An expression of degree of polarization(DOP) for metallic material is presented based on the three-component polarized bidirectional reflectance distribution function(p BRDF) model with considering specular reflec...An expression of degree of polarization(DOP) for metallic material is presented based on the three-component polarized bidirectional reflectance distribution function(p BRDF) model with considering specular reflection, directional diffuse reflection and ideal diffuse reflection. The three-component p BRDF model with a detailed reflection assumption is validated by comparing simulations with measurements. The DOP expression presented in this paper is related to surface roughness, which makes it more reasonable in physics. Test results for two metallic samples show that the DOP based on the three-component p BRDF model accords well with the measurement and the error of existing DOP expression is significantly reduced by introducing the diffuse reflection. It indicates that our DOP expression describes the polarized reflection properties of metallic surfaces more accurately.展开更多
Cholesteric liquid crystals(CLCs) have recently sparked an enormous amount of interest in the development of soft matter materials due to their unique ability to self-organize into a helical supra-molecular architec...Cholesteric liquid crystals(CLCs) have recently sparked an enormous amount of interest in the development of soft matter materials due to their unique ability to self-organize into a helical supra-molecular architecture and their excellent selective reflection of light based on the Bragg relationship.Nowadays,by the virtue of building the self-organized nanostructures with pitch gradient or non-uniform pitch distribution,extensive work has already been performed to obtain CLC films with a broad reflection band.Based on authors' many years' research experience,this critical review systematically summarizes the physical and optical background of the CLCs with broadband reflection characteristics,methods to obtain broadband reflection of CLCs,as well as the application in the field of intelligent optical modulation materials.Combined with the research status and the advantages in the field,the important basic and applied scientific problems in the research direction are also introduced.展开更多
Based on the three-component assumption that the reflection is divided into specular reflection,directional diffuse reflection,and ideal diffuse reflection,a bidirectional reflectance distribution function(BRDF) mod...Based on the three-component assumption that the reflection is divided into specular reflection,directional diffuse reflection,and ideal diffuse reflection,a bidirectional reflectance distribution function(BRDF) model of metallic materials is presented.Compared with the two-component assumption that the reflection is composed of specular reflection and diffuse reflection,the three-component assumption divides the diffuse reflection into directional diffuse and ideal diffuse reflection.This model effectively resolves the problem that constant diffuse reflection leads to considerable error for metallic materials.Simulation and measurement results validate that this three-component BRDF model can improve the modeling accuracy significantly and describe the reflection properties in the hemisphere space precisely for the metallic materials.展开更多
Near IR reflective functional material was made via hollow ballotini enwrapped by TiO2 according to IR reflective principles. Metatitanic acid covers on the surface of hollow ballotini through electrostatic attraction...Near IR reflective functional material was made via hollow ballotini enwrapped by TiO2 according to IR reflective principles. Metatitanic acid covers on the surface of hollow ballotini through electrostatic attraction as pH is less than 2.5. The results of SEM and XRD spectrum show that TiO2 enwraps hollow ballotini well and the crystal form is anatase. When TiO2 covering thickness is below 0.5 μm, reflectance swells along with the increase of thickness, whereas above 0.5 μm it keeps stable. Coatings made from mixing enwrapped I-IB with styrene-acrylic latex were coated on aluminum foil, and reflectances were mensurated. It is found that reflectance keeps stable when the coating can wrap the base and reflectances of the coating in visible range and in near IR range are 86% and 81%, resoectively.展开更多
The laser welding(LW)process of highly reflective materials presents low thermal efficiency and poor stability.To solve the problem,the effects of subatmospheric environment on LW process,technological parameters in s...The laser welding(LW)process of highly reflective materials presents low thermal efficiency and poor stability.To solve the problem,the effects of subatmospheric environment on LW process,technological parameters in subatmospheric environment on weld formation and welding with sinusoidal modulation of laser power on the stability of LW process in subatmospheric environment were explored.The AZ31magnesium(Mg)alloy was used as the test materials.The test result revealed that the weld penetration in subatmospheric environment can increase by more than ten times compared with that under normal pressure.After the keyhole depth greatly rises,significantly periodic local bulge is observed on the backwall surface of the keyhole and the position of the bulge shifts along the direction of the keyhole depth.Eventually,the hump-shaped surface morphology of the welded seam is formed;moreover,the weld width in local zones in the lower part of the welded seam remarkably grows.During LW in subatmospheric environment,the weld penetration can be further greatly increased through power modulation.Besides,power modulation can inhibit the occurrence of bulges in local zones on the backwall of the keyhole during LW in subatmospheric environment,thus further curbing the significant growth of the weld widths of hump-shaped welding beads and local zones in the lower part of welded seams.Finally,the mechanism of synchronously improving the thermal efficiency and stability of LW process of highly reflective materials through power modulation in subatmospheric environment was illustrated.This was conducted according to theoretical analysis of recoil pressure and observation results of dynamic behaviors of laser induced plasma clouds and keyholes in the molten pool through high speed photography.展开更多
La_(0.8)Sr_(0.2)MnO_3 samples with rhombohedral, orthohombic and monoclinic structures were prepared by solid state reaction, sol-gel and co-precipitation methods, respectively. Lattice parameters, grain size, mor...La_(0.8)Sr_(0.2)MnO_3 samples with rhombohedral, orthohombic and monoclinic structures were prepared by solid state reaction, sol-gel and co-precipitation methods, respectively. Lattice parameters, grain size, morphology, infrared absorption and emissivity of samples were investigated. The results indicated that the average crystallite size calculated from XRD result and particle size of orthohombic sample were smaller than those of the other two samples, and honeycomb shape grains were observed in orthohombic sample. Due to lower crystal symmetry, Mn-O stretching vibration peaks of the three samples shifted to higher infrared wavenumber. According to the theory of wave optics and Kirchhoff law, bigger rhombohedral sample showed higher emissivity than monoclinic one. However, due to the honeycomb structure of orthohombic sample, repeated reflection and scattering led to the increase of absorption, and orthohombic sample exhibited the highest emissivity.展开更多
文摘An expression of degree of polarization(DOP) for metallic material is presented based on the three-component polarized bidirectional reflectance distribution function(p BRDF) model with considering specular reflection, directional diffuse reflection and ideal diffuse reflection. The three-component p BRDF model with a detailed reflection assumption is validated by comparing simulations with measurements. The DOP expression presented in this paper is related to surface roughness, which makes it more reasonable in physics. Test results for two metallic samples show that the DOP based on the three-component p BRDF model accords well with the measurement and the error of existing DOP expression is significantly reduced by introducing the diffuse reflection. It indicates that our DOP expression describes the polarized reflection properties of metallic surfaces more accurately.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.51573006,51573003,51203003,51303008,51302006,51402006,51272026,and 51273022)the Major Project of Beijing Science and Technology Program,China(Grant Nos.Z151100003315023 and Z141100003814011)the Fok Ying Tung Education Foundation,China(Grant No.142009)
文摘Cholesteric liquid crystals(CLCs) have recently sparked an enormous amount of interest in the development of soft matter materials due to their unique ability to self-organize into a helical supra-molecular architecture and their excellent selective reflection of light based on the Bragg relationship.Nowadays,by the virtue of building the self-organized nanostructures with pitch gradient or non-uniform pitch distribution,extensive work has already been performed to obtain CLC films with a broad reflection band.Based on authors' many years' research experience,this critical review systematically summarizes the physical and optical background of the CLCs with broadband reflection characteristics,methods to obtain broadband reflection of CLCs,as well as the application in the field of intelligent optical modulation materials.Combined with the research status and the advantages in the field,the important basic and applied scientific problems in the research direction are also introduced.
文摘Based on the three-component assumption that the reflection is divided into specular reflection,directional diffuse reflection,and ideal diffuse reflection,a bidirectional reflectance distribution function(BRDF) model of metallic materials is presented.Compared with the two-component assumption that the reflection is composed of specular reflection and diffuse reflection,the three-component assumption divides the diffuse reflection into directional diffuse and ideal diffuse reflection.This model effectively resolves the problem that constant diffuse reflection leads to considerable error for metallic materials.Simulation and measurement results validate that this three-component BRDF model can improve the modeling accuracy significantly and describe the reflection properties in the hemisphere space precisely for the metallic materials.
文摘Near IR reflective functional material was made via hollow ballotini enwrapped by TiO2 according to IR reflective principles. Metatitanic acid covers on the surface of hollow ballotini through electrostatic attraction as pH is less than 2.5. The results of SEM and XRD spectrum show that TiO2 enwraps hollow ballotini well and the crystal form is anatase. When TiO2 covering thickness is below 0.5 μm, reflectance swells along with the increase of thickness, whereas above 0.5 μm it keeps stable. Coatings made from mixing enwrapped I-IB with styrene-acrylic latex were coated on aluminum foil, and reflectances were mensurated. It is found that reflectance keeps stable when the coating can wrap the base and reflectances of the coating in visible range and in near IR range are 86% and 81%, resoectively.
基金supported by National Natural Science Foundation of China(Grants No.52005393,51275391)National Thousand Talents Program of China(Grant No.WQ2017610446)。
文摘The laser welding(LW)process of highly reflective materials presents low thermal efficiency and poor stability.To solve the problem,the effects of subatmospheric environment on LW process,technological parameters in subatmospheric environment on weld formation and welding with sinusoidal modulation of laser power on the stability of LW process in subatmospheric environment were explored.The AZ31magnesium(Mg)alloy was used as the test materials.The test result revealed that the weld penetration in subatmospheric environment can increase by more than ten times compared with that under normal pressure.After the keyhole depth greatly rises,significantly periodic local bulge is observed on the backwall surface of the keyhole and the position of the bulge shifts along the direction of the keyhole depth.Eventually,the hump-shaped surface morphology of the welded seam is formed;moreover,the weld width in local zones in the lower part of the welded seam remarkably grows.During LW in subatmospheric environment,the weld penetration can be further greatly increased through power modulation.Besides,power modulation can inhibit the occurrence of bulges in local zones on the backwall of the keyhole during LW in subatmospheric environment,thus further curbing the significant growth of the weld widths of hump-shaped welding beads and local zones in the lower part of welded seams.Finally,the mechanism of synchronously improving the thermal efficiency and stability of LW process of highly reflective materials through power modulation in subatmospheric environment was illustrated.This was conducted according to theoretical analysis of recoil pressure and observation results of dynamic behaviors of laser induced plasma clouds and keyholes in the molten pool through high speed photography.
基金Funded by the National Natural Science Foundation of China(Nos.51302003 and 51274006)
文摘La_(0.8)Sr_(0.2)MnO_3 samples with rhombohedral, orthohombic and monoclinic structures were prepared by solid state reaction, sol-gel and co-precipitation methods, respectively. Lattice parameters, grain size, morphology, infrared absorption and emissivity of samples were investigated. The results indicated that the average crystallite size calculated from XRD result and particle size of orthohombic sample were smaller than those of the other two samples, and honeycomb shape grains were observed in orthohombic sample. Due to lower crystal symmetry, Mn-O stretching vibration peaks of the three samples shifted to higher infrared wavenumber. According to the theory of wave optics and Kirchhoff law, bigger rhombohedral sample showed higher emissivity than monoclinic one. However, due to the honeycomb structure of orthohombic sample, repeated reflection and scattering led to the increase of absorption, and orthohombic sample exhibited the highest emissivity.