A kind of second-order implicit fractional step characteristic finite difference method is presented in this paper for the numerically simulation coupled system of enhanced (chemical) oil production in porous media....A kind of second-order implicit fractional step characteristic finite difference method is presented in this paper for the numerically simulation coupled system of enhanced (chemical) oil production in porous media. Some techniques, such as the calculus of variations, energy analysis method, commutativity of the products of difference operators, decomposition of high-order difference operators and the theory of a priori estimates are introduced and an optimal order error estimates in l^2 norm is derived. This method has been applied successfully to the numerical simulation of enhanced oil production in actual oilfields, and the simulation results ate quite interesting and satisfactory.展开更多
A kind of second-order implicit upwind fractional step finite difference methods are presented for the numerical simulation of coupled systems for enhanced (chemical) oil production with capillary force in the porou...A kind of second-order implicit upwind fractional step finite difference methods are presented for the numerical simulation of coupled systems for enhanced (chemical) oil production with capillary force in the porous media. Some techniques, e.g., the calculus of variations, the energy analysis method, the commutativity of the products of difference operators, the decomposition of high-order difference operators, and the theory of a priori estimate, are introduced. An optimal order error estimate in the l2 norm is derived. The method is successfully used in the numerical simulation of the enhanced oil production in actual oilfields. The simulation results are satisfactory and interesting.展开更多
This paper reports a field survey undertaken to determine the availability of raw material for palm kernel oil commercial production for industrial applications. Both industrial and artisanal wastes from palm kernel o...This paper reports a field survey undertaken to determine the availability of raw material for palm kernel oil commercial production for industrial applications. Both industrial and artisanal wastes from palm kernel oil production were also surveyed as raw material (palm kernel seeds) for green energy production. Results of the field study show that 22% of palm kernel seeds (which represents tons of waste) resulting from palm oil processing plants are dumped while at the artisanal level, 80% of palm kernel seed waste is dumped. Analysis of field study data show<span>s</span><span> that large amounts of waste palm kernel seeds are available to enable large scale production of palm kernel oil (PKO) for desirable industrial applications in green energy production. The paper also reports on the physical and chemical properties of Cameroon palm kernel oil (PKO). Palm kernel oil was extracted using mechanical press and solvent extraction. The palm kernel oil (PKO) from Cameroon was analyzed by standard physico-chemical methods. Results of the physical measurements show a specific gravity of PKO of 0.92 kg/L, viscosity of 26.03 cSt and at 5.93 cSt at 40<span style="color:#4F4F4F;font-family:" font-size:14px;white-space:normal;background-color:#ffffff;"=""><span style="color:#4F4F4F;font-family:"font-size:14px;white-space:normal;background-color:#FFFFFF;">°</span></span>C and 100<span style="color:#4F4F4F;font-family:" font-size:14px;white-space:normal;background-color:#ffffff;"=""><span style="color:#4F4F4F;font-family:"font-size:14px;white-space:normal;background-color:#FFFFFF;">°</span></span>C respectively, viscosity index of 185, pour point of 20<span style="color:#4F4F4F;font-family:" font-size:14px;white-space:normal;background-color:#ffffff;"=""><span style="color:#4F4F4F;font-family:"font-size:14px;white-space:normal;background-color:#FFFFFF;">°</span></span>C, cloud point of 29<span style="color:#4F4F4F;font-family:" font-size:14px;white-space:normal;background-color:#ffffff;"=""><span style="color:#4F4F4F;font-family:"font-size:14px;white-space:normal;background-color:#FFFFFF;">°</span></span>C, flash point of 200<span style="color:#4F4F4F;font-family:" font-size:14px;white-space:normal;background-color:#ffffff;"=""><span style="color:#4F4F4F;font-family:"font-size:14px;white-space:normal;background-color:#FFFFFF;">°</span></span>C, aniline point of 105<span style="color:#4F4F4F;font-family:" font-size:14px;white-space:normal;background-color:#ffffff;"=""><span style="color:#4F4F4F;font-family:"font-size:14px;white-space:normal;background-color:#FFFFFF;">°</span></span>F, diesel index of 23, cetane number of 27 and ASTM (American Standards for Testing and Materials) color of less than 2.5. Results of chemical analyses showed an acid val<span>ue of 17.95 mg KOH/g, free fatty <span>acid (FFA) content of 8.98 mg KOH/g, iodine value o</span></span></span><span><span><span>f 2.10</span><span> mg</span></span></span><span> </span><span><span style="font-family:Verdana;">I</span><sub><span style="font-family:Verdana;">2</span></sub><span><span style="font-family:Verdana;">/g</span><span style="font-family:Verdana;">, peroxide value of 2.10 meq/kg, ester value of 123.0 mg KOH/g, hydroxyl value of 93.4 mg OH/g, saponification value of 140.95 mg KOH/g and a sulfur content of 0.016% w/v, signifying low sulfur content. Gas chromatography-mass spectrometry (GC-MS) showed the palm kernel oil to be predominantly made up of glycerides of various fatty acids with higher proportions of C12 to C16 fatty acid residues. Cameroon PKO therefore has a broad spectrum of industrial applications by virtue of its rich physical and chemical properties.</span></span></span>展开更多
Based on the analysis of the production composition of reservoirs developed by the second&tertiary recovery combination(STRC),the relationship between the overall output of the STRC project and the production leve...Based on the analysis of the production composition of reservoirs developed by the second&tertiary recovery combination(STRC),the relationship between the overall output of the STRC project and the production level during the blank water flooding stage is proposed.According to the basic principle of reservoir engineering that the“recovery factor is equal to sweeping coefficient multiplied by oil displacement efficiency”,the formula for calculating the ultimate oil recovery factor of chemical combination flooding reservoir was established.By dividing the reservoir into a series of grids according to differen-tial calculus thinking,the relationship between the ultimate recovery factor of a certain number of grids and the recovery de-gree of the reservoir was established,and then the variation law of oil production rate of the STRC reservoir was obtained.The concept of“oil rate enlargement factor of chemical combination flooding”was defined,and a production calculation method of reservoir developed by STRC was put forward based on practical oilfield development experience.The study shows that the oil production enhancing effect of STRC increases evenly with the in crease of the ratio of STRC displacement efficiency to water displacement efficiency,and increases rapidly with the increase of the ratio of recovery degree at flooding mode conversion to the water displacement efficiency.STRC is more effective in increasing oil production of reservoir with high recovery degree.Through practical tests of the alkali free binary flooding(polymer/surfactant)projects,the relative error of the oil production calculation method of STRC reservoir is about±10%,which meets the requirements of reservoir engineering.展开更多
Cold production is a challenge in the case of heavy oil because of its high viscosity and poor fluidity in reservoir conditions.Alkali-cosolvent-polymer flooding is a type of microemulsion flooding with low costs and ...Cold production is a challenge in the case of heavy oil because of its high viscosity and poor fluidity in reservoir conditions.Alkali-cosolvent-polymer flooding is a type of microemulsion flooding with low costs and possible potential for heavy oil reservoirs.However,the addition of polymer may cause problems with injection in the case of highly viscous oil.Hence,in this study the feasibility of alkali-cosolvent(AC)flooding in heavy oil reservoirs was investigated via several groups of experiments.The interfacial tension between various AC formulations and heavy crude oil was measured to select appropriate formulations.Phase behavior tests were performed to determine the most appropriate formulation and conditions for the generation of a microemulsion.Sandpack flooding experiments were carried out to investigate the displacement efficiency of the selected Ac formulation.The results showed that the interfacial tension between an AC formulation and heavy oil could be reduced to below 1o-3 mN/m but differed greatly between different types of cosolvent.A butanol random polyether series displayed good performance in reducing the water-oil interfacial tension,which made it possible to form a Type Il microemulsion in reservoir conditions.According to the results of the phase behavior tests,the optimal salinity for different formulations with four cosolvent concentrations(0.5 wt%,1 wt%,2 wt%,and 3 wt%)was 4000,8000,14000,and 20000 ppm,respectively.The results of rheological measurements showed that Type Ill microemulsion had a viscosity that was ten times that of water.The results of sandpack flooding experiments showed that,in comparison with waterflooding,the injection of a certain Ac formulation slug could reduce the injection pressure.The pressure gradient during waterflooding and AC flooding was around 870 and 30-57 kPa/m,respectively.With the addition of an AC slug,the displacement efficiency was 30%-50%higher than in the case of waterflooding.展开更多
基金supported by the Major State Basic Research Development Program of China(G19990328)National Tackling Key Program(2011ZX05011-004+6 种基金2011ZX0505220050200069)National Natural Science Foundation of China(11101244112712311077112410372052)Doctorate Foundation of the Ministry of Education of China(20030422047)
文摘A kind of second-order implicit fractional step characteristic finite difference method is presented in this paper for the numerically simulation coupled system of enhanced (chemical) oil production in porous media. Some techniques, such as the calculus of variations, energy analysis method, commutativity of the products of difference operators, decomposition of high-order difference operators and the theory of a priori estimates are introduced and an optimal order error estimates in l^2 norm is derived. This method has been applied successfully to the numerical simulation of enhanced oil production in actual oilfields, and the simulation results ate quite interesting and satisfactory.
基金Project supported by the Major State Basic Research Development Program of China(No.G19990328)the National Natural Science Foundation of China(Nos.10771124,10372052,and 11101244)+2 种基金the National Tackling Key Problems Program of China(Nos.2011ZX05011-004,2011ZX05052,and 2005020069)the Doctorate Foundation of the Ministry of Education of China(No.20030422047)the Natural Science Foundation of Shandong Province of China(No.ZR2011AM015)
文摘A kind of second-order implicit upwind fractional step finite difference methods are presented for the numerical simulation of coupled systems for enhanced (chemical) oil production with capillary force in the porous media. Some techniques, e.g., the calculus of variations, the energy analysis method, the commutativity of the products of difference operators, the decomposition of high-order difference operators, and the theory of a priori estimate, are introduced. An optimal order error estimate in the l2 norm is derived. The method is successfully used in the numerical simulation of the enhanced oil production in actual oilfields. The simulation results are satisfactory and interesting.
文摘This paper reports a field survey undertaken to determine the availability of raw material for palm kernel oil commercial production for industrial applications. Both industrial and artisanal wastes from palm kernel oil production were also surveyed as raw material (palm kernel seeds) for green energy production. Results of the field study show that 22% of palm kernel seeds (which represents tons of waste) resulting from palm oil processing plants are dumped while at the artisanal level, 80% of palm kernel seed waste is dumped. Analysis of field study data show<span>s</span><span> that large amounts of waste palm kernel seeds are available to enable large scale production of palm kernel oil (PKO) for desirable industrial applications in green energy production. The paper also reports on the physical and chemical properties of Cameroon palm kernel oil (PKO). Palm kernel oil was extracted using mechanical press and solvent extraction. The palm kernel oil (PKO) from Cameroon was analyzed by standard physico-chemical methods. Results of the physical measurements show a specific gravity of PKO of 0.92 kg/L, viscosity of 26.03 cSt and at 5.93 cSt at 40<span style="color:#4F4F4F;font-family:" font-size:14px;white-space:normal;background-color:#ffffff;"=""><span style="color:#4F4F4F;font-family:"font-size:14px;white-space:normal;background-color:#FFFFFF;">°</span></span>C and 100<span style="color:#4F4F4F;font-family:" font-size:14px;white-space:normal;background-color:#ffffff;"=""><span style="color:#4F4F4F;font-family:"font-size:14px;white-space:normal;background-color:#FFFFFF;">°</span></span>C respectively, viscosity index of 185, pour point of 20<span style="color:#4F4F4F;font-family:" font-size:14px;white-space:normal;background-color:#ffffff;"=""><span style="color:#4F4F4F;font-family:"font-size:14px;white-space:normal;background-color:#FFFFFF;">°</span></span>C, cloud point of 29<span style="color:#4F4F4F;font-family:" font-size:14px;white-space:normal;background-color:#ffffff;"=""><span style="color:#4F4F4F;font-family:"font-size:14px;white-space:normal;background-color:#FFFFFF;">°</span></span>C, flash point of 200<span style="color:#4F4F4F;font-family:" font-size:14px;white-space:normal;background-color:#ffffff;"=""><span style="color:#4F4F4F;font-family:"font-size:14px;white-space:normal;background-color:#FFFFFF;">°</span></span>C, aniline point of 105<span style="color:#4F4F4F;font-family:" font-size:14px;white-space:normal;background-color:#ffffff;"=""><span style="color:#4F4F4F;font-family:"font-size:14px;white-space:normal;background-color:#FFFFFF;">°</span></span>F, diesel index of 23, cetane number of 27 and ASTM (American Standards for Testing and Materials) color of less than 2.5. Results of chemical analyses showed an acid val<span>ue of 17.95 mg KOH/g, free fatty <span>acid (FFA) content of 8.98 mg KOH/g, iodine value o</span></span></span><span><span><span>f 2.10</span><span> mg</span></span></span><span> </span><span><span style="font-family:Verdana;">I</span><sub><span style="font-family:Verdana;">2</span></sub><span><span style="font-family:Verdana;">/g</span><span style="font-family:Verdana;">, peroxide value of 2.10 meq/kg, ester value of 123.0 mg KOH/g, hydroxyl value of 93.4 mg OH/g, saponification value of 140.95 mg KOH/g and a sulfur content of 0.016% w/v, signifying low sulfur content. Gas chromatography-mass spectrometry (GC-MS) showed the palm kernel oil to be predominantly made up of glycerides of various fatty acids with higher proportions of C12 to C16 fatty acid residues. Cameroon PKO therefore has a broad spectrum of industrial applications by virtue of its rich physical and chemical properties.</span></span></span>
基金Supported by the National Science and Technology Major Project of China (2016ZX05010).
文摘Based on the analysis of the production composition of reservoirs developed by the second&tertiary recovery combination(STRC),the relationship between the overall output of the STRC project and the production level during the blank water flooding stage is proposed.According to the basic principle of reservoir engineering that the“recovery factor is equal to sweeping coefficient multiplied by oil displacement efficiency”,the formula for calculating the ultimate oil recovery factor of chemical combination flooding reservoir was established.By dividing the reservoir into a series of grids according to differen-tial calculus thinking,the relationship between the ultimate recovery factor of a certain number of grids and the recovery de-gree of the reservoir was established,and then the variation law of oil production rate of the STRC reservoir was obtained.The concept of“oil rate enlargement factor of chemical combination flooding”was defined,and a production calculation method of reservoir developed by STRC was put forward based on practical oilfield development experience.The study shows that the oil production enhancing effect of STRC increases evenly with the in crease of the ratio of STRC displacement efficiency to water displacement efficiency,and increases rapidly with the increase of the ratio of recovery degree at flooding mode conversion to the water displacement efficiency.STRC is more effective in increasing oil production of reservoir with high recovery degree.Through practical tests of the alkali free binary flooding(polymer/surfactant)projects,the relative error of the oil production calculation method of STRC reservoir is about±10%,which meets the requirements of reservoir engineering.
基金support from the National Natural Science Foundation of China(52174034)the Sichuan Science and Technology Program(2021YFH0081).
文摘Cold production is a challenge in the case of heavy oil because of its high viscosity and poor fluidity in reservoir conditions.Alkali-cosolvent-polymer flooding is a type of microemulsion flooding with low costs and possible potential for heavy oil reservoirs.However,the addition of polymer may cause problems with injection in the case of highly viscous oil.Hence,in this study the feasibility of alkali-cosolvent(AC)flooding in heavy oil reservoirs was investigated via several groups of experiments.The interfacial tension between various AC formulations and heavy crude oil was measured to select appropriate formulations.Phase behavior tests were performed to determine the most appropriate formulation and conditions for the generation of a microemulsion.Sandpack flooding experiments were carried out to investigate the displacement efficiency of the selected Ac formulation.The results showed that the interfacial tension between an AC formulation and heavy oil could be reduced to below 1o-3 mN/m but differed greatly between different types of cosolvent.A butanol random polyether series displayed good performance in reducing the water-oil interfacial tension,which made it possible to form a Type Il microemulsion in reservoir conditions.According to the results of the phase behavior tests,the optimal salinity for different formulations with four cosolvent concentrations(0.5 wt%,1 wt%,2 wt%,and 3 wt%)was 4000,8000,14000,and 20000 ppm,respectively.The results of rheological measurements showed that Type Ill microemulsion had a viscosity that was ten times that of water.The results of sandpack flooding experiments showed that,in comparison with waterflooding,the injection of a certain Ac formulation slug could reduce the injection pressure.The pressure gradient during waterflooding and AC flooding was around 870 and 30-57 kPa/m,respectively.With the addition of an AC slug,the displacement efficiency was 30%-50%higher than in the case of waterflooding.