We investigate the finite-time performance of a quantum endoreversible Carnot engine cycle and its inverse operation-Carnot refrigeration cycle,employing a spin-1/2 system as the working substance.The thermal machine ...We investigate the finite-time performance of a quantum endoreversible Carnot engine cycle and its inverse operation-Carnot refrigeration cycle,employing a spin-1/2 system as the working substance.The thermal machine is alternatively driven by a hot boson bath of inverse temperatureβ_(h)and a cold boson bath at inverse temperatureβ_(c)(>βh).While for the engine model the hot bath is constructed to be squeezed,in the refrigeration cycle the cold bath is established to be squeezed,with squeezing parameter r.We obtain the analytical expressions for both efficiency and power in heat engines and for coefficient of performance and cooling rate in refrigerators.We find that,in the high-temperature limit,the efficiency at maximum power is bounded by the analytical valueη_(+)=√sech(2r)(1-η_(C)),and the coefficient of performance at the maximum figure of merit is limited byε_(+)=√sech(2r)(1+ε_(C))/sech(2r)(1+ε_(C))-εC)-1,whereη_(C)=1-β_(h)/β_(c)andε_(C)=β_(h)/(β_(c)-β_(h))are the respective Carnot values of the engines and refrigerators.These analytical results are identical to those obtained from the Carnot engines based on harmonic systems,indicating that the efficiency at maximum power and coefficient at maximum figure of merit are independent of the working substance.展开更多
On November 30, 2007, the China Association for Standardization (CAS) held a press conference at Beijing Diaoyutai State Guest House. Leaders from the China Household Electric Appliance Research Institute, the Chi... On November 30, 2007, the China Association for Standardization (CAS) held a press conference at Beijing Diaoyutai State Guest House. Leaders from the China Household Electric Appliance Research Institute, the China Household Electric Appliance Association, and the China Consumers' Association attended and made speeches.……展开更多
The dynamic stability analysis of an irreversible refrigerator working at the minimum power input P for given cooling load R was investigated.An irreversible refrigerator model was established based on coupled differe...The dynamic stability analysis of an irreversible refrigerator working at the minimum power input P for given cooling load R was investigated.An irreversible refrigerator model was established based on coupled differential equations.The global asymptotic stability characteristics were proved by constructing Lyapunov function based on Lyapunov stability theory and analyzed by sketching global phase portraits.The influence of parameters such as initial and operating parameters were studied for different values.It was found that an equilibrium point of nonlinear system was the global stability point,and the temperature of the working fluids converged to the stability value as time t approximated to positive infinite.Besides,numerical integrations were carried out to corroborate the global asymptotic stability properties of the system.Finally,the dynamic stability and the thermodynamic properties of the system were analyzed.It was found that the energetic characteristics and the dynamic stability properties were deteriorated as the dimensionless cooling load R~* and the thermal conductance ratio b increased.展开更多
We have successfully developed cryogen-free dilution refrigerators with medium cooling power that can be applied to quantum experiments. Breakthroughs have been made in some key technologies and components of heat swi...We have successfully developed cryogen-free dilution refrigerators with medium cooling power that can be applied to quantum experiments. Breakthroughs have been made in some key technologies and components of heat switches and dilution units. Our prototype has been running continuously and stably for more than 100 hours below 10 m K, with a minimum temperature of 7.6 m K and a cooling power of 450 μW at 100 m K. At the same time, we have also made progress in the application of dilution refrigerators, such as quantum computing, low-temperature detector, and magnet integration. These indicators and test results indicate good prospects for application in physics, astronomy, and quantum information.展开更多
The regenerative refrigeration is an important reverse work-heat conversion cycle with a theoretical coefficient of performance(COP)identical to the Carnot efficiency.Practical regenerative refrigerators are capable o...The regenerative refrigeration is an important reverse work-heat conversion cycle with a theoretical coefficient of performance(COP)identical to the Carnot efficiency.Practical regenerative refrigerators are capable of working down to 4 K and largely fulfill the refrigeration requirement of modern technologies in many fields,especially for space applications.However,the enthalpy flow associated with the pressure dependence,abbreviated as pressure-induced enthalpy flow,brought about by real gas effects degrades the theoretical COP of the refrigerator to below about 30% of the Carnot efficiency at the temperatures of below the critical point.This paper reviews the long history of exploring the real gas effects which dates back to the 1970 s and continues to now.Important explorations of uncovering the loss mechanism and reducing such losses are summarized.The theories that are in accordance with experimental results and simulation results are expounded.We further carry out analyses on the expansion components,including the pulse tube and the clearance gap.Several inferences are made in order to explore the long-lasting puzzles about real gas effects.It is emphasized that the underlying cause of the loss in the regenerator is an indirect effect of the real gas properties.Further study about carrying out a direct verification of the theory is proposed.展开更多
Er_(20)Ho_(20)Dy_(20)Cu_(20)Ni_(20)high-entropy metallic glass exhibited excellent magnetic refrigeration material with a wide temperature range and high refrigeration capacity(RC)was reported.Er_(20)Ho_(20)Dy_(20)Cu_...Er_(20)Ho_(20)Dy_(20)Cu_(20)Ni_(20)high-entropy metallic glass exhibited excellent magnetic refrigeration material with a wide temperature range and high refrigeration capacity(RC)was reported.Er_(20)Ho_(20)Dy_(20)Cu_(20)Ni_(20)high-entropy metallic glass was observed with typical spin glass behavior around 15.5 K.In addition,we find that the magnetic entropy change(-△S_(M))originates from the sample undergoing a ferromagnetic(FM)to paramagnetic(PM)transition around 20 K.Under a field change from 0 T to 7 T,the value of maximum magnetic entropy change(-△S_(M)^(max))reaches 12.5 J/kg·K,and the corresponding value of RC reaches 487.7 J/kg in the temperature range from 6 K to 60 K.The large RC and wide temperature range make the Er_(20)Ho_(20)Dy_(20)Cu_(20)Ni_(20)high-entropy metallic glass be a promising material for application in magnetic refrigerators.展开更多
Intermodal competition changes with changes in technology, economics, and environmental concerns. Trucks and airships are generally considered not to be competitors, but this depends on the distance of haul. The tonne...Intermodal competition changes with changes in technology, economics, and environmental concerns. Trucks and airships are generally considered not to be competitors, but this depends on the distance of haul. The tonne-kilometer cost of trucking rises much more quickly with distance than it does the cost of a cargo airship. At some distance, the two modes are direct substitutes. The costs of the Mexico-Canada refrigerated truck supply chain are compared with the costs of a 100t-lift, electrically-powered airship. The flight characteristics of the Hindenburg Zeppelin are used as a model for a modern cargo airship. The supply chain cost of trucking tomatoes is used to test the theorical proposition. The cost difference works out to about US10¢/kg (5¢/lb) advantage for trucking Mexican tomatoes to Canada. However, this cost disadvantage of the airship could be made up by their vibrationless ride, better air circulation and one-day service versus four days by truck. This alternative form of transportation could have a positive impact on worldwide north-south distribution of food. Airships can overcome trade barriers and distance to open new markets for perishable food exports. In addition, they would reduce the carbon emissions of transport. Canada imports 160,000 refrigerated truckloads of fruits and vegetables by from the southern US and Mexico. With an average driving distance of 3,000 km, these trucks emit 606,000 MT of CO<sub>2</sub> annually. Airships powered by hydrogen fuel cells would have zero-carbon emissions. Markets are not yet incorporating the environmental advantage of airships in any freight comparison, but inevitably this will be important.展开更多
The use of carbon dioxide as a working fluid has been the subject of extensive studies in recent years, particularly in the field of refrigeration where it is at the heart of research to replace CFC and HCFC. Its ther...The use of carbon dioxide as a working fluid has been the subject of extensive studies in recent years, particularly in the field of refrigeration where it is at the heart of research to replace CFC and HCFC. Its thermodynamic properties make it a fluid of choice in the efficient use of energy at low and medium temperatures in engine cycles. However, the performance of transcritical CO2 cycles weakens under high temperature and pressure conditions, especially in refrigeration systems;On the other hand, this disadvantage becomes rather interesting in engine cycles where CO2 can be used as an alternative to the organic working fluid in small and medium-sized electrical systems for low quality or waste heat sources. In order to improve the performance of systems operating with CO2 in the field of refrigeration and electricity production, research has made it possible to develop several concepts, of which this article deals with a review of the state of the art, followed by analyzes in-depth and critical of the various developments to the most recent modifications in these fields. Detailed discussions on the performance and technical characteristics of the different evolutions are also highlighted as well as the factors affecting the overall performance of the systems studied. Finally, perspectives on the future development of the use of CO2 in these different cycles are presented.展开更多
In this paper, an irreversible thermionic refrigerator model based on van der Waals heterostructure with various irreversibilities is established by utilizing combination of non-equilibrium thermodynamics and finite t...In this paper, an irreversible thermionic refrigerator model based on van der Waals heterostructure with various irreversibilities is established by utilizing combination of non-equilibrium thermodynamics and finite time thermodynamics. The basic performance characteristics of the refrigerator are obtained. The effects of key factors, such as bias voltages, Schottky barrier heights and heat leakages, on the performance are studied. Results show that cooling rates and coefficients of performances(COPs) can attain the double maximum with proper modulation of barrier heights and bias voltages. Increasing cross-plane thermal resistance as well as decreasing electrode-reservoir thermal resistance and reservoir-reservoir thermal resistance can enhance the performance of the device. The optimal performance region is the interval between the maximum cooling rate point and the maximum COP point. By modulating the bias voltage, the working state of the device can fall into the optimal performance region. The optimal performance of the refrigerator when using single layer graphene and a few layers graphene as electrode material is also compared.展开更多
As a novel generation of a rotational gas wave machine,the wave rotor refrigerator(WRR)is an unsteadyflow device used for refrigeration,in whose passages pressured streams directly contact and exchange energy due to th...As a novel generation of a rotational gas wave machine,the wave rotor refrigerator(WRR)is an unsteadyflow device used for refrigeration,in whose passages pressured streams directly contact and exchange energy due to the movement of pressure waves.In this paper,the working mechanism and refrigeration principle are inves-tigated based on the one-dimensional unsteadyflow theory.A basic limitation on main structural parameters and operating parameters is deduced and the wave diagram of WRR to guide designing is sketched.The main influential factors are studied through an experiment.In the DUT Gas Wave Refrigeration Studying and Development Center(GWRSDC)lab,the isentropic efficiency can now reach about 65%.The results show that the WRR is a feasible and promising technology in pressured gas refrigeration cases.展开更多
In recent years, microchannel heat exchangers have begun to be used in refrigeration and air conditioning systems. This paper introduces a microchannel condenser for domestic refrigerators with a theoretical model to ...In recent years, microchannel heat exchangers have begun to be used in refrigeration and air conditioning systems. This paper introduces a microchannel condenser for domestic refrigerators with a theoretical model to evaluate its performance. The model was used to obtain the optimal design parameters for different numbers of tubes and tube lengths. The results show that the needed tube height of the down- ward section decreases with the number of tubes and the tube diameter. Compared with the original con- denser, the present optimal design parameters can reduce the total metal mass by 48.6% for the two wall two side design and by 26% for the two wall one side design. Thus, the present condenser is much better than the condensers usually used in actual domestic refrigerators.展开更多
We present a simple hot press-based method for processing La(Fe,Si)13-based compounds consisting of La–Fe–Co–Si–C particles and phenolic resin. The magnetic entropy change △S per unit mass for the La Fe_(10.87)Co...We present a simple hot press-based method for processing La(Fe,Si)13-based compounds consisting of La–Fe–Co–Si–C particles and phenolic resin. The magnetic entropy change △S per unit mass for the La Fe_(10.87)Co_(0.63)Si_(1.5)C_(0.2)/phenolic resin compounds have nearly the same magnitude with the base materials. With the content of phenolic resin of 5.0 wt%, the compound conductivity is 3.13 W·m^(-1)·K^(-1). In order to measure the cooling performance of La(Fe,Si)13-based compounds,the La(Fe_(11.6-x)Co_(x))Si_(1.4)C_(0.15)(x =0.60, 0.65, 0.75, 0.80, 0.85)/phenolic resin compounds were pressed into thin plates and tested in a hybrid refrigerator that combines the active magnetic refrigeration effect with the Stirling cycle refrigeration effect. The test results showed that a maximum cooling power of 41 W was achieved over a temperature span of 30 K.展开更多
The Mixed Refrigerant(MR)component is an important factor influencing the performances of natural gas lique-faction processes.However,there is a lack of systematic research about the utilization of propane pre-cooled(...The Mixed Refrigerant(MR)component is an important factor influencing the performances of natural gas lique-faction processes.However,there is a lack of systematic research about the utilization of propane pre-cooled(C3/MRC).In this paper,this mixed refrigerant cycle liquefaction process is simulated using the HYSYS software and the main influential parameters involved in the process are varied to analyze their influence on the liquefaction rate and power consumption.The results show that an effective way for lowering the power consumption of the compressor consists of reducing the flow through the compressor through optimization of the percentage of mixed refrigerant.The power consumption of the compressor in the hybrid refrigeration process is affected by both flow and pressure ratios.Its specific power consumption can be reduced by increasing the flow and decreasing the pressure ratio at the same time.The increase in refrigerant pressure at the high-pressure end can significantly mitigate the energy loss of the heat exchanger and compressor.展开更多
Conventional refrigeration processes release ammonia and freon into the atmosphere,which results in global warming.These problems may be overcome by using thermoelectric modules because of the absence of coolants or r...Conventional refrigeration processes release ammonia and freon into the atmosphere,which results in global warming.These problems may be overcome by using thermoelectric modules because of the absence of coolants or refrigerants in these systems.However,the cooling performances of such modules are relatively small in comparison to those of conventional refrigerators.In this paper,the working principles of thermoelectric modules are discussed together with a review of different relevant aspects,namely:the thermoelectric materials,and their mechanical properties used to build thermoelectric devices,different types of thermoelectric devices available on the market,mathematical modeling of thermoelectric materials,and various applications of thermoelectric materials in different fields.展开更多
A theoretical investigation is presented about a double evaporator ejector refrigeration cycle(DEERC).Special attention is paid to take into account the influence of the sub-cooling and superheating effects induced by...A theoretical investigation is presented about a double evaporator ejector refrigeration cycle(DEERC).Special attention is paid to take into account the influence of the sub-cooling and superheating effects induced by an internal heat exchanger(IHX).The ejector is introduced into the baseline cycle in order to mitigate the throttling process losses and increase the compressor suction pressure.Moreover,the IHX has the structure of a concentric counter-flow type heat exchanger and is intentionally used to ensure that the fluid at the compressor inlet is vapor.To assess accurately the influence of the IHX on the DEERC performance,a mathematical model is derived in the frame of the dominant one-dimensional theory for ejectors.The model also accounts for the friction effect in the ejector mixing section.The equations of this model are solved using an Engineering Equation Solver(EES)for different fluids.These are:R134a as baseline fluid and other environment friendly refrigerants used for comparison,namely,R1234yf,R1234ze,R600,R600a,R290,R717 and R1270.The simulation results show that the DEERC with an IHX can achieve COP(the coefficient of performance)improvements from 5.2 until 10%.展开更多
We investigate the structure, magnetic properties, magnetic phase transitions and magnetocaloric effects(MCEs) of Er5Si3Bx(x=0.3,0.6) compounds. The Er5Si3Bx(x = 0.3, 0.6) compounds crystalize in a Mn5Si3type hexagona...We investigate the structure, magnetic properties, magnetic phase transitions and magnetocaloric effects(MCEs) of Er5Si3Bx(x=0.3,0.6) compounds. The Er5Si3Bx(x = 0.3, 0.6) compounds crystalize in a Mn5Si3type hexagonal structure(space group: P63/cm) and exhibit a successive complicated magnetic phase transition. The extensive magnetic phase transitions contribute to the broad temperature range of MCEs exhibiting in Er_(5)Si_(3)B_(x)(x=0.3,0.6) compounds, with maximum magnetic entropy change(-ΔSM_(max)) and refrigeration capacity of 10.2 J·kg^(-1)·K^(-1), 356.3 J/kg and 11.5 J·kg^(-1)·K^(-1),393.3 J/kg under varying magnetic fields 0–5 T, respectively. Remarkably, the δTFWHMvalues(the temperature range corresponding to 1/2×|-ΔSM_(max)|) of Er5Si3Bx(x=0.3,0.6) compounds were up to 41.8 K and 39.6 K, respectively. Thus, the present work provides a potential magnetic refrigeration material with a broad temperature range MCEs for applications in cryogenic magnetic refrigerators.展开更多
In order to ensure the safe operation of the compressors used in water chillers,in the present study some interlock protections have been added to the related design.These include a low pressure protection,a high pres...In order to ensure the safe operation of the compressors used in water chillers,in the present study some interlock protections have been added to the related design.These include a low pressure protection,a high pressure protection,an exhaust temperature protection and a differential pressure protection.Some tests have been conducted by tuning the saturation suction and exhaust temperatures of the compressor through adjustment of the cold source outlet temperature and the ambient temperature.The results show that the ambient temperature increases with decreasing device load and increasing fan speed under the same saturated suction temperature;the device refrigerating capacity steps up with augmenting load and dropping saturation exhaust temperature,while it is not greatly affected by the fan speed.Moreover,the Energy efficiency ratio(COP)decreases with the rise of the saturation exhaust temperature.This parameter is not affected much by the device load and fan speed at high saturation exhaust temperature,while it improves on increasing the device load and decreasing the fan speed at low saturation exhaust temperature.展开更多
A study is conducted on the performances of a solar powered continuous-adsorption refrigerator considering two particular days as references cases,namely,the summer solstice(June 21st)and the autumn equinox(September ...A study is conducted on the performances of a solar powered continuous-adsorption refrigerator considering two particular days as references cases,namely,the summer solstice(June 21st)and the autumn equinox(September 21st).The cooling capacity,system performance coefficient and the daily rate of available cooling energy are assessed.The main goal is to compare the performances of a solar adsorption chiller equipped with a hot water tank(HWT)with an equivalent system relying on solar collectors with no heat storage module.The daily cooling rates for the solar refrigerator are found to be 102.4 kWh and 74.3 kWh,respectively,on June 21st and on September 21st,using a total collector’s area of 43.47 m2.The corresponding values for the adsorption chiller equipped with a hot water tank of 2 m3(and using a total collector’s area of 72.45 m2),are 127.1 kWh and 106.13 kWh,respectively.展开更多
This paper deals with the evaluation of the Coefficient of Performance (COP) of solar adsorption refrigeration. In the literature, simulation models to predict the thermal behaviour and the coefficient of performance ...This paper deals with the evaluation of the Coefficient of Performance (COP) of solar adsorption refrigeration. In the literature, simulation models to predict the thermal behaviour and the coefficient of performance of these systems are uncommon. This is why we suggest a model to simulate the operation of the machine in a typical hot and dry climate of the city of Ouagadougou. The objective is to provide a model for calculating the COP from the measurement of the ambient temperature and the irradiation of a given site. Starting from mathematical modelling, a resolution and simulation were made with COMSOL software based on the Dubinin-Astakhov adsorption model, the heat transfer balance equations, and the Linear Driving Force (LDF) model to describe the thermal behaviour of the system. A one-week measurement sequence on the adsorption solar refrigerator at the Albert Schweitzer Ecological Centre (CEAS) validated the numerical results. The measurement shows that for the days with high sunshine, the temperature of the reaction medium reaches 110°C, and the pressure reaches 500 mbar. This leads to a production of cold that allows it to reach the temperature of -5°C at the evaporator. Under these conditions, the COP is worth 14%. These results are obtained both by numerical simulation using the COMSOL 5.1 software and after a measurement session on the solar refrigerator available to the CEAS. We obtained an experimental and theoretical coefficient of performance varying between 9% and 14% with a difference of between 0% and 3%. We conclude that our model is suitable to estimate the COP of any device based on its thermal properties, the ambient temperature and the irradiation of a given site.展开更多
基金the National Natural Science Foundation of China(Grant No.11875034)the Opening Project of Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology.
文摘We investigate the finite-time performance of a quantum endoreversible Carnot engine cycle and its inverse operation-Carnot refrigeration cycle,employing a spin-1/2 system as the working substance.The thermal machine is alternatively driven by a hot boson bath of inverse temperatureβ_(h)and a cold boson bath at inverse temperatureβ_(c)(>βh).While for the engine model the hot bath is constructed to be squeezed,in the refrigeration cycle the cold bath is established to be squeezed,with squeezing parameter r.We obtain the analytical expressions for both efficiency and power in heat engines and for coefficient of performance and cooling rate in refrigerators.We find that,in the high-temperature limit,the efficiency at maximum power is bounded by the analytical valueη_(+)=√sech(2r)(1-η_(C)),and the coefficient of performance at the maximum figure of merit is limited byε_(+)=√sech(2r)(1+ε_(C))/sech(2r)(1+ε_(C))-εC)-1,whereη_(C)=1-β_(h)/β_(c)andε_(C)=β_(h)/(β_(c)-β_(h))are the respective Carnot values of the engines and refrigerators.These analytical results are identical to those obtained from the Carnot engines based on harmonic systems,indicating that the efficiency at maximum power and coefficient at maximum figure of merit are independent of the working substance.
文摘 On November 30, 2007, the China Association for Standardization (CAS) held a press conference at Beijing Diaoyutai State Guest House. Leaders from the China Household Electric Appliance Research Institute, the China Household Electric Appliance Association, and the China Consumers' Association attended and made speeches.……
基金the Fundamental Research Fund for the Central Universities,China(No.2011011302)National Natural Science Foundation of China(No.51078068)
文摘The dynamic stability analysis of an irreversible refrigerator working at the minimum power input P for given cooling load R was investigated.An irreversible refrigerator model was established based on coupled differential equations.The global asymptotic stability characteristics were proved by constructing Lyapunov function based on Lyapunov stability theory and analyzed by sketching global phase portraits.The influence of parameters such as initial and operating parameters were studied for different values.It was found that an equilibrium point of nonlinear system was the global stability point,and the temperature of the working fluids converged to the stability value as time t approximated to positive infinite.Besides,numerical integrations were carried out to corroborate the global asymptotic stability properties of the system.Finally,the dynamic stability and the thermodynamic properties of the system were analyzed.It was found that the energetic characteristics and the dynamic stability properties were deteriorated as the dimensionless cooling load R~* and the thermal conductance ratio b increased.
基金supported by the Beijing Commission of Science and Technology(Grant No.Z211100004021012)Special Research Assistant Program of the Chinese Academy of Sciences(Grant No.E3VP021RX4)。
文摘We have successfully developed cryogen-free dilution refrigerators with medium cooling power that can be applied to quantum experiments. Breakthroughs have been made in some key technologies and components of heat switches and dilution units. Our prototype has been running continuously and stably for more than 100 hours below 10 m K, with a minimum temperature of 7.6 m K and a cooling power of 450 μW at 100 m K. At the same time, we have also made progress in the application of dilution refrigerators, such as quantum computing, low-temperature detector, and magnet integration. These indicators and test results indicate good prospects for application in physics, astronomy, and quantum information.
基金supported by National Natural Science Foundation of China(No.51506152 and No.51777141)the Fundamental Research Funds for the Central Universities(inter-disciplinary program)under the contract No.kx0080020173427。
文摘The regenerative refrigeration is an important reverse work-heat conversion cycle with a theoretical coefficient of performance(COP)identical to the Carnot efficiency.Practical regenerative refrigerators are capable of working down to 4 K and largely fulfill the refrigeration requirement of modern technologies in many fields,especially for space applications.However,the enthalpy flow associated with the pressure dependence,abbreviated as pressure-induced enthalpy flow,brought about by real gas effects degrades the theoretical COP of the refrigerator to below about 30% of the Carnot efficiency at the temperatures of below the critical point.This paper reviews the long history of exploring the real gas effects which dates back to the 1970 s and continues to now.Important explorations of uncovering the loss mechanism and reducing such losses are summarized.The theories that are in accordance with experimental results and simulation results are expounded.We further carry out analyses on the expansion components,including the pulse tube and the clearance gap.Several inferences are made in order to explore the long-lasting puzzles about real gas effects.It is emphasized that the underlying cause of the loss in the regenerator is an indirect effect of the real gas properties.Further study about carrying out a direct verification of the theory is proposed.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.52371203 and 52271192)the Ministry of Science and Technology of China(Grant No.2021YFB3501201)。
文摘Er_(20)Ho_(20)Dy_(20)Cu_(20)Ni_(20)high-entropy metallic glass exhibited excellent magnetic refrigeration material with a wide temperature range and high refrigeration capacity(RC)was reported.Er_(20)Ho_(20)Dy_(20)Cu_(20)Ni_(20)high-entropy metallic glass was observed with typical spin glass behavior around 15.5 K.In addition,we find that the magnetic entropy change(-△S_(M))originates from the sample undergoing a ferromagnetic(FM)to paramagnetic(PM)transition around 20 K.Under a field change from 0 T to 7 T,the value of maximum magnetic entropy change(-△S_(M)^(max))reaches 12.5 J/kg·K,and the corresponding value of RC reaches 487.7 J/kg in the temperature range from 6 K to 60 K.The large RC and wide temperature range make the Er_(20)Ho_(20)Dy_(20)Cu_(20)Ni_(20)high-entropy metallic glass be a promising material for application in magnetic refrigerators.
文摘Intermodal competition changes with changes in technology, economics, and environmental concerns. Trucks and airships are generally considered not to be competitors, but this depends on the distance of haul. The tonne-kilometer cost of trucking rises much more quickly with distance than it does the cost of a cargo airship. At some distance, the two modes are direct substitutes. The costs of the Mexico-Canada refrigerated truck supply chain are compared with the costs of a 100t-lift, electrically-powered airship. The flight characteristics of the Hindenburg Zeppelin are used as a model for a modern cargo airship. The supply chain cost of trucking tomatoes is used to test the theorical proposition. The cost difference works out to about US10¢/kg (5¢/lb) advantage for trucking Mexican tomatoes to Canada. However, this cost disadvantage of the airship could be made up by their vibrationless ride, better air circulation and one-day service versus four days by truck. This alternative form of transportation could have a positive impact on worldwide north-south distribution of food. Airships can overcome trade barriers and distance to open new markets for perishable food exports. In addition, they would reduce the carbon emissions of transport. Canada imports 160,000 refrigerated truckloads of fruits and vegetables by from the southern US and Mexico. With an average driving distance of 3,000 km, these trucks emit 606,000 MT of CO<sub>2</sub> annually. Airships powered by hydrogen fuel cells would have zero-carbon emissions. Markets are not yet incorporating the environmental advantage of airships in any freight comparison, but inevitably this will be important.
文摘The use of carbon dioxide as a working fluid has been the subject of extensive studies in recent years, particularly in the field of refrigeration where it is at the heart of research to replace CFC and HCFC. Its thermodynamic properties make it a fluid of choice in the efficient use of energy at low and medium temperatures in engine cycles. However, the performance of transcritical CO2 cycles weakens under high temperature and pressure conditions, especially in refrigeration systems;On the other hand, this disadvantage becomes rather interesting in engine cycles where CO2 can be used as an alternative to the organic working fluid in small and medium-sized electrical systems for low quality or waste heat sources. In order to improve the performance of systems operating with CO2 in the field of refrigeration and electricity production, research has made it possible to develop several concepts, of which this article deals with a review of the state of the art, followed by analyzes in-depth and critical of the various developments to the most recent modifications in these fields. Detailed discussions on the performance and technical characteristics of the different evolutions are also highlighted as well as the factors affecting the overall performance of the systems studied. Finally, perspectives on the future development of the use of CO2 in these different cycles are presented.
基金supported by the National Natural Science Foundation of China (Grant Nos.51779262, 51576207, 51306206)the Hubei Province Natural Science Foundation of China (Grant No.2017CFB498)。
文摘In this paper, an irreversible thermionic refrigerator model based on van der Waals heterostructure with various irreversibilities is established by utilizing combination of non-equilibrium thermodynamics and finite time thermodynamics. The basic performance characteristics of the refrigerator are obtained. The effects of key factors, such as bias voltages, Schottky barrier heights and heat leakages, on the performance are studied. Results show that cooling rates and coefficients of performances(COPs) can attain the double maximum with proper modulation of barrier heights and bias voltages. Increasing cross-plane thermal resistance as well as decreasing electrode-reservoir thermal resistance and reservoir-reservoir thermal resistance can enhance the performance of the device. The optimal performance region is the interval between the maximum cooling rate point and the maximum COP point. By modulating the bias voltage, the working state of the device can fall into the optimal performance region. The optimal performance of the refrigerator when using single layer graphene and a few layers graphene as electrode material is also compared.
基金supported by the National High Technology Research and Development Program of China(2006AA05Z216).
文摘As a novel generation of a rotational gas wave machine,the wave rotor refrigerator(WRR)is an unsteadyflow device used for refrigeration,in whose passages pressured streams directly contact and exchange energy due to the movement of pressure waves.In this paper,the working mechanism and refrigeration principle are inves-tigated based on the one-dimensional unsteadyflow theory.A basic limitation on main structural parameters and operating parameters is deduced and the wave diagram of WRR to guide designing is sketched.The main influential factors are studied through an experiment.In the DUT Gas Wave Refrigeration Studying and Development Center(GWRSDC)lab,the isentropic efficiency can now reach about 65%.The results show that the WRR is a feasible and promising technology in pressured gas refrigeration cases.
基金Supported by the National Natural Science Foundation of China(No. 50676045)the National High-Tech Research and Devel-opment (863) Program of China (No. 2006AA05Z207)
文摘In recent years, microchannel heat exchangers have begun to be used in refrigeration and air conditioning systems. This paper introduces a microchannel condenser for domestic refrigerators with a theoretical model to evaluate its performance. The model was used to obtain the optimal design parameters for different numbers of tubes and tube lengths. The results show that the needed tube height of the down- ward section decreases with the number of tubes and the tube diameter. Compared with the original con- denser, the present optimal design parameters can reduce the total metal mass by 48.6% for the two wall two side design and by 26% for the two wall one side design. Thus, the present condenser is much better than the condensers usually used in actual domestic refrigerators.
基金supported by the National Natural Science Foundation of China (Grant Nos. 52171054 and 52171195)the National Natural Science Foundation for Distinguished Young Scholars (Grant No. 51925605)。
文摘We present a simple hot press-based method for processing La(Fe,Si)13-based compounds consisting of La–Fe–Co–Si–C particles and phenolic resin. The magnetic entropy change △S per unit mass for the La Fe_(10.87)Co_(0.63)Si_(1.5)C_(0.2)/phenolic resin compounds have nearly the same magnitude with the base materials. With the content of phenolic resin of 5.0 wt%, the compound conductivity is 3.13 W·m^(-1)·K^(-1). In order to measure the cooling performance of La(Fe,Si)13-based compounds,the La(Fe_(11.6-x)Co_(x))Si_(1.4)C_(0.15)(x =0.60, 0.65, 0.75, 0.80, 0.85)/phenolic resin compounds were pressed into thin plates and tested in a hybrid refrigerator that combines the active magnetic refrigeration effect with the Stirling cycle refrigeration effect. The test results showed that a maximum cooling power of 41 W was achieved over a temperature span of 30 K.
基金supported by the Science Development Funding Program of Dongying of China(Grant No.DJ2021006)Science Development Funding Program of Dongying of China(Grant No.DJ2021008).
文摘The Mixed Refrigerant(MR)component is an important factor influencing the performances of natural gas lique-faction processes.However,there is a lack of systematic research about the utilization of propane pre-cooled(C3/MRC).In this paper,this mixed refrigerant cycle liquefaction process is simulated using the HYSYS software and the main influential parameters involved in the process are varied to analyze their influence on the liquefaction rate and power consumption.The results show that an effective way for lowering the power consumption of the compressor consists of reducing the flow through the compressor through optimization of the percentage of mixed refrigerant.The power consumption of the compressor in the hybrid refrigeration process is affected by both flow and pressure ratios.Its specific power consumption can be reduced by increasing the flow and decreasing the pressure ratio at the same time.The increase in refrigerant pressure at the high-pressure end can significantly mitigate the energy loss of the heat exchanger and compressor.
文摘Conventional refrigeration processes release ammonia and freon into the atmosphere,which results in global warming.These problems may be overcome by using thermoelectric modules because of the absence of coolants or refrigerants in these systems.However,the cooling performances of such modules are relatively small in comparison to those of conventional refrigerators.In this paper,the working principles of thermoelectric modules are discussed together with a review of different relevant aspects,namely:the thermoelectric materials,and their mechanical properties used to build thermoelectric devices,different types of thermoelectric devices available on the market,mathematical modeling of thermoelectric materials,and various applications of thermoelectric materials in different fields.
文摘A theoretical investigation is presented about a double evaporator ejector refrigeration cycle(DEERC).Special attention is paid to take into account the influence of the sub-cooling and superheating effects induced by an internal heat exchanger(IHX).The ejector is introduced into the baseline cycle in order to mitigate the throttling process losses and increase the compressor suction pressure.Moreover,the IHX has the structure of a concentric counter-flow type heat exchanger and is intentionally used to ensure that the fluid at the compressor inlet is vapor.To assess accurately the influence of the IHX on the DEERC performance,a mathematical model is derived in the frame of the dominant one-dimensional theory for ejectors.The model also accounts for the friction effect in the ejector mixing section.The equations of this model are solved using an Engineering Equation Solver(EES)for different fluids.These are:R134a as baseline fluid and other environment friendly refrigerants used for comparison,namely,R1234yf,R1234ze,R600,R600a,R290,R717 and R1270.The simulation results show that the DEERC with an IHX can achieve COP(the coefficient of performance)improvements from 5.2 until 10%.
基金supported by Science and Technology Research Project for Education Department of Jiangxi Province, China (Grant No. GJJ218509)。
文摘We investigate the structure, magnetic properties, magnetic phase transitions and magnetocaloric effects(MCEs) of Er5Si3Bx(x=0.3,0.6) compounds. The Er5Si3Bx(x = 0.3, 0.6) compounds crystalize in a Mn5Si3type hexagonal structure(space group: P63/cm) and exhibit a successive complicated magnetic phase transition. The extensive magnetic phase transitions contribute to the broad temperature range of MCEs exhibiting in Er_(5)Si_(3)B_(x)(x=0.3,0.6) compounds, with maximum magnetic entropy change(-ΔSM_(max)) and refrigeration capacity of 10.2 J·kg^(-1)·K^(-1), 356.3 J/kg and 11.5 J·kg^(-1)·K^(-1),393.3 J/kg under varying magnetic fields 0–5 T, respectively. Remarkably, the δTFWHMvalues(the temperature range corresponding to 1/2×|-ΔSM_(max)|) of Er5Si3Bx(x=0.3,0.6) compounds were up to 41.8 K and 39.6 K, respectively. Thus, the present work provides a potential magnetic refrigeration material with a broad temperature range MCEs for applications in cryogenic magnetic refrigerators.
基金This work was supported by the National Natural Science Foundation of China(No.41877251)Major Science and Technology Projects of Xinxiang City(No.21ZD012).
文摘In order to ensure the safe operation of the compressors used in water chillers,in the present study some interlock protections have been added to the related design.These include a low pressure protection,a high pressure protection,an exhaust temperature protection and a differential pressure protection.Some tests have been conducted by tuning the saturation suction and exhaust temperatures of the compressor through adjustment of the cold source outlet temperature and the ambient temperature.The results show that the ambient temperature increases with decreasing device load and increasing fan speed under the same saturated suction temperature;the device refrigerating capacity steps up with augmenting load and dropping saturation exhaust temperature,while it is not greatly affected by the fan speed.Moreover,the Energy efficiency ratio(COP)decreases with the rise of the saturation exhaust temperature.This parameter is not affected much by the device load and fan speed at high saturation exhaust temperature,while it improves on increasing the device load and decreasing the fan speed at low saturation exhaust temperature.
基金supported by Campus France in the frame of the PHC-Maghreb 19Mag29 Project.We would like to thank also our Ministries and research units。
文摘A study is conducted on the performances of a solar powered continuous-adsorption refrigerator considering two particular days as references cases,namely,the summer solstice(June 21st)and the autumn equinox(September 21st).The cooling capacity,system performance coefficient and the daily rate of available cooling energy are assessed.The main goal is to compare the performances of a solar adsorption chiller equipped with a hot water tank(HWT)with an equivalent system relying on solar collectors with no heat storage module.The daily cooling rates for the solar refrigerator are found to be 102.4 kWh and 74.3 kWh,respectively,on June 21st and on September 21st,using a total collector’s area of 43.47 m2.The corresponding values for the adsorption chiller equipped with a hot water tank of 2 m3(and using a total collector’s area of 72.45 m2),are 127.1 kWh and 106.13 kWh,respectively.
文摘This paper deals with the evaluation of the Coefficient of Performance (COP) of solar adsorption refrigeration. In the literature, simulation models to predict the thermal behaviour and the coefficient of performance of these systems are uncommon. This is why we suggest a model to simulate the operation of the machine in a typical hot and dry climate of the city of Ouagadougou. The objective is to provide a model for calculating the COP from the measurement of the ambient temperature and the irradiation of a given site. Starting from mathematical modelling, a resolution and simulation were made with COMSOL software based on the Dubinin-Astakhov adsorption model, the heat transfer balance equations, and the Linear Driving Force (LDF) model to describe the thermal behaviour of the system. A one-week measurement sequence on the adsorption solar refrigerator at the Albert Schweitzer Ecological Centre (CEAS) validated the numerical results. The measurement shows that for the days with high sunshine, the temperature of the reaction medium reaches 110°C, and the pressure reaches 500 mbar. This leads to a production of cold that allows it to reach the temperature of -5°C at the evaporator. Under these conditions, the COP is worth 14%. These results are obtained both by numerical simulation using the COMSOL 5.1 software and after a measurement session on the solar refrigerator available to the CEAS. We obtained an experimental and theoretical coefficient of performance varying between 9% and 14% with a difference of between 0% and 3%. We conclude that our model is suitable to estimate the COP of any device based on its thermal properties, the ambient temperature and the irradiation of a given site.