚 李永 谭细绢 岑炬标 何蕾 《岩石学报》 SCIE EI CAS CSCD 北大核心 2024年第9期2753-2768,共16页
大红柳滩稀有金属矿田位于西昆仑中段,是松潘-甘孜-西昆仑花岗伟晶岩型稀有金属成矿带的重要组成部分,已发现白龙山、509道班西、大红柳滩东、507锂矿等大中型花岗伟晶岩型锂矿床7处,探获Li_(2)O储量达到1Mt以上,成矿潜力巨大。本文梳... 大红柳滩稀有金属矿田位于西昆仑中段,是松潘-甘孜-西昆仑花岗伟晶岩型稀有金属成矿带的重要组成部分,已发现白龙山、509道班西、大红柳滩东、507锂矿等大中型花岗伟晶岩型锂矿床7处,探获Li_(2)O储量达到1Mt以上,成矿潜力巨大。本文梳理了前人对大红柳滩稀有金属矿田的成矿特征及成矿作用研究,得出以下认识:(1)花岗伟晶岩与大红柳滩复式岩体形成于晚三叠世,两者空间关系密切,自岩体向远端可分成微斜长石型(矿物组合为微斜长石、石英和白云母)、锂辉石型(矿物组合为锂辉石、钠长石、石英和白云母)的分带规律,锂辉石伟晶岩多数分布在岩体外接触带1~2km范围内;(2)石英闪长岩、黑云母二长花岗岩和二云母二长花岗岩具有不同的地球化学特征以及ε_(Hf)(t)、ε_(Nd)(t)和δ^(7)Li值,是晚三叠世同碰撞构造背景下不同源区熔融的产物;(3)花岗伟晶岩与二云母二长花岗岩形成时代基本一致,具有相似的Hf、Li同位素特征,反映其源于相同的源区,形成于富白云母矿物的变沉积岩通过白云母脱水熔融;(4)初始熔体富助熔元素P、B、F和碱金属,能够增加H_(2)O在熔体中的溶解度,有利于Na、Li碱金属元素的富集,形成初始富锂熔体;(5)二云母二长花岗岩和花岗伟晶岩的空间关系、地球化学和Li同位素特征与岩浆分离结晶模型不同,与花岗岩浆的不混溶作用有关。综上所述,富挥发分、碱金属元素的初始富锂熔体上升过程中的熔体-流体分离作用可能是稀有金属元素超常富集的主要机制。大红柳滩复式岩体的外围,特别是二云母二长花岗岩的外接触带1~2km范围是寻找锂辉石伟晶岩的有利地区。 展开更多
关键词 稀有金属 伟晶岩 花岗岩 成矿机制 大红柳滩
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喜马拉雅琼嘉岗伟晶岩型锂矿成矿地质特征和形成机制
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作者 赵俊兴 秦克章 +7 位作者 何畅通 李俊瑜 刘宇超 施睿哲 朱丽群 赵永能 林伟 吴福元 《岩石学报》 SCIE EI CAS CSCD 北大核心 2024年第9期2664-2678,共15页
西藏喜马拉雅琼嘉岗伟晶岩型锂矿是喜马拉雅稀有金属成矿带标志性的伟晶岩型矿床。其成矿地质特征、成矿机理-机制和含矿性评价的研究对喜马拉雅稀有金属成矿带的形成机制和找矿勘查工作研究具有重要意义。中国科学院地质与地球物理研... 西藏喜马拉雅琼嘉岗伟晶岩型锂矿是喜马拉雅稀有金属成矿带标志性的伟晶岩型矿床。其成矿地质特征、成矿机理-机制和含矿性评价的研究对喜马拉雅稀有金属成矿带的形成机制和找矿勘查工作研究具有重要意义。中国科学院地质与地球物理研究所在2021~2023年期间对喜马拉雅琼嘉岗伟晶岩型锂矿形成机制研究中,获得如下认识:(1)琼嘉岗锂辉石伟晶岩的主矿体主要顺矽卡岩化大理岩和钙质千枚岩面理侵入,中部整体上呈板状近水平(10°~20°),主矿体两侧倾角相对较大(30°~50°);(2)琼嘉岗矿床的富锂矿物主要为锂辉石(包括3个期次),次为透锂长石、锂绿泥石、锂云母等,其他稀有金属矿物包括绿柱石、日光榴石、羟硅铍石、铌锰矿-铌铁矿、锡石等,围岩蚀变主要为矽卡岩化并含有少量锡矿化;(3)琼嘉岗锂矿中花岗岩-伟晶岩的演化和成矿受岩浆结晶分异过程控制,锂辉石伟晶岩矿体的形成与系统大量流体出溶有关,花岗质熔体演化的早期阶段稀有金属可能达到饱和;(4)钾长石Ti温度计和流体包裹体等容线相交法揭示出从电气石白云母花岗岩到锂辉石伟晶岩呈现降温趋势,锂辉石伟晶岩石英形成时流体的捕获温度为410~475℃,捕获压力为180~240MPa,结合含锂矿物相关系揭示出降压是锂辉石伟晶岩形成的重要机制;(5)建立了琼嘉岗锂矿的成矿模式,指出高度结晶分异、流体出溶和降压过程控制了琼嘉岗锂辉石伟晶岩的形成,流体交代作用形成了稀有金属矿化;(6)长石结构和化学成分(Rb、Cs、Sr、Ba、K/Rb和形成温度)、石榴子石组成(高水含量、高Mn/(Mn+Fe)的锰铝榴石)、副矿物组成及其包裹矿物类型是琼嘉岗及周边伟晶岩含矿性评价的有效指标。 展开更多
关键词 琼嘉岗锂矿 地质特征 成矿机制 成矿模型 喜马拉雅稀有金属成矿带
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华北板块北缘东段稀有-稀土成矿作用综述
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作者 鞠楠 施璐 +6 位作者 杨高 陈明哲 伍月 刘欣 赵忠海 刘博 冯玉辉 《地质与资源》 CAS 2024年第4期537-550,共14页
华北克拉通北缘东段稀有-稀土矿产资源主要分布在板块边缘或不同时代的构造接合处,受郯庐断裂带、索伦-西拉木伦-长春-延吉断裂带等区域性大断裂控制,主要经历了吕梁期、印支期和燕山期等3期的构造-岩浆事件.区内的稀有-稀土矿产与中元... 华北克拉通北缘东段稀有-稀土矿产资源主要分布在板块边缘或不同时代的构造接合处,受郯庐断裂带、索伦-西拉木伦-长春-延吉断裂带等区域性大断裂控制,主要经历了吕梁期、印支期和燕山期等3期的构造-岩浆事件.区内的稀有-稀土矿产与中元古代和中生代岩浆岩关系密切.目前,研究区内已发现稀有-稀土矿床或矿点10余处,主要分布于辽宁省和内蒙古东部地区,成矿类型以碱性花岗岩-碱性岩型为主,伟晶岩型次之.区内稀有-稀土成矿均与碱性岩浆作用有关,成矿岩体的年代学研究表明,成矿作用可分为3个阶段,即燕山期的120~140 Ma、印支期的200~230 Ma以及与吕梁运动有关的2500~2510 Ma.本区稀有-稀土元素富集成矿过程主要与碱性岩浆的高度演化密切相关,在水和挥发分作用下,岩浆强烈分异结晶,导致成矿元素迁移聚集,随着温度、压力等成矿条件的变化,含矿流体在岩浆作用晚期随着主要造岩矿物的晶出而富集成矿. 展开更多
关键词 稀有金属 稀土元素 矿床成因 成矿作用 岩浆作用 华北板块
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湘东北白沙窝稀有金属矿床电性特征与找矿预测研究
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作者 柳建新 曹丽 +2 位作者 郭振威 曹创华 陈旭 《地质力学学报》 CSCD 北大核心 2024年第5期768-780,共13页
花岗伟晶岩型稀有金属矿床是最重要的稀有金属矿床类型之一。连云山东部新发现了白沙窝伟晶岩型矿床,初步评估白沙窝矿床深部稀有金属资源潜力巨大,但该矿床的矿产开采程度很低,围绕深部隐伏花岗伟晶岩脉的研究程度不高。通过研究白沙... 花岗伟晶岩型稀有金属矿床是最重要的稀有金属矿床类型之一。连云山东部新发现了白沙窝伟晶岩型矿床,初步评估白沙窝矿床深部稀有金属资源潜力巨大,但该矿床的矿产开采程度很低,围绕深部隐伏花岗伟晶岩脉的研究程度不高。通过研究白沙窝伟晶岩型矿床的深部电性结构特征,探讨稀有金属成矿模型及赋矿载体的空间分布,阐明矿脉就位关系,旨为稀有金属找矿预测提供依据。通过可控源音频大地电磁法(CSAMT)在白沙窝岩体东南方向开展深部隐伏岩(矿)体的探测工作,采用共轭梯度法反演实测3条探测剖面数据,探测深部隐伏岩(矿)体,并结合钻孔信息和元素地球化学异常特征信息进行综合分析,揭示隐伏岩脉的分布及成矿特征。研究结果表明,隐伏伟晶岩脉主要位于冷家溪群中,集中分布在花岗岩体顶部及构造裂隙周围,埋深在50~300 m;伟晶岩脉的成矿地球物理标志为深部高阻体侵入浅部低阻体中的高阻脉状地质体。研究成果为白沙窝矿床后续勘查工作提供了科学依据,揭示了伟晶岩脉的形成机理,并为湘东北及华南地区的稀有金属勘查提供了可靠的物探预测技术和经验。 展开更多
关键词 伟晶岩 连云山 CSAMT 锂-铍-铌-钽矿床 稀有金属
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新疆阿尔金西段瓦石峡南锂铍稀有金属矿成矿背景与勘查进展
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作者 张朋 刘豹 +8 位作者 杨晓飞 罗新涛 邓浪江 樊自春 刘兴忠 陈建中 刘善宝 王登红 代鸿章 《中国地质调查》 CAS 2024年第3期17-24,共8页
锂、铍等稀有金属矿产是重要的战略矿产资源。近年来,在阿尔金地区发现了多处稀有金属伟晶岩型矿床,已成为我国一处新的稀有金属成矿带,但调查研究水平总体较低。通过对阿尔金造山带的成矿动力背景的讨论,得出阿尔金造山带的稀有金属成... 锂、铍等稀有金属矿产是重要的战略矿产资源。近年来,在阿尔金地区发现了多处稀有金属伟晶岩型矿床,已成为我国一处新的稀有金属成矿带,但调查研究水平总体较低。通过对阿尔金造山带的成矿动力背景的讨论,得出阿尔金造山带的稀有金属成矿作用涵盖了多个不同的造山运动构造演化阶段,证明该区域具备良好的稀有金属成矿条件,并具有巨大的找矿潜力。通过对位于阿尔金西段的瓦石峡南锂铍稀有金属矿进行勘查评价,发现其具有大型远景:瓦石峡南锂铍稀有金属矿体主要赋存于绿片岩相-角闪岩相变质岩系中的伟晶岩脉中,矿床类型为花岗伟晶岩型稀有金属矿床;已有勘查成果显示此矿床目前推断的稀有金属资源量达到中型以上矿床规模,并且随着勘查工作的进行,在深部及外围还有极大增储空间。研究成果对在阿尔金造山带内寻找同类型矿床具有借鉴意义。 展开更多
关键词 阿尔金 瓦石峡南锂铍稀有金属矿 花岗伟晶岩型稀有金属矿床 成矿动力背景 找矿前景
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新疆阿尔泰可可托海矿区伟晶岩成因与矿化潜力研究:来自石英SEM-CL和微量元素的指示
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作者 曹冲 申萍 +3 位作者 冯浩轩 罗耀清 楚翔凯 任文斌 《岩石学报》 SCIE EI CAS CSCD 北大核心 2024年第3期889-906,共18页
新疆阿尔泰可可托海3号脉矿床是世界瞩目的伟晶岩型稀有金属Li-Be-Nb-Ta-Rb-Cs-Hf矿床。尽管前人对3号脉伟晶岩矿床已经进行了大量的研究工作,然而在伟晶岩稀有金属成矿潜力以及伟晶岩成因问题上仍存在一些争议。本文以发育在可可托海... 新疆阿尔泰可可托海3号脉矿床是世界瞩目的伟晶岩型稀有金属Li-Be-Nb-Ta-Rb-Cs-Hf矿床。尽管前人对3号脉伟晶岩矿床已经进行了大量的研究工作,然而在伟晶岩稀有金属成矿潜力以及伟晶岩成因问题上仍存在一些争议。本文以发育在可可托海矿区不同规模的伟晶岩脉以及淡色花岗岩为研究对象,利用石英SEM-CL和原位微量元素技术手段,查明各伟晶岩脉和花岗岩的稀有金属禀赋差异及成因联系。研究结果表明,石英的Li和Al含量可以用来指示伟晶岩的矿化潜力。与1号和2号伟晶岩脉相比,3号伟晶岩脉具有更宽的分异范围,以石英中Ge/Ti变化于1.83×10^(-6)~159×10^(-6)范围为特征,更高的Li含量,其中外侧带平均Li含量为39×10^(-6),因而成矿潜力最大。此外,证实了白云母钠长花岗岩为矿化花岗岩,其微量元素组成和演化程度与3号脉伟晶岩外侧带相当,而白云母碱长花岗岩为贫矿花岗岩。更重要的是,本文利用各伟晶岩结构分带内的石英中Ge/Ti-Ge以及Ge/Ti-Al/Ti图解,确定了各伟晶岩脉具有相似的演化趋势,指示它们可能源于相同的花岗岩母岩。与世界上典型的RMG(花岗岩浆演化后残余熔浆结晶)和DPA(直接深部地壳熔融)成因的伟晶岩相比,可可托海矿区含矿伟晶岩和花岗岩中石英微量元素与RMG成因伟晶岩存在地球化学亲和性,这指示它们来源于花岗质岩浆的残留熔浆。 展开更多
关键词 可可托海稀有金属伟晶岩型矿床 石英微量元素 成矿潜力 岩石成因
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皖南姚村A型花岗岩磷灰石特征及其对成岩成矿的指示
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作者 朱永胜 李超 +3 位作者 刘群 江志 郑荥 郭君 《华东地质》 CAS 2024年第3期302-317,共16页
磷灰石作为岩浆岩中的常见副矿物,其地球化学特征常被用来指示火成岩的岩浆过程和岩浆属性。中生代A型花岗岩广泛分布于江南造山带东段,其岩石成因和成矿潜力仍有待进一步研究。文章选择江南造山带东段具代表性的皖南姚村A型花岗岩开展... 磷灰石作为岩浆岩中的常见副矿物,其地球化学特征常被用来指示火成岩的岩浆过程和岩浆属性。中生代A型花岗岩广泛分布于江南造山带东段,其岩石成因和成矿潜力仍有待进一步研究。文章选择江南造山带东段具代表性的皖南姚村A型花岗岩开展磷灰石的地球化学组成研究,为其岩石成因及成矿潜力研究提供新的信息。姚村花岗岩中的磷灰石普遍发育振荡环带,部分表现为均质结构,成分上具有低氯及高氟、稀土、钇、钍含量的特点,指示其为典型的岩浆成因磷灰石。单颗粒磷灰石的稀土、钇和钍等元素含量从核部到边缘呈连续变化,稀土配分模式显示其具有明显的铕负异常,指示岩浆经历过显著的结晶分异作用。磷灰石-熔体的模拟定量计算表明,姚村花岗质岩浆具有高氟和硫、低H_(2)O-Cl和低氧逸度的特征。综合考虑岩浆的物理化学特征与成矿元素行为之间的联系,认为姚村A型花岗岩具有稀有金属成矿潜力。 展开更多
关键词 磷灰石 花岗岩 稀有金属成矿 江南造山带东段 姚村
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新疆阿尔泰造山带伟晶岩型稀有金属矿床成矿作用
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作者 陈衍景 韩金生 《地质学报》 EI CAS CSCD 北大核心 2024年第5期1452-1472,共21页
花岗伟晶岩与稀有金属(Li、Be、Nb、Ta等)矿床关系密切。关于伟晶岩成矿模式、伟晶岩与花岗岩之间的成因关系等,已有大量研究和讨论,但仍然存在争议。新疆阿尔泰是我国著名的伟晶岩及稀有金属矿床集中区,研究资料丰富。本文系统分析了... 花岗伟晶岩与稀有金属(Li、Be、Nb、Ta等)矿床关系密切。关于伟晶岩成矿模式、伟晶岩与花岗岩之间的成因关系等,已有大量研究和讨论,但仍然存在争议。新疆阿尔泰是我国著名的伟晶岩及稀有金属矿床集中区,研究资料丰富。本文系统分析了阿尔泰伟晶岩的地质背景与成矿地质特征,阐明阿尔泰造山带伟晶岩与花岗岩存在3种关系:(1)缺乏成因联系,伟晶岩可能为变质脱水熔融形成的独立伟晶岩;(2)可能为“兄弟关系”;(3)可能为“母子关系”,共同构成花岗岩-伟晶岩成岩成矿系统。作者提出一个包含多种成因伟晶岩的成岩成矿构造模式,可能在矿带、矿田、矿床尺度上都适用。阿尔泰造山带稀有金属伟晶岩成矿省的形成受到古生代地层的控制。阿尔泰造山带处于典型的幔坡带,为长期活跃的构造活动带,极易受到外部构造域的干扰,在晚三叠纪受到特提斯构造域的一系列陆块向北漂移并拼贴到欧亚大陆南缘的远程效应影响而发生大规模的稀有金属成矿作用,在侏罗纪,其构造活动及成岩成矿作用则受新特提斯构造域和蒙古-鄂霍茨克洋构造域地质作用的远程效应共同影响。 展开更多
关键词 稀有金属 伟晶岩 花岗岩 阿尔泰造山带 伟晶岩成岩成矿构造模式 远程效应
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