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Genesis and metallogenic characteristic of Dongnan Cu–Mo deposit associated granitoids:LA-ICP-MS zircon U–Pb dating and isotope constraint from Zijinshan ore field in southeastern China
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作者 Qifeng Xie Mingguo Zhai +3 位作者 Yuanfeng Cai Yunpeng Dong Hong Zhang Aifang Xiao 《Acta Geochimica》 EI CAS CSCD 2023年第2期332-345,共14页
The Dongnan Cu–Mo deposit,located in the southeast of the Zijinshan ore field(the largest porphyry–epithermal system in Southeast China),represents the complex magmatic and metallogenesis events in the region.The pe... The Dongnan Cu–Mo deposit,located in the southeast of the Zijinshan ore field(the largest porphyry–epithermal system in Southeast China),represents the complex magmatic and metallogenesis events in the region.The petrogenesis and metallogenesis of granitoids from the deposit are not determined,especially the interactions between ore-bearing(granodiorite porphyry)and barren samples(granodiorite and diorite).In the paper,the whole rock geochemical features shared a similar affinity to the middle-lower content and revealed that they derived from partial melting of the Cathaysian basement with the contribution of mantle materials,even represented that they generated in the plate subduction;LA-ICP-MS zircon U–Pb ages show that these granodiorites,granodioritic porphyry and diorite,were generated during 114–103 Ma.The ore-bearing samples mostly presented ε_(Hf)(t)of negative values(peak value is-4 to-3)with old two-stage Hf model ages(t_(DM)^(2))(peak value is 1.10–1.15 Ga),while the barren sample showed slightly negative ε_(Hf)(t)(peak value is-1 to 0)values with young t_(DM)^(2)(peak value is 1.00–1.05 Ga).The value of zircon Ce^(4+)/Ce^(3+)ratio mostly higher than 450 was first verified for the ore-bearing samples in the Dongnan Cu–Mo deposit,and the values of ore-bearing were found to be higher than those from the barren,which suggests that the ore-bearing formed in more oxidized parental magma with higher oxygen fugacity.Based on the geochemical characteristic of the element and isotope,we concluded that the Early Cretaceous multiphases magmatic activities,low melting temperature and low pressure of pluton,and high oxygen fugacity of zircon,were the favorable conditions for metallogenesis of Dongnan Cu–Mo deposit. 展开更多
关键词 Magmatism METALLOGENESIS Dongnan cu–Mo deposit Zijinshan ore field
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An Application of Microwave Pre-oxidation in Improving Gold Recovery of a Refractory Gold Ore 被引量:21
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作者 黄建辉 《Rare Metals》 SCIE EI CAS CSCD 2000年第3期161-171,共11页
Microwave radiation was employed as a pretreating technology to oxidise a refractory gold ore. Heating characteristics showed that, in an identical microwave field, the bulk temperature of the sample increased with mi... Microwave radiation was employed as a pretreating technology to oxidise a refractory gold ore. Heating characteristics showed that, in an identical microwave field, the bulk temperature of the sample increased with microwave power, microwave radiation time and particle size. The rate of sulphur removal increased with microwave radiation time. Particle size also had a significant effect on the oxidation rate. Pyrite and marcasite could be oxidised into Fe 2O 3 with a high porous structure. When microwave radiation was carried out in a rotary bed, the oxidation was more uniformly developed, in comparison with in a fixed bed. Gold extraction by cyanidation could be remarkably improved after the ore was subjected to microwave radiation. The results showed that gold recovery could be improved from 37% to 69%~ 81.2 %. 展开更多
关键词 Microwave radiation OXIDATION refractory gold ore RECOVERY
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Ore Genesis of the Kalatongke Cu-Ni Sulfide Deposits, Western China: Constraints from Volatile Chemical and Carbon Isotopic Compositions 被引量:11
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作者 FU Piaoer TANG Qingyan +3 位作者 ZHANG Mmgjie ZHANG Zhaowei LI Liwu LI Wenyuan 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2012年第3期568-578,共11页
The Kalatongke Cu-Ni sulfide deposits located in the East Junggar terrane, northern Xinjiang, western China are the largest magmatic sulfide deposits in the Central Asian Orogenic Belt (CAOB). The chemical and carbo... The Kalatongke Cu-Ni sulfide deposits located in the East Junggar terrane, northern Xinjiang, western China are the largest magmatic sulfide deposits in the Central Asian Orogenic Belt (CAOB). The chemical and carbon isotopic compositions of the volatiles trapped in olivine, pyroxene and sulfide mineral separates were analyzed by vacuum stepwise-heating mass spectrometry. The results show that the released volatiles are concentrated at three temperature intervals of 200-400°C, 400-900°C and 900-1200°C. The released volatiles from silicate mineral separates at 400-900°C and 900-1200°C have similar chemical and carbon isotopic compositions, which are mainly composed of H2O (av. ~92 mol%) with minor H2, CO2, H2S and SO2, and they are likely associated with the ore-forming magmatic volatiles. Light δ13CCO2 values (from -20.86‰ to -12.85‰) of pyroxene indicate crustal contamination occurred prior to or synchronous with pyroxene crystallization of mantlederived ore-forming magma. The elevated contents of H2 and H2O in the olivine and pyroxene suggest a deep mantle-originated ore-forming volatile mixed with aqueous volatiles from recycled subducted slab. High contents of CO2 in the ore-forming magma volatiles led to an increase in oxygen fugacity, and thereby reduced the solubility of sulfur in the magma, then triggered sulfur saturation followed by sulfide melt segregation; CO2 contents correlated with Cu contents in the whole rocks suggest that a supercritical state of CO2 in the ore-forming magma system under high temperature and pressure conditions might play a key role in the assemblage of huge Cu and Ni elements. The volatiles released from constituent minerals of intrusion 1# have more CO2 and SO2 oxidized gases, higher CO2/CH4 and SO2/H2S ratios and lighter δ13CCO2 than those of intrusions 2# and 3#. This combination suggests that the higher oxidation state of the volatiles in intrusion 1# than intrusions 2# and 3#, which could be one of key ore-forming factors for large amounts of ores and high contents of Cu and Ni in intrusion 1#. The volatiles released at 200-400°C are dominated by H2O with minor CO2, N2+CO and SO2, with δ13CCO2 values (-25.66‰ to -22.98‰) within the crustal ranges, and are considered to be related to secondary tectonic-hydrothermal activities. 展开更多
关键词 ore genesis chemical composition carbon isotope VOLATILE mafic–ultramafic intrusion Kalatongke cu–Ni sulfide deposits Xinjiang
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Flotation technology of refractory low-grade molybdenum ore 被引量:9
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作者 Du Shuhua Luo Zhenfu 《International Journal of Mining Science and Technology》 SCIE EI 2013年第2期260-265,共6页
Because of the low grade, high oxidation rate and the accumulation of little associated metal sulfide ore in the molybdenum concentrate during flotation, the Qingyang molybdenum ore is difficult to beneficiate. The ex... Because of the low grade, high oxidation rate and the accumulation of little associated metal sulfide ore in the molybdenum concentrate during flotation, the Qingyang molybdenum ore is difficult to beneficiate. The experimental studies of grinding fineness, the amount of roughing modifier, depressant and collector were completed. In the cleaning process, the contrast experiments of one regrinding, the regrinding and scrubbing, two-stage regrinding was carried. The result shows that the grade of molybdenum ore concentrate is 45.31%, the recovery is 65.98% and the rich ore ratio reaches 20.59% by the regrinding and scrubbing seven cleaning, the regrinding of concentrations from middling of molybdenum-sulfur separation. The regularly-concentrated material from the apparatus was as the middling products. Hence, ideal beneficiation index can be obtained with a rational mineral processing, which offers new beneficiating technology for the refractory low-grade molybdenum ore in China. 展开更多
关键词 Flotation Molybdenum ore Low grade refractory
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Experimental Study of the Distribution of Au and Cu in Aqueous Vapor Phase at High Temperatures and Its Role on Ore-forming Transportation 被引量:3
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作者 ZHANG Ronghua HU Shumin ZHANG Xuetong 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2008年第4期875-883,共9页
This study focuses on experiments of Au and Cu dissolved in vapor phase in hydrothermal fluids. Experiments prove that Au and Cu can re-distribute in vapor phase and liquid phase during separation of Au- and Cu-bearin... This study focuses on experiments of Au and Cu dissolved in vapor phase in hydrothermal fluids. Experiments prove that Au and Cu can re-distribute in vapor phase and liquid phase during separation of Au- and Cu-bearing supercritical fluids to vapor and liquid phases. These experimental results can illustrate some ore geneses, where boiling phenomena of ore fluids were found. Au- and Cubearing NaHCO3-HCl solutions were heated up to more than 350℃ in the main vessel, and then passed through a phase separator in a temperature range from 250℃ to 300℃, separated into vapor and liquid phases. We collected and analyzed the liquid and vapor samples separately, and found that Au and Cu dissolved and distributed in vapor phase. In some cases, the concentrations of Au and Cu in vapor are higher than those in liquid phase. Those experiments are used to interpret field observations of fluid inclusion data of some Au and Cu deposits, and demonstrate that some Au and Cu ore deposits are derived from metals transportation in vapor phase. 展开更多
关键词 Au and cu in vapor phase ore genesis boiling phenomena liquid and vapor phase separation metal transportation in gases
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Recovery of gold from refractory gold ores: Effect of pyrite on the stability of the thiourea leaching system 被引量:1
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作者 Hong Qin Xue-yi Guo +1 位作者 Qing-hua Tian Lei Zhang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2021年第6期956-964,共9页
The extraction of gold from refractory gold ores(RGOs)without side reactions is an extremely promising endeavor.However,most RGOs contain large amounts of sulfide,such as pyrite.Thus,investigation of the influence of ... The extraction of gold from refractory gold ores(RGOs)without side reactions is an extremely promising endeavor.However,most RGOs contain large amounts of sulfide,such as pyrite.Thus,investigation of the influence of sulfide on the gold leaching process is important to maximize the utilization of RGOs.In this work,the effects of pyrite on the stability of the thiourea system were systematically investigated under different conditions.Results showed that the decomposition rate of thiourea was accelerated sharply in the presence of pyrite.The effect of pyrite on gold recovery in thiourea leaching systems was then confirmed via a series of experiments.The decomposition efficiency of thiourea decreased by 40%and the recovery efficiency of gold increased by 56%after the removal of sulfide by roasting.Under optimal conditions,the efficiency of the gold recovery system increased to 83.69%and only 57.92%of thiourea decomposition was observed.The high consumption of thiourea by the leaching system may be attributed to not only adsorption by mineral particles but also catalytic decomposition by some impurities in the ores,such as pyrite and soluble ferric oxide. 展开更多
关键词 thiourea leaching stability PYRITE refractory gold ores
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Effect of technological factors on bacterial leaching of low-grade Ni-Cu sulfide ore 被引量:2
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作者 方兆珩 陈泉军 《中国有色金属学会会刊:英文版》 CSCD 2001年第5期774-777,共4页
The bioleaching of a low grade Ni Cu sulfide ore from Jinchuan Mine with Thiobacillus ferrooxidans (TF5) and Thiobacillus thiooxidans (TT) was investigated. The effect of pH, the initial cell numbers of bacteria, the ... The bioleaching of a low grade Ni Cu sulfide ore from Jinchuan Mine with Thiobacillus ferrooxidans (TF5) and Thiobacillus thiooxidans (TT) was investigated. The effect of pH, the initial cell numbers of bacteria, the pulp density and the ratio of TF5 and TT on leaching was described, and the favorable bioleaching conditions for the ore were experimentally confirmed. The aeration leaching, agitation leaching with air bubbling, and column leaching were respectively tested. The highest recovery was achieved in the aeration leaching. After leaching for 20?d with pulp density of 15%, the extractions of Ni, Cu and Co were respectively 95.4%, 48.6% and 82.6%. 展开更多
关键词 Thiobacillus ferrooxidans Thiobacillus thiooxidans low grade Ni cu sulfide ore BIOLEACHING
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Comprehensive recovery of gold and base-metal sulfide minerals from a low-grade refractory ore
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作者 Wen-juan Li Shuang Liu +3 位作者 Yong-sheng Song Jian-kang Wen Gui-ying Zhou Yong Chen 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2016年第12期1377-1386,共10页
The comprehensive recovery of small amounts of valuable minerals such as gold and base-metal sulfide minerals from a low-grade refractory ore was investigated. The following treatment strategy was applied to a sample ... The comprehensive recovery of small amounts of valuable minerals such as gold and base-metal sulfide minerals from a low-grade refractory ore was investigated. The following treatment strategy was applied to a sample of this ore: gold flotation-gold concen- trate leaching-lead and zinc flotation from the gold concentrate leaching residue. Closed-circuit trials of gold flotation yielded a gold concen- trate that assayed at 40.23 g·t-1 Au with a recovery of 86.25%. The gold concentrate leaching rate was 98.76%. Two variants of lead-zinc flotation from the residue--preferential flotation of lead and zinc and bulk flotation of lead and zinc--were tested using the middling processing method. Foam from the reflotation was returned to the lead rougher flotation or lead-zinc bulk flotation, whereas middlings from reflotation were discarded. Sulfur concentrate was a byproduct. The combined strategy of flotation, leaching, and flotation is recommended for the treatment of this kind of ore. 展开更多
关键词 comprehensive recovery GOLD sulfide minerals MINERALOGY refractory ore treatment
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Research on Technology of Pressure Pretreatment with Oxygen for Refractory Gold Ores
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作者 刘升明 孙体昌 +1 位作者 陈景河 王淀佐 《Journal of Rare Earths》 SCIE EI CAS CSCD 2007年第S2期270-272,共3页
An combined technology of pressure pretreatment with oxygen on refractory gold ores is pointed out and discussed on this paper, according to the experiments included the test in 1 kg grade batch pressure pretreatment ... An combined technology of pressure pretreatment with oxygen on refractory gold ores is pointed out and discussed on this paper, according to the experiments included the test in 1 kg grade batch pressure pretreatment with oxygen of the concentrate from the refractory gold ores of Dongbeizhai in Sichuan province, which is called the most refractory gold ores in China. It is shown that gold recovery reach 91.73% in the combined process which is described as follows: The flotation of the sulphide gold ores is under controlled conditions, producing the concentrate for pressure pretreatment with oxygen in acidic medium and the middling for the pressure pretreatment with oxygen in alkaline medium. The thickening and washing process substitute the pressure filtration process of the pulp after pressure pretreatment. The thick slimes of the two kinds of pressure pretreatment were mixed and then enter the CIL process for simplifying the flowsheet. The possible superabundance of acid of pressure pretreatment with oxygen in acidic medium was neutralized by the tailings of flotation and the cost of neutralization will be lower. The combined technology of pressure pretreatment with oxygen has the same advantages as the normal technology of pressure pretreatment and both is helpful for environment protection. 展开更多
关键词 combined technology pressure pretreatment refractory gold ores
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Slag Resistance of Refractories for Direct Reduction of Laterite Nickel Ores in Rotary Kilns
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作者 CHEN Wei ZHANG Xiaohui ZHANG Haijun 《China's Refractories》 CAS 2020年第2期11-20,共10页
Aiming at prolonging the service life of refractories for direct reduction of laterite nickel ores in rotary kilns,the slag resistance of ten materials(corundum bricks,chrome corundum bricks,silicon nitride bonded sil... Aiming at prolonging the service life of refractories for direct reduction of laterite nickel ores in rotary kilns,the slag resistance of ten materials(corundum bricks,chrome corundum bricks,silicon nitride bonded silicon carbide bricks,high alumina silicon carbide bricks,high alumina bricks,magnesia chrome bricks,magnesium aluminate spinel bricks,spinel chrome corundum bricks,chrome corundum castables and magnesia alumina chrome composite spinel bricks)was evaluated by rotary slag tests,which simulate the service conditions in rotary kilns.The corroded residual bricks were analyzed by SEM and EDS.The results show that the magnesia alumina chrome composite spinel brick possesses the advantages of magnesium aluminate spinel bricks and chrome corundum bricks;MgO-rich spinel can absorb the penetrated ferric oxide,and forms a dense zeylanite layer,which prevents the penetration of the molten laterite nickel ores;therefore,it is an ideal lining of rotary kilns for direct reduction of laterite nickel ores. 展开更多
关键词 laterite nickel ore direct reduction REFRACTORIES rotary slag test slag resistance
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A Report of the Newly Discovered Cu–Ni Ore Deposit in the West of East Tianshan, North Xinjiang, China
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作者 CHEN Baoyun YU Jinjie +4 位作者 WANG Junliang TIAN Jiangtao LI Dahai LIU shuaijie WANG Cheng 《Acta Geologica Sinica(English Edition)》 CAS CSCD 2018年第2期857-858,共2页
Objective The Early Permian mafic-ultramafic intrusions (298- 270 Ma, Mao et al., 2008), which are widely distributed in different tectonic domains in North Xinjiang, host magmatic sulfide ore deposits, making Nort... Objective The Early Permian mafic-ultramafic intrusions (298- 270 Ma, Mao et al., 2008), which are widely distributed in different tectonic domains in North Xinjiang, host magmatic sulfide ore deposits, making North Xinjiang the second most important region for Ni resources in China. The bulk of Cu-Ni ore deposits in East Tianshan, making up a large portion of Ni resources in North Xinjiang, were concentrated in the east of East Tianshan (the Huangshan- Jing'erquan region) (Feng Yanqing, et al., 2017), while no any analogue was discovered in the west of East Tianshan until the Lubei Cu-Ni (Co) ore deposit (90°21'E, 42°10rN) was identified by Xinjiang Geological Survey in 2014. The Lubei Cu-Ni (Co) ore deposit is a medium- to large- sized deposit with Ni and Cu grades in the range 0.2%- 7.76% and 0.2%-2.30%, respectively. This work has initiated the prospection for a large-sized Cu-Ni ore deposit in the west of East Tianshan. 展开更多
关键词 North Xinjiang A Report of the Newly Discovered cu China Ni ore Deposit in the West of East Tianshan
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Preliminary Study of the Characteristics and Genesis of Arsenate Minerals in the Oxidized Zone of the Debao Skarn-Type Cu-Sn Ore Deposit in Guangxi
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作者 Li Yi Lai Lairen Institute of Geology and Mineral Resources,China National Nonferrous Metals Industry Corporation Zhang Zhongmin 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 1991年第2期187-194,共8页
Through the study of the oxidized zone of the Debao skarn-type Cu-Sn deposit in Guangxi, the authorshave found 14 arsenate minerals, most of which are for the first time reported in China. They are mainly Cuarsenate m... Through the study of the oxidized zone of the Debao skarn-type Cu-Sn deposit in Guangxi, the authorshave found 14 arsenate minerals, most of which are for the first time reported in China. They are mainly Cuarsenate minerals with subordinate Cu-Pb arsenate minerals and minor Fe-Pb-Ba varieties. Based on their paragenesis these minerals may be divided into the following series: (1) the clinoclasite-olivenite-cornwallite- cornubite- debaoite- copper silicarsenate association, (2) the scorodite- carminite- beudan-tite-bayldonite- duftite association, and (3) the scorodite-Ba-bearing pharmacosiderite- dussertite association. Arsenate minerals are formed generally in the oxidized zone of the sulfide-type deposits which lie in thewarm, humid and rainy torrid-subtropical zone with pH=6-8 and contain large amounts of arsenopyrite andcarbonate rocks. 展开更多
关键词 Preliminary Study of the Characteristics and Genesis of Arsenate Minerals in the Oxidized Zone of the Debao Skarn-Type cu-Sn ore Deposit in Guangxi cu Sn
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Influence of sintering time on microstructure and properties of hot oscillatory pressing sintered W–Cu refractory alloys
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作者 Zi-Qian Wu Wei Zhao +4 位作者 Ka Gao Shi-Hao Du Qing-Quan Kong De-Jian Sun Yang Gao 《Tungsten》 EI CSCD 2024年第2期323-332,共10页
W–Cu refractory alloys are widely used in aerospace,aviation,electronics,power,and other fi elds.However,because of its large melting point diff erence between alloy elements,the conventional powder metallurgy method... W–Cu refractory alloys are widely used in aerospace,aviation,electronics,power,and other fi elds.However,because of its large melting point diff erence between alloy elements,the conventional powder metallurgy method required a long time of high temperature sintering is very likely to cause low density and abnormal grain size growth.Therefore,90W-10Cu refractory alloys were successfully prepared by hot oscillatory pressing(HOP)under diff erent sintering time in this work.Then the infl uence of sintering time on the microstructure,grain size,density,Vickers hardness,room-tensile property,and electrical conductivity of the W–Cu refractory alloy was systematically invested.The results showed that during the short sintering time(30–90 min),the density,Vickers hardness,tensile strength,and electrical conductivity of the W–Cu refractory alloy increased signifi cantly to 98.7%,163.29 HV 30,507.3 MPa,and 14.2%International Annealed Copper Standard with the sintering time increasing,respectively,while its grain size showed no obvious change.When the sintering time further increased to 120 min,the density was basically consistent with the sintering time of 90 min.Nevertheless,the prolonged high temperature sintering resulted in the grain growth of the samples,which caused the deterioration of the Vickers hardness,room-tensile strength,and conductivity properties of the W–Cu refractory alloy.At the same sintering time,the density,Vickers hardness,and electrical conductivity of the HOP sintered W–Cu refractory alloy were signifi cantly higher than those of the HP sintered sample.It was indicated that high density,fi ne-grain,and excellent properties W–Cu refractory alloys could be prepared by hot oscillatory pressing under appropriate sintering time. 展开更多
关键词 W–cu refractory alloy Hot oscillatory pressing Sintering time Microstructure Property
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Roasting and chlorine leaching of gold-bearing refractory concentrate:Experimental and process analysis 被引量:10
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作者 Ida De Michelis Agostino Olivieri +3 位作者 Stefano Ubaldini Francesco Ferella Francesca Beolchini Francesco Vegliò 《International Journal of Mining Science and Technology》 SCIE EI 2013年第5期709-715,共7页
This paper deals with gold extraction from a refractory concentrate by chlorine leaching.The process considers a pre-treatment of refractory materials by low temperature oxidation carried out with low oxygen concentra... This paper deals with gold extraction from a refractory concentrate by chlorine leaching.The process considers a pre-treatment of refractory materials by low temperature oxidation carried out with low oxygen concentration.The oxidized material is treated by leaching with brine.After gold adsorption/reduction onto activated carbon,iron and base metals can be precipitated by NaOH.Roasting tests show the necessity to carry out a thermal pre-treatment at least at 550°C to obtain a reduction of sulfur and mercury in the material(50%and 90%,respectively).Highest gold extraction yield(around 93%)is obtained in the leaching test performed with material sample treated at 650°C.This result confrms the necessity to optimize the thermal pre-treatment to improve Au recovery and to reduce chlorine consumption.A comparison with conventional cyanidation confrms that chlorination could be an useful alternative:in fact,gold extraction yield is quite low:57%in non-pre-treated material and 25%in pre-treatment material. 展开更多
关键词 Gold ores refractory ores LEACHING CHLORINE
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Contrast in Fluid M etallogeny between the Tianmashan Au-S Deposit and the Datuanshan Cu Deposit in Tongling,Anhui Province 被引量:2
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作者 LEE Hyun Koo 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2003年第1期116-124,共9页
A comprehensive contrast of ore-forming geological background and ore-forming fluid features, especially fluid ore-forming processes, has been performed between the Tianmashan and the Datuanshan ore deposits in Tongli... A comprehensive contrast of ore-forming geological background and ore-forming fluid features, especially fluid ore-forming processes, has been performed between the Tianmashan and the Datuanshan ore deposits in Tongling, Anhui Province. The major reasons for the formation of the stratabound skarn Au-S ore deposit in Tianmashan and the stratabound skarn Cu ore deposit in Datuanshan are analyzed in accordance with this contrast. The magmatic pluton in Tianmashan is rich in Au and poor in Cu, but that in Datuanshan is rich in Cu and Au. The wallrock strata in Tianmashan contain Au-bearing pyrite layers with some organic substance but those in Datuanshan contain no such layers. Moreover, the ore-forming fluids in Tianmashan are dominantly magmatic ones at the oxide and sulfide stages, but those with high content of Cu in Datuanshan are mainly groundwater fluids. In addition, differences in compositional evolution and physicochemical condition variation of the ore-forming fluids result in gradual dispersion 展开更多
关键词 fluid inclusion fluid ore-forming process contrast in fluid metallogeny Au-S ore deposit cu ore deposit magmatic fluid groundwater fluid TONGLING Anhui Province
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Geology,Geochemistry,and Genesis of the Tongcun Reduced Porphyry Mo(Cu) Deposit,NW Zhejiang Province,China
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作者 TANG Yanwen LI Xiaofeng +6 位作者 XIE Yuling HUANG Cheng WEI Hao CAI Jiali YIN Yifan QIN Chaojian LIU Rong 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2015年第3期766-782,共17页
The Tongcun Mo(Cu) deposit in Kaihua city of Zhejiang Province,eastern China,occurs in and adjacent to the Songjiazhuang granodiorite porphyry and is a medium-sized and important porphyry type ore deposit.Two irregu... The Tongcun Mo(Cu) deposit in Kaihua city of Zhejiang Province,eastern China,occurs in and adjacent to the Songjiazhuang granodiorite porphyry and is a medium-sized and important porphyry type ore deposit.Two irregular Mo(Cu) orebodies consist of various types of hydrothermal veinlets.Intensive hydrothermal alteration contains skarnization,chloritization,carbonatization,silicification and sericitization.Based on mineral assemblages and crosscutting relationships,the oreforming processes are divided into five stages,i.e.,the early stage of garnet + epidote ± chlorite associated with skarnization and K-feldspar + quartz ± molybdenite veins associated with potassicsilicic alteration,the quartz-sulfides stage of quartz + molybdenite ± chalcopyrite ± pyrite veins,the carbonatization stage of calcite veinlets or stockworks,the sericite + chalcopyrite ± pyrite stage,and the late calcite + quartz stage.Only the quartz-bearing samples in the early stage and in the quartzsulfides stage are suitable for fluid inclusions(FIs) study.Four types of FIs were observed,including1) CO2-CH4 single phase FIs,2) CO2-bearing two- or three-phase FIs,3) Aqueous two-phase FIs,and4) Aqueous single phase FIs.FIs of the early stages are predominantly CO2- and CH4-rich FIs of the CO2-CH4-H2O-NaCl system,whereas minerals in the quartz-sulfides stage contain CO2-rich FIs of the CO2-H2O-NaCl system and liquid-rich FIs of the H2O-NaCl system.For the CO2-CH4 single phase FIs of the early mineralization stage,the homogenization temperatures of the CO2 phase range from 15.4 ℃ to 25.3 ℃(to liquid),and the fluid density varies from 0.7 g/cm^3 to 0.8 g/cm^3;for two- or three-phase FIs of the CO2-CH4-H2O-NaCl system,the homogenization temperatures,salinities and densities range from 312℃ to 412℃,7.7 wt%NaCl eqv.to 10.9 wt%NaCl eqv.,and 0.9 g/cm^3 to 1.0 g/cm^3,respectively.For CO2-H2O-NaCI two- or threephase FIs of the quartz-sulfides stage,the homogenization temperatures and salinities range from255℃ to 418℃,4.8 wt%NaCl eqv.to 12.4 wt%NaCl eqv.,respectively;for H2O-NaCl two-phase FIs,the homogenization temperatures range from 230 ℃ to 368 ℃,salinities from 11.7 wt%NaCl eqv.to16.9 wt%NaCl eqv.,and densities from 0.7 g/cm^3 to 1.0 g/cm^3.Microthermometric measurements and Laser Raman spectroscopy analyses indicate that CO2 and CH4 contents and reducibility(indicated by the presence of CH4) of the fluid inclusions trapped in quartz-sulfides stage minerals are lower than those in the early stage.Twelve molybdenite separates yield a Re-Os isochron age of 163 ± 2.4 Ma,which is consistent with the emplacement age of the Tongcun,Songjiazhuang,Dayutang and Huangbaikeng granodiorite porphyries.The 〈S18OSMow values of fluids calculated from quartz of the quartz-sulfides stage range from 5.6‰ to 8.6‰,and the 〈JDSMOw values of fluid inclusions in quartz of this stage range from-71.8‰ to-88.9‰,indicating a primary magmatic fluid source.〈534SV-cdt values of sulfides range from+1.6‰ to +3.8‰,which indicate that the sulfur in the ores was sourced from magmatic origins.Phase separation is inferred to have occurred from the early stage to the quartz-sulfides stage and resulted in ore mineral precipitation.The characteristics of alteration and mineralization,fluid inclusion,sulfur and hydrogen-oxygen isotope data,and molybdenite Re-Os ages all suggest that the Tongcun Mo(Cu) deposit is likely to be a reduced porphyry Mo(Cu) deposit associated with the granodiorite porphyry in the Tongcun area. 展开更多
关键词 Tongcun Mo cu deposit fluid inclusions reduced ore fluids porphyry type isotopegeochemistry ore genesis
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Optimal bandwidth selection for retrieving Cu content in rock based on hyperspectral remote sensing
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作者 MA Xiumei ZHOU Kefa +4 位作者 WANG Jinlin CUI Shichao ZHOU Shuguang WANG Shanshan ZHANG Guanbin 《Journal of Arid Land》 SCIE CSCD 2022年第1期102-114,共13页
Hyperspectral remote sensing technology is widely used to detect element contents because of its multiple bands,high resolution,and abundant information.Although researchers have paid considerable attention to selecti... Hyperspectral remote sensing technology is widely used to detect element contents because of its multiple bands,high resolution,and abundant information.Although researchers have paid considerable attention to selecting the optimal bandwidth for the hyperspectral inversion of metal element contents in rocks,the influence of bandwidth on the inversion accuracy are ignored.In this study,we collected 258 rock samples in and near the Kalatage polymetallic ore concentration area in the southwestern part of Hami City,Xinjiang Uygur Autonomous Region,China and measured the ground spectra of these samples.The original spectra were resampled with different bandwidths.A Partial Least Squares Regression(PLSR)model was used to invert Cu contents of rock samples and then the influence of different bandwidths on Cu content inversion accuracy was explored.According to the results,the PLSR model obtains the highest Cu content inversion accuracy at a bandwidth of 35 nm,with the model determination coefficient(R^(2))of 0.5907.The PLSR inversion accuracy is relatively unaffected by the bandwidth within 5-80 nm,but the accuracy decreases significantly at 85 nm bandwidth(R^(2)=0.5473),and the accuracy gradually decreased at bandwidths beyond 85 nm.Hence,bandwidth has a certain impact on the inversion accuracy of Cu content in rocks using the PLSR model.This study provides an indicator argument and theoretical basis for the future design of hyperspectral sensors for rock geochemistry. 展开更多
关键词 hyperspectral remote sensing cu element BANDWIDTH Partial Least Squares Regression inversion accuracy Kalatage polymetallic ore concentration area
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BIOOXIDATION OF TWO ARSENICAL REFRACTORY GOLD CONCENTRATES AND GOLD CYANIDATION
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作者 Zhang, Yongzhu Lu, Yiyuan +1 位作者 Zhang, Chuanfu Zhao, Tiancong(Deptartment.of Nonferrous Metallurgy,Central South University of Technology, 410083 Changsha)Qiu , Rongqing(Microbilolgy Institute, Academia Sinica,Beijing 100080) 《中国有色金属学会会刊:英文版》 CSCD 1994年第3期41-45,共5页
BIOOXIDATIONOFTWOARSENICALREFRACTORYGOLDCONCENTRATESANDGOLDCYANIDATIONZhang,Yongzhu;Lu,Yiyuan;Zhang,Chuanfu;... BIOOXIDATIONOFTWOARSENICALREFRACTORYGOLDCONCENTRATESANDGOLDCYANIDATIONZhang,Yongzhu;Lu,Yiyuan;Zhang,Chuanfu;Zhao,Tiancong(Dep... 展开更多
关键词 GOLD bacterial leaching refractory GOLD oreS
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增材制造钨基合金的研究进展 被引量:1
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作者 刘震 尤畅 +5 位作者 刘世昌 关书文 时坚 高鹏 魏彦鹏 苗治全 《铸造》 CAS 北大核心 2023年第7期781-793,共13页
钨基合金是仅次于硬质合金的第二大类钨的深加工制品,钨基合金具有的独特物理和力学性能使得其在国防工业和国民经济各领域发挥着巨大的作用,但随着未来制造业对零件的精度要求越来越高以及更为复杂的零部件设计,采用传统的粉末冶金方... 钨基合金是仅次于硬质合金的第二大类钨的深加工制品,钨基合金具有的独特物理和力学性能使得其在国防工业和国民经济各领域发挥着巨大的作用,但随着未来制造业对零件的精度要求越来越高以及更为复杂的零部件设计,采用传统的粉末冶金方法难以实现这些要求。增材制造(AM)为其提供了独特的几何设计自由度和快速原型制作能力。本文对国内外增材制造钨基合金的研究进展进行了介绍,并对研究面临的主要问题、研究趋势进行分析和展望。 展开更多
关键词 钨基合金 W-NI-FE W-Ni W-cu 增材制造 难熔高熵合金
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地质冶金学建模在刚果(金)SICOMINES难处理铜钴矿中的应用
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作者 王玲 杜宇航 +3 位作者 赵战锋 张文娟 马保中 王成彦 《工程科学学报》 EI CSCD 北大核心 2023年第11期1847-1858,共12页
SICOMINES铜钴矿位于刚果(金)科卢韦齐南西侧,是中部非洲加丹加铜矿带的典型矿床.由于矿床成因复杂,矿石中形成了十多种铜、钴矿物,尤其各种钴矿物选冶性质差异大,一直存在选冶工艺复杂,生产不稳定,回收率低的问题.为此,本文首次采用Dat... SICOMINES铜钴矿位于刚果(金)科卢韦齐南西侧,是中部非洲加丹加铜矿带的典型矿床.由于矿床成因复杂,矿石中形成了十多种铜、钴矿物,尤其各种钴矿物选冶性质差异大,一直存在选冶工艺复杂,生产不稳定,回收率低的问题.为此,本文首次采用Datamine和Leapfrog软件构建了钴的冶金地质学模型,首先,收集历史勘查资料,建立矿区地层和矿化域模型,初步获得钴在空间的品位变化规律;其次,进行采样设计,采集代表钴在地层和矿体中品位分布规律的工艺矿物学样品;再次,采用工艺矿物学综合手段,获得各样品中矿物含量和钴赋存状态的定量数据,并采用单一域赋值法和距离幂次反比法等插值手段写入模型;然后,根据钴矿物选冶类型的空间分布规律划分了5个空间选冶域,分别为适于浮选域(TYPE1)、适于磁选域(TYPE2)、适于浮选-磁选联合分选域(TYPE3)、适于浸出域(TYPE4)和难以分选域(TYPE5),构建初步地质冶金学模型;最后,通过对5个选冶域中综合样分别进行选矿实验来验证模型.实验结果显示,采用矿山现行的浮选–磁选联合工艺流程,5个选冶域中钴的回收率和精矿品位差距明显,现有工艺流程只适用于空间域TYPE1、TYPE2和TYPE3,模型中选冶域的划分合理.根据模型中钴的赋存状态和有效钴品位进行配矿,可以起到稳定现行生产工艺,提高钴回收率的作用,同时,构建的地质冶金学模型为今后实现SICOMINES矿区钴的分采分选提供指导. 展开更多
关键词 地质冶金学 SICOMINES 难处理铜钴矿 工艺矿物学 选冶空间域 矿石可选性
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