NaOH/Urea Swelling Treatment and Hydrothermal Degradation of Waste Cotton Fiber

In this study,waste cotton fabric was used as cellulose raw material and pretreated in aqueous NaOH/urea solution system to investigate the effect of NaOH/urea pretreatment solution on the hydrolysis of cotton fiber.The cotton fiber was pretreated with different conditions of aqueous NaOH/urea solution,and the pretreated cotton fiber was hydrolyzed under the same conditions as the original cotton fiber.The results of characterization analysis showed that water retention value of pretreated cotton fiber was higher than that of unpretreated sample.Moreover,the cotton fiber presented both a convoluted structure and a coarser surface,XRD results suggested that the crystallinity degree of cellulose decreased dramatically,more cellulose II appeared,and the hydrogen bond is broken.Among the different pretreatment conditions,the pretreatment effect was the best when the reaction temperature was 0°C,the solid-liquid ratio was 2:50,and the NaOH/urea ratio was 7:12.The hydrolysis experiments of pretreated and unpretreated cotton fibers showed that when the hydrothermal temperature was 230°C,the heat preservation was 2 h,and the hydrochloric acid concentration was 5 wt.%,the glucose yield reached 29.99%.H+could catalyze the hydrolysis of cotton fiber more effectively due to damage to crystal structure and hydrogen bonds.

Review on the Estimating the Effective Way for Managing the Produced Water: Case Study

Water manufactured is the primary waste source in the oil and gas industry. Because of the rising amount of waste worldwide, the environmental effect of wastewater has become a primary environmental concern in recent years. The vast amounts involved have resulted in considerable costs to the industry for handling produced water. This research explains the wide variety of choices for water management. This research’s first phase was water minimization techniques, consisting of three different applications made in three different wells (Well 1, Well 2 and Well 3) and water recycling and reuse by two techniques. In Well 1, Mechanical shut-off technique was applied using through tubing bridge plug and 5 m cement dumped above it to isolate the watered out zone;as per water oil ration plot the water cut is decreased from 100% to 4% and the production is increased from 0 to 400 bcpd. In Well 2, Chemical shut-off technique using a polymer called Brightwater has been used to block channeling through high permeability intervals after PLT log detected it, and the result was brilliant, the water cut decreased from 60% to 25%, also the oil production increase from 500 to 3000 bopd. In Well 3, downhole separator installed in it using workover (unfortunately, this technique is not applied in middle east till the moment so this application is taken from an oil field in Canada)and the result was perfect, the water cut decreased from 70% to 28%, also the oil production increase from 44 to 100 bopd. This study tried to clarify and compare the most widely used water management techniques using one of the Western Desert (W.D.) (enhanced for oil recovery, constructed wetland).