SURFACE REARRANGEMENTS OF OXYGEN PLASMA TREATED POLYSTYRENE:SURFACE DYNAMICS AND HUMIDITY EFFECT

The time evolution of oxygen plasma treated polystyrene(PS)surfaces was investigated upon storing them in theair under controlled humidity conditions.The methods of water contact angle,X-ray photoelectron spectroscopy(XPS),sumfrequency generation(SFG)vibrational spectroscopy,and atomic force microscopy(AFM)were used to infer the surfaceproperties and structure.Chemical groups containing oxygen were formed on the PS surface with the plasma treatment,demonstrated by water contact angle and XPS.The surface polarity decayed markedly on time,as assessed by steady increasein the water contact angle as a function of storage time,from zero to around 60°.The observed decay is interpreted as arisingfrom surface rearrangement processes to burying polar groups away from the uppermost layer of the surfaces,which is incontact with air.On the other hand,XPS results show that the chemical composition in the first 3 nm surface layer isunaffected by the surface aging,and the depth profile of oxygen is essentially the same with time.A possible change of PSsurface roughness was examined by AFM,and it showed that the increase of water contact angle during surface aging couldnot be attributed to surface roughness.Thus,it is concluded that surface aging is attributable to surface reorganization andthe motion of oxygen containing groups is confined within the XPS probing depth.SFG spectroscopy,which is intrinsicallyinterface-specific,was used to detect the chemical structure of PS surface at the molecular level after various aging times.The results are interpreted as follows.During the aging of the plasma treated PS surfaces,the oxygen containing groupsundergo reorientation processes toward the polymer bulk and/or parallel to the surface,while the CH_2 moiety stands up onthe PS surface.Our results indicate that the surface configuration changes do not require large length scale segmentalmotions or migration of macromolecules.Motions that are responsible for surface configuration changes could be relativelysmall rotational motions.The aging behaviors under different relative humidity conditions were shown to be similar from18% to 91%,whereas the kinetics of surface polarity decays were faster in higher relative humidity.Here,the surfacerearrangement of polystyrene films that were previously treated by oxygen plasma and aged,and was investigated in terms ofcontact angle after the water immersion.The contact angles of the water-immersed samples were found to change andapproach the initial values before the immersion asymptotically.

Springback behavior of tailor rolled blank in U-shape forming

The springback of tailor rolled blanks with quenching and partitioning steels was investigated.In order to find out the springback behavior and related influence factors for the novel sheets,both experimental and simulation methods have been used to compare and analyze the springback characteristics of equal thickness blanks and tailor rolled blanks in U-channel forming.From the results,the overall springback angles of tailor rolled blanks at thin and thick sides are respectively 106.79° and 99.705°,which are both lower than those of the corresponding equal thickness blanks.Due to the existence of the thickness transition zone,the stress distribution in thin and thick sides of blanks is changed.The location of dangerous region in thin side of tailor rolled blanks is closer to the end of side,and the thick side moved to the middle of straight wall,which are different with the equal thickness blanks.Afterwards,the released quantitles of tangential stress and strain per unit section of blank are adopted to calculate relative springback angles and give novel evaluation criteria for qualitatively analyzing the amount of springback angles.By comparing the results,it shows that the tangential strain method is more suitable for the actual situation.