The demanganization reaction kinetics of carbon-saturated liquid iron with an eight-component slag consisting of CaO–SiO2–MgO–FeO–MnO–Al2O3–TiO2–CaF2 was investigated at 1553, 1623, and 1673 K in this study. Th...The demanganization reaction kinetics of carbon-saturated liquid iron with an eight-component slag consisting of CaO–SiO2–MgO–FeO–MnO–Al2O3–TiO2–CaF2 was investigated at 1553, 1623, and 1673 K in this study. The rate-controlling step（RCS） for the demanganization reaction with regard to the hot metal pretreatment conditions was studied via kinetics analysis based on the fundamental equation of heterogeneous reaction kinetics. From the temperature dependence of the mass transfer coefficient of a transition-metal oxide（MnO）, the apparent activation energy of the demanganization reaction was estimated to be 189.46 kJ·mol^–1 in the current study, which indicated that the mass transfer of MnO in the molten slag controlled the overall rate of the demanganization reaction. The calculated apparent activation energy was slightly lower than the values reported in the literature for mass transfer in a slag phase. This difference was attributed to an increase in the ＂specific reaction interface＂（SRI） value, either as a result of turbulence at the reaction interface or a decrease of the absolute amount of slag phase during sampling, and to the addition of calcium fluoride to the slag.展开更多
A numerical model is presented to investigate the performance of homogeneous charge compression ignition(HCCI) engines fueled with ethanol. Two approaches are studied. On one hand, two-step reaction mechanisms with Ar...A numerical model is presented to investigate the performance of homogeneous charge compression ignition(HCCI) engines fueled with ethanol. Two approaches are studied. On one hand, two-step reaction mechanisms with Arrhenius reaction rates are implemented in combustion chemistry modeling. On the other hand, a reduced mechanism containing important reactions of ethanol involving heat release rate and reaction rates compatible with experimental data is employed. Since controls of combustion phenomenon and ignition timing are the main issues of these engines, the effects of inlet temperature and equivalence ratio as the controlling factors on the operating parameters such as ignition timing, burn duration, in-cylinder temperature and pressure of HCCI engines are explored. The results show that the maximum predicted pressures for thermodynamic model are about 71.3×10~5 Pa and 79.79×10~5 Pa, and for chemical kinetic model, they are about 71.48×10~5 Pa and 78.123×10~5 Pa, fairly comparable with corresponding experimental values of 72×10~5 Pa and 78.7×10~5 Pa. It is observed that increasing the initial temperature advances the ignition timing, decreases the burn duration and increases the peak temperature and pressure. Moreover, the maximum temperature and pressure are associated with richer mixtures.展开更多
采用改进的高精度时-空守恒元解元算法(the space-time conservation element and solution element meth-od,CE/SE method)和考虑组分的二阶段化学反应模型(Sichel的二步模型)对气相爆轰问题的数值模拟进行了分析。分析发现采用Sichel...采用改进的高精度时-空守恒元解元算法(the space-time conservation element and solution element meth-od,CE/SE method)和考虑组分的二阶段化学反应模型(Sichel的二步模型)对气相爆轰问题的数值模拟进行了分析。分析发现采用Sichel的二步模型得到的数值结果虽然比早期二阶段化学反应模型(旧二步模型)更接近实验值,但是仍然不能得到爆轰过程准确气体动力学参数。为此通过修改组分的质量分数分布形式对Sichel的二步模型进行了改造,然后采用新的二步模型对平面爆轰波进行了数值模拟。数值结果表明采用新的二步模型计算得到气体动力学参数更接近于实验值和基元反应模型的计算值,在计算精度上有较大提高。展开更多
基金support from the National Natural Science Foundation of China (Nos. U1560203 and 51274031)the Beijing Key Laboratory of Special Melting and Preparation of High-End Metal Materials in the School of Metallurgical and Ecological Engineering of University of Science and Technology Beijing, China
文摘The demanganization reaction kinetics of carbon-saturated liquid iron with an eight-component slag consisting of CaO–SiO2–MgO–FeO–MnO–Al2O3–TiO2–CaF2 was investigated at 1553, 1623, and 1673 K in this study. The rate-controlling step（RCS） for the demanganization reaction with regard to the hot metal pretreatment conditions was studied via kinetics analysis based on the fundamental equation of heterogeneous reaction kinetics. From the temperature dependence of the mass transfer coefficient of a transition-metal oxide（MnO）, the apparent activation energy of the demanganization reaction was estimated to be 189.46 kJ·mol^–1 in the current study, which indicated that the mass transfer of MnO in the molten slag controlled the overall rate of the demanganization reaction. The calculated apparent activation energy was slightly lower than the values reported in the literature for mass transfer in a slag phase. This difference was attributed to an increase in the ＂specific reaction interface＂（SRI） value, either as a result of turbulence at the reaction interface or a decrease of the absolute amount of slag phase during sampling, and to the addition of calcium fluoride to the slag.
文摘A numerical model is presented to investigate the performance of homogeneous charge compression ignition(HCCI) engines fueled with ethanol. Two approaches are studied. On one hand, two-step reaction mechanisms with Arrhenius reaction rates are implemented in combustion chemistry modeling. On the other hand, a reduced mechanism containing important reactions of ethanol involving heat release rate and reaction rates compatible with experimental data is employed. Since controls of combustion phenomenon and ignition timing are the main issues of these engines, the effects of inlet temperature and equivalence ratio as the controlling factors on the operating parameters such as ignition timing, burn duration, in-cylinder temperature and pressure of HCCI engines are explored. The results show that the maximum predicted pressures for thermodynamic model are about 71.3×10~5 Pa and 79.79×10~5 Pa, and for chemical kinetic model, they are about 71.48×10~5 Pa and 78.123×10~5 Pa, fairly comparable with corresponding experimental values of 72×10~5 Pa and 78.7×10~5 Pa. It is observed that increasing the initial temperature advances the ignition timing, decreases the burn duration and increases the peak temperature and pressure. Moreover, the maximum temperature and pressure are associated with richer mixtures.
文摘采用改进的高精度时-空守恒元解元算法(the space-time conservation element and solution element meth-od,CE/SE method)和考虑组分的二阶段化学反应模型(Sichel的二步模型)对气相爆轰问题的数值模拟进行了分析。分析发现采用Sichel的二步模型得到的数值结果虽然比早期二阶段化学反应模型(旧二步模型)更接近实验值,但是仍然不能得到爆轰过程准确气体动力学参数。为此通过修改组分的质量分数分布形式对Sichel的二步模型进行了改造,然后采用新的二步模型对平面爆轰波进行了数值模拟。数值结果表明采用新的二步模型计算得到气体动力学参数更接近于实验值和基元反应模型的计算值,在计算精度上有较大提高。
