Occurrence and influence of residual gas released by crush methods on pore structure in Longmaxi shale in Yangtze Plate, Southern China

The composition of gas released under vacuum by crushing from the gas shale of Longmaxi Formation in Upper Yangtze Plate,Southern China was systematically investigated in this study.The effect of residual gas release on pore structures was checked using low-pressure nitrogen adsorption techniques.The influence of particle size on the determination of pore structure characteristics was considered.Using the Frenkel-Halsey-Hill method from low-pressure nitrogen adsorption data,the fractal dimensions were identified at relative pressures of 0‒0.5 and 0.5‒1 as D1 and D2,respectively,and the evolution of fractal features related to gas release was also discussed.The results showed that a variety component of residual gas was released from all shale samples,containing hydrocarbon gas of CH4(29.58%‒92.53%),C2H6(0.97%‒2.89%),C3H8(0.01%‒0.65%),and also some non-hydrocarbon gas such as CO2(3.54%‒67.09%)and N2(1.88%‒8.07%).The total yield of residual gas was in a range from 6.1μL/g to 17.0μL/g related to rock weight.The geochemical and mineralogical analysis suggested that the residual gas yield was positively correlated with quartz(R^2=0.5480)content.The residual gas released shale sample has a higher surface area of 17.20‒25.03 m^2/g and the nitrogen adsorption capacity in a range of 27.32‒40.86 ml/g that is relatively higher than the original samples(with 9.22‒16.30 m^2/g and 10.84‒17.55 ml/g).Clearer hysteresis loop was observed for the original shale sample in nitrogen adsorption-desorption isotherms than residual gas released sample.Pore structure analysis showed that the proportions of micro-,meso-and macropores were changed as micropores decreased while meso-and macropores increased.The fractal dimensions D1 were in range from 2.5466 to 2.6117 and D2 from 2.6998 to 2.7119 for the residual gas released shale,which is smaller than the original shale.This factor may indicate that the pore in residual gas released shale was more homogeneous than the original shale.The results indicated that both residual gas and their pore space have few contributions to shale gas production and effective reservoir evaluation.The larger fragments samples of granular rather than powdery smaller than 60 mesh fraction of shale seem to be better for performing effective pore structure analysis to the Longmaxi shale.

Residual gas properties in a field emission device with ZnO emitters

In this paper, a vacuum system is employed to compare the emission stabilities of the same ZnO cathode in a sealed field emission (FE) device and under ultrahigh vacuum (UHV) conditions. It is observed that the emission current is more stable under the UHV level than in the device. When all conditions except the ambient gases are kept unchanged, the emission current degradation is mainly caused by the residual gases in the sealed device. The quadrupole mass spectrometer (QMS) equipped on the vacuum system is used to investigate the residual gas components. Based on the obtained QMS data, the following conclusions can be drawn: the residual gases in ZnO-FE devices are H2 , CH4 , CO, Ar, and CO2 . These residual gases can change the work function at the surface through adsorption or ion bombardment, thereby degrading the emission current of the cathode.

CO_(2) storage in depleted gas reservoirs:A study on the effect of residual gas saturation

Depleted gas reservoirs are recognized as the most promising candidate for carbon dioxide storage.Primary gas production followed by injection of carbon dioxide after depletion is the strategy adopted for secondary gas recovery and storage practices.This strategy,however,depends on the injection strategy,reservoir characteristics and operational parameters.There have been many studies to-date discussing critical factors influencing the storage performance in depleted gas reservoirs while little attention was given to the effect of residual gas.In this paper,an attempt was made to highlight the importance of residual gas on the capacity,injectivity,reservoir pressurization,and trapping mechanisms of storage sites through the use of numerical simulation.The results obtained indicated that the storage performance is proportionally linked to the amount of residual gas in the medium and reservoirs with low residual fluids are a better choice for storage purposes.Therefore,it would be wise to perform the secondary recovery before storage in order to have the least amount of residual gas in the medium.Although the results of this study are useful to screen depleted gas reservoirs for the storage purpose,more studies are required to confirm the finding presented in this paper.

Assessing roles of geochemical reactions on CO_(2)plume,injectivity and residual trapping

With increasing CO_(2)concentration in the atmosphere,CO_(2)geo-aequestration has become a popular technique to counter the dangers of global warming resulting from high levels of CO_(2)in the atmosphere.This paper examins sequestration parameters such as CO_(2)plume behaviour,residual gas trapping and injectivity as a means of achieving safe and successful CO_(2)storage in saline aquifers.Mineral precipitation/dissolution rates are used to establish a relationship between these parameters and geochemical reactions in saline aquifers.To achieve this,mechanistic models(6 models with different inputs,created using CMG e GEM,2016 and WINPROP,2016)are simulated using input data from literature and studying changes in fluids and formation properties as well as mineral precipitation/dissolution rates in aquifers when subjected to different conditions in the different models.The results from the models show that high CO_(2)dissolution,which creates large CO_(2)plume,leads to high mineral dissolution/precipitation as results of increased fluid-rock interactions(geochemical reactions);whereas injectivity,although enhanced by CO_(2)-water cyclic injection,does not show much increase in bottom hole pressure when mineral trapping(thus geochemical reactions)is introduced into the model.Sensitivity study on residual gas trapping shows that high residual gas saturation leads to reduced mineral precipitation/dissolution due to the reduced amount of dissolved CO_(2)in brine.Also,rapid changes in the bottom hole pressure at high residual gas saturation means that a formation that fosters high residual gas trapping,rather than CO_(2)dissolution in brine,is more likely to experience injectivity issues during the sequestration process.

Estimation of Residual Exhaust Gas of Homogeneous Charge Compression Ignition Gasoline Engine Operating Under Negative Valve Overlap Strategy

To meet the requirements of the homogeneous charge compression ignition gasoline engine’s rapid cylinder exhaust gas rate and accurate control of combustion phasing,a residual exhaust gas rate model was proposed.A heat dissipation model for gas flow in the exhaust passage and exhaust pipe was established,and the exhaust gas was established.Flow through the exhaust valve was considered as an adiabatic expansion process,the exhaust temperature was used to estimate the temperature in the cylinder at the time that the valve was closed,and the cylinder exhaust gas rate was calculated.To meet the requirements of transient operating conditions,a first-order inertial link was used to correct the thermocouple temperature measurement.Addressing this delay problem and modification of the exhaust wall temperature according to different conditions effectively improved the accuracy of the model.The relative error between the calculated results of this model and the simulation results determined using GT-POWER software was within 3.5%.

Experimental investigations on combustion characteristics of syngas composed of CH_(4),CO,and H_(2)

The residual gas and remained raw gas in dual gas resources polygeneration system are quite complex in components(mainly CH_(4),CO,and H_(2)),and these results to the distinguished differences in combustion reaction.Experimental investigations on basic combustion characteristics of syngas referred above are conducted on a laboratory-scale combustor with flame temperature and flue gas composition measured and analyzed.Primary air coefficient(PA),total air coefficient(TA),and components of the syngas(CS)are selected as key factors,and it is found that PA dominates mostly the ignition of syngas and NOx formation,while TA affects the flue gas temperature after high temperature region and NOx formation trend to be positive as H_(2)/CO components increase.The results provide references for industrial utilization.

A new method to measure the concentration of argon-xenon gas mixture

RGAs are widely used in molec Background RGAs are widely used in molecular component examination,impurity analysis,leak detection and test of vacuum system performance.However,RGAs have different sensitivities to different gases,and the sensitivities can change quickly and depend on so many parameters,which make its ability severely limited.Methods In thiswork we established a newpractical method to precisely measure noble gas ratio of argon-xenon gasmixture.Gaseous argon and xenon were controlled,respectively,by two mass flow controller(MFC).A variable leak valve(VLV)was used to introduce the gas mixture sample into the RGA measurement chamber.Gas mixtures with xenon concentration from 200ppm to 20000ppm(by mass)were introduced and tested by RGA.Results The time stability of RGA-measurement system was optimized to 2.1%.A good linearity of MFC-RGA response was achieved,verifying the reliability of RGA in measuring noble gas mixture with component concentration down to several hundred ppm level.Conclusions Since the approach we used in our experiment is gas-species independent,we believe that it can be popularized to other gas species when properly applied.