By using fluid dynamics theory with the effects of adsorption and reaction, the chromatography model with a reaction A →B was established as a system of two hyperbolic partial differential equations (PDE’s)....By using fluid dynamics theory with the effects of adsorption and reaction, the chromatography model with a reaction A →B was established as a system of two hyperbolic partial differential equations (PDE’s). In some practical situations, the reaction chromatography model was simplified a semi-coupled system of two linear hyperbolic PDE’s. In which, the reactant concentration wave model was the initial-boundary value problem of a self-closed hyperbolic PDE, while the resultant concentration wave model was the initial-boundary value problem of hyperbolic PDE coupling reactant concentration. The general explicit expressions for the concentration wave of the reactants and resultants were derived by Laplace transform. The δ-pulse and wide pulse injections were taken as the examples to discuss detailedly, and then the stability analysis between the resultant solutions of the two modes of pulse injection was further discussed. It was significant for further analysis of chromatography, optimizing chromatographic separation, determining the physical and chemical characters.展开更多
The ideal reaction chromatography model can be regarded as a semi-coupled system of two hyperbolic partial differential equations, in which, one is a self-closed nonlinear equation for the reactant concentration and a...The ideal reaction chromatography model can be regarded as a semi-coupled system of two hyperbolic partial differential equations, in which, one is a self-closed nonlinear equation for the reactant concentration and another is a linear equation coupling the reactant concentration for the resultant concentration. This paper is concerned with the initial-boundary value problem for the above model. By the characteristic method and the truncation method, we construct the global weak entropy solution of this initial initial-boundary value problem for Riemann type of initial-boundary data. Moreover, as examples, we apply the obtained results to the cases of head-on and wide pulse injections and give the expression of the global weak entropy solution.展开更多
文摘By using fluid dynamics theory with the effects of adsorption and reaction, the chromatography model with a reaction A →B was established as a system of two hyperbolic partial differential equations (PDE’s). In some practical situations, the reaction chromatography model was simplified a semi-coupled system of two linear hyperbolic PDE’s. In which, the reactant concentration wave model was the initial-boundary value problem of a self-closed hyperbolic PDE, while the resultant concentration wave model was the initial-boundary value problem of hyperbolic PDE coupling reactant concentration. The general explicit expressions for the concentration wave of the reactants and resultants were derived by Laplace transform. The δ-pulse and wide pulse injections were taken as the examples to discuss detailedly, and then the stability analysis between the resultant solutions of the two modes of pulse injection was further discussed. It was significant for further analysis of chromatography, optimizing chromatographic separation, determining the physical and chemical characters.
基金supported by the State Key Program of National Natural Science Foundation of China(Grants No.11731008)the National Natural Science Foundation of China(Grants No.10771087)。
文摘The ideal reaction chromatography model can be regarded as a semi-coupled system of two hyperbolic partial differential equations, in which, one is a self-closed nonlinear equation for the reactant concentration and another is a linear equation coupling the reactant concentration for the resultant concentration. This paper is concerned with the initial-boundary value problem for the above model. By the characteristic method and the truncation method, we construct the global weak entropy solution of this initial initial-boundary value problem for Riemann type of initial-boundary data. Moreover, as examples, we apply the obtained results to the cases of head-on and wide pulse injections and give the expression of the global weak entropy solution.
