In a preceding publication a fundamentally oriented and irreversible world was shown to be derivable from the important principle of least action. A consequence of such a paradigm change is avoidance of paradoxes with...In a preceding publication a fundamentally oriented and irreversible world was shown to be derivable from the important principle of least action. A consequence of such a paradigm change is avoidance of paradoxes within a “dynamic” quantum physics. This becomes essentially possible because fundamental irreversibility allows consideration of the “entropy” concept in elementary processes. For this reason, and for a compensation of entropy in the spread out energy of the wave, the duality of particle and wave has to be mediated via an information self-image of matter. In this publication considerations are extended to irreversible thermodynamics, to gravitation and cosmology with its dependence on quantum interpretations. The information self-image of matter around particles could be identified with gravitation. Because information can also impose an always constant light velocity there is no need any more to attribute such a property to empty space, as done in relativity theory. In addition, the possibility is recognized to consider entropy generation by expanding photon fields in the universe. Via a continuous activation of information on matter photons can generate entropy and release small energy packages without interacting with matter. This facilitates a new interpretation of galactic redshift, emphasizes an information link between quantum- and cosmological phenomena, and evidences an information-triggered origin of the universe. Self-organized processes approach maximum entropy production within their constraints. In a far from equilibrium world also information, with its energy content, can self-organize to a higher hierarchy of computation. It is here identified with consciousness. This appears to explain evolution of spirit and intelligence on a materialistic basis. Also gravitation, here identified as information on matter, could, under special conditions, self-organize to act as a super-gravitation, offering an alternative to dark matter. Time is not an illusion, but has to be understood as flux of action, which is the ultimate reality of change. The concept of an irreversible physical world opens a route towards a rational understanding of complex contexts in nature.展开更多
The structure stability and electronic and optical properties of a series of Au@ZnS core-shell nanocomposites with different sizes were investigated theoretically by first-principle calculation based on density functi...The structure stability and electronic and optical properties of a series of Au@ZnS core-shell nanocomposites with different sizes were investigated theoretically by first-principle calculation based on density functional theory(DFT).A series of Aun@(ZnS)(42)structures with different n values from 6 to 16 were optimized and obtained.Based on the core-shell interaction energy and second-order difference of total energy of these structures,it is found that Au(13)@(ZnS)(42)turns out to be the most stable structure.Based on the model of Au(13)@(ZnS)(42),the density of state and charge density difference were studied and provided a deeper understanding of the electronic structures of Au@ZnS.On the other hand,absorption coefficient and dielectric function were investigated to study the optical properties.It is found that an optical absorption peak appears in visible-light region,indicating that the photo-catalytic can be improved prominently due to the optical redshift to visible-light region when forming core-shell structure from ZnS bulk.And the redshift phenomenon accords well with experiment.Furthermore,the electronic structure further confirms the existence of redshift of optical absorption spectrum.展开更多
文摘In a preceding publication a fundamentally oriented and irreversible world was shown to be derivable from the important principle of least action. A consequence of such a paradigm change is avoidance of paradoxes within a “dynamic” quantum physics. This becomes essentially possible because fundamental irreversibility allows consideration of the “entropy” concept in elementary processes. For this reason, and for a compensation of entropy in the spread out energy of the wave, the duality of particle and wave has to be mediated via an information self-image of matter. In this publication considerations are extended to irreversible thermodynamics, to gravitation and cosmology with its dependence on quantum interpretations. The information self-image of matter around particles could be identified with gravitation. Because information can also impose an always constant light velocity there is no need any more to attribute such a property to empty space, as done in relativity theory. In addition, the possibility is recognized to consider entropy generation by expanding photon fields in the universe. Via a continuous activation of information on matter photons can generate entropy and release small energy packages without interacting with matter. This facilitates a new interpretation of galactic redshift, emphasizes an information link between quantum- and cosmological phenomena, and evidences an information-triggered origin of the universe. Self-organized processes approach maximum entropy production within their constraints. In a far from equilibrium world also information, with its energy content, can self-organize to a higher hierarchy of computation. It is here identified with consciousness. This appears to explain evolution of spirit and intelligence on a materialistic basis. Also gravitation, here identified as information on matter, could, under special conditions, self-organize to act as a super-gravitation, offering an alternative to dark matter. Time is not an illusion, but has to be understood as flux of action, which is the ultimate reality of change. The concept of an irreversible physical world opens a route towards a rational understanding of complex contexts in nature.
基金financially supported by the National Key Research and Development Program of China(Nos.2016YFB0700500 and 2018YFB0704300)。
文摘The structure stability and electronic and optical properties of a series of Au@ZnS core-shell nanocomposites with different sizes were investigated theoretically by first-principle calculation based on density functional theory(DFT).A series of Aun@(ZnS)(42)structures with different n values from 6 to 16 were optimized and obtained.Based on the core-shell interaction energy and second-order difference of total energy of these structures,it is found that Au(13)@(ZnS)(42)turns out to be the most stable structure.Based on the model of Au(13)@(ZnS)(42),the density of state and charge density difference were studied and provided a deeper understanding of the electronic structures of Au@ZnS.On the other hand,absorption coefficient and dielectric function were investigated to study the optical properties.It is found that an optical absorption peak appears in visible-light region,indicating that the photo-catalytic can be improved prominently due to the optical redshift to visible-light region when forming core-shell structure from ZnS bulk.And the redshift phenomenon accords well with experiment.Furthermore,the electronic structure further confirms the existence of redshift of optical absorption spectrum.
