Coal gasification fine slag(FS)is a typical solid waste generated in coal gasification.Its current disposal methods of stockpil-ing and landfilling have caused serious soil and ecological hazards.Separation recovery a...Coal gasification fine slag(FS)is a typical solid waste generated in coal gasification.Its current disposal methods of stockpil-ing and landfilling have caused serious soil and ecological hazards.Separation recovery and the high-value utilization of residual carbon(RC)in FS are the keys to realizing the win-win situation of the coal chemical industry in terms of economic and environmental benefits.The structural properties,such as pore,surface functional group,and microcrystalline structures,of RC in FS(FS-RC)not only affect the flotation recovery efficiency of FS-RC but also form the basis for the high-value utilization of FS-RC.In this paper,the characteristics of FS-RC in terms of pore structure,surface functional groups,and microcrystalline structure are sorted out in accordance with gasification type and FS particle size.The reasons for the formation of the special structural properties of FS-RC are analyzed,and their influence on the flotation separation and high-value utilization of FS-RC is summarized.Separation methods based on the pore structural characterist-ics of FS-RC,such as ultrasonic pretreatment-pore-blocking flotation and pore breaking-flocculation flotation,are proposed to be the key development technologies for improving FS-RC recovery in the future.The design of low-cost,low-dose collectors containing polar bonds based on the surface and microcrystalline structures of FS-RC is proposed to be an important breakthrough point for strengthening the flotation efficiency of FS-RC in the future.The high-value utilization of FS should be based on the physicochemical structural proper-ties of FS-RC and should focus on the environmental impact of hazardous elements and the recyclability of chemical waste liquid to es-tablish an environmentally friendly utilization method.This review is of great theoretical importance for the comprehensive understand-ing of the unique structural properties of FS-RC,the breakthrough of the technological bottleneck in the efficient flotation separation of FS,and the expansion of the field of the high value-added utilization of FS-RC.展开更多
Plastic film mulch in agricultural production becomes essential to maintaining crop yields in arid and semiarid areas.However,the presence of residual film in farmland soil has also drawn much attention.In this study,...Plastic film mulch in agricultural production becomes essential to maintaining crop yields in arid and semiarid areas.However,the presence of residual film in farmland soil has also drawn much attention.In this study,three experiments were conducted.The first two experimental designs included 0,450,1350,and 2700 kg ha^(-1) of residual film pieces of approximately 5 cm side length added to field soil(0-20 cm soil depth)for seven years and added to pots for four years.In the third experiment,1350 kg ha^(-1)of the residual film with different side lengths(2-5,5-10,10-15,and 15-20 cm)was added to field soil for six years to explore the effect of residual film fragment size on soil nutrients,soil microorganisms,crop growth and yields.The residual film had little effect on the soil moisture at a field depth of 0-2(or 0-1.8)m.There were no significant effects on organic carbon,total nitrogen,inorganic nitrogen,total phosphorus or available phosphorus in the 0-20 cm soil layer.The presence of residual film decreased the richness and diversity of the bacterial community of the surface soil of the residual film,but it had no significant effect on the microbial community of the non-surface soil.The emergence rates of wheat and lentils occasionally decreased significantly with different amounts of residue fragments added to the field.At 450-2700 kg ha^(-1),the residual film reduced the plant height and stem diameter of maize and significantly reduced the shoot biomass of harvested maize by 11-19%.The average yields of maize and potato over the seven years decreased,but there were almost no significant statistical differences among the treatments.These results provide important data for a comprehensive scientific understanding of the effects of residual film on soil and crops in dryland farming systems.展开更多
With the rapid development of deep learning methods, the data-driven approach has shown powerful advantages over the model-driven one. In this paper, we propose an end-to-end autoencoder communication system based on ...With the rapid development of deep learning methods, the data-driven approach has shown powerful advantages over the model-driven one. In this paper, we propose an end-to-end autoencoder communication system based on Deep Residual Shrinkage Networks (DRSNs), where neural networks (DNNs) are used to implement the coding, decoding, modulation and demodulation functions of the communication system. Our proposed autoencoder communication system can better reduce the signal noise by adding an “attention mechanism” and “soft thresholding” modules and has better performance at various signal-to-noise ratios (SNR). Also, we have shown through comparative experiments that the system can operate at moderate block lengths and support different throughputs. It has been shown to work efficiently in the AWGN channel. Simulation results show that our model has a higher Bit-Error-Rate (BER) gain and greatly improved decoding performance compared to conventional modulation and classical autoencoder systems at various signal-to-noise ratios.展开更多
High-energy density lithium-ion batteries(LIBs)with layered high-nickel oxide cathodes(LiNi_(x)Co_(y)Mn_(1-x-y)O_(2),x≥0.8)show great promise in consumer electronics and vehicular applications.However,LiNi_(x)Co_(y)M...High-energy density lithium-ion batteries(LIBs)with layered high-nickel oxide cathodes(LiNi_(x)Co_(y)Mn_(1-x-y)O_(2),x≥0.8)show great promise in consumer electronics and vehicular applications.However,LiNi_(x)Co_(y)Mn_(1-x-y)O_(2)faces challenges related to capacity decay caused by residual alkalis owing to high sensitivity to air.To address this issue,we propose a hazardous substances upcycling method that fundamentally mitigates alkali content and concurrently induces the emergence of an anti-air-sensitive layer on the cathode surface.Through the neutralization of polyacrylic acid(PAA)with residual alkalis and then coupling it with 3-aminopropyl triethoxysilane(KH550),a stable and ion-conductive cross-linked polymer layer is in situ integrated into the LiNi_(0.89)Co_(0.06)Mn_(0.05)O_(2)(NCM)cathode.Our characterization and measurements demonstrate its effectiveness.The NCM material exhibits impressive cycling performance,retaining 88.4%of its capacity after 200 cycles at 5 C and achieving an extraordinary specific capacity of 170.0 mA h g^(-1) at 10 C.Importantly,this layer on the NCM efficiently suppresses unfavorable phase transitions,severe electrolyte degradation,and CO_(2)gas evolution,while maintaining commendable resistance to air exposure.This surface modification strategy shows widespread potential for creating air-stable LiNi_(x)Co_(y)Mn_(1-x-y)O_(2)cathodes,thereby advancing high-performance LIBs.展开更多
A numerical model based on measured fictive temperature distributions is explored to evaluate the residual stress fields of CO_(2)laser-annealed mitigated fused silica damage sites.The proposed model extracts the resi...A numerical model based on measured fictive temperature distributions is explored to evaluate the residual stress fields of CO_(2)laser-annealed mitigated fused silica damage sites.The proposed model extracts the residual strain from the differences in thermoelastic contraction of fused silica with different fictive temperatures from the initial frozen-in temperatures to ambient temperature.The residual stress fields of mitigated damage sites for the CO_(2)laser-annealed case are obtained by a finite element analysis of equilibrium equations and constitutive equations.The simulated results indicate that the proposed model can accurately evaluate the residual stress fields of laser-annealed mitigated damage sites with a complex thermal history.The calculated maximum hoop stress is in good agreement with the reported experimental result.The estimated optical retardance profiles from the calculated radial and hoop stress fields are consistent with the photoelastic measurements.These results provide sufficient evidence to demonstrate the suitability of the proposed model for describing the residual stresses of mitigated fused silica damage sites after CO_(2)laser annealing.展开更多
A rotating packed bed is a typical chemical process enhancement equipment that can strengthen micromixing and mass transfer.During the operation of the rotating packed bed,the nonreactants and products irregularly adh...A rotating packed bed is a typical chemical process enhancement equipment that can strengthen micromixing and mass transfer.During the operation of the rotating packed bed,the nonreactants and products irregularly adhere to the wire mesh packing in the rotor,thus resulting in an imbalance in the vibration of the rotor,which may cause serious damage to the bearing and material leakage.This study proposes a model prediction for estimating the bearing residual life of a rotating packed bed based on rotor imbalance response analysis.This method is used to determine the influence of the mass on the imbalance in the vibration of the rotor on bearing damage.The major influence on rotor vibration was found to be exerted by the imbalanced mass and its distribution radius,as revealed by the results of orthogonal experiments.Through implementing finite element analysis,the imbalance response curve for the rotating packed bed rotor was obtained,and a correlation among rotor imbalance mass,distribution radius of imbalance mass,and bearing residue life was established via data fitting.The predicted value of the bearing life can be used as the reference basis for an early safety warning of a rotating packed bed to effectively avoid accidents.展开更多
Transition metal chalcogenides(TMCs)are recognized as pre-catalysts,and their(oxy)hydroxides derived from electrochemical reconstruction are the active species in the water oxidation.However,understanding the role of ...Transition metal chalcogenides(TMCs)are recognized as pre-catalysts,and their(oxy)hydroxides derived from electrochemical reconstruction are the active species in the water oxidation.However,understanding the role of the residual chalcogen in the reconstructed layer is lacking in detail,and the corresponding catalytic mechanism remains controversial.Here,taking Cu_(1-x)Co_(x)S as a platform,we explore the regulating effect and existence form of the residual S doped into the reconstructive layer for oxygen evolution reaction(OER),where a dual-path OER mechanism is proposed.First-principles calculations and operando~(18)O isotopic labeling experiments jointly reveal that the residual S in the reconstructive layer of Cu_(1-x)Co_(x)S can wisely balance the adsorbate evolution mechanism(AEM)and lattice oxygen oxidation mechanism(LOM)by activating lattice oxygen and optimizing the adsorption/desorption behaviors at metal active sites,rather than change the reaction mechanism from AEM to LOM.Following such a dual-path OER mechanism,Cu_(0.4)Co_(0.6)S-derived Cu_(0.4)Co_(0.6)OSH not only overcomes the restriction of linear scaling relationship in AEM,but also avoids the structural collapse caused by lattice oxygen migration in LOM,so as to greatly reduce the OER potential and improved stability.展开更多
Electrocardiogram(ECG)signal is one of the noninvasive physiological measurement techniques commonly usedin cardiac diagnosis.However,in real scenarios,the ECGsignal is susceptible to various noise erosion,which affec...Electrocardiogram(ECG)signal is one of the noninvasive physiological measurement techniques commonly usedin cardiac diagnosis.However,in real scenarios,the ECGsignal is susceptible to various noise erosion,which affectsthe subsequent pathological analysis.Therefore,the effective removal of the noise from ECG signals has becomea top priority in cardiac diagnostic research.Aiming at the problem of incomplete signal shape retention andlow signal-to-noise ratio(SNR)after denoising,a novel ECG denoising network,named attention-based residualdense shrinkage network(ARDSN),is proposed in this paper.Firstly,the shallow ECG characteristics are extractedby a shallow feature extraction network(SFEN).Then,the residual dense shrinkage attention block(RDSAB)isused for adaptive noise suppression.Finally,feature fusion representation(FFR)is performed on the hierarchicalfeatures extracted by a series of RDSABs to reconstruct the de-noised ECG signal.Experiments on the MIT-BIHarrhythmia database and MIT-BIH noise stress test database indicate that the proposed scheme can effectively resistthe interference of different sources of noise on the ECG signal.展开更多
The estimation of residual displacements in a structure due to an anticipated earthquake event has increasingly become an important component of performance-based earthquake engineering because controlling these displ...The estimation of residual displacements in a structure due to an anticipated earthquake event has increasingly become an important component of performance-based earthquake engineering because controlling these displacements plays an important role in ensuring cost-feasible or cost-effective repairs in a damaged structure after the event.An attempt is made in this study to obtain statistical estimates of constant-ductility residual displacement spectra for bilinear and pinching oscillators with 5%initial damping,directly in terms of easily available seismological,site,and model parameters.None of the available models for the bilinear and pinching oscillators are useful when design spectra for a seismic hazard at a site are not available.The statistical estimates of a residual displacement spectrum are proposed in terms of earthquake magnitude,epicentral distance,site geology parameter,and three model parameters for a given set of ductility demand and a hysteretic energy capacity coefficient in the case of bilinear and pinching models,as well as for a given set of pinching parameters for displacement and strength at the breakpoint in the case of pinching model alone.The proposed scaling model is applicable to horizontal ground motions in the western U.S.for earthquake magnitudes less than 7 or epicentral distances greater than 20 km.展开更多
This paper analyzed GPS data from the Topo-Iberia network spanning almost 12 years(2008-2020).The data quality information for all 26 Topo-Iberia stations is provided for the first time,complementing the Spanish Geolo...This paper analyzed GPS data from the Topo-Iberia network spanning almost 12 years(2008-2020).The data quality information for all 26 Topo-Iberia stations is provided for the first time,complementing the Spanish Geological Survey’s storage work.Data analyses based on quality indicators obtained using TEQC have been carried out.The guidelines and data quality information from the IGS stations have been considered as the quality references,with the stations ALJI,EPCU,and TIOU standing out as the worst stations,while on the contrary,FUEN,PALM,PILA,and TRIA meet the quality requirements to become an IGS station.The relationship between the GPS data quality and their GAMIT-and Gipsy X-derived postfit ionosphere-free phase residuals has also been investigated,and the results reveal an inversely proportional relationship.It has been found that the stations showing an increase in elevation of the horizon line,also show an increase in cycle slips and multipath,are among the poorest quality stations,and among those with the highest postfit RMS of phase residuals.Moreover,the evolution of the vegetation around the antenna should be considered as it could cause a progressive loss of quality,which is not complying with the IGS standards.The quality assessment shows that the Topo-Iberia stations are appropriate for geodetic purposes,but permanent monitoring would be necessary to avoid the least possible loss of data and quality.In addition,a method to characterize the GNSS data quality is proposed.展开更多
Automatic modulation recognition(AMR)of radiation source signals is a research focus in the field of cognitive radio.However,the AMR of radiation source signals at low SNRs still faces a great challenge.Therefore,the ...Automatic modulation recognition(AMR)of radiation source signals is a research focus in the field of cognitive radio.However,the AMR of radiation source signals at low SNRs still faces a great challenge.Therefore,the AMR method of radiation source signals based on two-dimensional data matrix and improved residual neural network is proposed in this paper.First,the time series of the radiation source signals are reconstructed into two-dimensional data matrix,which greatly simplifies the signal preprocessing process.Second,the depthwise convolution and large-size convolutional kernels based residual neural network(DLRNet)is proposed to improve the feature extraction capability of the AMR model.Finally,the model performs feature extraction and classification on the two-dimensional data matrix to obtain the recognition vector that represents the signal modulation type.Theoretical analysis and simulation results show that the AMR method based on two-dimensional data matrix and improved residual network can significantly improve the accuracy of the AMR method.The recognition accuracy of the proposed method maintains a high level greater than 90% even at -14 dB SNR.展开更多
Unsupervised methods based on density representation have shown their abilities in anomaly detection,but detection performance still needs to be improved.Specifically,approaches using normalizing flows can accurately ...Unsupervised methods based on density representation have shown their abilities in anomaly detection,but detection performance still needs to be improved.Specifically,approaches using normalizing flows can accurately evaluate sample distributions,mapping normal features to the normal distribution and anomalous features outside it.Consequently,this paper proposes a Normalizing Flow-based Bidirectional Mapping Residual Network(NF-BMR).It utilizes pre-trained Convolutional Neural Networks(CNN)and normalizing flows to construct discriminative source and target domain feature spaces.Additionally,to better learn feature information in both domain spaces,we propose the Bidirectional Mapping Residual Network(BMR),which maps sample features to these two spaces for anomaly detection.The two detection spaces effectively complement each other’s deficiencies and provide a comprehensive feature evaluation from two perspectives,which leads to the improvement of detection performance.Comparative experimental results on the MVTec AD and DAGM datasets against the Bidirectional Pre-trained Feature Mapping Network(B-PFM)and other state-of-the-art methods demonstrate that the proposed approach achieves superior performance.On the MVTec AD dataset,NF-BMR achieves an average AUROC of 98.7%for all 15 categories.Especially,it achieves 100%optimal detection performance in five categories.On the DAGM dataset,the average AUROC across ten categories is 98.7%,which is very close to supervised methods.展开更多
In view of low recognition rate of complex radar intra-pulse modulation signal type by traditional methods under low signal-to-noise ratio(SNR),the paper proposes an automatic recog-nition method of complex radar intr...In view of low recognition rate of complex radar intra-pulse modulation signal type by traditional methods under low signal-to-noise ratio(SNR),the paper proposes an automatic recog-nition method of complex radar intra-pulse modulation signal type based on deep residual network.The basic principle of the recognition method is to obtain the transformation relationship between the time and frequency of complex radar intra-pulse modulation signal through short-time Fourier transform(STFT),and then design an appropriate deep residual network to extract the features of the time-frequency map and complete a variety of complex intra-pulse modulation signal type recognition.In addition,in order to improve the generalization ability of the proposed method,label smoothing and L2 regularization are introduced.The simulation results show that the proposed method has a recognition accuracy of more than 95%for complex radar intra-pulse modulation sig-nal types under low SNR(2 dB).展开更多
Recently,researchers have proposed an emitter localization method based on passive synthetic aperture.However,the unknown residual frequency offset(RFO)between the transmit-ter and the receiver causes the received Dop...Recently,researchers have proposed an emitter localization method based on passive synthetic aperture.However,the unknown residual frequency offset(RFO)between the transmit-ter and the receiver causes the received Doppler signal to shift,which affects the localization accu-racy.To solve this issue,this paper proposes a RFO estimation method based on range migration fitting.Due to the high frequency modulation slope of the linear frequency modulation(LFM)-mod-ulation radar signal,it is not affected by RFO in range compression.Therefore,the azimuth time can be estimated by fitting the peak value position of the pulse compression in range direction.Then,the matched filters are designed under different RFOs.When the zero-Doppler time obtained by the matched filters is consistent with the estimated azimuth time,the given RFO is the real RFO between the transceivers.The simulation results show that the estimation error of azimuth distance does not exceed 20 m when the received signal duration is not less than 3 s,the pulse repe-tition frequency(PRF)of the transmitter radar signal is not less than 1 kHz,the range detection is not larger than 1000 km,and the signal noise ratio(SNR)is not less than-5 dB.展开更多
The accumulation of snow and ice on PV modules can have a detrimental impact on power generation,leading to reduced efficiency for prolonged periods.Thus,it becomes imperative to develop an intelligent system capable ...The accumulation of snow and ice on PV modules can have a detrimental impact on power generation,leading to reduced efficiency for prolonged periods.Thus,it becomes imperative to develop an intelligent system capable of accurately assessing the extent of snow and ice coverage on PV modules.To address this issue,the article proposes an innovative ice and snow recognition algorithm that effectively segments the ice and snow areas within the collected images.Furthermore,the algorithm incorporates an analysis of the morphological characteristics of ice and snow coverage on PV modules,allowing for the establishment of a residual ice and snow recognition process.This process utilizes both the external ellipse method and the pixel statistical method to refine the identification process.The effectiveness of the proposed algorithm is validated through extensive testing with isolated and continuous snow area pictures.The results demonstrate the algorithm’s accuracy and reliability in identifying and quantifying residual snow and ice on PV modules.In conclusion,this research presents a valuable method for accurately detecting and quantifying snow and ice coverage on PV modules.This breakthrough is of utmost significance for PV power plants,as it enables predictions of power generation efficiency and facilitates efficient PV maintenance during the challenging winter conditions characterized by snow and ice.By proactively managing snow and ice coverage,PV power plants can optimize energy production and minimize downtime,ensuring a sustainable and reliable renewable energy supply.展开更多
In an effort to reduce vehicle collisions with snowplows in poor weather conditions, this paper details the development of a real time thermal image based machine learning approach to an early collision avoidance syst...In an effort to reduce vehicle collisions with snowplows in poor weather conditions, this paper details the development of a real time thermal image based machine learning approach to an early collision avoidance system for snowplows, which intends to detect and estimate the distance of trailing vehicles. Due to the operational conditions of snowplows, which include heavy-blowing snow, traditional optical sensors like LiDAR and visible spectrum cameras have reduced effectiveness in detecting objects in such environments. Thus, we propose using a thermal infrared camera as the primary sensor along with machine learning algorithms. First, we curate a large dataset of thermal images of vehicles in heavy snow conditions. Using the curated dataset, two machine-learning models based on the modified ResNet architectures were trained to detect and estimate the trailing vehicle distance using real-time thermal images. The trained detection network was capable of detecting trailing vehicles 99.0% of the time at 1500.0 ft distance from the snowplow. The trained trailing distance network was capable of estimating distance with an average estimation error of 10.70 ft. The inference performance of the trained models is discussed, along with the interpretation of the performance.展开更多
We explore the (2+l)-dimensional dispersive long-wave (DLW) system. From the standard truncated Painleve expansion, the Baicklund transformation (BT) and residual symmetries of this system are derived. The intr...We explore the (2+l)-dimensional dispersive long-wave (DLW) system. From the standard truncated Painleve expansion, the Baicklund transformation (BT) and residual symmetries of this system are derived. The introduction to an appropriate auxiliary dependent variable successfully localizes the residual symmetries to Lie point symmetries. In particular, it is verified that the (2+l)-dimensional DLW system is consistent Riccati expansion (CRE) solvable. If the special form of (CRE)-consistent tanh-function expansion (CTE) is taken, the soliton-cnoidal wave solutions and corresponding images can be explicitly given. Furthermore, the conservation laws of the DLW system are investigated with symmetries and Ibragimov theorem.展开更多
Structures undergoing inelastic displacements during earthquake ground motions are known to sustain some amount of residual displacements, which may make them unusable or unsafe. In this study an attempt is made to es...Structures undergoing inelastic displacements during earthquake ground motions are known to sustain some amount of residual displacements, which may make them unusable or unsafe. In this study an attempt is made to estimate residual displacements for elastic-perfectly-plastic single-degree-of-freedom oscillators with a given lateral strength ratio. It is observed in the case of a class of ground motions that there are no trends in the dependence of residual displacement on the temporal features of the ground motion, and thus any estimation of residual displacements should be carried out only in the statistical sense. Statistical estimation of residual displacement spectrum via normalization with respect to inelastic or elastic spectral displacements is considered, and it is found that normalization with respect to inelastic spectral displacements is preferable. Expressions for residual displacement spectra are proposed for both types of normalizations and for the givenlateral-strength-ratio type oscillators.展开更多
Water quality within water distribution system may vary with both location and time. Water quality models are used to predict the spatial and temporal variation of water quality throughout water system. A model of res...Water quality within water distribution system may vary with both location and time. Water quality models are used to predict the spatial and temporal variation of water quality throughout water system. A model of residual chlorine decay in water pipe has been developed, given the consumption of chlorine in reactions with chemicals in bulk water, bio films on pipe wall, in corrosion process, and the mass transport of chlorine from bulk water to pipe wall. Analytical methods of the flow path from water sources to the observed point and the water age of every observed node were proposed. Model is used to predict the decay of residual chlorine in an actual distribution system. Good agreement between calculated and measured values was obtained.展开更多
Through an integrated study of Mesozoic and Palaeozoic petroleum geology insouthern China and a summing-up of the results of exploration, the authors tentatively put forward aset of methods of studying petroleum syste...Through an integrated study of Mesozoic and Palaeozoic petroleum geology insouthern China and a summing-up of the results of exploration, the authors tentatively put forward aset of methods of studying petroleum systems in modified residual basins or superposed basins. Itscore idea is to put emphasis on the study of the dynamic evolution of petroleum systems. Thetempo-spatial evolution, hydrocarbon-generating processes and hydrocarbon-generating intensities andamounts of resources in different geological stages of chief source rocks are mainly deducedbackward by 3-D basin modelling. The regularities of formation and destruction of oil and gasaccumulations are summarized by analyzing the fossil and existing oil and gas accumulations, thedirection of migration is studied by palaeo-structural analysis, and the dynamic evolution ofPalaeozoic and Mesozoic petroleum systems in southern China is studied according to stages of majortectonic movements. The authors suggest that the realistic exploration targets of Palaeozoic andMesozoic petroleum systems in southern China are secondary and hydrocarbon-regeneration petroleumsystems, while the existing primary petroleum systems are rare. They propose that the favourableareas for exploration of Palaeozoic and Mesozoic petroleum systems in southern China are the frontarea of the Daba Mountains and the steep anticlinal zone on the western side of the Shizhusynclinorium in northeastern Sichuan, the Funin-Yancheng-Hai'an-Xinghua-Baoying area in the northernJiangsu basin, the Qianjiang-Xiantao-Paizhou-Chacan 1 well area in the southern part of the Chenhuarea of the Jianghan basin, the South Poyang basin in Jiangxi and the North subbasin of the Chuxiongbasin. This view has been supported by the discovery of the Zhujiadun gas field in the Yanchengsubbasin of the northern Jiangsu basin and the Kaixiantaixi oil-bearing structure in the southernpart of the Chenhu area of the Jianghan basin.展开更多
基金the National Natural Science Foundation of China(No.52374279)the Natural Science Foundation of Shaanxi Province(No.2023-YBGY-055).
文摘Coal gasification fine slag(FS)is a typical solid waste generated in coal gasification.Its current disposal methods of stockpil-ing and landfilling have caused serious soil and ecological hazards.Separation recovery and the high-value utilization of residual carbon(RC)in FS are the keys to realizing the win-win situation of the coal chemical industry in terms of economic and environmental benefits.The structural properties,such as pore,surface functional group,and microcrystalline structures,of RC in FS(FS-RC)not only affect the flotation recovery efficiency of FS-RC but also form the basis for the high-value utilization of FS-RC.In this paper,the characteristics of FS-RC in terms of pore structure,surface functional groups,and microcrystalline structure are sorted out in accordance with gasification type and FS particle size.The reasons for the formation of the special structural properties of FS-RC are analyzed,and their influence on the flotation separation and high-value utilization of FS-RC is summarized.Separation methods based on the pore structural characterist-ics of FS-RC,such as ultrasonic pretreatment-pore-blocking flotation and pore breaking-flocculation flotation,are proposed to be the key development technologies for improving FS-RC recovery in the future.The design of low-cost,low-dose collectors containing polar bonds based on the surface and microcrystalline structures of FS-RC is proposed to be an important breakthrough point for strengthening the flotation efficiency of FS-RC in the future.The high-value utilization of FS should be based on the physicochemical structural proper-ties of FS-RC and should focus on the environmental impact of hazardous elements and the recyclability of chemical waste liquid to es-tablish an environmentally friendly utilization method.This review is of great theoretical importance for the comprehensive understand-ing of the unique structural properties of FS-RC,the breakthrough of the technological bottleneck in the efficient flotation separation of FS,and the expansion of the field of the high value-added utilization of FS-RC.
基金funded by the National Natural Science Foundation of China (31470496)the Fundamental Research Funds for the Central Universities, China (lzujbky-2021-sp42)the ‘111’ Programme 2.0, China (BP0719040)。
文摘Plastic film mulch in agricultural production becomes essential to maintaining crop yields in arid and semiarid areas.However,the presence of residual film in farmland soil has also drawn much attention.In this study,three experiments were conducted.The first two experimental designs included 0,450,1350,and 2700 kg ha^(-1) of residual film pieces of approximately 5 cm side length added to field soil(0-20 cm soil depth)for seven years and added to pots for four years.In the third experiment,1350 kg ha^(-1)of the residual film with different side lengths(2-5,5-10,10-15,and 15-20 cm)was added to field soil for six years to explore the effect of residual film fragment size on soil nutrients,soil microorganisms,crop growth and yields.The residual film had little effect on the soil moisture at a field depth of 0-2(or 0-1.8)m.There were no significant effects on organic carbon,total nitrogen,inorganic nitrogen,total phosphorus or available phosphorus in the 0-20 cm soil layer.The presence of residual film decreased the richness and diversity of the bacterial community of the surface soil of the residual film,but it had no significant effect on the microbial community of the non-surface soil.The emergence rates of wheat and lentils occasionally decreased significantly with different amounts of residue fragments added to the field.At 450-2700 kg ha^(-1),the residual film reduced the plant height and stem diameter of maize and significantly reduced the shoot biomass of harvested maize by 11-19%.The average yields of maize and potato over the seven years decreased,but there were almost no significant statistical differences among the treatments.These results provide important data for a comprehensive scientific understanding of the effects of residual film on soil and crops in dryland farming systems.
文摘With the rapid development of deep learning methods, the data-driven approach has shown powerful advantages over the model-driven one. In this paper, we propose an end-to-end autoencoder communication system based on Deep Residual Shrinkage Networks (DRSNs), where neural networks (DNNs) are used to implement the coding, decoding, modulation and demodulation functions of the communication system. Our proposed autoencoder communication system can better reduce the signal noise by adding an “attention mechanism” and “soft thresholding” modules and has better performance at various signal-to-noise ratios (SNR). Also, we have shown through comparative experiments that the system can operate at moderate block lengths and support different throughputs. It has been shown to work efficiently in the AWGN channel. Simulation results show that our model has a higher Bit-Error-Rate (BER) gain and greatly improved decoding performance compared to conventional modulation and classical autoencoder systems at various signal-to-noise ratios.
基金supported by the National Natural Science Foundation of China(52162030)the Yunnan Major Scientific and Technological Projects(202202AG050003)+4 种基金the Key Research and Development Program of Yunnan Province(202103AA080019)the Scientific Research Foundation of Kunming University of Science and Technology(20220122)the Graduate Student Top Innovative Talent Program of Kunming University of Science and Technology(CA23107M139A)the Analysis and Testing Foundation of Kunming University of Science and Technology(2023T20220122)the Shenzhen Science and Technology Program(KCXST20221021111201003)。
文摘High-energy density lithium-ion batteries(LIBs)with layered high-nickel oxide cathodes(LiNi_(x)Co_(y)Mn_(1-x-y)O_(2),x≥0.8)show great promise in consumer electronics and vehicular applications.However,LiNi_(x)Co_(y)Mn_(1-x-y)O_(2)faces challenges related to capacity decay caused by residual alkalis owing to high sensitivity to air.To address this issue,we propose a hazardous substances upcycling method that fundamentally mitigates alkali content and concurrently induces the emergence of an anti-air-sensitive layer on the cathode surface.Through the neutralization of polyacrylic acid(PAA)with residual alkalis and then coupling it with 3-aminopropyl triethoxysilane(KH550),a stable and ion-conductive cross-linked polymer layer is in situ integrated into the LiNi_(0.89)Co_(0.06)Mn_(0.05)O_(2)(NCM)cathode.Our characterization and measurements demonstrate its effectiveness.The NCM material exhibits impressive cycling performance,retaining 88.4%of its capacity after 200 cycles at 5 C and achieving an extraordinary specific capacity of 170.0 mA h g^(-1) at 10 C.Importantly,this layer on the NCM efficiently suppresses unfavorable phase transitions,severe electrolyte degradation,and CO_(2)gas evolution,while maintaining commendable resistance to air exposure.This surface modification strategy shows widespread potential for creating air-stable LiNi_(x)Co_(y)Mn_(1-x-y)O_(2)cathodes,thereby advancing high-performance LIBs.
基金Project supported by the National Natural Science Foundation of China(Grant No.62275235).
文摘A numerical model based on measured fictive temperature distributions is explored to evaluate the residual stress fields of CO_(2)laser-annealed mitigated fused silica damage sites.The proposed model extracts the residual strain from the differences in thermoelastic contraction of fused silica with different fictive temperatures from the initial frozen-in temperatures to ambient temperature.The residual stress fields of mitigated damage sites for the CO_(2)laser-annealed case are obtained by a finite element analysis of equilibrium equations and constitutive equations.The simulated results indicate that the proposed model can accurately evaluate the residual stress fields of laser-annealed mitigated damage sites with a complex thermal history.The calculated maximum hoop stress is in good agreement with the reported experimental result.The estimated optical retardance profiles from the calculated radial and hoop stress fields are consistent with the photoelastic measurements.These results provide sufficient evidence to demonstrate the suitability of the proposed model for describing the residual stresses of mitigated fused silica damage sites after CO_(2)laser annealing.
基金the High-Performance Computing Platform of Beijing University of Chemical Technology(BUCT)for supporting this papersupported by the Fundamental Research Funds for the Central Universities(JD2319)+2 种基金the CNOOC Technical Cooperation Project(ZX2022ZCTYF7612)the National Natural Science Foundation of China(51775029,52004014)the Chinese Universities Scientific Fund(XK2020-04)。
文摘A rotating packed bed is a typical chemical process enhancement equipment that can strengthen micromixing and mass transfer.During the operation of the rotating packed bed,the nonreactants and products irregularly adhere to the wire mesh packing in the rotor,thus resulting in an imbalance in the vibration of the rotor,which may cause serious damage to the bearing and material leakage.This study proposes a model prediction for estimating the bearing residual life of a rotating packed bed based on rotor imbalance response analysis.This method is used to determine the influence of the mass on the imbalance in the vibration of the rotor on bearing damage.The major influence on rotor vibration was found to be exerted by the imbalanced mass and its distribution radius,as revealed by the results of orthogonal experiments.Through implementing finite element analysis,the imbalance response curve for the rotating packed bed rotor was obtained,and a correlation among rotor imbalance mass,distribution radius of imbalance mass,and bearing residue life was established via data fitting.The predicted value of the bearing life can be used as the reference basis for an early safety warning of a rotating packed bed to effectively avoid accidents.
基金supported by the Science and Technology Research Program of Chongqing Municipal Education Commission(KJQN202200550)the Natural Science Foundation Joint Fund for Innovation and Development of Chongqing Municipal Education Commission(CSTB2022NSCQ-LZX0077)+4 种基金the National Natural Science Foundation of China(No.52100065)the Science and Technology Research Program of Natural Science Foundation of Chongqing(cstc2021ycjh-bgzxm0037)the Science and Technology Research Program of Chongqing Municipal Education Commission(KJZD-M202200503)the Chongqing Innovation Research Group Project(No.CXQT21015),the Doctor Start/Talent Introduction Program of Chongqing Normal University(No.02060404/2020009000321)。
文摘Transition metal chalcogenides(TMCs)are recognized as pre-catalysts,and their(oxy)hydroxides derived from electrochemical reconstruction are the active species in the water oxidation.However,understanding the role of the residual chalcogen in the reconstructed layer is lacking in detail,and the corresponding catalytic mechanism remains controversial.Here,taking Cu_(1-x)Co_(x)S as a platform,we explore the regulating effect and existence form of the residual S doped into the reconstructive layer for oxygen evolution reaction(OER),where a dual-path OER mechanism is proposed.First-principles calculations and operando~(18)O isotopic labeling experiments jointly reveal that the residual S in the reconstructive layer of Cu_(1-x)Co_(x)S can wisely balance the adsorbate evolution mechanism(AEM)and lattice oxygen oxidation mechanism(LOM)by activating lattice oxygen and optimizing the adsorption/desorption behaviors at metal active sites,rather than change the reaction mechanism from AEM to LOM.Following such a dual-path OER mechanism,Cu_(0.4)Co_(0.6)S-derived Cu_(0.4)Co_(0.6)OSH not only overcomes the restriction of linear scaling relationship in AEM,but also avoids the structural collapse caused by lattice oxygen migration in LOM,so as to greatly reduce the OER potential and improved stability.
基金the National Natural Science Foundation of China under Grant 62172059 and 62072055Hunan Provincial Natural Science Foundations of China under Grant 2022JJ50318 and 2022JJ30621Scientific Research Fund of Hunan Provincial Education Department of China under Grant 22A0200 and 20K098。
文摘Electrocardiogram(ECG)signal is one of the noninvasive physiological measurement techniques commonly usedin cardiac diagnosis.However,in real scenarios,the ECGsignal is susceptible to various noise erosion,which affectsthe subsequent pathological analysis.Therefore,the effective removal of the noise from ECG signals has becomea top priority in cardiac diagnostic research.Aiming at the problem of incomplete signal shape retention andlow signal-to-noise ratio(SNR)after denoising,a novel ECG denoising network,named attention-based residualdense shrinkage network(ARDSN),is proposed in this paper.Firstly,the shallow ECG characteristics are extractedby a shallow feature extraction network(SFEN).Then,the residual dense shrinkage attention block(RDSAB)isused for adaptive noise suppression.Finally,feature fusion representation(FFR)is performed on the hierarchicalfeatures extracted by a series of RDSABs to reconstruct the de-noised ECG signal.Experiments on the MIT-BIHarrhythmia database and MIT-BIH noise stress test database indicate that the proposed scheme can effectively resistthe interference of different sources of noise on the ECG signal.
文摘The estimation of residual displacements in a structure due to an anticipated earthquake event has increasingly become an important component of performance-based earthquake engineering because controlling these displacements plays an important role in ensuring cost-feasible or cost-effective repairs in a damaged structure after the event.An attempt is made in this study to obtain statistical estimates of constant-ductility residual displacement spectra for bilinear and pinching oscillators with 5%initial damping,directly in terms of easily available seismological,site,and model parameters.None of the available models for the bilinear and pinching oscillators are useful when design spectra for a seismic hazard at a site are not available.The statistical estimates of a residual displacement spectrum are proposed in terms of earthquake magnitude,epicentral distance,site geology parameter,and three model parameters for a given set of ductility demand and a hysteretic energy capacity coefficient in the case of bilinear and pinching models,as well as for a given set of pinching parameters for displacement and strength at the breakpoint in the case of pinching model alone.The proposed scaling model is applicable to horizontal ground motions in the western U.S.for earthquake magnitudes less than 7 or epicentral distances greater than 20 km.
基金supported in part by the University of Jaén and the Spanish Ministry of Economy, Industry and Competitiveness (PTA2015-11507-I MINECO)。
文摘This paper analyzed GPS data from the Topo-Iberia network spanning almost 12 years(2008-2020).The data quality information for all 26 Topo-Iberia stations is provided for the first time,complementing the Spanish Geological Survey’s storage work.Data analyses based on quality indicators obtained using TEQC have been carried out.The guidelines and data quality information from the IGS stations have been considered as the quality references,with the stations ALJI,EPCU,and TIOU standing out as the worst stations,while on the contrary,FUEN,PALM,PILA,and TRIA meet the quality requirements to become an IGS station.The relationship between the GPS data quality and their GAMIT-and Gipsy X-derived postfit ionosphere-free phase residuals has also been investigated,and the results reveal an inversely proportional relationship.It has been found that the stations showing an increase in elevation of the horizon line,also show an increase in cycle slips and multipath,are among the poorest quality stations,and among those with the highest postfit RMS of phase residuals.Moreover,the evolution of the vegetation around the antenna should be considered as it could cause a progressive loss of quality,which is not complying with the IGS standards.The quality assessment shows that the Topo-Iberia stations are appropriate for geodetic purposes,but permanent monitoring would be necessary to avoid the least possible loss of data and quality.In addition,a method to characterize the GNSS data quality is proposed.
基金National Natural Science Foundation of China under Grant No.61973037China Postdoctoral Science Foundation under Grant No.2022M720419。
文摘Automatic modulation recognition(AMR)of radiation source signals is a research focus in the field of cognitive radio.However,the AMR of radiation source signals at low SNRs still faces a great challenge.Therefore,the AMR method of radiation source signals based on two-dimensional data matrix and improved residual neural network is proposed in this paper.First,the time series of the radiation source signals are reconstructed into two-dimensional data matrix,which greatly simplifies the signal preprocessing process.Second,the depthwise convolution and large-size convolutional kernels based residual neural network(DLRNet)is proposed to improve the feature extraction capability of the AMR model.Finally,the model performs feature extraction and classification on the two-dimensional data matrix to obtain the recognition vector that represents the signal modulation type.Theoretical analysis and simulation results show that the AMR method based on two-dimensional data matrix and improved residual network can significantly improve the accuracy of the AMR method.The recognition accuracy of the proposed method maintains a high level greater than 90% even at -14 dB SNR.
基金This work was supported in part by the National Key R&D Program of China 2021YFE0110500in part by the National Natural Science Foundation of China under Grant 62062021in part by the Guiyang Scientific Plan Project[2023]48-11.
文摘Unsupervised methods based on density representation have shown their abilities in anomaly detection,but detection performance still needs to be improved.Specifically,approaches using normalizing flows can accurately evaluate sample distributions,mapping normal features to the normal distribution and anomalous features outside it.Consequently,this paper proposes a Normalizing Flow-based Bidirectional Mapping Residual Network(NF-BMR).It utilizes pre-trained Convolutional Neural Networks(CNN)and normalizing flows to construct discriminative source and target domain feature spaces.Additionally,to better learn feature information in both domain spaces,we propose the Bidirectional Mapping Residual Network(BMR),which maps sample features to these two spaces for anomaly detection.The two detection spaces effectively complement each other’s deficiencies and provide a comprehensive feature evaluation from two perspectives,which leads to the improvement of detection performance.Comparative experimental results on the MVTec AD and DAGM datasets against the Bidirectional Pre-trained Feature Mapping Network(B-PFM)and other state-of-the-art methods demonstrate that the proposed approach achieves superior performance.On the MVTec AD dataset,NF-BMR achieves an average AUROC of 98.7%for all 15 categories.Especially,it achieves 100%optimal detection performance in five categories.On the DAGM dataset,the average AUROC across ten categories is 98.7%,which is very close to supervised methods.
文摘In view of low recognition rate of complex radar intra-pulse modulation signal type by traditional methods under low signal-to-noise ratio(SNR),the paper proposes an automatic recog-nition method of complex radar intra-pulse modulation signal type based on deep residual network.The basic principle of the recognition method is to obtain the transformation relationship between the time and frequency of complex radar intra-pulse modulation signal through short-time Fourier transform(STFT),and then design an appropriate deep residual network to extract the features of the time-frequency map and complete a variety of complex intra-pulse modulation signal type recognition.In addition,in order to improve the generalization ability of the proposed method,label smoothing and L2 regularization are introduced.The simulation results show that the proposed method has a recognition accuracy of more than 95%for complex radar intra-pulse modulation sig-nal types under low SNR(2 dB).
基金supported in part by the National Natural Foundation of China(No.62027801).
文摘Recently,researchers have proposed an emitter localization method based on passive synthetic aperture.However,the unknown residual frequency offset(RFO)between the transmit-ter and the receiver causes the received Doppler signal to shift,which affects the localization accu-racy.To solve this issue,this paper proposes a RFO estimation method based on range migration fitting.Due to the high frequency modulation slope of the linear frequency modulation(LFM)-mod-ulation radar signal,it is not affected by RFO in range compression.Therefore,the azimuth time can be estimated by fitting the peak value position of the pulse compression in range direction.Then,the matched filters are designed under different RFOs.When the zero-Doppler time obtained by the matched filters is consistent with the estimated azimuth time,the given RFO is the real RFO between the transceivers.The simulation results show that the estimation error of azimuth distance does not exceed 20 m when the received signal duration is not less than 3 s,the pulse repe-tition frequency(PRF)of the transmitter radar signal is not less than 1 kHz,the range detection is not larger than 1000 km,and the signal noise ratio(SNR)is not less than-5 dB.
基金supported by the Key Research and Development Projects in Shaanxi Province(Program No.2021GY-306)the Innovation Capability Support Program of Shaanxi(Program No.2022KJXX-41)the Key Scientific and Technological Projects of Xi’an(Program No.2022JH-RGZN-0005).
文摘The accumulation of snow and ice on PV modules can have a detrimental impact on power generation,leading to reduced efficiency for prolonged periods.Thus,it becomes imperative to develop an intelligent system capable of accurately assessing the extent of snow and ice coverage on PV modules.To address this issue,the article proposes an innovative ice and snow recognition algorithm that effectively segments the ice and snow areas within the collected images.Furthermore,the algorithm incorporates an analysis of the morphological characteristics of ice and snow coverage on PV modules,allowing for the establishment of a residual ice and snow recognition process.This process utilizes both the external ellipse method and the pixel statistical method to refine the identification process.The effectiveness of the proposed algorithm is validated through extensive testing with isolated and continuous snow area pictures.The results demonstrate the algorithm’s accuracy and reliability in identifying and quantifying residual snow and ice on PV modules.In conclusion,this research presents a valuable method for accurately detecting and quantifying snow and ice coverage on PV modules.This breakthrough is of utmost significance for PV power plants,as it enables predictions of power generation efficiency and facilitates efficient PV maintenance during the challenging winter conditions characterized by snow and ice.By proactively managing snow and ice coverage,PV power plants can optimize energy production and minimize downtime,ensuring a sustainable and reliable renewable energy supply.
文摘In an effort to reduce vehicle collisions with snowplows in poor weather conditions, this paper details the development of a real time thermal image based machine learning approach to an early collision avoidance system for snowplows, which intends to detect and estimate the distance of trailing vehicles. Due to the operational conditions of snowplows, which include heavy-blowing snow, traditional optical sensors like LiDAR and visible spectrum cameras have reduced effectiveness in detecting objects in such environments. Thus, we propose using a thermal infrared camera as the primary sensor along with machine learning algorithms. First, we curate a large dataset of thermal images of vehicles in heavy snow conditions. Using the curated dataset, two machine-learning models based on the modified ResNet architectures were trained to detect and estimate the trailing vehicle distance using real-time thermal images. The trained detection network was capable of detecting trailing vehicles 99.0% of the time at 1500.0 ft distance from the snowplow. The trained trailing distance network was capable of estimating distance with an average estimation error of 10.70 ft. The inference performance of the trained models is discussed, along with the interpretation of the performance.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11371293 and 11505090)the Natural Science Foundation of Shaanxi Province,China(Grant No.2014JM2-1009)+1 种基金the Research Award Foundation for Outstanding Young Scientists of Shandong Province,China(Grant No.BS2015SF009)the Science and Technology Innovation Foundation of Xi’an,China(Grant No.CYX1531WL41)
文摘We explore the (2+l)-dimensional dispersive long-wave (DLW) system. From the standard truncated Painleve expansion, the Baicklund transformation (BT) and residual symmetries of this system are derived. The introduction to an appropriate auxiliary dependent variable successfully localizes the residual symmetries to Lie point symmetries. In particular, it is verified that the (2+l)-dimensional DLW system is consistent Riccati expansion (CRE) solvable. If the special form of (CRE)-consistent tanh-function expansion (CTE) is taken, the soliton-cnoidal wave solutions and corresponding images can be explicitly given. Furthermore, the conservation laws of the DLW system are investigated with symmetries and Ibragimov theorem.
文摘Structures undergoing inelastic displacements during earthquake ground motions are known to sustain some amount of residual displacements, which may make them unusable or unsafe. In this study an attempt is made to estimate residual displacements for elastic-perfectly-plastic single-degree-of-freedom oscillators with a given lateral strength ratio. It is observed in the case of a class of ground motions that there are no trends in the dependence of residual displacement on the temporal features of the ground motion, and thus any estimation of residual displacements should be carried out only in the statistical sense. Statistical estimation of residual displacement spectrum via normalization with respect to inelastic or elastic spectral displacements is considered, and it is found that normalization with respect to inelastic spectral displacements is preferable. Expressions for residual displacement spectra are proposed for both types of normalizations and for the givenlateral-strength-ratio type oscillators.
基金TheNationalNaturalScienceFoundationofChina (No .5 96 780 18)
文摘Water quality within water distribution system may vary with both location and time. Water quality models are used to predict the spatial and temporal variation of water quality throughout water system. A model of residual chlorine decay in water pipe has been developed, given the consumption of chlorine in reactions with chemicals in bulk water, bio films on pipe wall, in corrosion process, and the mass transport of chlorine from bulk water to pipe wall. Analytical methods of the flow path from water sources to the observed point and the water age of every observed node were proposed. Model is used to predict the decay of residual chlorine in an actual distribution system. Good agreement between calculated and measured values was obtained.
文摘Through an integrated study of Mesozoic and Palaeozoic petroleum geology insouthern China and a summing-up of the results of exploration, the authors tentatively put forward aset of methods of studying petroleum systems in modified residual basins or superposed basins. Itscore idea is to put emphasis on the study of the dynamic evolution of petroleum systems. Thetempo-spatial evolution, hydrocarbon-generating processes and hydrocarbon-generating intensities andamounts of resources in different geological stages of chief source rocks are mainly deducedbackward by 3-D basin modelling. The regularities of formation and destruction of oil and gasaccumulations are summarized by analyzing the fossil and existing oil and gas accumulations, thedirection of migration is studied by palaeo-structural analysis, and the dynamic evolution ofPalaeozoic and Mesozoic petroleum systems in southern China is studied according to stages of majortectonic movements. The authors suggest that the realistic exploration targets of Palaeozoic andMesozoic petroleum systems in southern China are secondary and hydrocarbon-regeneration petroleumsystems, while the existing primary petroleum systems are rare. They propose that the favourableareas for exploration of Palaeozoic and Mesozoic petroleum systems in southern China are the frontarea of the Daba Mountains and the steep anticlinal zone on the western side of the Shizhusynclinorium in northeastern Sichuan, the Funin-Yancheng-Hai'an-Xinghua-Baoying area in the northernJiangsu basin, the Qianjiang-Xiantao-Paizhou-Chacan 1 well area in the southern part of the Chenhuarea of the Jianghan basin, the South Poyang basin in Jiangxi and the North subbasin of the Chuxiongbasin. This view has been supported by the discovery of the Zhujiadun gas field in the Yanchengsubbasin of the northern Jiangsu basin and the Kaixiantaixi oil-bearing structure in the southernpart of the Chenhu area of the Jianghan basin.