One of the new directions in the field of Cretaceous research is to elucidate the mechanism of the sedimentary transition from the Cretaceous black shales to oceanic red beds. A chemical sequential extraction method w...One of the new directions in the field of Cretaceous research is to elucidate the mechanism of the sedimentary transition from the Cretaceous black shales to oceanic red beds. A chemical sequential extraction method was applied to these two types of rocks from southern Tibet to investigate the burial records of reactive iron. Results indicate that carbonate-associated iron and pyrite are relatively enriched in the black shales, but depleted or absent in red beds. The main feature of the reactive iron in the red beds is relative enrichment of iron oxides （largely hematite）, which occurred during syn-depostion or early diagenesis. The ratio between iron oxides and the total iron indicates an oxygen-enriched environment for red bed deposition. A comparison between the reactive iron burial records and proxies of paleo-productivity suggests that paleo-productivity decreases when the ratio between iron oxides and the total iron increases in the red beds. This phenomenon could imply that the relationship between marine redox and productivity might be one of the reasons for the sedimentary transition from Cretaceous black shale to oceanic red bed deposition.展开更多
The mechanism of sedimentary transition from the Cretaceous black shales to the oceanic red beds is a new and important direction of Cretaceous research. Chemical sequential extraction is applied to study the burial r...The mechanism of sedimentary transition from the Cretaceous black shales to the oceanic red beds is a new and important direction of Cretaceous research. Chemical sequential extraction is applied to study the burial records of reactive phosphorus in the black shale of the Gyabula Formation and oceanic red beds of the Chuangde Formation, Southern Tibet. Results indicate that the principal reactive phosphorus species is the authigenic and carbonate-associated phosphorus （CAP） in the Gyabula Formation and iron oxides-associated phosphorus （FeP） in the Chuangde Formation which accounts for more than half of their own total phosphorus content. While the authigenic and carbonate-associated phosphorus （CAP） is almost equal in the two Formations; the iron oxidesassociated phosphorus is about 1.6 times higher in the Chuangde Formation than that in the Gyabula Formation resulting in a higher content of the total phosphorus in the Chuangde Formation. According to the observations on the marine phosphorus cyde in Modern Ocean, it is found that preferential burial and regeneration of reactive phosphorus corresponds to highly oxic and reducing conditions, respectively, leading to the different distribution of phosphorus in these two distinct type of marine sediments. It is the redox-sensitive behavior of phosphorus cycle to the different redox conditions in the ocean and the controlling effects of phosphorus to the marine production that stimulate the local sedimentary transition from the Cretaceous black shale to the oceanic red beds.展开更多
白垩系大洋红层(Cretaceous Oceanic Red Beds,CORBs)在我国西藏江孜地区广泛发育,以床得组最为典型。本文以床得组红色页岩为研究对象,通过电子探针背散射电子像观察和成分定量分析、主量元素分析、X射线衍射分析,结合CBD(Citrate Bica...白垩系大洋红层(Cretaceous Oceanic Red Beds,CORBs)在我国西藏江孜地区广泛发育,以床得组最为典型。本文以床得组红色页岩为研究对象,通过电子探针背散射电子像观察和成分定量分析、主量元素分析、X射线衍射分析,结合CBD(Citrate Bicarbonate Dithionite)提取铁氧化物前后漫反射光谱分析,认为床得组红色页岩中的铁氧化物只有赤铁矿,没有其它铁氧化物,赤铁矿是唯一的致色铁氧化物。电子探针背散射电子图像显示,赤铁矿分为结晶好和结晶差的两种形态。CBD提取前后反射光谱红度的变化,指示结晶差的赤铁矿的致色作用要远大于结晶好的赤铁矿,主要是细分散状、结晶差的赤铁矿造成了床得组红色页岩的红色。赤铁矿是同沉积-成岩早期阶段的产物,赤铁矿形成所需的铁来源于陆源输入。展开更多
基金This work is supported by the National Key Basic Research Program （2006CB701406）；Natural Science Foundation of China for Youth （40403003） ；Key Project of the Natural Science Foundation of China （40332020）, and is a contribution to IGCP 463.
文摘One of the new directions in the field of Cretaceous research is to elucidate the mechanism of the sedimentary transition from the Cretaceous black shales to oceanic red beds. A chemical sequential extraction method was applied to these two types of rocks from southern Tibet to investigate the burial records of reactive iron. Results indicate that carbonate-associated iron and pyrite are relatively enriched in the black shales, but depleted or absent in red beds. The main feature of the reactive iron in the red beds is relative enrichment of iron oxides （largely hematite）, which occurred during syn-depostion or early diagenesis. The ratio between iron oxides and the total iron indicates an oxygen-enriched environment for red bed deposition. A comparison between the reactive iron burial records and proxies of paleo-productivity suggests that paleo-productivity decreases when the ratio between iron oxides and the total iron increases in the red beds. This phenomenon could imply that the relationship between marine redox and productivity might be one of the reasons for the sedimentary transition from Cretaceous black shale to oceanic red bed deposition.
基金supported by the Natural Science Foundation of China for Youth(40403003)National Key Basic Research Program(2006CB701406)Key Project of Natural Science Foundation of China(40332020),and is a contribution to IGCP 463/555.
文摘The mechanism of sedimentary transition from the Cretaceous black shales to the oceanic red beds is a new and important direction of Cretaceous research. Chemical sequential extraction is applied to study the burial records of reactive phosphorus in the black shale of the Gyabula Formation and oceanic red beds of the Chuangde Formation, Southern Tibet. Results indicate that the principal reactive phosphorus species is the authigenic and carbonate-associated phosphorus （CAP） in the Gyabula Formation and iron oxides-associated phosphorus （FeP） in the Chuangde Formation which accounts for more than half of their own total phosphorus content. While the authigenic and carbonate-associated phosphorus （CAP） is almost equal in the two Formations; the iron oxidesassociated phosphorus is about 1.6 times higher in the Chuangde Formation than that in the Gyabula Formation resulting in a higher content of the total phosphorus in the Chuangde Formation. According to the observations on the marine phosphorus cyde in Modern Ocean, it is found that preferential burial and regeneration of reactive phosphorus corresponds to highly oxic and reducing conditions, respectively, leading to the different distribution of phosphorus in these two distinct type of marine sediments. It is the redox-sensitive behavior of phosphorus cycle to the different redox conditions in the ocean and the controlling effects of phosphorus to the marine production that stimulate the local sedimentary transition from the Cretaceous black shale to the oceanic red beds.
