Composite Li metal anodes based on three-dimensional(3D) porous frameworks have been considered as an effective material for achieving stable Li metal batteries with high energy density.However,uneven Li deposition be...Composite Li metal anodes based on three-dimensional(3D) porous frameworks have been considered as an effective material for achieving stable Li metal batteries with high energy density.However,uneven Li deposition behavior still occurs at the top of 3D frameworks owing to the local accumulation of Li ions.To promote uniform Li deposition without top dendrite growth,herein,a layered multifunctional framework based on oxidation-treated polyacrylonitrile(OPAN) and metal-organic framework(MOF) derivatives was proposed for rationally regulating the distribution of Li ions flux,nucleation sites,and electrical conductivity.Profiting from these merits,the OPAN/carbon nano fiber-MOF(CMOF) composite framework demonstrated a reversible Li plating/stripping behavior for 500 cycles with a stable Coulombic efficiency of around 99.0% at the current density of 2 mA/cm~2.Besides,such a Li composite anode exhibited a superior cycle lifespan of over 1300 h under a low polarized voltage of 18 mV in symmetrical cells.When the Li composite anode was paired with LiFePO_(4)(LFP) cathode,the obtained full cell exhibited a stable cycling over 500 cycles.Moreover,the COMSOL Multiphysics simulation was conducted to reveal the effects on homogeneous Li ions distribution derived from the above-mentioned OPAN/CMOF framework and electrical insulation/conduction design.These electrochemical and simulated results shed light on the difficulties of designing stable and safe Li metal anode via optimizing the 3D frameworks.展开更多
The issue whether transition from laminar flow to turbulent flow on a flat plate should be characterized as a vorticity redistribution process or a vorticity increasing process is investigated by a high-order direct n...The issue whether transition from laminar flow to turbulent flow on a flat plate should be characterized as a vorticity redistribution process or a vorticity increasing process is investigated by a high-order direct numerical simulation on a flat plate boundary layer.The local vorticity can either increase or decrease due to tilting and stretching of vortex filaments according to the vorticity transport equation while the total vorticity cannot be changed in a boundary layer flow in conforming to the Fppl theorem of total vorticity conservation.This seemingly contradictory problem can be well resolved by the introduction of a new term:volume vorticity of a vorticity tube,defined as vorticity flux timed by the vorticity tube length.It has been shown that,although vorticity flux must keep conserved,the total volume vorticity is significantly increased during boundary layer transition according to our direct numerical simulation(DNS)computation,which directly results from the lengthening(stretching and tilting)of vortex filaments.Therefore,the flow transition is a process with appreciable increase of volume vorticity,and cannot be only viewed as a vorticity redistribution process.展开更多
基金supported by the National Natural Science Foundation of China (52302292, 52302058, 52302085)the China Postdoctoral Science Foundation (2021M702225)+1 种基金the Anhui Province University Natural Science Research Project (2023AH030093, 2023AH040301)the Startup Research Fund of Chaohu University (KYQD-2023005, KYQD-2023051)。
文摘Composite Li metal anodes based on three-dimensional(3D) porous frameworks have been considered as an effective material for achieving stable Li metal batteries with high energy density.However,uneven Li deposition behavior still occurs at the top of 3D frameworks owing to the local accumulation of Li ions.To promote uniform Li deposition without top dendrite growth,herein,a layered multifunctional framework based on oxidation-treated polyacrylonitrile(OPAN) and metal-organic framework(MOF) derivatives was proposed for rationally regulating the distribution of Li ions flux,nucleation sites,and electrical conductivity.Profiting from these merits,the OPAN/carbon nano fiber-MOF(CMOF) composite framework demonstrated a reversible Li plating/stripping behavior for 500 cycles with a stable Coulombic efficiency of around 99.0% at the current density of 2 mA/cm~2.Besides,such a Li composite anode exhibited a superior cycle lifespan of over 1300 h under a low polarized voltage of 18 mV in symmetrical cells.When the Li composite anode was paired with LiFePO_(4)(LFP) cathode,the obtained full cell exhibited a stable cycling over 500 cycles.Moreover,the COMSOL Multiphysics simulation was conducted to reveal the effects on homogeneous Li ions distribution derived from the above-mentioned OPAN/CMOF framework and electrical insulation/conduction design.These electrochemical and simulated results shed light on the difficulties of designing stable and safe Li metal anode via optimizing the 3D frameworks.
基金supported by Department of Mathematics at University of Texas at Arlingtonthe Chinese Scholarship Council(CSC)for financial support
文摘The issue whether transition from laminar flow to turbulent flow on a flat plate should be characterized as a vorticity redistribution process or a vorticity increasing process is investigated by a high-order direct numerical simulation on a flat plate boundary layer.The local vorticity can either increase or decrease due to tilting and stretching of vortex filaments according to the vorticity transport equation while the total vorticity cannot be changed in a boundary layer flow in conforming to the Fppl theorem of total vorticity conservation.This seemingly contradictory problem can be well resolved by the introduction of a new term:volume vorticity of a vorticity tube,defined as vorticity flux timed by the vorticity tube length.It has been shown that,although vorticity flux must keep conserved,the total volume vorticity is significantly increased during boundary layer transition according to our direct numerical simulation(DNS)computation,which directly results from the lengthening(stretching and tilting)of vortex filaments.Therefore,the flow transition is a process with appreciable increase of volume vorticity,and cannot be only viewed as a vorticity redistribution process.
