In the real-time plasma electron density measurement using far infrared (FIR) laser interferometry, the plasma electron density can be calculated by measuring the real time phase difference between the reference sig...In the real-time plasma electron density measurement using far infrared (FIR) laser interferometry, the plasma electron density can be calculated by measuring the real time phase difference between the reference signal and the probe signal. A novel Real-time Phase Jump Process (RPJP) method is applied to the HL-2A tokamak. With this method, the phase difference 1 precision is up to 1/3600 fringe (1 fringe is equal to a phase shift of 2π), and the dynamic measure- ment range is extensible 65536 fringes. The time resolution of the phase difference is 80 ns, while the feedback delay is 180 its.展开更多
A real-time data processing system is designed for the carbon dioxide dispersion interferometer(CO_(2)-DI)on EAST.The system utilizes the parallel and pipelining capabilities of an fieldprogrammable gate array(FPGA)to...A real-time data processing system is designed for the carbon dioxide dispersion interferometer(CO_(2)-DI)on EAST.The system utilizes the parallel and pipelining capabilities of an fieldprogrammable gate array(FPGA)to digitize and process the intensity of signals from the detector.Finally,the real-time electron density signals are exported through a digital-to-analog converter(DAC)module in the form of analog signals.The system has been successfully applied in the CO_(2)-DI system to provide low-latency electron density input to the plasma control system on EAST.Experimental results of the latest campaign with long-pulse discharges on EAST(2022–2023)demonstrate that the system can respond effectively in the case of rapid density changes,proving its reliability and accuracy for future electron density calculation.展开更多
Far-infrared(FIR)interferometer is widely used to measure the electron density in the magnetically confined fusion plasma devices.A new FIR laser interferometer with a total of 13 channels(8 horizontal channels and 5 ...Far-infrared(FIR)interferometer is widely used to measure the electron density in the magnetically confined fusion plasma devices.A new FIR laser interferometer with a total of 13 channels(8 horizontal channels and 5 oblique channels)is under development on the HL-3tokamak by using the formic-acid laser(HCOOH,f=694 GHz).In order to investigate the boundary electron density activity during the divertor discharge,three horizontal interferometry channels located at Z=-97,-76,76.5 cm have been successfully developed on HL-3 in 2023,and put into operation in recent experimental campaign,with a time resolution of<1.0μs and lineintegrated electron density resolution of~7.0×10^(16) m^(-2).This paper mainly focuses on the optical design of the three-channel interferometry system,as well as optical elements and recent experimental result on HL-3.展开更多
A non-contact low-frequency(LF)method of diagnosing the plasma surrounding a scaled model in a shock tube is proposed.This method utilizes the phase shift occurring after the transmission of an LF alternating magnetic...A non-contact low-frequency(LF)method of diagnosing the plasma surrounding a scaled model in a shock tube is proposed.This method utilizes the phase shift occurring after the transmission of an LF alternating magnetic field through the plasma to directly measure the ratio of the plasma loop average electron density to collision frequency.An equivalent circuit model is used to analyze the relationship of the phase shift of the magnetic field component of LF electromagnetic waves with the plasma electron density and collision frequency.The applicable range of the LF method on a given plasma scale is analyzed.The upper diagnostic limit for the ratio of the electron density(unit:m^(-3))to collision frequency(unit:Hz)exceeds 1×10^(11),enabling an electron density to exceed 1×10^(20)m^(-3)and a collision frequency to be less than 1 GHz.In this work,the feasibility of using the LF phase shift to implement the plasma diagnosis is also assessed.Diagnosis experiments on shock tube equipment are conducted by using both the electrostatic probe method and LF method.By comparing the diagnostic results of the two methods,the inversion results are relatively consistent with each other,thereby preliminarily verifying the feasibility of the LF method.The ratio of the electron density to the collision frequency has a relatively uniform distribution during the plasma stabilization.The LF diagnostic path is a loop around the model,which is suitable for diagnosing the plasma that surrounds the model.Finally,the causes of diagnostic discrepancy between the two methods are analyzed.The proposed method provides a new avenue for diagnosing high-density enveloping plasma.展开更多
During the course of ionospheric heating experiments, researchers at the European Incoherent Scatter Scientific Association (EISCAT) observed an apparent electron density enhancement. The enhancement extended over a w...During the course of ionospheric heating experiments, researchers at the European Incoherent Scatter Scientific Association (EISCAT) observed an apparent electron density enhancement. The enhancement extended over a wide range of altitudes, above the reflection altitude of the high-frequency pump wave. However, whether this enhancement actually corresponds to a true enhancement in electron density remains an open question. When the dispersion relation of ion acoustic waves is followed, the frequency ratio of the enhanced ion line to the background ion line suggests that the profile of the effective ion mass may have remained unchanged. Furthermore, the solar radio flux and ion drift velocity indicate no significant changes in the ion species and their densities. In conclusion, the electron density enhancement observed at EISCAT should not, in fact, be considered a true enhancement.展开更多
A real-time operating system (RTOS), also named OS, is designed based on the hardware platform of MC68376, and is implemented in the electronic control system for unit pump in diesel engine. A parallel and time-base...A real-time operating system (RTOS), also named OS, is designed based on the hardware platform of MC68376, and is implemented in the electronic control system for unit pump in diesel engine. A parallel and time-based task division method is introduced and the multi-task software architecture is built in the software system for electronic unit pump (EUP) system. The V-model software development process is used to control algorithm of each task. The simulation results of the hardware-in-the-loop simulation system (HILSS) and the engine experimental results show that the OS is an efficient real-time kernel, and can meet the real-time demands of EUP system; The built multi-task software system is real-time, determinate and reliable. V-model development is a good development process of control algorithms for EUP system, the control precision of control system can be ensured, and the development cycle and cost are also decreased.展开更多
Real-time monitoring and forecast of large scale active population density is of great significance as it can warn and prevent possible public safety accident caused by abnormal population aggregation.Active populatio...Real-time monitoring and forecast of large scale active population density is of great significance as it can warn and prevent possible public safety accident caused by abnormal population aggregation.Active population is defined as the number of people with their mobile phone powered on.Recently,an unfortunate deadly stampede occurred in Shanghai on December 31th 2014 causing the death of 39 people.We hope that our research can help avoid similar unfortunate accident from happening.In this paper we propose a method for active population density real-time monitoring and forecasting based on data from mobile network operators.Our method is based solely on mobile network operators existing infrastructure and barely requires extra investment,and mobile devices play a very limited role in the process of population locating.Four series forecasting methods,namely Simple Exponential Smoothing(SES),Double exponential smoothing(DES),Triple exponential smoothing(TES)and Autoregressive integrated moving average(ARIMA)are used in our experiments.Our experimental results suggest that we can achieve good forecast result for 135 min in future.展开更多
The electronic property of pyrite supercell containing As,Se,Te,Co or Ni hetero atoms were calculated using density functional theory(DFT),and the reactivities of pyrite with oxygen and xanthate were discussed by fr...The electronic property of pyrite supercell containing As,Se,Te,Co or Ni hetero atoms were calculated using density functional theory(DFT),and the reactivities of pyrite with oxygen and xanthate were discussed by frontier orbital methods.The cell volume expands due to the presence of impurity.Co and Ni mainly affect the bands near Fermi levels,while As mainly affects the shallow and deep valence bands,and Se and Te mainly affect the deep valence bands.Electronic density analysis suggests that there exists a strong covalent interaction between hetero atom and its surrounding atoms.By frontier orbital calculation,it is suggested that As,Co and Ni have greater influence on the HOMO and LUMO of pyrite than Se and Te.In addition,pyrite containing As,Co or Ni is easier to oxidize by oxygen than pyrite containing Se or Te,and pyrite containing Co or Ni has greater interaction with collector.These are in agreement with the observed pyrite practice.展开更多
We study the geometries, stabilities, electronic and magnetic properties of (MgO)n (n=2-10) clusters doped with a single Mn atom using the density functional theory with the gener- alized gradient approximation. T...We study the geometries, stabilities, electronic and magnetic properties of (MgO)n (n=2-10) clusters doped with a single Mn atom using the density functional theory with the gener- alized gradient approximation. The optimized geometries show that the impurity Mn atom prefers to replace the Mg atom which has low coordination number in all the lowest-energy MnMgn-1On (n=2-10) structures. The stability analysis clearly represents that the average binding energies of the doped clusters are larger than those of the corresponding pure (MgO)n clusters. Maximum peaks of the second order energy differences are observed for MnMg~_1On clusters at n=6, 9, implying that these clusters exhibit higher stability than their neighboring clusters. In addition, all the Mn-doped Mg clusters exhibit high total magnetic moments with the exception of MnMgO2 which has 3.00μB. Their magnetic behavior is attributed to the impurity Mn atom, the charge transfer modes, and the size of MnMgn- 1On clusters.展开更多
The effect of In doping on the electronic structure and optical properties of SrTiO3 is investigated by the first-principles calculation of plane wave ultra-soft pseudo-potential based on the density function theory ...The effect of In doping on the electronic structure and optical properties of SrTiO3 is investigated by the first-principles calculation of plane wave ultra-soft pseudo-potential based on the density function theory (DFT). The calculated results reveal that due to the hole doping, the Fermi level shifts into valence bands (VBs) for SrTi1-x InxO3 with x = 0.125 and the system exhibits p-type degenerate semiconductor features. It is suggested according to the density of states (DOS) of SrTi0.875In0.125O3 that the band structure of p-type SrTIO3 can be described by a rigid band model. At the same time, the DOS shifts towards high energies and the optical band gap is broadened. The wide band gap, small transition probability and weak absorption due to the low partial density of states (PDOS) of impurity in the Fermi level result in the optical transparency of the film. The optical transmittance of In doped SrTiO3 is higher than 85% in a visible region, and the transmittance improves greatly. And the cut-off wavelength shifts into a blue-light region with the increase of In doping concentration.展开更多
Various incorporation of Au in pyrite and its effects on the geometrical structure,electronic structure and flotability of pyrite were theoretically investigated and fully discussed by performing density functional th...Various incorporation of Au in pyrite and its effects on the geometrical structure,electronic structure and flotability of pyrite were theoretically investigated and fully discussed by performing density functional theory(DFT).The calculated incorporation energy shows that gold would most likely exist in pyrite via incorporating into interstitial lattice sites in the absence of As impurity.As a result of incorporated Au,the covalence levels of the S—Fe and S—S bonds are changed,and the tonicity of Au—S bonds and antibonding of Au—Fe bonds are found to form in the pyrite,which would change the natural flotability of pyrite.The Au impurity energy levels are introduced into the energy band and result in the transformation of pyrite semiconductivity type.The calculated band-gap value suggests that the incorporated Au significantly decreases pyrite semiconductivity level,which enhances the formation and the adsorption stability of dixanthogen during pyrite flotation.The DOS results reveal that the stability and depression difficulty level of pyrites increases in the following order:Fe_(32)S_(63)As<Fe_(32)S_(64)<Fe_(32)S_(63)As Au<Fe_(32)S_(64)Au.展开更多
As advanced linear plasma sources, cascaded arc plasma devices have been used to generate steady plasma with high electron density, high particle flux and low electron temperature. To measure electron density and elec...As advanced linear plasma sources, cascaded arc plasma devices have been used to generate steady plasma with high electron density, high particle flux and low electron temperature. To measure electron density and electron temperature of the plasma device accurately, a laser Thomson scattering(LTS) system, which is generally recognized as the most precise plasma diagnostic method, has been established in our lab in Dalian University of Technology. The electron density has been measured successfully in the region of 4.5?×10^19m^-3 to7.1?×10^20m^-3 and electron temperature in the region of 0.18 eV to 0.58 eV. For comparison,an optical emission spectroscopy(OES) system was established as well. The results showed that the electron excitation temperature(configuration temperature) measured by OES is significantly higher than the electron temperature(kinetic electron temperature) measured by LTS by up to 40% in the given discharge conditions. The results indicate that the cascaded arc plasma is recombining plasma and it is not in local thermodynamic equilibrium(LTE). This leads to significant error using OES when characterizing the electron temperature in a non-LTE plasma.展开更多
This work investigates internal plasma process parameters using a hairpin resonance probe and optical emission spectroscopy. The dependence of electron density and atomic fluorine on the percentage of oxygen in an SF6...This work investigates internal plasma process parameters using a hairpin resonance probe and optical emission spectroscopy. The dependence of electron density and atomic fluorine on the percentage of oxygen in an SF6/O2 discharge was measured using these methods. An RIE Oxford Instruments 80 plus chamber was used for the experiments. Two different process powers (100 W and 300 W) at a constant pressure (100 mTorr) were used, and it was found that the optical emission intensity of the 703.7 nm and 685.6 nm lines of atomic fluorine increased rapidly as oxygen was added to the SF6 discharge, reached their maximum at an O2 fraction of 20% and then decreased with further addition of oxygen. The plasma electron density was also strongly influenced by the addition of O2.展开更多
Emission spectra of a semiconductor bridge (SCB) plasma in a visible range was studied in air. The electron density was measured in a conventional way from the broadening of the Al Ⅰ 394.4 nm Stark width. Based on ...Emission spectra of a semiconductor bridge (SCB) plasma in a visible range was studied in air. The electron density was measured in a conventional way from the broadening of the Al Ⅰ 394.4 nm Stark width. Based on the Saha equation, a system for recording the intensity of Si Ⅰ 390.5 nm and Si Ⅱ 413.1 nm was designed. With this technique, the SCB plasma electron density was measured well and accurately. Moreover, the electron density distribution Vs time was acquired from one SCB discharge. The individual result from the broadening of the Al Ⅰ 394.4 nm Stark width and Saha equation was all in the range of 1015 cm^-3 to 1016 cm^-3. Finally the presumption of the local thermodynamic equilibrium (LTE) condition was validated.展开更多
Ultrafast imaging tools are of great importance for determining the dynamic density distribution in high energy density(HED)matter.In this work,we designed a high energy electron radiography(HEER)system based on a lin...Ultrafast imaging tools are of great importance for determining the dynamic density distribution in high energy density(HED)matter.In this work,we designed a high energy electron radiography(HEER)system based on a linear electron accelerator to evaluate its capability for imaging HED matter.40 MeV electron beams were used to image an aluminum target to study the density resolution and spatial resolution of HEER.The results demonstrate a spatial resolution of tens of micrometers.The interaction of the beams with the target and the beam transport of the transmitted electrons are further simulated with EGS5 and PARMELA codes,with the results showing good agreement with the experimental resolution.Furthermore,the experiment can be improved by adding an aperture at the Fourier plane.展开更多
We report spectroscopic studies on plasma electron number density of laser-induced plasma produced by ns-Nd:YAG laser light pulses on an aluminum sample in air at atmospheric pressure. The effect of different laser e...We report spectroscopic studies on plasma electron number density of laser-induced plasma produced by ns-Nd:YAG laser light pulses on an aluminum sample in air at atmospheric pressure. The effect of different laser energy and the effect of different laser wavelengths were compared. The experimentally observed line profiles of neutral aluminum have been used to extract the excitation temperature using the Boltzmann plot method, whereas the electron number density has been determined from the Stark broadened as well as using the Saha-Boltzmann equation (SBE). Each approach was also carried out by using the AI emission line and Mg emission lines. It was observed that the,SBE method generated a little higher electron number density value than the Stark broadening, method, but within the experimental uncertainty range. Comparisons of Ne determined by the two methods show the presence of a linear relation which is independent of laser energy or laser wavelength. These results show the applicability of the SBE method for Are determination, especially when the system does not have any pure emission lines whose electron impact factor is known, Also use of Mg lines gives superior results than Al lines.展开更多
Despite the tremendous efforts devoted to enhancing the activity of oxygen evolution reaction(OER)catalysts,there is still a huge challenge to deeply understand the electronic structure characteristics of transition m...Despite the tremendous efforts devoted to enhancing the activity of oxygen evolution reaction(OER)catalysts,there is still a huge challenge to deeply understand the electronic structure characteristics of transition metal oxide to guide the design of more active catalysts.Herein,Fe_(3)O_(4)with oxygen vacancies(Fe_(3)O_(4)-Vac)was synthesized via Ar ion irradiation method and its OER activity was greatly improved by properly modulating the electron density around Fe atoms.The electron density of Fe_(3)O_(4)-Vac around Fe atoms increased compared to that of Fe_(3)O_(4)according to the characterization of synchrotron-based X-ray absorption near-edge structure(XANES),extended X-ray absorption fine structure(EXAFS)spectra,and density functional theory(DFT)calculation.Moreover,the DFT results indicate the enhancement of the desorption of HOO^(*)groups which significantly reduced the OER reaction barrier.Fe_(3)O_(4)-Vac catalyst shows an overpotential of 353 m V,lower than that of Fe OOH(853 m V)and Fe_(3)O_(4)(415 m V)at 10 m A cm^(-2),and a low Tafel slope of 50 m V dec^(-1)in 1 M KOH,which was even better than commercial RuO_(2)at high potential.This modulation approach provides us with valuable insights for exploring efficient and robust water-splitting electrocatalysts.展开更多
A density functional theory investigation on the geometries, electronic structures, and electron detachment energies of BS, BS2, B(BS)2 and B(BS)3 has been performed in this work. The linear ground-state structure...A density functional theory investigation on the geometries, electronic structures, and electron detachment energies of BS, BS2, B(BS)2 and B(BS)3 has been performed in this work. The linear ground-state structures of BS (C∞v, ^1∑^+) and BS2^- (O∞h, ^1∑g^+) prove to be similar to the previously reported BO and BO2 with systematically lower electron detachment energies. Small boron sulfide clusters are found to favor the formation of -B=S groups which function basically as a-radicals and dominate the ground-state structures of the systems. The perfect linear B(BS)2^-(D∞h, ^3∑g) and beautiful equilateral triangle B(BS)3^- (D3h,^2A1”) turn out to be analogous to the well-known C2v BH2 and O3h BH3, respectively. The electron affinities of BS, BS2, B(BS)2 and B(BS)3 are predicted to be 2.3, 3.69, 3.00 and 3.45 eV, respectively. The electron detachment energies calculated for BS^-, BS2^-, B(BS)2^-, and B(BS)3^- may facilitate future photoelectron spectroscopy measurements to characterize the geometrical and electronic structures of these anions.展开更多
Observations are presented of the phenomenon of the enhancement in electron density and temperature that is caused by a powerful pump wave at a frequency near the fifth gyrofrequency. The observations show that the ap...Observations are presented of the phenomenon of the enhancement in electron density and temperature that is caused by a powerful pump wave at a frequency near the fifth gyrofrequency. The observations show that the apparent enhancement in electron density extending over a wide altitude range and the enhancement in electron temperature around the reflection altitude occur as a function of pump frequency. Additionally, the plasma line spectra show unusual behavior as a function of pump frequency. In conclusion, the upper hybrid wave resonance excited by the pump wave plays a dominating role and leads to the enhancement in electron temperature at the upper hybrid altitude. The phenomenon of apparent enhancement in electron density does not correspond to the true enhancement in electron density, this may be due to some mechanism that preferentially involves the plasma transport process and leads to the strong backscatter of radar wave along the magnetic line, which remains to be determined.展开更多
基金supported by National Natural Science Foundation of China(Nos.11375195,11275059)the National Magnetic Confinement Fusion Science Program of China(No.2013GB104003)
文摘In the real-time plasma electron density measurement using far infrared (FIR) laser interferometry, the plasma electron density can be calculated by measuring the real time phase difference between the reference signal and the probe signal. A novel Real-time Phase Jump Process (RPJP) method is applied to the HL-2A tokamak. With this method, the phase difference 1 precision is up to 1/3600 fringe (1 fringe is equal to a phase shift of 2π), and the dynamic measure- ment range is extensible 65536 fringes. The time resolution of the phase difference is 80 ns, while the feedback delay is 180 its.
基金funded and supported by the Comprehensive Research Facility for Fusion Technology Program of China(No.2018-000052-73-01-001228)the HFIPS Director’s Fund(No.YZJJKX202301)+1 种基金the Anhui Provincial Major Science and Technology Project(No.2023z020004)Task JB22001 from the Anhui Provincial Department of Economic and Information Technology。
文摘A real-time data processing system is designed for the carbon dioxide dispersion interferometer(CO_(2)-DI)on EAST.The system utilizes the parallel and pipelining capabilities of an fieldprogrammable gate array(FPGA)to digitize and process the intensity of signals from the detector.Finally,the real-time electron density signals are exported through a digital-to-analog converter(DAC)module in the form of analog signals.The system has been successfully applied in the CO_(2)-DI system to provide low-latency electron density input to the plasma control system on EAST.Experimental results of the latest campaign with long-pulse discharges on EAST(2022–2023)demonstrate that the system can respond effectively in the case of rapid density changes,proving its reliability and accuracy for future electron density calculation.
基金supported by the National Magnetic Confinement Fusion Science Program of China(Nos.2019YFE03020004,2018YFE0304102 and 2019YFE03020002)the Department of Science and Technology of Sichuan Province(No.2020YJ0463)。
文摘Far-infrared(FIR)interferometer is widely used to measure the electron density in the magnetically confined fusion plasma devices.A new FIR laser interferometer with a total of 13 channels(8 horizontal channels and 5 oblique channels)is under development on the HL-3tokamak by using the formic-acid laser(HCOOH,f=694 GHz).In order to investigate the boundary electron density activity during the divertor discharge,three horizontal interferometry channels located at Z=-97,-76,76.5 cm have been successfully developed on HL-3 in 2023,and put into operation in recent experimental campaign,with a time resolution of<1.0μs and lineintegrated electron density resolution of~7.0×10^(16) m^(-2).This paper mainly focuses on the optical design of the three-channel interferometry system,as well as optical elements and recent experimental result on HL-3.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.52107162 and 12202479)the Science and Technology Projects of Shaanxi Province,China(Grant Nos.2022CGBX-12 and 2022KXJ-57)the Science and Technology Projects of Xi’an City,China(Grant Nos.23KGDW0023-2022 and 23GXFW0011)。
文摘A non-contact low-frequency(LF)method of diagnosing the plasma surrounding a scaled model in a shock tube is proposed.This method utilizes the phase shift occurring after the transmission of an LF alternating magnetic field through the plasma to directly measure the ratio of the plasma loop average electron density to collision frequency.An equivalent circuit model is used to analyze the relationship of the phase shift of the magnetic field component of LF electromagnetic waves with the plasma electron density and collision frequency.The applicable range of the LF method on a given plasma scale is analyzed.The upper diagnostic limit for the ratio of the electron density(unit:m^(-3))to collision frequency(unit:Hz)exceeds 1×10^(11),enabling an electron density to exceed 1×10^(20)m^(-3)and a collision frequency to be less than 1 GHz.In this work,the feasibility of using the LF phase shift to implement the plasma diagnosis is also assessed.Diagnosis experiments on shock tube equipment are conducted by using both the electrostatic probe method and LF method.By comparing the diagnostic results of the two methods,the inversion results are relatively consistent with each other,thereby preliminarily verifying the feasibility of the LF method.The ratio of the electron density to the collision frequency has a relatively uniform distribution during the plasma stabilization.The LF diagnostic path is a loop around the model,which is suitable for diagnosing the plasma that surrounds the model.Finally,the causes of diagnostic discrepancy between the two methods are analyzed.The proposed method provides a new avenue for diagnosing high-density enveloping plasma.
基金supported by research organizations in China (CRIRP), Finland (SA), Japan (NIPR and STEL), Norway (NFR), Sweden (VR), and the United Kingdom (NERC)supported by the Taishan Scholars Project of Shandong Province (Grant No. ts20190968)supported by the foundation of National Key Laboratory of Electromagnetic Environment (Grant No. 6142403230303)
文摘During the course of ionospheric heating experiments, researchers at the European Incoherent Scatter Scientific Association (EISCAT) observed an apparent electron density enhancement. The enhancement extended over a wide range of altitudes, above the reflection altitude of the high-frequency pump wave. However, whether this enhancement actually corresponds to a true enhancement in electron density remains an open question. When the dispersion relation of ion acoustic waves is followed, the frequency ratio of the enhanced ion line to the background ion line suggests that the profile of the effective ion mass may have remained unchanged. Furthermore, the solar radio flux and ion drift velocity indicate no significant changes in the ion species and their densities. In conclusion, the electron density enhancement observed at EISCAT should not, in fact, be considered a true enhancement.
文摘A real-time operating system (RTOS), also named OS, is designed based on the hardware platform of MC68376, and is implemented in the electronic control system for unit pump in diesel engine. A parallel and time-based task division method is introduced and the multi-task software architecture is built in the software system for electronic unit pump (EUP) system. The V-model software development process is used to control algorithm of each task. The simulation results of the hardware-in-the-loop simulation system (HILSS) and the engine experimental results show that the OS is an efficient real-time kernel, and can meet the real-time demands of EUP system; The built multi-task software system is real-time, determinate and reliable. V-model development is a good development process of control algorithms for EUP system, the control precision of control system can be ensured, and the development cycle and cost are also decreased.
文摘Real-time monitoring and forecast of large scale active population density is of great significance as it can warn and prevent possible public safety accident caused by abnormal population aggregation.Active population is defined as the number of people with their mobile phone powered on.Recently,an unfortunate deadly stampede occurred in Shanghai on December 31th 2014 causing the death of 39 people.We hope that our research can help avoid similar unfortunate accident from happening.In this paper we propose a method for active population density real-time monitoring and forecasting based on data from mobile network operators.Our method is based solely on mobile network operators existing infrastructure and barely requires extra investment,and mobile devices play a very limited role in the process of population locating.Four series forecasting methods,namely Simple Exponential Smoothing(SES),Double exponential smoothing(DES),Triple exponential smoothing(TES)and Autoregressive integrated moving average(ARIMA)are used in our experiments.Our experimental results suggest that we can achieve good forecast result for 135 min in future.
基金Project (50864001) supported by the National Natural Science Foundation of China
文摘The electronic property of pyrite supercell containing As,Se,Te,Co or Ni hetero atoms were calculated using density functional theory(DFT),and the reactivities of pyrite with oxygen and xanthate were discussed by frontier orbital methods.The cell volume expands due to the presence of impurity.Co and Ni mainly affect the bands near Fermi levels,while As mainly affects the shallow and deep valence bands,and Se and Te mainly affect the deep valence bands.Electronic density analysis suggests that there exists a strong covalent interaction between hetero atom and its surrounding atoms.By frontier orbital calculation,it is suggested that As,Co and Ni have greater influence on the HOMO and LUMO of pyrite than Se and Te.In addition,pyrite containing As,Co or Ni is easier to oxidize by oxygen than pyrite containing Se or Te,and pyrite containing Co or Ni has greater interaction with collector.These are in agreement with the observed pyrite practice.
文摘We study the geometries, stabilities, electronic and magnetic properties of (MgO)n (n=2-10) clusters doped with a single Mn atom using the density functional theory with the gener- alized gradient approximation. The optimized geometries show that the impurity Mn atom prefers to replace the Mg atom which has low coordination number in all the lowest-energy MnMgn-1On (n=2-10) structures. The stability analysis clearly represents that the average binding energies of the doped clusters are larger than those of the corresponding pure (MgO)n clusters. Maximum peaks of the second order energy differences are observed for MnMg~_1On clusters at n=6, 9, implying that these clusters exhibit higher stability than their neighboring clusters. In addition, all the Mn-doped Mg clusters exhibit high total magnetic moments with the exception of MnMgO2 which has 3.00μB. Their magnetic behavior is attributed to the impurity Mn atom, the charge transfer modes, and the size of MnMgn- 1On clusters.
基金Project supported by the Natural Science Foundation of Shaanxi Province, China (Grant No 2005F06).
文摘The effect of In doping on the electronic structure and optical properties of SrTiO3 is investigated by the first-principles calculation of plane wave ultra-soft pseudo-potential based on the density function theory (DFT). The calculated results reveal that due to the hole doping, the Fermi level shifts into valence bands (VBs) for SrTi1-x InxO3 with x = 0.125 and the system exhibits p-type degenerate semiconductor features. It is suggested according to the density of states (DOS) of SrTi0.875In0.125O3 that the band structure of p-type SrTIO3 can be described by a rigid band model. At the same time, the DOS shifts towards high energies and the optical band gap is broadened. The wide band gap, small transition probability and weak absorption due to the low partial density of states (PDOS) of impurity in the Fermi level result in the optical transparency of the film. The optical transmittance of In doped SrTiO3 is higher than 85% in a visible region, and the transmittance improves greatly. And the cut-off wavelength shifts into a blue-light region with the increase of In doping concentration.
基金Projects(51504109,51504107)supported by the National Natural Science Foundation of China
文摘Various incorporation of Au in pyrite and its effects on the geometrical structure,electronic structure and flotability of pyrite were theoretically investigated and fully discussed by performing density functional theory(DFT).The calculated incorporation energy shows that gold would most likely exist in pyrite via incorporating into interstitial lattice sites in the absence of As impurity.As a result of incorporated Au,the covalence levels of the S—Fe and S—S bonds are changed,and the tonicity of Au—S bonds and antibonding of Au—Fe bonds are found to form in the pyrite,which would change the natural flotability of pyrite.The Au impurity energy levels are introduced into the energy band and result in the transformation of pyrite semiconductivity type.The calculated band-gap value suggests that the incorporated Au significantly decreases pyrite semiconductivity level,which enhances the formation and the adsorption stability of dixanthogen during pyrite flotation.The DOS results reveal that the stability and depression difficulty level of pyrites increases in the following order:Fe_(32)S_(63)As<Fe_(32)S_(64)<Fe_(32)S_(63)As Au<Fe_(32)S_(64)Au.
基金supported by the National Magnetic Confinement Fusion Science Program of China(No.2013GB109005)the Fundamental Research Funds for the Central Universities(Nos.DUT15RC(3)072,DUT15TD44,DUT16TD13)
文摘As advanced linear plasma sources, cascaded arc plasma devices have been used to generate steady plasma with high electron density, high particle flux and low electron temperature. To measure electron density and electron temperature of the plasma device accurately, a laser Thomson scattering(LTS) system, which is generally recognized as the most precise plasma diagnostic method, has been established in our lab in Dalian University of Technology. The electron density has been measured successfully in the region of 4.5?×10^19m^-3 to7.1?×10^20m^-3 and electron temperature in the region of 0.18 eV to 0.58 eV. For comparison,an optical emission spectroscopy(OES) system was established as well. The results showed that the electron excitation temperature(configuration temperature) measured by OES is significantly higher than the electron temperature(kinetic electron temperature) measured by LTS by up to 40% in the given discharge conditions. The results indicate that the cascaded arc plasma is recombining plasma and it is not in local thermodynamic equilibrium(LTE). This leads to significant error using OES when characterizing the electron temperature in a non-LTE plasma.
基金supported by the EC Framework 7 IMPROVE research project (IR -2008-0013)the Science Foundation Ireland PRECISION project (08-SRC-I1411)
文摘This work investigates internal plasma process parameters using a hairpin resonance probe and optical emission spectroscopy. The dependence of electron density and atomic fluorine on the percentage of oxygen in an SF6/O2 discharge was measured using these methods. An RIE Oxford Instruments 80 plus chamber was used for the experiments. Two different process powers (100 W and 300 W) at a constant pressure (100 mTorr) were used, and it was found that the optical emission intensity of the 703.7 nm and 685.6 nm lines of atomic fluorine increased rapidly as oxygen was added to the SF6 discharge, reached their maximum at an O2 fraction of 20% and then decreased with further addition of oxygen. The plasma electron density was also strongly influenced by the addition of O2.
基金supported by National Major Base Projects of China
文摘Emission spectra of a semiconductor bridge (SCB) plasma in a visible range was studied in air. The electron density was measured in a conventional way from the broadening of the Al Ⅰ 394.4 nm Stark width. Based on the Saha equation, a system for recording the intensity of Si Ⅰ 390.5 nm and Si Ⅱ 413.1 nm was designed. With this technique, the SCB plasma electron density was measured well and accurately. Moreover, the electron density distribution Vs time was acquired from one SCB discharge. The individual result from the broadening of the Al Ⅰ 394.4 nm Stark width and Saha equation was all in the range of 1015 cm^-3 to 1016 cm^-3. Finally the presumption of the local thermodynamic equilibrium (LTE) condition was validated.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11435015 and 11505251)the Ministry of Science and Technology of China(Grant No.2016YFE0104900)the Chinese Academy of Sciences(Grant Nos.28Y740010 and 113462KYSB20160036)
文摘Ultrafast imaging tools are of great importance for determining the dynamic density distribution in high energy density(HED)matter.In this work,we designed a high energy electron radiography(HEER)system based on a linear electron accelerator to evaluate its capability for imaging HED matter.40 MeV electron beams were used to image an aluminum target to study the density resolution and spatial resolution of HEER.The results demonstrate a spatial resolution of tens of micrometers.The interaction of the beams with the target and the beam transport of the transmitted electrons are further simulated with EGS5 and PARMELA codes,with the results showing good agreement with the experimental resolution.Furthermore,the experiment can be improved by adding an aperture at the Fourier plane.
文摘We report spectroscopic studies on plasma electron number density of laser-induced plasma produced by ns-Nd:YAG laser light pulses on an aluminum sample in air at atmospheric pressure. The effect of different laser energy and the effect of different laser wavelengths were compared. The experimentally observed line profiles of neutral aluminum have been used to extract the excitation temperature using the Boltzmann plot method, whereas the electron number density has been determined from the Stark broadened as well as using the Saha-Boltzmann equation (SBE). Each approach was also carried out by using the AI emission line and Mg emission lines. It was observed that the,SBE method generated a little higher electron number density value than the Stark broadening, method, but within the experimental uncertainty range. Comparisons of Ne determined by the two methods show the presence of a linear relation which is independent of laser energy or laser wavelength. These results show the applicability of the SBE method for Are determination, especially when the system does not have any pure emission lines whose electron impact factor is known, Also use of Mg lines gives superior results than Al lines.
基金financially supported by the National Natural Science Foundation of China(U1867215,11722543,11875211,U1932134)Suzhou Key Industrial Technology Innovation project(SYG201828)+1 种基金Hubei Provincial Natural Science Foundation(2019CFA036)the Fundamental Research Funds for the Central Universities(2042020kf0211)
文摘Despite the tremendous efforts devoted to enhancing the activity of oxygen evolution reaction(OER)catalysts,there is still a huge challenge to deeply understand the electronic structure characteristics of transition metal oxide to guide the design of more active catalysts.Herein,Fe_(3)O_(4)with oxygen vacancies(Fe_(3)O_(4)-Vac)was synthesized via Ar ion irradiation method and its OER activity was greatly improved by properly modulating the electron density around Fe atoms.The electron density of Fe_(3)O_(4)-Vac around Fe atoms increased compared to that of Fe_(3)O_(4)according to the characterization of synchrotron-based X-ray absorption near-edge structure(XANES),extended X-ray absorption fine structure(EXAFS)spectra,and density functional theory(DFT)calculation.Moreover,the DFT results indicate the enhancement of the desorption of HOO^(*)groups which significantly reduced the OER reaction barrier.Fe_(3)O_(4)-Vac catalyst shows an overpotential of 353 m V,lower than that of Fe OOH(853 m V)and Fe_(3)O_(4)(415 m V)at 10 m A cm^(-2),and a low Tafel slope of 50 m V dec^(-1)in 1 M KOH,which was even better than commercial RuO_(2)at high potential.This modulation approach provides us with valuable insights for exploring efficient and robust water-splitting electrocatalysts.
基金Supported by the National Natural Science Foundation of China (No. 20573088)
文摘A density functional theory investigation on the geometries, electronic structures, and electron detachment energies of BS, BS2, B(BS)2 and B(BS)3 has been performed in this work. The linear ground-state structures of BS (C∞v, ^1∑^+) and BS2^- (O∞h, ^1∑g^+) prove to be similar to the previously reported BO and BO2 with systematically lower electron detachment energies. Small boron sulfide clusters are found to favor the formation of -B=S groups which function basically as a-radicals and dominate the ground-state structures of the systems. The perfect linear B(BS)2^-(D∞h, ^3∑g) and beautiful equilateral triangle B(BS)3^- (D3h,^2A1”) turn out to be analogous to the well-known C2v BH2 and O3h BH3, respectively. The electron affinities of BS, BS2, B(BS)2 and B(BS)3 are predicted to be 2.3, 3.69, 3.00 and 3.45 eV, respectively. The electron detachment energies calculated for BS^-, BS2^-, B(BS)2^-, and B(BS)3^- may facilitate future photoelectron spectroscopy measurements to characterize the geometrical and electronic structures of these anions.
基金supported by National Natural Science Foundation of China(No.40831062)
文摘Observations are presented of the phenomenon of the enhancement in electron density and temperature that is caused by a powerful pump wave at a frequency near the fifth gyrofrequency. The observations show that the apparent enhancement in electron density extending over a wide altitude range and the enhancement in electron temperature around the reflection altitude occur as a function of pump frequency. Additionally, the plasma line spectra show unusual behavior as a function of pump frequency. In conclusion, the upper hybrid wave resonance excited by the pump wave plays a dominating role and leads to the enhancement in electron temperature at the upper hybrid altitude. The phenomenon of apparent enhancement in electron density does not correspond to the true enhancement in electron density, this may be due to some mechanism that preferentially involves the plasma transport process and leads to the strong backscatter of radar wave along the magnetic line, which remains to be determined.