The distribution of reducing gas in a shaft furnace dominates the temperature profile,gas utilization ratio,metallization degree and is the overwhelming factor for stable,high productivities and low-energy-consumption...The distribution of reducing gas in a shaft furnace dominates the temperature profile,gas utilization ratio,metallization degree and is the overwhelming factor for stable,high productivities and low-energy-consumption operation.At the same time,the distribution of gas flow is mainly determined by the position of gas inlet,the packed bed porosity distribution as well as its change due to the difference on the mode of top charge and bottom discharge.When injecting position of the process is fixed,the charge mode is the only means for regulating the gas flow distribution.In this paper,a numerical simulation model of burden distribution in the shaft furnace of COREX 3000 has been developed to analyze the porosity distribution under the different charge modes by means of Discrete Element Method(DEM).The effects of the particle size and its distribution under conditions of different charge batches,chute angle,stoke line on the burden surface shape and burden bed particle size distribution and segregation were investigated,and then the porosity distribution in the shaft of corresponding charging pattern was quantitatively accessed.Therefore,the results can be used to optimize the charge patterns base on required gas distribution.展开更多
In recent years, the reformed coke oven gas (COG) was proposed to be used as reducing gas in a shaft furnace. A mathematical model of gas flow based on the reformed COG was built. The effects of the pressure ratio of ...In recent years, the reformed coke oven gas (COG) was proposed to be used as reducing gas in a shaft furnace. A mathematical model of gas flow based on the reformed COG was built. The effects of the pressure ratio of reducing gas to cooling gas (k) on the gas distribution in the shaft furnace were investigated. The calculation results show that k is an important operation parameter, which can obviously affect the gas distribution in the shaft furnace. The value of k should be compromised. Both too big and too small k values are not appropriate, and the most reasonable value for k is 1:1.33.Under this condition, the utilization coefficient of reducing gas, the utilization coefficient of cooling gas and the coefficient of upward gas are 0.94, 0.92 and 1.03, respectively. Based on the validation of physical experiments, the calculated values of the model agreed well with the physical experimental data. Thus, the established model can properly describe the reformed COG distribution in an actual shaft furnace.展开更多
Based on the principles of mass,momentum and heat transfers between the reducing gas and the iron ore solid,a two-dimensional mathematical model for above two phases is established to study the influences of reducing ...Based on the principles of mass,momentum and heat transfers between the reducing gas and the iron ore solid,a two-dimensional mathematical model for above two phases is established to study the influences of reducing gas composition on thermal and reduction conditions in pre-reduction shaft furnace with the temperature ranging from 1 023 to 1 223 K.Due to the strong endothermic effect of iron ore reduction participated by hydrogen (H2),increasing the ratio of carbon monoxide(CO)to H2 enlarges high temperature zone under present calculation conditions,thus improves reduction efficiency inside the furnace.In addition,replacing of the reducing gas with an appropriate proportion of nitrogen(N2)featuring the same temperature has a potential to reduce fuel consumption by as much as 6.5%while the products of similar quality are yielded.展开更多
The occurrence of moissanite(SiC), as xenocrysts in mantle-derived basaltic and kimberlitic rocks sheds light on the interplay between carbon, hydrogen and oxygen in the lithospheric and sublithospheric mantle. SiC is...The occurrence of moissanite(SiC), as xenocrysts in mantle-derived basaltic and kimberlitic rocks sheds light on the interplay between carbon, hydrogen and oxygen in the lithospheric and sublithospheric mantle. SiC is stable only at fO2< △IW-6, while the lithospheric mantle and related melts commonly are considered to be much more oxidized. SiC grains from both basaltic volcanoclastic rocks and kimberlites contain metallic inclusions whose shapes suggest they were entrapped as melts. The inclusions consist of Si^0+ Fe3Si7± FeSi2 Ti ± CaSi2Al2± FeSi2Al3± CaSi2, and some of the phases show euhedral shapes toward Si^0. Crystallographically-oriented cavities are common in SiC, suggesting the former presence of volatile phase(s), and the volatiles extracted from crushed SiC grains contain H2+ CH4± CO2± CO.Our observations suggest that SiC crystalized from metallic melts(Si-Fe-Ti-C ± Al ± Ca), with dissolved H2+ CH4± CO2± CO derived from the sublithospheric mantle and concentrated around interfaces such as the lithosphere-asthenosphere and crust-mantle boundaries. When mafic/ultramafic magmas are continuously fluxed with H2+ CH4 they can be progressively reduced, to a point where silicide melts become immiscible, and crystallize phases such as SiC. The occurrence of SiC in explosive volcanic rocks from different tectonic settings indicates that the delivery of H2+ CH4 from depth may commonly accompany explosive volcanism and modify the redox condition of some lithospheric mantle volumes. The heterogeneity of redox states further influences geochemical reactions such as melting and geophysical properties such as seismic velocity and the viscosity of mantle rocks.展开更多
Corex is an alternative ironmaking process and raceway is one of the important areas to maintain the stability of the furnace. The raceway parameters are well established for blast furnace operation. But for Corex pro...Corex is an alternative ironmaking process and raceway is one of the important areas to maintain the stability of the furnace. The raceway parameters are well established for blast furnace operation. But for Corex process,it has not yet been established and optimized. Thus,a mathematical model was developed to determine various raceway parameters such as RAFT (raceway adiabatic flame temperature),tuyere gas velocity and kinetic energy. The model provides an idea about the raceway geometry,zone temperature and kinetic energy accumulated in tuyere gas. Besides,all the raceway parameters have been analyzed to find out their effects on the Corex process. It is found that RAFT influences the gasification reaction kinetics and higher RAFT generates more CO in reduction gas,which improves the metallisation degree of the DRI in shaft. It is also found that increased gas velocity and kinetic energy generate more fines and demand more coke to maintain char bed permeability. High coke rate increases the production cost and lowers the production of hot metal.展开更多
For a typical pressurized system with a novel dual-stage gas pressure reducing regulator,a system model is established with modular models of various typical components. The simulation study on the whole working perio...For a typical pressurized system with a novel dual-stage gas pressure reducing regulator,a system model is established with modular models of various typical components. The simulation study on the whole working period shows that the general trends and magnitudes of simulation curves are in agreement with experimental measured curves. As the key component in the pressurized system, the regulator is studied by a series of numerical simulations to reveal the influences of various structure parameters on its stability. Furthermore, the variable ranges which can guarantee the stability of regulator and system are obtained to provide guidance for design. The modeling and analysis approach can be applied to other systems and components.展开更多
文摘The distribution of reducing gas in a shaft furnace dominates the temperature profile,gas utilization ratio,metallization degree and is the overwhelming factor for stable,high productivities and low-energy-consumption operation.At the same time,the distribution of gas flow is mainly determined by the position of gas inlet,the packed bed porosity distribution as well as its change due to the difference on the mode of top charge and bottom discharge.When injecting position of the process is fixed,the charge mode is the only means for regulating the gas flow distribution.In this paper,a numerical simulation model of burden distribution in the shaft furnace of COREX 3000 has been developed to analyze the porosity distribution under the different charge modes by means of Discrete Element Method(DEM).The effects of the particle size and its distribution under conditions of different charge batches,chute angle,stoke line on the burden surface shape and burden bed particle size distribution and segregation were investigated,and then the porosity distribution in the shaft of corresponding charging pattern was quantitatively accessed.Therefore,the results can be used to optimize the charge patterns base on required gas distribution.
基金The financial supports of the National Natural Science Foundation of China(NSFC 51874080,NSFC 62001312,NSFC 51774071 and NSFC 51974073)Natural Science Foun-dation of Liaoning(2019-MS-132)are much appreciated.
文摘In recent years, the reformed coke oven gas (COG) was proposed to be used as reducing gas in a shaft furnace. A mathematical model of gas flow based on the reformed COG was built. The effects of the pressure ratio of reducing gas to cooling gas (k) on the gas distribution in the shaft furnace were investigated. The calculation results show that k is an important operation parameter, which can obviously affect the gas distribution in the shaft furnace. The value of k should be compromised. Both too big and too small k values are not appropriate, and the most reasonable value for k is 1:1.33.Under this condition, the utilization coefficient of reducing gas, the utilization coefficient of cooling gas and the coefficient of upward gas are 0.94, 0.92 and 1.03, respectively. Based on the validation of physical experiments, the calculated values of the model agreed well with the physical experimental data. Thus, the established model can properly describe the reformed COG distribution in an actual shaft furnace.
文摘Based on the principles of mass,momentum and heat transfers between the reducing gas and the iron ore solid,a two-dimensional mathematical model for above two phases is established to study the influences of reducing gas composition on thermal and reduction conditions in pre-reduction shaft furnace with the temperature ranging from 1 023 to 1 223 K.Due to the strong endothermic effect of iron ore reduction participated by hydrogen (H2),increasing the ratio of carbon monoxide(CO)to H2 enlarges high temperature zone under present calculation conditions,thus improves reduction efficiency inside the furnace.In addition,replacing of the reducing gas with an appropriate proportion of nitrogen(N2)featuring the same temperature has a potential to reduce fuel consumption by as much as 6.5%while the products of similar quality are yielded.
基金supported by grants from the ARC Centre of Excellence for Core to Crust Fluid Systems。
文摘The occurrence of moissanite(SiC), as xenocrysts in mantle-derived basaltic and kimberlitic rocks sheds light on the interplay between carbon, hydrogen and oxygen in the lithospheric and sublithospheric mantle. SiC is stable only at fO2< △IW-6, while the lithospheric mantle and related melts commonly are considered to be much more oxidized. SiC grains from both basaltic volcanoclastic rocks and kimberlites contain metallic inclusions whose shapes suggest they were entrapped as melts. The inclusions consist of Si^0+ Fe3Si7± FeSi2 Ti ± CaSi2Al2± FeSi2Al3± CaSi2, and some of the phases show euhedral shapes toward Si^0. Crystallographically-oriented cavities are common in SiC, suggesting the former presence of volatile phase(s), and the volatiles extracted from crushed SiC grains contain H2+ CH4± CO2± CO.Our observations suggest that SiC crystalized from metallic melts(Si-Fe-Ti-C ± Al ± Ca), with dissolved H2+ CH4± CO2± CO derived from the sublithospheric mantle and concentrated around interfaces such as the lithosphere-asthenosphere and crust-mantle boundaries. When mafic/ultramafic magmas are continuously fluxed with H2+ CH4 they can be progressively reduced, to a point where silicide melts become immiscible, and crystallize phases such as SiC. The occurrence of SiC in explosive volcanic rocks from different tectonic settings indicates that the delivery of H2+ CH4 from depth may commonly accompany explosive volcanism and modify the redox condition of some lithospheric mantle volumes. The heterogeneity of redox states further influences geochemical reactions such as melting and geophysical properties such as seismic velocity and the viscosity of mantle rocks.
文摘Corex is an alternative ironmaking process and raceway is one of the important areas to maintain the stability of the furnace. The raceway parameters are well established for blast furnace operation. But for Corex process,it has not yet been established and optimized. Thus,a mathematical model was developed to determine various raceway parameters such as RAFT (raceway adiabatic flame temperature),tuyere gas velocity and kinetic energy. The model provides an idea about the raceway geometry,zone temperature and kinetic energy accumulated in tuyere gas. Besides,all the raceway parameters have been analyzed to find out their effects on the Corex process. It is found that RAFT influences the gasification reaction kinetics and higher RAFT generates more CO in reduction gas,which improves the metallisation degree of the DRI in shaft. It is also found that increased gas velocity and kinetic energy generate more fines and demand more coke to maintain char bed permeability. High coke rate increases the production cost and lowers the production of hot metal.
基金financially supported by the National Natural Science Foundation of China (No.11101023)the China Scholarship Council (No.201203070237)
文摘For a typical pressurized system with a novel dual-stage gas pressure reducing regulator,a system model is established with modular models of various typical components. The simulation study on the whole working period shows that the general trends and magnitudes of simulation curves are in agreement with experimental measured curves. As the key component in the pressurized system, the regulator is studied by a series of numerical simulations to reveal the influences of various structure parameters on its stability. Furthermore, the variable ranges which can guarantee the stability of regulator and system are obtained to provide guidance for design. The modeling and analysis approach can be applied to other systems and components.