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Research on the Real-Time Phase Jump Process Method for Plasma Electron Density Measurement in HL-2A Tokamak 被引量:2
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作者 丁宝钢 陈超 +3 位作者 王闻迪 吴彤宇 周艳 阴泽杰 《Plasma Science and Technology》 SCIE EI CAS CSCD 2015年第10期837-841,共5页
In the real-time plasma electron density measurement using far infrared (FIR) laser interferometry, the plasma electron density can be calculated by measuring the real time phase difference between the reference sig... In the real-time plasma electron density measurement using far infrared (FIR) laser interferometry, the plasma electron density can be calculated by measuring the real time phase difference between the reference signal and the probe signal. A novel Real-time Phase Jump Process (RPJP) method is applied to the HL-2A tokamak. With this method, the phase difference 1 precision is up to 1/3600 fringe (1 fringe is equal to a phase shift of 2π), and the dynamic measure- ment range is extensible 65536 fringes. The time resolution of the phase difference is 80 ns, while the feedback delay is 180 its. 展开更多
关键词 RPJP FPGA FRINGE real-time electron density
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Real-time data processing method for CO_(2) dispersion interferometer on EAST
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作者 张家敏 姚远 +6 位作者 刘郁阳 储宇奇 阮天翼 张耀 刘海庆 揭银先 凌必利 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第8期121-126,共6页
A real-time data processing system is designed for the carbon dioxide dispersion interferometer(CO_(2)-DI)on EAST.The system utilizes the parallel and pipelining capabilities of an fieldprogrammable gate array(FPGA)to... A real-time data processing system is designed for the carbon dioxide dispersion interferometer(CO_(2)-DI)on EAST.The system utilizes the parallel and pipelining capabilities of an fieldprogrammable gate array(FPGA)to digitize and process the intensity of signals from the detector.Finally,the real-time electron density signals are exported through a digital-to-analog converter(DAC)module in the form of analog signals.The system has been successfully applied in the CO_(2)-DI system to provide low-latency electron density input to the plasma control system on EAST.Experimental results of the latest campaign with long-pulse discharges on EAST(2022–2023)demonstrate that the system can respond effectively in the case of rapid density changes,proving its reliability and accuracy for future electron density calculation. 展开更多
关键词 dispersion interferometer real-time electron density FPGA EAST
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Electron density measurement by the three boundary channels of HCOOH laser interferometer on the HL-3 tokamak
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作者 牟俊任 李永高 +5 位作者 李远 王再宏 丁宝钢 王浩西 易江 石中兵 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第3期88-93,共6页
Far-infrared(FIR)interferometer is widely used to measure the electron density in the magnetically confined fusion plasma devices.A new FIR laser interferometer with a total of 13 channels(8 horizontal channels and 5 ... Far-infrared(FIR)interferometer is widely used to measure the electron density in the magnetically confined fusion plasma devices.A new FIR laser interferometer with a total of 13 channels(8 horizontal channels and 5 oblique channels)is under development on the HL-3tokamak by using the formic-acid laser(HCOOH,f=694 GHz).In order to investigate the boundary electron density activity during the divertor discharge,three horizontal interferometry channels located at Z=-97,-76,76.5 cm have been successfully developed on HL-3 in 2023,and put into operation in recent experimental campaign,with a time resolution of<1.0μs and lineintegrated electron density resolution of~7.0×10^(16) m^(-2).This paper mainly focuses on the optical design of the three-channel interferometry system,as well as optical elements and recent experimental result on HL-3. 展开更多
关键词 electron density INTERFEROMETER HL-3
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Diagnosing ratio of electron density to collision frequency of plasma surrounding scaled model in a shock tube using low-frequency alternating magnetic field phase shift
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作者 吴明兴 谢楷 +3 位作者 刘艳 徐晗 张宝 田得阳 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第5期519-530,共12页
A non-contact low-frequency(LF)method of diagnosing the plasma surrounding a scaled model in a shock tube is proposed.This method utilizes the phase shift occurring after the transmission of an LF alternating magnetic... A non-contact low-frequency(LF)method of diagnosing the plasma surrounding a scaled model in a shock tube is proposed.This method utilizes the phase shift occurring after the transmission of an LF alternating magnetic field through the plasma to directly measure the ratio of the plasma loop average electron density to collision frequency.An equivalent circuit model is used to analyze the relationship of the phase shift of the magnetic field component of LF electromagnetic waves with the plasma electron density and collision frequency.The applicable range of the LF method on a given plasma scale is analyzed.The upper diagnostic limit for the ratio of the electron density(unit:m^(-3))to collision frequency(unit:Hz)exceeds 1×10^(11),enabling an electron density to exceed 1×10^(20)m^(-3)and a collision frequency to be less than 1 GHz.In this work,the feasibility of using the LF phase shift to implement the plasma diagnosis is also assessed.Diagnosis experiments on shock tube equipment are conducted by using both the electrostatic probe method and LF method.By comparing the diagnostic results of the two methods,the inversion results are relatively consistent with each other,thereby preliminarily verifying the feasibility of the LF method.The ratio of the electron density to the collision frequency has a relatively uniform distribution during the plasma stabilization.The LF diagnostic path is a loop around the model,which is suitable for diagnosing the plasma that surrounds the model.Finally,the causes of diagnostic discrepancy between the two methods are analyzed.The proposed method provides a new avenue for diagnosing high-density enveloping plasma. 展开更多
关键词 low-frequency alternating magnetic field phase shift shock-tube plasma diagnosis electron density collision frequency
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The nature of electron density enhancement over a wide altitude range during ionosphere heating experiments at EISCAT
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作者 Jun Wu Jian Wu +5 位作者 Jie Feng QingLiang Li ShuJi Hao ZhengWen Xu HaiSheng Zhao YaBin Zhang 《Earth and Planetary Physics》 EI CAS CSCD 2024年第2期408-414,共7页
During the course of ionospheric heating experiments, researchers at the European Incoherent Scatter Scientific Association (EISCAT) observed an apparent electron density enhancement. The enhancement extended over a w... During the course of ionospheric heating experiments, researchers at the European Incoherent Scatter Scientific Association (EISCAT) observed an apparent electron density enhancement. The enhancement extended over a wide range of altitudes, above the reflection altitude of the high-frequency pump wave. However, whether this enhancement actually corresponds to a true enhancement in electron density remains an open question. When the dispersion relation of ion acoustic waves is followed, the frequency ratio of the enhanced ion line to the background ion line suggests that the profile of the effective ion mass may have remained unchanged. Furthermore, the solar radio flux and ion drift velocity indicate no significant changes in the ion species and their densities. In conclusion, the electron density enhancement observed at EISCAT should not, in fact, be considered a true enhancement. 展开更多
关键词 incoherent scatter radar(ISR) ionospheric heating electron density ion acoustic wave
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MODEL-BASED DEVELOPMENT OF REAL-TIME SOFTWARE SYSTEM FOR ELECTRONIC UNIT PUMP SYSTEM 被引量:1
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作者 YU Shitao YANG Shiwei YANG Lin GONG Yuanming ZHUO Bin 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2007年第1期25-30,共6页
A real-time operating system (RTOS), also named OS, is designed based on the hardware platform of MC68376, and is implemented in the electronic control system for unit pump in diesel engine. A parallel and time-base... A real-time operating system (RTOS), also named OS, is designed based on the hardware platform of MC68376, and is implemented in the electronic control system for unit pump in diesel engine. A parallel and time-based task division method is introduced and the multi-task software architecture is built in the software system for electronic unit pump (EUP) system. The V-model software development process is used to control algorithm of each task. The simulation results of the hardware-in-the-loop simulation system (HILSS) and the engine experimental results show that the OS is an efficient real-time kernel, and can meet the real-time demands of EUP system; The built multi-task software system is real-time, determinate and reliable. V-model development is a good development process of control algorithms for EUP system, the control precision of control system can be ensured, and the development cycle and cost are also decreased. 展开更多
关键词 real-time operating system (RTOS) Multi-task V-model development Hardware-in-the-loop simulation system(HILSS) electronic unit pump (EUP)
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Real-Time Monitoring and Forecast of Active Population Density Using Mobile Phone Data
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作者 Qi Li Bin Xu +1 位作者 Yukun Ma Tonglee Chung 《国际计算机前沿大会会议论文集》 2015年第B12期31-33,共3页
Real-time monitoring and forecast of large scale active population density is of great significance as it can warn and prevent possible public safety accident caused by abnormal population aggregation.Active populatio... Real-time monitoring and forecast of large scale active population density is of great significance as it can warn and prevent possible public safety accident caused by abnormal population aggregation.Active population is defined as the number of people with their mobile phone powered on.Recently,an unfortunate deadly stampede occurred in Shanghai on December 31th 2014 causing the death of 39 people.We hope that our research can help avoid similar unfortunate accident from happening.In this paper we propose a method for active population density real-time monitoring and forecasting based on data from mobile network operators.Our method is based solely on mobile network operators existing infrastructure and barely requires extra investment,and mobile devices play a very limited role in the process of population locating.Four series forecasting methods,namely Simple Exponential Smoothing(SES),Double exponential smoothing(DES),Triple exponential smoothing(TES)and Autoregressive integrated moving average(ARIMA)are used in our experiments.Our experimental results suggest that we can achieve good forecast result for 135 min in future. 展开更多
关键词 real-time FORECAST POPULATION density PUBLIC safety Mobile PHONE DATA
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Density functional theory study of influence of impurity on electronic properties and reactivity of pyrite 被引量:8
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作者 李玉琼 陈建华 +1 位作者 陈晔 郭进 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2011年第8期1887-1895,共9页
The electronic property of pyrite supercell containing As,Se,Te,Co or Ni hetero atoms were calculated using density functional theory(DFT),and the reactivities of pyrite with oxygen and xanthate were discussed by fr... The electronic property of pyrite supercell containing As,Se,Te,Co or Ni hetero atoms were calculated using density functional theory(DFT),and the reactivities of pyrite with oxygen and xanthate were discussed by frontier orbital methods.The cell volume expands due to the presence of impurity.Co and Ni mainly affect the bands near Fermi levels,while As mainly affects the shallow and deep valence bands,and Se and Te mainly affect the deep valence bands.Electronic density analysis suggests that there exists a strong covalent interaction between hetero atom and its surrounding atoms.By frontier orbital calculation,it is suggested that As,Co and Ni have greater influence on the HOMO and LUMO of pyrite than Se and Te.In addition,pyrite containing As,Co or Ni is easier to oxidize by oxygen than pyrite containing Se or Te,and pyrite containing Co or Ni has greater interaction with collector.These are in agreement with the observed pyrite practice. 展开更多
关键词 PYRITE IMPURITY density functional theory electronic properties REACTIVITY
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Density Functional Theory Study on Electronic and Magnetic Properties of Mn-doped (MgO)n (n=2-10) Clusters
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作者 王鹏 杨明霞 +2 位作者 张胜利 黄世萍 田辉平 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2013年第1期35-42,I0003,共9页
We study the geometries, stabilities, electronic and magnetic properties of (MgO)n (n=2-10) clusters doped with a single Mn atom using the density functional theory with the gener- alized gradient approximation. T... We study the geometries, stabilities, electronic and magnetic properties of (MgO)n (n=2-10) clusters doped with a single Mn atom using the density functional theory with the gener- alized gradient approximation. The optimized geometries show that the impurity Mn atom prefers to replace the Mg atom which has low coordination number in all the lowest-energy MnMgn-1On (n=2-10) structures. The stability analysis clearly represents that the average binding energies of the doped clusters are larger than those of the corresponding pure (MgO)n clusters. Maximum peaks of the second order energy differences are observed for MnMg~_1On clusters at n=6, 9, implying that these clusters exhibit higher stability than their neighboring clusters. In addition, all the Mn-doped Mg clusters exhibit high total magnetic moments with the exception of MnMgO2 which has 3.00μB. Their magnetic behavior is attributed to the impurity Mn atom, the charge transfer modes, and the size of MnMgn- 1On clusters. 展开更多
关键词 density functional theory MnMgn-1On cluster electronic property MAGNETICPROPERTY
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Electronic structure and optical properties of In-doped SrTiO3 by density function theory 被引量:4
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作者 张志勇 贠江妮 张富春 《Chinese Physics B》 SCIE EI CAS CSCD 2007年第9期2791-2797,共7页
The effect of In doping on the electronic structure and optical properties of SrTiO3 is investigated by the first-principles calculation of plane wave ultra-soft pseudo-potential based on the density function theory ... The effect of In doping on the electronic structure and optical properties of SrTiO3 is investigated by the first-principles calculation of plane wave ultra-soft pseudo-potential based on the density function theory (DFT). The calculated results reveal that due to the hole doping, the Fermi level shifts into valence bands (VBs) for SrTi1-x InxO3 with x = 0.125 and the system exhibits p-type degenerate semiconductor features. It is suggested according to the density of states (DOS) of SrTi0.875In0.125O3 that the band structure of p-type SrTIO3 can be described by a rigid band model. At the same time, the DOS shifts towards high energies and the optical band gap is broadened. The wide band gap, small transition probability and weak absorption due to the low partial density of states (PDOS) of impurity in the Fermi level result in the optical transparency of the film. The optical transmittance of In doped SrTiO3 is higher than 85% in a visible region, and the transmittance improves greatly. And the cut-off wavelength shifts into a blue-light region with the increase of In doping concentration. 展开更多
关键词 the density function theory SRTIO3 In-doping electronic structure optical transmittance
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Electronic structure and flotability of gold-bearing pyrite:A density functional theory study 被引量:2
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作者 LIU Dan WANG Yi-jie +1 位作者 XIAN Yong-jun WEN Shu-ming 《Journal of Central South University》 SCIE EI CAS CSCD 2017年第10期2288-2293,共6页
Various incorporation of Au in pyrite and its effects on the geometrical structure,electronic structure and flotability of pyrite were theoretically investigated and fully discussed by performing density functional th... Various incorporation of Au in pyrite and its effects on the geometrical structure,electronic structure and flotability of pyrite were theoretically investigated and fully discussed by performing density functional theory(DFT).The calculated incorporation energy shows that gold would most likely exist in pyrite via incorporating into interstitial lattice sites in the absence of As impurity.As a result of incorporated Au,the covalence levels of the S—Fe and S—S bonds are changed,and the tonicity of Au—S bonds and antibonding of Au—Fe bonds are found to form in the pyrite,which would change the natural flotability of pyrite.The Au impurity energy levels are introduced into the energy band and result in the transformation of pyrite semiconductivity type.The calculated band-gap value suggests that the incorporated Au significantly decreases pyrite semiconductivity level,which enhances the formation and the adsorption stability of dixanthogen during pyrite flotation.The DOS results reveal that the stability and depression difficulty level of pyrites increases in the following order:Fe_(32)S_(63)As<Fe_(32)S_(64)<Fe_(32)S_(63)As Au<Fe_(32)S_(64)Au. 展开更多
关键词 PYRITE GOLD density FUNCTIONAL theory electronic structure flotability
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Measurement of electron density and electron temperature of a cascaded arc plasma using laser Thomson scattering compared to an optical emission spectroscopic approach 被引量:2
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作者 Yong WANG Cong LI +2 位作者 Jielin SHI Xingwei WU Hongbin DING 《Plasma Science and Technology》 SCIE EI CAS CSCD 2017年第11期23-30,共8页
As advanced linear plasma sources, cascaded arc plasma devices have been used to generate steady plasma with high electron density, high particle flux and low electron temperature. To measure electron density and elec... As advanced linear plasma sources, cascaded arc plasma devices have been used to generate steady plasma with high electron density, high particle flux and low electron temperature. To measure electron density and electron temperature of the plasma device accurately, a laser Thomson scattering(LTS) system, which is generally recognized as the most precise plasma diagnostic method, has been established in our lab in Dalian University of Technology. The electron density has been measured successfully in the region of 4.5?×10^19m^-3 to7.1?×10^20m^-3 and electron temperature in the region of 0.18 eV to 0.58 eV. For comparison,an optical emission spectroscopy(OES) system was established as well. The results showed that the electron excitation temperature(configuration temperature) measured by OES is significantly higher than the electron temperature(kinetic electron temperature) measured by LTS by up to 40% in the given discharge conditions. The results indicate that the cascaded arc plasma is recombining plasma and it is not in local thermodynamic equilibrium(LTE). This leads to significant error using OES when characterizing the electron temperature in a non-LTE plasma. 展开更多
关键词 laser Thomson scattering optical emission spectroscopy cascaded arc plasma electron density electron temperature electron excitation temperature
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Electron Density and Optical Emission Measurements of SF_6/O_2 Plasmas for Silicon Etch Processes 被引量:2
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作者 M.M.MORSHED S.M.DANIELS 《Plasma Science and Technology》 SCIE EI CAS CSCD 2012年第4期316-320,共5页
This work investigates internal plasma process parameters using a hairpin resonance probe and optical emission spectroscopy. The dependence of electron density and atomic fluorine on the percentage of oxygen in an SF6... This work investigates internal plasma process parameters using a hairpin resonance probe and optical emission spectroscopy. The dependence of electron density and atomic fluorine on the percentage of oxygen in an SF6/O2 discharge was measured using these methods. An RIE Oxford Instruments 80 plus chamber was used for the experiments. Two different process powers (100 W and 300 W) at a constant pressure (100 mTorr) were used, and it was found that the optical emission intensity of the 703.7 nm and 685.6 nm lines of atomic fluorine increased rapidly as oxygen was added to the SF6 discharge, reached their maximum at an O2 fraction of 20% and then decreased with further addition of oxygen. The plasma electron density was also strongly influenced by the addition of O2. 展开更多
关键词 OES hairpin probe SF6 O2 electron density atomic fluorine
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Atomic Emission Spectra Diagnosis and Electron Density Measurement of Semiconductor Bridge (SCB) Plasma 被引量:2
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作者 冯红艳 朱顺官 +3 位作者 张琳 万晓霞 李燕 沈瑞琪 《Plasma Science and Technology》 SCIE EI CAS CSCD 2010年第1期49-52,共4页
Emission spectra of a semiconductor bridge (SCB) plasma in a visible range was studied in air. The electron density was measured in a conventional way from the broadening of the Al Ⅰ 394.4 nm Stark width. Based on ... Emission spectra of a semiconductor bridge (SCB) plasma in a visible range was studied in air. The electron density was measured in a conventional way from the broadening of the Al Ⅰ 394.4 nm Stark width. Based on the Saha equation, a system for recording the intensity of Si Ⅰ 390.5 nm and Si Ⅱ 413.1 nm was designed. With this technique, the SCB plasma electron density was measured well and accurately. Moreover, the electron density distribution Vs time was acquired from one SCB discharge. The individual result from the broadening of the Al Ⅰ 394.4 nm Stark width and Saha equation was all in the range of 1015 cm^-3 to 1016 cm^-3. Finally the presumption of the local thermodynamic equilibrium (LTE) condition was validated. 展开更多
关键词 SCB plasma electron density Stark broadening Saha equation
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Areal density and spatial resolution of high energy electron radiography 被引量:4
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作者 Jiahao Xiao Zimin Zhang +13 位作者 Shuchun Cao Ping Yuan Xiaokang Shen Rui Cheng Quantang Zhao Yang Zong Ming Liu Xianming Zhou Zhongping Li Yongtao Zhao Chuanxiang Tang Wenhui Huang Yingchao Du Wei Gai 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第3期321-326,共6页
Ultrafast imaging tools are of great importance for determining the dynamic density distribution in high energy density(HED)matter.In this work,we designed a high energy electron radiography(HEER)system based on a lin... Ultrafast imaging tools are of great importance for determining the dynamic density distribution in high energy density(HED)matter.In this work,we designed a high energy electron radiography(HEER)system based on a linear electron accelerator to evaluate its capability for imaging HED matter.40 MeV electron beams were used to image an aluminum target to study the density resolution and spatial resolution of HEER.The results demonstrate a spatial resolution of tens of micrometers.The interaction of the beams with the target and the beam transport of the transmitted electrons are further simulated with EGS5 and PARMELA codes,with the results showing good agreement with the experimental resolution.Furthermore,the experiment can be improved by adding an aperture at the Fourier plane. 展开更多
关键词 high energy density matter high energy electron radiography areal density resolution spatial resolution
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A PAT STUDY OF INFLUENCES OF PRECIPITATION ON DEFECTS AND ELECTRONIC DENSITY IN Al-Li-Cu-Mg-Zr ALLOYS 被引量:2
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作者 Wu, WM Gao, YJ +4 位作者 Luo, LX Deng, W Xu, SJ Zhong, XP Jiang, XJ 《中国有色金属学会会刊:英文版》 CSCD 1997年第1期43-46,共4页
APATSTUDYOFINFLUENCESOFPRECIPITATIONONDEFECTSANDELECTRONICDENSITYINAlLiCuMgZrALLOYS①WuWeiming,GaoYingjun... APATSTUDYOFINFLUENCESOFPRECIPITATIONONDEFECTSANDELECTRONICDENSITYINAlLiCuMgZrALLOYS①WuWeiming,GaoYingjun,LuoLixiong,DengW... 展开更多
关键词 positron lifetime spectra Al Li Cu Mg ZR alloy ageing PRECIPITATION DEFECTS bulk electronIC density
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Laser-induced plasma electron number density:Stark broadening method versus the Saha-Boltzmann equation 被引量:2
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作者 Arnab SARKAR Manjeet SINGH 《Plasma Science and Technology》 SCIE EI CAS CSCD 2017年第2期43-51,共9页
We report spectroscopic studies on plasma electron number density of laser-induced plasma produced by ns-Nd:YAG laser light pulses on an aluminum sample in air at atmospheric pressure. The effect of different laser e... We report spectroscopic studies on plasma electron number density of laser-induced plasma produced by ns-Nd:YAG laser light pulses on an aluminum sample in air at atmospheric pressure. The effect of different laser energy and the effect of different laser wavelengths were compared. The experimentally observed line profiles of neutral aluminum have been used to extract the excitation temperature using the Boltzmann plot method, whereas the electron number density has been determined from the Stark broadened as well as using the Saha-Boltzmann equation (SBE). Each approach was also carried out by using the AI emission line and Mg emission lines. It was observed that the,SBE method generated a little higher electron number density value than the Stark broadening, method, but within the experimental uncertainty range. Comparisons of Ne determined by the two methods show the presence of a linear relation which is independent of laser energy or laser wavelength. These results show the applicability of the SBE method for Are determination, especially when the system does not have any pure emission lines whose electron impact factor is known, Also use of Mg lines gives superior results than Al lines. 展开更多
关键词 plasma parameter laser induced plasma plasma electron density Saha-Boltzmannmethod Stark broadening method
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Oxygen Vacancy-induced Electron Density Tuning of Fe_(3)O_(4) for Enhanced Oxygen Evolution Catalysis 被引量:4
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作者 Lulu Gao Chongyang Tang +8 位作者 Jiangchao Liu Lanli He Hongbo Wang Zunjian Ke Wenqing Li Changzhong Jiang Dong He Li Cheng Xiangheng Xiao 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2021年第3期392-398,共7页
Despite the tremendous efforts devoted to enhancing the activity of oxygen evolution reaction(OER)catalysts,there is still a huge challenge to deeply understand the electronic structure characteristics of transition m... Despite the tremendous efforts devoted to enhancing the activity of oxygen evolution reaction(OER)catalysts,there is still a huge challenge to deeply understand the electronic structure characteristics of transition metal oxide to guide the design of more active catalysts.Herein,Fe_(3)O_(4)with oxygen vacancies(Fe_(3)O_(4)-Vac)was synthesized via Ar ion irradiation method and its OER activity was greatly improved by properly modulating the electron density around Fe atoms.The electron density of Fe_(3)O_(4)-Vac around Fe atoms increased compared to that of Fe_(3)O_(4)according to the characterization of synchrotron-based X-ray absorption near-edge structure(XANES),extended X-ray absorption fine structure(EXAFS)spectra,and density functional theory(DFT)calculation.Moreover,the DFT results indicate the enhancement of the desorption of HOO^(*)groups which significantly reduced the OER reaction barrier.Fe_(3)O_(4)-Vac catalyst shows an overpotential of 353 m V,lower than that of Fe OOH(853 m V)and Fe_(3)O_(4)(415 m V)at 10 m A cm^(-2),and a low Tafel slope of 50 m V dec^(-1)in 1 M KOH,which was even better than commercial RuO_(2)at high potential.This modulation approach provides us with valuable insights for exploring efficient and robust water-splitting electrocatalysts. 展开更多
关键词 electron density ion irradiation oxygen evolution reaction oxygen vacancy
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Geometries, Electronic Structures, and Electron Detachment Energies of Small Boron Sulfide Anions: A Density Functional Theory Investigation 被引量:1
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作者 郭巧灵 郭谨昌 李思殿 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2008年第6期651-658,共8页
A density functional theory investigation on the geometries, electronic structures, and electron detachment energies of BS, BS2, B(BS)2 and B(BS)3 has been performed in this work. The linear ground-state structure... A density functional theory investigation on the geometries, electronic structures, and electron detachment energies of BS, BS2, B(BS)2 and B(BS)3 has been performed in this work. The linear ground-state structures of BS (C∞v, ^1∑^+) and BS2^- (O∞h, ^1∑g^+) prove to be similar to the previously reported BO and BO2 with systematically lower electron detachment energies. Small boron sulfide clusters are found to favor the formation of -B=S groups which function basically as a-radicals and dominate the ground-state structures of the systems. The perfect linear B(BS)2^-(D∞h, ^3∑g) and beautiful equilateral triangle B(BS)3^- (D3h,^2A1”) turn out to be analogous to the well-known C2v BH2 and O3h BH3, respectively. The electron affinities of BS, BS2, B(BS)2 and B(BS)3 are predicted to be 2.3, 3.69, 3.00 and 3.45 eV, respectively. The electron detachment energies calculated for BS^-, BS2^-, B(BS)2^-, and B(BS)3^- may facilitate future photoelectron spectroscopy measurements to characterize the geometrical and electronic structures of these anions. 展开更多
关键词 boron sulfides density functional theory GEOMETRIES electronic structures electron detachment energies photoelectron spectroscopy
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Results of Ionospheric Heating Experiments Involving an Enhancement in Electron Density in the High Latitude Ionosphere 被引量:1
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作者 WU Jun WU Jian Zhengwen 《Plasma Science and Technology》 SCIE EI CAS CSCD 2016年第9期890-896,共7页
Observations are presented of the phenomenon of the enhancement in electron density and temperature that is caused by a powerful pump wave at a frequency near the fifth gyrofrequency. The observations show that the ap... Observations are presented of the phenomenon of the enhancement in electron density and temperature that is caused by a powerful pump wave at a frequency near the fifth gyrofrequency. The observations show that the apparent enhancement in electron density extending over a wide altitude range and the enhancement in electron temperature around the reflection altitude occur as a function of pump frequency. Additionally, the plasma line spectra show unusual behavior as a function of pump frequency. In conclusion, the upper hybrid wave resonance excited by the pump wave plays a dominating role and leads to the enhancement in electron temperature at the upper hybrid altitude. The phenomenon of apparent enhancement in electron density does not correspond to the true enhancement in electron density, this may be due to some mechanism that preferentially involves the plasma transport process and leads to the strong backscatter of radar wave along the magnetic line, which remains to be determined. 展开更多
关键词 ionospheric heating electron density enhancement electron temperatureenhancement
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