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术前IDEAS模式访视在肺癌胸腔镜辅助小切口手术患者中的应用效果
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作者 王琼 刘慧 +1 位作者 王莎莎 曹文秀 《癌症进展》 2024年第10期1155-1159,共5页
目的 探讨术前IDEAS模式访视在肺癌胸腔镜辅助小切口手术(VAMT)患者中的应用效果。方法根据干预方式的不同将80例肺癌VAMT患者分为对照组(n=34)和IDEAS组(n=46),对照组患者给予常规术前访视,IDEAS组患者给予术前IDEAS模式访视。比较两... 目的 探讨术前IDEAS模式访视在肺癌胸腔镜辅助小切口手术(VAMT)患者中的应用效果。方法根据干预方式的不同将80例肺癌VAMT患者分为对照组(n=34)和IDEAS组(n=46),对照组患者给予常规术前访视,IDEAS组患者给予术前IDEAS模式访视。比较两组患者的生理指标[脉率(PR)、舒张压(DBP)、收缩压(SBP)]、疼痛程度[视觉模拟评分法(VAS)]、心理状态[汉密尔顿焦虑量表(HAMA)、汉密尔顿抑郁量表(HAMD)]、希望水平[Herth希望量表(HHI)]、满意度、住院时间及并发症发生情况。结果 干预后,两组患者PR、DBP、SBP均高于本组干预前,IDEAS组患者PR、DBP、SBP均低于对照组,差异均有统计学意义(P﹤0.05)。干预后,两组患者VAS、HAMD、HAMA评分均低于本组干预前,HHI量表各维度评分均高于本组干预前,IDEAS组患者VAS、HAMD、HAMA评分均低于对照组,HHI量表各维度评分均高于对照组,差异均有统计学意义(P﹤0.05)。IDEAS组患者的总满意率为100%,明显高于对照组患者的82.35%,住院时间明显短于对照组,差异均有统计学意义(P﹤0.01)。IDEAS组患者的并发症总发生率为4.35%,与对照组患者的11.76%比较,差异无统计学意义(P﹥0.05)。结论 术前IDEAS模式访视能有效改善肺癌VAMT患者的生理指标、心理状态和疼痛程度,提高希望水平,患者的满意度高。 展开更多
关键词 术前ideas模式访视 肺癌 胸腔镜辅助小切口手术 心理状态 希望水平
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内镜息肉冷圈套切除术联合IDEAS护理模式访视用于结直肠息肉切除患者的效果观察
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作者 李抗抗 郭玲玲 +2 位作者 魏绮丽 陈金连 黄丽芳 《现代医学与健康研究电子杂志》 2024年第15期131-133,共3页
目的探讨内镜息肉冷圈套切除术(CSP)结合识别问题-确定选项-评估并选择最佳选项-行动-检验有效性(IDEAS)护理模式访视应用于结直肠息肉患者的临床疗效,并分析对患者疼痛因子的影响,为提高该疾病的临床治疗效果提供依据。方法选取2021年... 目的探讨内镜息肉冷圈套切除术(CSP)结合识别问题-确定选项-评估并选择最佳选项-行动-检验有效性(IDEAS)护理模式访视应用于结直肠息肉患者的临床疗效,并分析对患者疼痛因子的影响,为提高该疾病的临床治疗效果提供依据。方法选取2021年1月至2023年1月南方医科大学南方医院增城院区收治的112例结直肠息肉患者进行前瞻性研究,根据不同的手术方式分为A组[56例,IDEAS护理模式访视+内镜息肉热圈套切除术(HSP)]和B组(56例,IDEAS护理模式访视+CSP),术后随访6个月。比较两组患者息肉切除情况,术前和术后3d的疼痛因子指标及血清血栓素B2(TXB2)、血管内皮生长因子(VEGF)、碱性成纤维细胞生长因子(bFGF)水平,以及息肉完整切除率和术后6个月并发症发生情况。结果B组患者手术时间短于A组;与术前比,术后3 d两组患者血清前列腺素E2(PGE2)、神经生长因子(NGF)、TXB2、VEGF、bFGF水平均升高,但B组均低于A组;血清P物质(SP)水平均降低,且B组低于A组(均P<0.05)。两组患者内镜操作时间、息肉切除时间、息肉直径、息肉切除数量、息肉完整切除率及术后6个月并发症总发生率比较,差异均无统计学意义(均P>0.05)。结论CSP结合IDEAS护理模式访视应用于结直肠息肉患者的治疗可显著缩短手术时间,患者术后疼痛较轻,有利于减轻机体炎症反应,促进疾病转归。 展开更多
关键词 结直肠息肉 内镜息肉冷切除术 热圈套切除术 ideas护理模式访视 疼痛因子
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基于IDEAS的多元化护理对溃疡性结肠炎患者生活质量及满意度的影响
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作者 付玲 赵丽 +1 位作者 凌佳 胡春慧 《中外医疗》 2024年第3期171-174,共4页
目的探究基于IDEAS的多元化护理模式对溃疡性结肠炎患者生活质量及满意度的影响。方法方便选取2018年9月—2023年9月盐城市第三人民医院消化内科收治的84例溃疡性结肠炎患者作为研究对象,以随机数表法分为两组,对照组(42例)实行常规护理... 目的探究基于IDEAS的多元化护理模式对溃疡性结肠炎患者生活质量及满意度的影响。方法方便选取2018年9月—2023年9月盐城市第三人民医院消化内科收治的84例溃疡性结肠炎患者作为研究对象,以随机数表法分为两组,对照组(42例)实行常规护理,观察组(42例)实行基于IDEAS的多元化护理模式。比较两组生活质量评分及护理满意度。结果观察组生活质量评分高于对照组,差异有统计学意义(P<0.05)。观察组护理总满意率远高于对照组,差异有统计学意义(P<0.05)。结论基于IDEAS的多元化护理模式对溃疡性结肠炎护理效果具有积极影响,利于提高患者生存质量与护理满意度。 展开更多
关键词 ideas多元化护理 溃疡性结肠炎 生活质量 护理满意度
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基于IDEAS访视模式对腹腔镜下全子宫切除术患者生理、心理应激反应及应对方式的影响
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作者 冯颖 武丹 +1 位作者 顾洁玲 钟鸣兴 《中外医药研究》 2024年第21期79-81,共3页
目的:探讨基于IDEAS访视模式对腹腔镜下全子宫切除术患者生理、心理应激反应及应对方式的影响。方法:选取2021年1月—2022年12月于肇庆市第一人民医院拟行腹腔镜下全子宫切除术的患者60例作为研究对象,以随机数字表法分为对照组(实施常... 目的:探讨基于IDEAS访视模式对腹腔镜下全子宫切除术患者生理、心理应激反应及应对方式的影响。方法:选取2021年1月—2022年12月于肇庆市第一人民医院拟行腹腔镜下全子宫切除术的患者60例作为研究对象,以随机数字表法分为对照组(实施常规术前访视)和观察组(实施基于IDEAS的访视模式),各30例。比较两组患者生理应激指标、心理应激水平、应对方式及护理满意度。结果:访视后,两组脉率、舒张压、收缩压水平高于访视前,观察组脉率、舒张压、收缩压水平低于对照组,差异有统计学意义(P<0.05);访视后,两组面对评分高于访视前,焦虑自评量表、抑郁自评量表评分及回避、屈服评分低于访视前,观察组优于对照组,差异有统计学意义(P<0.05);观察组护理满意度高于对照组,差异有统计学意义(P=0.0022)。结论:应用基于IDEAS访视模式于腹腔镜下全子宫切除术患者中的临床效果显著,有利于缓解患者的生理、心理应激反应,改善患者的应对方式,提高护理满意度。 展开更多
关键词 基于ideas访视模式 腹腔镜下全子宫切除术 应激反应
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基于IDEAS模式的术前访视联合共情支持对严重烧伤患者生理应激、应对方式和瘢痕恢复的影响
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作者 余娅薇 卢小检 《中国美容医学》 CAS 2024年第5期160-164,共5页
目的:基于IDEAS模式(即识别问题、确认选项、评估并选择最佳选项、行动和检验有效性)的术前访视联合共情支持对严重烧伤患者生理应激、应对方式和瘢痕恢复的影响。方法:选取2021年2月-2023年2月笔者科室收治的90例严重烧伤患者为研究对... 目的:基于IDEAS模式(即识别问题、确认选项、评估并选择最佳选项、行动和检验有效性)的术前访视联合共情支持对严重烧伤患者生理应激、应对方式和瘢痕恢复的影响。方法:选取2021年2月-2023年2月笔者科室收治的90例严重烧伤患者为研究对象,按照随机数字表法分为观察组和对照组,各45例。对照组给予共情支持,观察组给予基于IDEAS模式的术前访视护理联合共情支持,比较两组生理应激[去甲肾上腺素(Norepinephrine,NE)、血管紧张素Ⅱ(Angiotensin Ⅱ,AngⅡ)水平]、心理状况[采用汉密尔顿焦虑量表(Hamilton anxiety scale,HAMA)和汉密尔顿抑郁量表(Hamilton depression scale,HAMD)评估]、应对方式[采用医学应对问卷(Medical coping modes questionnaire,MCMQ)评估]、自理能力[采用自我护理能力量表(Exercise of self-care agency scale,ESCA)]和瘢痕恢复情况[采用温哥华瘢痕量表(Vancouver scar scale,VSS)评估]。结果:干预后,观察组血清NE、AngⅡ水平低于对照组,HAMA、HAMD评分低于对照组,MCMQ评分优于对照组,ESCA各维度评分高于对照组,VSS评分及总分低于对照组,差异均有统计学意义(P<0.05)。结论:基于IDEAS模式的术前访视联合共情支持可有效减轻严重烧伤患者生理应激,改善不良心理和应对方式,提高自我护理能力,进而促进瘢痕快速恢复。 展开更多
关键词 严重烧伤 ideas模式 共情支持 应激 应对方式
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Upcycling municipal solid waste to sustainable hydrogen via two-stage gasification-reforming
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作者 Hui Zhou Shuzhuang Sun +3 位作者 Yikai Xu Yeshui Zhang Shouliang Yi Chunfei Wu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第9期611-624,共14页
As global municipal solid waste(MSW)quantities continue to escalate,serious socio-environmental challenges arise,necessitating innovative solutions.Waste-to-hydrogen(WTH)via two-stage gasification-reforming(TSGR)prese... As global municipal solid waste(MSW)quantities continue to escalate,serious socio-environmental challenges arise,necessitating innovative solutions.Waste-to-hydrogen(WTH)via two-stage gasification-reforming(TSGR)presents an emergent technology for MSW upcycling,offering to ease waste management burdens and bolster the burgeoning hydrogen economy.Despite early initiatives to advance TSGR technology,a cohesive and critical analysis of cutting-edge knowledge and strategies to enhance hydrogen production remains lacking.This review aggregates literature on MSW upcycling to hydrogen via TSGR,with a focus on optimizing process control and catalytic efficiency.It underscores technological avenues to augment hydrogen output,curtail catalyst costs,and refine system performance.Particularly,the review illuminates the potential for integrating chemical and calcium looping into TSGR processes,identifying opportunities,and pinpointing challenges.The review concludes with a summary of the current state of techno-economic analysis for this technology,presenting outstanding challenges and future research directions,with the ultimate goal of transitioning WTH from theoretical to practical application. 展开更多
关键词 Municipal solidwaste Upcycling GASIFICATION reforming HYDROGEN
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Methanol steam reforming for hydrogen production driven by an atomically precise Cu catalyst
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作者 Weigang Hu Haoqi Liu +7 位作者 Yuankun Zhang Jiawei Ji Guangjun Li Xiao Cai Xu Liu Wen Wu Xu Weiping Ding Yan Zhu 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第7期1079-1084,共6页
Plasmon-induced hot-electron transfer from metal nanostructures is being intensely pursed in current photocatalytic research,however it remains elusive whether molecular-like metal clusters with excitonic behavior can... Plasmon-induced hot-electron transfer from metal nanostructures is being intensely pursed in current photocatalytic research,however it remains elusive whether molecular-like metal clusters with excitonic behavior can be used as light-harvesting materials in solar energy utilization such as photocatalytic methanol steam reforming.In this work,we report an atomically precise Cu_(13)cluster protected by dual ligands of thiolate and phosphine that can be viewed as the assembly of one top Cu atom and three Cu_(4)tetrahedra.The Cu_(13)H_(10)(SR)_(3)(PR’_(3))_(7)(SR=2,4-dichlorobenzenethiol,PR’_(3)=P(4-FC_(6)H_(4))_(3))cluster can give rise to highly efficient light-driven activity for methanol steam reforming toward H_(2)production. 展开更多
关键词 NANOCLUSTER PHOTOCATALYSIS Methanol steam reforming Atomically precise Copper catalyst
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Chemical looping reforming of the micromolecular component from biomass pyrolysis via Fe_(2)O_(3)@SBA-16
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作者 Yunchang Li Bo Zhang +3 位作者 Xiantan Yang Bolun Yang Shengyong Zhang Zhiqiang Wu 《International Journal of Coal Science & Technology》 EI CAS CSCD 2024年第3期120-134,共15页
To solve the problems of low gasification efficiency and high tar content caused by solid–solid contact between biomass and oxygen carrier in traditional biomass chemical looping gasification process.The decoupling s... To solve the problems of low gasification efficiency and high tar content caused by solid–solid contact between biomass and oxygen carrier in traditional biomass chemical looping gasification process.The decoupling strategy was adopted to decouple the biomass gasification process,and the composite oxygen carrier was prepared by embedding Fe_(2)O_(3) in molecular sieve SBA-16 for the chemical looping reforming process of pyrolysis micromolecular model compound methane,which was expected to realize the directional reforming of pyrolysis volatiles to prepare hydrogen-rich syngas.Thermodynamic analysis of the reaction system was carried out based on the Gibbs free energy minimization method,and the reforming performance was evaluated by a fixed bed reactor,and the kinetic parameters were solved based on the gas–solid reaction model.Thermodynamic analysis verified the feasibility of the reaction and provided theoretical guidance for experimental design.The experimental results showed that the reaction performance of Fe_(2)O_(3)@SBA-16 was compared with that of pure Fe_(2)O_(3) and Fe_(2)O_(3)@SBA-15,and the syngas yield was increased by 55.3%and 20.7%respectively,and it had good cycle stability.Kinetic analysis showed that the kinetic model changed from three-dimensional diffusion to first-order reaction with the increase of temperature.The activation energy was 192.79 kJ/mol by fitting.This paper provides basic data for the directional preparation of hydrogen-rich syngas from biomass and the design of oxygen carriers for pyrolysis of all-component chemical looping reforming. 展开更多
关键词 Biomass pyrolysis METHANE Chemical looping reforming Oxygen carrier Kinetic analysis
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Optimizing the sulfur-resistance and activity of perovskite oxygen carrier for chemical looping dry reforming of methane
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作者 Yuelun Li Dong Tian +6 位作者 Lei jiang Huicong Zuo LiNan Huang Mingyi Chen Jianchun Zuo Hua Wang Kongzhai Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第9期259-271,共13页
Perovskite oxides has been attracted much attention as high-performance oxygen carriers for chemical looping reforming of methane,but they are easily inactivated by the presence of trace H_(2)S.Here,we propose to modu... Perovskite oxides has been attracted much attention as high-performance oxygen carriers for chemical looping reforming of methane,but they are easily inactivated by the presence of trace H_(2)S.Here,we propose to modulate both the activity and resistance to sulfur poisoning by dual substitution of Mo and Ni ions with the Fe-sites of LaFeO_(3)perovskite.It is found that partial substitution of Ni for Fe substantially improves the activity of LaFeO_(3)perovskite,while Ni particles prefer to grow and react with H_(2)S during the long-term successive redox process,resulting in the deactivation of oxygen carriers.With the presence of Mo in LaNi_(0.05)Fe_(0.95)O_(3−σ)perovskite,H_(2)S preferentially reacts with Mo to generate MoS_(2),and then the CO_(2)oxidation can regenerate Mo via removing sulfur.In addition,Mo can inhibit the accumulation and growth of Ni,which helps to improve the redox stability of oxygen carriers.The LaNi_(0.05)Mo_(0.07)Fe_(0.88)O_(3−σ)oxygen carrier exhibits stable and excellent performance,with the CH_(4)conversion higher than 90%during the 50 redox cycles in the presence of 50 ppm H_(2)S at 800℃.This work highlights a synergistic effect in the perovskite oxides induced by dual substitution of different cations for the development of high-performance oxygen carriers with excellent sulfur tolerance. 展开更多
关键词 Perovskite oxygen carriers Chemical looping reforming Sulfur-resistance Dual substitution SYNGAS
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网络关系视角下的用户创新生存影响因素分析——以LEGO Ideas为例
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作者 张畅 《科技创业月刊》 2024年第1期35-45,共11页
以LEGO Ideas作为数据来源,在社交网络平台的相关研究基础上,构建出作者网络和内容网络,并计算出用户创新节点在网络中的中心性。采用生存分析法,将用户创新的“存活”视为生存事件,建立生存回归模型,分阶段计算出网络中心性对用户创新... 以LEGO Ideas作为数据来源,在社交网络平台的相关研究基础上,构建出作者网络和内容网络,并计算出用户创新节点在网络中的中心性。采用生存分析法,将用户创新的“存活”视为生存事件,建立生存回归模型,分阶段计算出网络中心性对用户创新生存的影响系数。研究认为,两类网络属性在用户创新发布早期为其生存提供正向影响,作者网络的影响在后期愈发明显,而内容网络则逐渐出现负向影响的迹象。企业应鼓励OI平台中高质量作者间的互动,更多地根据作者行为识别出高质量的用户创新。 展开更多
关键词 用户创新 生存分析 社会网络 LEGO ideas
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Machine learning-driven optimization of plasma-catalytic dry reforming of methane
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作者 Yuxiang Cai Danhua Mei +2 位作者 Yanzhen Chen Annemie Bogaerts Xin Tu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第9期153-163,共11页
This study investigates the dry reformation of methane(DRM)over Ni/Al_(2)O_(3)catalysts in a dielectric barrier discharge(DBD)non-thermal plasma reactor.A novel hybrid machine learning(ML)model is developed to optimiz... This study investigates the dry reformation of methane(DRM)over Ni/Al_(2)O_(3)catalysts in a dielectric barrier discharge(DBD)non-thermal plasma reactor.A novel hybrid machine learning(ML)model is developed to optimize the plasma-catalytic DRM reaction with limited experimental data.To address the non-linear and complex nature of the plasma-catalytic DRM process,the hybrid ML model integrates three well-established algorithms:regression trees,support vector regression,and artificial neural networks.A genetic algorithm(GA)is then used to optimize the hyperparameters of each algorithm within the hybrid ML model.The ML model achieved excellent agreement with the experimental data,demonstrating its efficacy in accurately predicting and optimizing the DRM process.The model was subsequently used to investigate the impact of various operating parameters on the plasma-catalytic DRM performance.We found that the optimal discharge power(20 W),CO_(2)/CH_(4)molar ratio(1.5),and Ni loading(7.8 wt%)resulted in the maximum energy yield at a total flow rate of∼51 mL/min.Furthermore,we investigated the relative significance of each operating parameter on the performance of the plasma-catalytic DRM process.The results show that the total flow rate had the greatest influence on the conversion,with a significance exceeding 35%for each output,while the Ni loading had the least impact on the overall reaction performance.This hybrid model demonstrates a remarkable ability to extract valuable insights from limited datasets,enabling the development and optimization of more efficient and selective plasma-catalytic chemical processes. 展开更多
关键词 Plasma catalysis Machine learning Process optimization Dry reforming of methane Syngas production
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Engineering oxygen vacancies on Tb-doped ceria supported Pt catalyst for hydrogen production through steam reforming of long-chain hydrocarbon fuels
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作者 Zhourong Xiao Changxuan Zhang +5 位作者 Peng Li Desong Wang Xiangwen Zhang Li Wang Jijun Zou Guozhu Li 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第4期181-192,共12页
Steam reforming of long-chain hydrocarbon fuels for hydrogen production has received great attention for thermal management of the hypersonic vehicle and fuel-cell application.In this work,Pt catalysts supported on Ce... Steam reforming of long-chain hydrocarbon fuels for hydrogen production has received great attention for thermal management of the hypersonic vehicle and fuel-cell application.In this work,Pt catalysts supported on CeO_(2)and Tb-doped CeO_(2)were prepared by a precipitation method.The physical structure and chemical properties of the as-prepared catalysts were characterized by powder X-ray diffraction,scanning electron microscopy,transmission electron microscopy,Raman spectroscopy,H_(2)temperature programmed reduction,and X-ray photoelectron spectroscopy.The results show that Tb-doped CeO_(2)supported Pt possesses abundant surface oxygen vacancies,good inhibition of ceria sintering,and strong metal-support interaction compared with CeO_(2)supported Pt.The catalytic performance of hydrogen production via steam reforming of long-chain hydrocarbon fuels(n-dodecane)was tested.Compared with 2Pt/CeO_(2),2Pt/Ce_(0.9)Tb_(0.1)O_(2),and 2Pt/Ce_(0.5)Tb_(0.5)O_(2),the 2Pt/Ce_(0.7)Tb_(0.3)O_(2)has higher activity and stability for hydrogen production,on which the conversion of n-dodecane was maintained at about 53.2%after 600 min reaction under 700℃at liquid space velocity of 9 ml·g^(-1)·h^(-1).2Pt/CeO_(2)rapidly deactivated,the conversion of n-dodecane was reduced to only 41.6%after 600 min. 展开更多
关键词 Steam reforming N-DODECANE Hydrogen production Pt-based catalyst Oxygen vacancy CeO_(2)
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Controllable synthesis of CuAlO_(2) via solid-phase method and its catalytic performance for methanol steam reforming to hydrogen
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作者 QING Shaojun SUN Xun +3 位作者 LI Xinglong WANG Lei WU Zhiwei WANG Jianguo 《燃料化学学报(中英文)》 EI CAS CSCD 北大核心 2024年第11期1641-1651,共11页
This study explores the controllable synthesis of CuAlO_(2) using copper hydroxide and pseudo-boehmite powders as raw materials via a simple solid-phase ball milling method,along with its catalytic performance investi... This study explores the controllable synthesis of CuAlO_(2) using copper hydroxide and pseudo-boehmite powders as raw materials via a simple solid-phase ball milling method,along with its catalytic performance investigation in methanol steam reforming(MSR).Various catalysts were prepared under different conditions,such as calcination temperature,calcination atmosphere,and heating rate.Characterization techniques including BET,XRD,XPS,SEM and H2-TPR were employed to analyze the samples.The results revealed significant effects of calcination temperature on the phase compositions,specific surface area,reduction performance,and surface properties of the CA-T catalysts.Based on the findings,a synthesis route of CuAlO_(2) via the solid-phase method was proposed,highlighting the importance of high calcination temperature,nitrogen atmosphere,and low heating rate for CuAlO_(2) formation.Catalytic evaluation data demonstrated that CuAlO_(2) could catalyze MSR without pre-reduction,with the catalytic performance of CA-T catalysts being notably influenced by calcination temperature.Among the prepared catalysts,the CA-1100 catalyst exhibited the highest catalytic activity and stability.The findings of this study might be useful for the further study of the catalytic material for sustained release catalysis,including the synthesis of catalytic materials and the regulation of sustained release catalytic performance. 展开更多
关键词 CuAlO_(2) solid-phase method methanol steam reforming sustained release catalysis calcination temperature
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Steam reforming of acetic acid over Ni/biochar of low metal-loading:Involvement of biochar in tailoring reaction intermediates renders superior catalytic performance
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作者 Yunyu Guo Yiran Wang +5 位作者 Shu Zhang Yi Wang Song Hu Jun Xiang Walid Nabgan Xun Hu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第4期241-252,共12页
Biochar is a reactive carrier as it may be partially gasified with steam in steam reforming,which could influence the formation of reaction intermediates and modify catalytic behaviors.Herein,the Ni/biochar as well as... Biochar is a reactive carrier as it may be partially gasified with steam in steam reforming,which could influence the formation of reaction intermediates and modify catalytic behaviors.Herein,the Ni/biochar as well as two comparative catalysts,Ni/Al_(2)O_(3) and Ni/SiO_(2),with low nickel loading(2%(mass))was conducted to probe involvement of the varied carriers in the steam reforming.The results indicated that the Ni/biochar performed excellent catalytic activity than Ni/SiO_(2) and Ni/Al_(2)O_(3),as the biochar carrier facilitated quick conversion of the -OH from dissociation of steam to gasify the oxygen-rich carbonaceous intermediates like C=O and C-O-C,resulting in low coverage while high exposure of nickel species for maintaining the superior catalytic performance.In converse,strong adsorption of aliphatic intermediates over Ni/Al_(2)O_(3) and Ni/SiO_(2) induced serious coking with polymeric coke as the main type(21.5%and 32.1%,respectively),which was significantly higher than that over Ni/biochar(3.9%).The coke over Ni/biochar was mainly aromatic or catalytic type with nanotube morphology and high crystallinity.The high resistivity of Ni/biochar towards coking was due to the balance between formation of coke and gasification of coke and partially biochar with steam,which created developed mesopores in spent Ni/biochar while the coke blocked pores in Ni/Al_(2)O_(3) and Ni/SiO_(2) catalysts. 展开更多
关键词 Steam reforming Acetic acid Ni/biochar catalyst Property of coke Reaction intermediates
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Ethanol steam reforming over Ni/ZSM-5 nanosheet for hydrogen production
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作者 Porapak Suriya Shanshan Xu +8 位作者 Shengzhe Ding Sarayute Chansai Yilai Jiao Joseph Hurd Daniel Lee Yuxin Zhang Christopher Hardacre Prasert Reubroycharoen Xiaolei Fan 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第3期247-256,共10页
Compared to reforming reactions using hydrocarbons,ethanol steam reforming(ESR)is a sustainable alternative for hydrogen(H_(2))production since ethanol can be produced sustainably using biomass.This work explores the ... Compared to reforming reactions using hydrocarbons,ethanol steam reforming(ESR)is a sustainable alternative for hydrogen(H_(2))production since ethanol can be produced sustainably using biomass.This work explores the catalyst design strategies for preparing the Ni supported on ZSM-5 zeolite catalysts to promote ESR.Specifically,two-dimensional ZSM-5 nanosheet and conventional ZSM-5 crystal were used as the catalyst carriers and two synthesis strategies,i.e.,in situ encapsulation and wet impregnation method,were employed to prepare the catalysts.Based on the comparative characterization of the catalysts and comparative catalytic assessments,it was found that the combination of the in situ encapsulation synthesis and the ZSM-5 nanosheet carrier was the effective strategy to develop catalysts for promoting H_(2) production via ESR due to the improved mass transfer(through the 2-D structure of ZSM-5 nanosheet)and formation of confined small Ni nanoparticles(resulted via the in situ encapsulation synthesis).In addition,the resulting ZSM-5 nanosheet supported Ni catalyst also showed high Ni dispersion and high accessibility to Ni sites by the reactants,being able to improve the activity and stability of catalysts and suppress metal sintering and coking during ESR at high reaction temperatures.Thus,the Ni supported on ZSM-5 nanosheet catalyst prepared by encapsulation showed the stable performance with~88% ethanol conversion and~65% H_(2) yield achieved during a 48-h longevity test at 550-C. 展开更多
关键词 ZSM-5 nanosheet In situ encapsulation Ni catalyst Ethanol steam reforming Hydrogen production
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Regulating crystal phase of TiO_(2) to enhance catalytic activity of Ni/TiO_(2) for solar-driven dry reforming of methane
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作者 HE Zhanjun GONG Kun +3 位作者 DAI Yuanyuan NIU Qiang LIN Tiejun ZHONG Liangshu 《燃料化学学报(中英文)》 EI CAS CSCD 北大核心 2024年第9期1203-1213,共11页
Ni/TiO_(2) catalyst is widely employed for photo-driven DRM reaction while the influence of crystal structure of TiO_(2) remains unclear.In this work,the rutile/anatase ratio in supports was successfully controlled by... Ni/TiO_(2) catalyst is widely employed for photo-driven DRM reaction while the influence of crystal structure of TiO_(2) remains unclear.In this work,the rutile/anatase ratio in supports was successfully controlled by varying the calcination temperature of anatase-TiO_(2).Structural characterizations revealed that a distinct TiO_(x) coating on the Ni nanoparticles(NPs)was evident for Ni/TiO_(2)-700 catalyst due to strong metal-support interaction.It is observed that the TiOx overlayer gradually disappeared as the ratio of rutile/anatase increased,thereby enhancing the exposure of Ni active sites.The exposed Ni sites enhanced visible light absorption and boosted the dissociation capability of CH4,which led to the much elevated catalytic activity for Ni/TiO_(2)-950 in which rutile dominated.Therefore,the catalytic activity of solar-driven DRM reaction was significantly influenced by the rutile/anatase ratio.Ni/TiO_(2)-950,characterized by a predominant rutile phase,exhibited the highest DRM reactivity,with remarkable H_(2) and CO production rates reaching as high as 87.4 and 220.2 mmol/(g·h),respectively.These rates were approximately 257 and 130 times higher,respectively,compared to those obtained on Ni/TiO_(2)-700 with anatase.This study suggests that the optimization of crystal structure of TiO_(2) support can effectively enhance the performance of photothermal DRM reaction. 展开更多
关键词 dry reforming of methane photothermal catalysis crystal phase TiO_(2) metal-support interaction
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Pt nanoclusters modified porous g-C_(3)N_(4)nanosheets to significantly enhance hydrogen production by photocatalytic water reforming of methanol
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作者 Yi-Fei Liang Jin-Rong Lu +2 位作者 Shang-Kun Tian Wen-Quan Cui Li Liu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第2期40-50,共11页
For the use of green hydrogen energy,it is crucial to have efficient photocatalytic activity for hydrogen generation by water reforming of methanol under mild conditions.Much attention has been paid to gC_(3)N_(4)as a... For the use of green hydrogen energy,it is crucial to have efficient photocatalytic activity for hydrogen generation by water reforming of methanol under mild conditions.Much attention has been paid to gC_(3)N_(4)as a promising photocatalyst for the generation of hydrogen.To improve the separation of photogenerated charge,porous nanosheet g-C_(3)N_(4)was modified with Pt nanoclusters(Pt/g-C_(3)N_(4))through impregnation and following photo-induced reduction.This catalyst showed excellent photocatalytic activity of water reforming of methanol fo r hydrogen production with a 17.12 mmol·g^(-1)·h^(-1)rate at room temperature,which was 311 times higher than that of the unmodified g-C_(3)N_(4).The strong interactions of Pt-N in Pt/g-C_(3)N_(4)constructed effective electron transfer channels to promote the separation of photogenerated electrons and holes effectively.In addition,in-situ infrared spectroscopy was used to investigate the intermediates of the hydrogen production reaction,which proved that methanol and water eventually turn into H_(2)and CO_(2)via formaldehyde and formate.This study provides insights for understanding the photocatalytic hydrogen production in the water reforming of methanol. 展开更多
关键词 Water reforming of methanol Photocatalysis g-C_(3)N_(4) Pt nanoclusters Hydrogen production
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术前IDEAS模式访视在胸腔镜下肺癌根治术患者中的应用
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作者 刘东平 王严慧 +1 位作者 陈彬 宋宗工 《齐鲁护理杂志》 2024年第18期106-109,共4页
目的:探讨术前IDEAS模式访视在胸腔镜下肺癌根治术患者中的应用效果。方法:选取2021年12月1日~2022年12月31日接受胸腔镜下肺癌根治术的120例肺癌患者作为研究对象,根据随机数字表法分为对照组和研究组各60例,对照组有1例患者因问卷填... 目的:探讨术前IDEAS模式访视在胸腔镜下肺癌根治术患者中的应用效果。方法:选取2021年12月1日~2022年12月31日接受胸腔镜下肺癌根治术的120例肺癌患者作为研究对象,根据随机数字表法分为对照组和研究组各60例,对照组有1例患者因问卷填写有误剔除,最终纳入59例,对照组行常规术前访视,研究组行术前IDEAS模式访视。比较两组希望水平[采用中文版Herth希望量表(HHI)]、应对方式[采用中文版医学应对方式量表(MCMQ)]、生理应激指标。结果:手术当日,两组HHI各维度评分及总分均高于预约手术日(P<0.05),且研究组高于对照组(P<0.05,P<0.01);手术当日,两组MCMQ中面对、回避、屈服评分优于预约手术日(P<0.05),且研究组优于对照组(P<0.05);手术当日,两组应激指标水平均优于预约手术日(P<0.05),且研究组优于对照组(P<0.05,P<0.01)。结论:术前IDEAS模式访视可有效提升胸腔镜下肺癌根治术患者希望水平,改善其应对方式及应激反应指标。 展开更多
关键词 术前ideas模式访视 肺癌 肺癌根治术 胸腔镜 希望水平
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Tar formation characteristic of integrated process of coal pyrolysis with dry reforming of low carbon alkane over Ni/La_(2)O_(3)-ZrO_(2)
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作者 LÜJiannan LI Yang +1 位作者 JIN Lijun HU Haoquan 《燃料化学学报(中英文)》 EI CAS CSCD 北大核心 2024年第12期1823-1833,I0001-I0006,共17页
Coal pyrolysis integrated with dry reforming of low-carbon alkane(CP-DRA)is an effective way to improve tar yield.Ni/La_(2)O_(3)-ZrO_(2)with a La/Zr ratio of 4 was a good catalyst for DRA to inhibit carbon deposition ... Coal pyrolysis integrated with dry reforming of low-carbon alkane(CP-DRA)is an effective way to improve tar yield.Ni/La_(2)O_(3)-ZrO_(2)with a La/Zr ratio of 4 was a good catalyst for DRA to inhibit carbon deposition and obtain high tar yield in CP-DRA.In this study,the fraction distribution and component of tars from CP-DRA and coal pyrolysis in N_(2)atmosphere(CP-N_(2))were characterized by using several methods to understand the effect of DRA on coal pyrolysis.The isotope trace method was also used to discuss the role of low-carbon alkane in CP-DRA.The results showed that the tar from CP-N_(2)is mainly composed of aliphatic compounds with more C_(al),H_(al)and CH+CH_(2),and the tar from CP-DRA contains more Car,Har,and CH_(3),and has lower weight-average molecular weight and more light tar content than CP-N_(2).A small amount of C2H6 addition in CP-DRA will raise the ratio of H_(β)and CH+CH_(2).Electron paramagnetic resonance(EPR)analysis shows that the tar from CP-DRA has a higher radical concentration while the corresponding char has a lower radical concentration.The isotope trace experiment showed that alkanes provide·H,·CH_(3),etc.to stabilize the radicals from coal pyrolysis and result in more alkyl aromatic compounds during CP-DRA. 展开更多
关键词 coal pyrolysis dry reforming low carbon alkane Ni/La_(2)O_(3)-ZrO_(2) TAR
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Performance of a Combined Energy System Consisting of Solar Collector, Biogas Dry Reforming and Solid Oxide Fuel Cell: An Indian Case Study
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作者 Akira Nishimura Ryotaro Sato +1 位作者 Ryota Nakajima Eric Hu 《Smart Grid and Renewable Energy》 2024年第10期217-247,共31页
An energy production system consisting of a solar collector, biogas dry reforming reactor and solid oxide fuel cell (SOFC) was assumed to be installed in Kolkata, India. This study aims to understand the impact of cli... An energy production system consisting of a solar collector, biogas dry reforming reactor and solid oxide fuel cell (SOFC) was assumed to be installed in Kolkata, India. This study aims to understand the impact of climate conditions on the performance of solar collectors with different lengths of parabolic trough solar collector (dx) and mass flow rate of heat transfer fluid (m). In addition, this study has evaluated the amount of H2 produced by biogas dry reforming (GH2), the amount of power generated by SOFC (PSOFC) and the maximum number of possible households (N) whose electricity demand could be met by the energy system proposed, considering the performance of solar collector with the different dx and m. As a result, the optimum dx was found to be 4 m. This study revealed that the temperature of heat transfer fluid (Tfb) decreased with the increase in m. Tfb in March, April and May was higher than that in other months, while Tfb from June to December was the lowest. GH2, PSOFC and N in March, April and May were higher than those in other months, irrespective of m. The optimum m was 0.030 kg/s. 展开更多
关键词 Solar Collector Temperature of Simulated Biogas Case Study of Installation in India H2 Production by Dry reforming Power Generated by SOFC
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