Cubic Mn_(2)Ru_(x)Ga Heusler compound is a typical example of compensated ferrimagnet with attractive potential for high-density,ultrafast,and low-power spintronic applications.In the form of epitaxial thin films,Mn_(...Cubic Mn_(2)Ru_(x)Ga Heusler compound is a typical example of compensated ferrimagnet with attractive potential for high-density,ultrafast,and low-power spintronic applications.In the form of epitaxial thin films,Mn_(2)Ru_(x)Ga exhibits high spin polarization and high tunability of compensation temperature by freely changing the Ru content x in a broad range(0.3<x<1.0).Herein Mn-Ru-Ga-based polycrystalline bulk buttons prepared by arc melting are systematically studied and it is found that in equilibrium bulk form,the cubic structure is unstable when x<0.75.To overcome this limitation,Mn-Ru-Ga is alloyed with a fourth element V.By adjusting the content of V in the By adjusting the content of V in the Mn_(2)Ru_(0.75)V_(y)Ga and Mn_(2.25-y)Ru_(0.75)V_(y)Ga quaternary systems the magnetic compensation temperature is tuned.Compensation is achieved near 300 K which is confirmed by both the magnetic measurement and anomalous Hall effect measurement.The analyses of the anomalous Hall effect scaling in quaternary Mn-Ru-V-Ga alloy reveal the dominant role of skew scattering,notably that contributed caused by the thermally excited phonons,in contrast to the dominant intrinsic mechanism found in many other 3d ferromagnets and Heusler compounds.It is further shown that the Ga antisites and V content can simultaneously control the residual resistivity ratio(RRR)as well as the relative contribution of phonon and defect to the anomalous Hall effect a"/a0'in Mn-Ru-V-Ga,resulting in a scaling relation a"/a0'∝RRR^(1.8).展开更多
For sites susceptible to liquefaction induced lateral spreading during a probable earthquake, geotechnical engineers often need to know the undrained residual shear strength of the liquefied soil deposit to estimate l...For sites susceptible to liquefaction induced lateral spreading during a probable earthquake, geotechnical engineers often need to know the undrained residual shear strength of the liquefied soil deposit to estimate lateral spreading displacements, and the forces acting on the piles from the liquefied soils in order to perform post liquefaction stability analyses. The most commonly used methods to estimate the undrained residual shear strength (Su~) of liquefied sand deposits are based on the correlations determined from liquefaction induced flow failures with SPT and CPT data. In this study, 44 lateral spread case histories are analyzed and a new relationship based on only lateral spread case histories is recommended, which estimates the residual shear strength ratio of the liquefiable soil layer from normalized shear wave velocity. The new proposed method is also utilized to estimate the residual lateral displacement of an example bridge problem in an area susceptible to lateral spreading in order to provide insight into how the proposed relationship can be used in geotechnical engineering practice.展开更多
Accurate crop residue resource estimation is important for bioenergy development.This is done by the ratio of residue to grain(R/G),which is usually regarded constant and is widely used for crop residue estimation tho...Accurate crop residue resource estimation is important for bioenergy development.This is done by the ratio of residue to grain(R/G),which is usually regarded constant and is widely used for crop residue estimation though uncertainty is inevitable in practice.In this study,a Monte Carlo algorithm was applied to estimate national crop residue by R/G taken from published reports in China.The estimated result was further mapped in pixels by geographic information system.In2009,the amount of crop residue was found to be 802.32 million tons(Mt),with 679.36 and 947.28 Mt as the lower and upper limits for 95%confidence limits.Chinese crop residue was dominated by rice,wheat,and corn,accounting for74.57%(598.29 Mt).From 1949 to 2009,the amount of crop residue increased by four times,accompanied by component change.The spatial distribution of crop residue in China is markedly heterogeneous.Compared to the shortage of crop residue in northwest China,there is an abundant crop residue of about 334 Mt in eastern China,attracting 90%of the country's electricity or heat generation plants.展开更多
To clarify liquefaction ratios and their construction variations of the main chemical compositions of wood in phenol using phosphoric acid as a catalyst, the chemical ingredients of wood such as holocellulose, cellulo...To clarify liquefaction ratios and their construction variations of the main chemical compositions of wood in phenol using phosphoric acid as a catalyst, the chemical ingredients of wood such as holocellulose, cellulose and lignin, were measured and extracted according to GB methods. With Fourier transform infrared (FTIR), the product identification of reactant before and after liquefaction in phenol was investigated. The molecular weights and their distributions of the liquefaction results (acetone soluble parts) were studied by gel permeation chromatography (GPC). Results show that the molecular weights and their distributions of poplar and Chinese fir are almost the same. In poplar, the distribution of cellulose is the largest, and that ofholocellulose the smallest after liquefaction. For Chinese fir, the distribution of holocellulose is the largest, and that of cellulose the smallest. After liquefaction of poplar cellulose, the change bands of FTIR spectrum observed below 1 600 cm^-1, can be attributed to new substitute groups. The same is true for poplar lignin. For Chinese fir, the spectra of liquefaction results of all chemical compositions differ from that of wood meal. This reveals the more activity groups were produced because of the reactions between Chinese fir and phenol. The research shows that the liquefaction ratios of poplar decrease in the following order: holocellulose 〉 lignin 〉 cellulose, and those of Chinese fir in the order: lignin 〉 cellulose 〉 holocellulose.展开更多
The Sinai Peninsula has been recognized as a subplate of the African Plate located at the triple junction of the Gulf of Suez rift,the Dead Sea Transform fault,and the Red Sea rift.The upper and lower crustal structur...The Sinai Peninsula has been recognized as a subplate of the African Plate located at the triple junction of the Gulf of Suez rift,the Dead Sea Transform fault,and the Red Sea rift.The upper and lower crustal structures of this tectonically active,rapidly developing region are yet poorly understood because of many limitations.For this reason,a set of P- and S-wave travel times recorded at 14 seismic stations belonging to the Egyptian National Seismographic Network(ENSN) from 111 local and regional events are analyzed to investigate the crustal structures and the locations of the seismogenic zones beneath central and southern Sinai.Because the velocity model used for routine earthquake location by ENSN is one-dimensional,the travel-time residuals will show lateral heterogeneity of the velocity structures and unmodeled vertical structures.Seismic activity is strong along the eastern and southern borders of the study area but low to moderate along the northern boundary and the Gulf of Suez to the west.The crustal V_P/V_S ratio is 1.74 from shallow(depth≤10 km) earthquakes and 1.76 from deeper(depth 〉 10 km) crustal events.The majority of the regional and local travel-time residuals are positive relative to the Preliminary Reference Earth Model(PREM),implying that the seismic stations are located above widely distributed,tectonically-induced low-velocity zones.These low-velocity zones are mostly related to the local crustal faults affecting the sedimentary section and the basement complex as well as the rifting processes prevailing in the northern Red Sea region and the ascending of hot mantle materials along crustal fractures.The delineation of these low-velocity zones and the locations of big crustal earthquakes enable the identification of areas prone to intense seismotectonic activities,which should be excluded from major future development projects and large constructions in central and southern Sinai.展开更多
An aluminum fractionation study was conducted for a surface reservoir water treatment to understand the performance of poly- aluminum-silicate-chloride (PASiC) in terms of the residual A1 fractions as a function of ...An aluminum fractionation study was conducted for a surface reservoir water treatment to understand the performance of poly- aluminum-silicate-chloride (PASiC) in terms of the residual A1 fractions as a function of initial pH. The coagulation performance expressed as turbidity and organic matter removal was established as supporting data. Some extra data were evaluated in terms of the residual A1 ratio of the composite PASiC coagulant. The main residual A1 sources were the A1 fractions derived from the use of PASiC. The turbidity and organic matter removal ability was optimal at initial pH 6.00-7.00, while the concentrations of various residual A1 species and the residual A1 ratio of PASiC were minimal at an initial pH range of 7.00-8.00. Under the conditions of OH/AI molar ratio = 2.00 and Si/A1 molar ratio = 0.05, PASiC had superior coagulation performance and comparatively low residual A1 concentrations. The A1 fraction in the composite PASiC coagulant seldom remained under such conditions. Experimental data also indicated that the suspended (filterable) AI fraction was the dominant species, and organic-bound or organo-A1 complex A1 was considered to be the major species of dissolved A1 in water treated by PASiC coagulation. Additionally, the dissolved inorganic monomeric A1 species dominated the dissolved monomeric A1 fraction.展开更多
SnO2-based varistor samples doped with Co2O3,Nb2O5 and Cr2O3 were prepared by ball-mixed oxide method.The microstructure,nonlinear I-V characteristic and surge current performances of these samples were investigated.T...SnO2-based varistor samples doped with Co2O3,Nb2O5 and Cr2O3 were prepared by ball-mixed oxide method.The microstructure,nonlinear I-V characteristic and surge current performances of these samples were investigated.This paper mainly focused on the dependence of the residual voltage ratio behavior of SnO2-based varistors on Nb2O5 addition,different factors influencing the residual voltage ratio in different concentration of Nb2O5 were analyzed.The Nb2O5 addition influences its residual voltage ratio by changing the grain size,forming defects(especially the free electrons) and cumulative effect.The measured results indicated that the optimally obtained sample with 0.07mol% Nb2O5 possesses the lowest residual voltage ratio of 1.86,the corresponding nonlinear coefficient and the threshold electric field are 42.6 and 364.6 V/mm,respectively.展开更多
The effects of manganese dioxide (MnO 2 ) additives on the electrical characteristics of the Al-doped ZnO varistors are investigated. The leakage current densities of the samples decrease first and then increase again...The effects of manganese dioxide (MnO 2 ) additives on the electrical characteristics of the Al-doped ZnO varistors are investigated. The leakage current densities of the samples decrease first and then increase again with the increase of the amount of MnO 2 additives. Correspondingly, the nonlinear coefficients of the samples keep on increasing and then decrease. In addition, the donor densities increase monotonously with the amount of the doped MnO 2 increasing. The effects of MnO 2 additives on the electrical characteristics of the samples are different from the conclusion of previous literatures. The reasons of the distinct effects are supposed to be related with the donor and interface state densities of the samples.展开更多
Split fertilization strategy is popularly adopted in rice to synchronize soil nitrogen(N) supply and crop N demand. Attention has been paid more on mid-season topdressing N, but limited on basal N. A clearer understan...Split fertilization strategy is popularly adopted in rice to synchronize soil nitrogen(N) supply and crop N demand. Attention has been paid more on mid-season topdressing N, but limited on basal N. A clearer understanding of the basal N fate under split fertilization is crucial for determining rational basal N split ratio to improve the yield and reduce the loss to environment. A two-year field experiment with two N rates of 150 and 300 kg Nha^(-1), two split ratios of basal N, 40% and 25%, and two rice varieties,Wuyunjing 23(japonica) and Y-liangyou 2(super hybrid indica), was conducted. Labelled ^(15) N urea was supplied in micro-plots as basal fertilizer to determine the plant uptake, translocation, soil residual, and loss of basal N fertilizer. The results showed that basal N absorbed by rice was only 1.6%–11.5% before tillering fertilization(8–10 d after transplanting), 6.5%–21.4% from tillering fertilization to panicle fertilization, and little(0.1%–4.4%) after panicle fertilization. The recovery efficiency of basal N for the entire rice growth stage was low and ranged from 18.7% to 24.8%, not significantly affected by cultivars or N treatments. Soil residual basal N accounted for 10.3%–36.4% and decreased with increasing total N rate and basal N ratio, regardless of variety and year. 43.8%–70.4% of basal N was lost into the environment based on the N balance. Basal N loss was significantly linearly positive related with the basal N rate and obviously enhanced by the increasing basal N ratio for both varieties in both 2012 and 2013. The N use efficiency and yield was significantly improved when decreasing the basal N ratio from 40% to 25%. The results indicated that the basal N ratio should be reduced, especially with limited N inputs, to improve the yield and reduce the N loss to the environment.展开更多
Purpose Recent researches of RF gun operated at cryogenic temperature have many advantages to serve as the technology to realize the future light source.In order to further improve the accelerating gradient of acceler...Purpose Recent researches of RF gun operated at cryogenic temperature have many advantages to serve as the technology to realize the future light source.In order to further improve the accelerating gradient of accelerators,the cryogenic acceleration structure is studied.Design/methodology/approach The cryogenic accelerating structure is studied by numerical analysis and simulation.Findings In this paper,the low-temperature characteristics of the material are analyzedfirstly,and then the preliminary design scheme of the cavity is proposed according to the analysis results.Furthermore,the prototype with RF coupler is designed and optimized systemically,and the modified Poynting vector distribution is calculated.Finally,the high-power test based on existed setup is also proposed.Originality/value The study of the cryogenic structure in this paper is helpful for improving the accelerating gradient and developing compact accelerators.展开更多
基金Project supported by the National Key Research and Development Program of China(Grant No.2022YFA1402600)the National Natural Science Foundation of China(Grant No.12274438)the Beijing Natural Science Foundation,China(Grant No.Z230006)。
文摘Cubic Mn_(2)Ru_(x)Ga Heusler compound is a typical example of compensated ferrimagnet with attractive potential for high-density,ultrafast,and low-power spintronic applications.In the form of epitaxial thin films,Mn_(2)Ru_(x)Ga exhibits high spin polarization and high tunability of compensation temperature by freely changing the Ru content x in a broad range(0.3<x<1.0).Herein Mn-Ru-Ga-based polycrystalline bulk buttons prepared by arc melting are systematically studied and it is found that in equilibrium bulk form,the cubic structure is unstable when x<0.75.To overcome this limitation,Mn-Ru-Ga is alloyed with a fourth element V.By adjusting the content of V in the By adjusting the content of V in the Mn_(2)Ru_(0.75)V_(y)Ga and Mn_(2.25-y)Ru_(0.75)V_(y)Ga quaternary systems the magnetic compensation temperature is tuned.Compensation is achieved near 300 K which is confirmed by both the magnetic measurement and anomalous Hall effect measurement.The analyses of the anomalous Hall effect scaling in quaternary Mn-Ru-V-Ga alloy reveal the dominant role of skew scattering,notably that contributed caused by the thermally excited phonons,in contrast to the dominant intrinsic mechanism found in many other 3d ferromagnets and Heusler compounds.It is further shown that the Ga antisites and V content can simultaneously control the residual resistivity ratio(RRR)as well as the relative contribution of phonon and defect to the anomalous Hall effect a"/a0'in Mn-Ru-V-Ga,resulting in a scaling relation a"/a0'∝RRR^(1.8).
文摘For sites susceptible to liquefaction induced lateral spreading during a probable earthquake, geotechnical engineers often need to know the undrained residual shear strength of the liquefied soil deposit to estimate lateral spreading displacements, and the forces acting on the piles from the liquefied soils in order to perform post liquefaction stability analyses. The most commonly used methods to estimate the undrained residual shear strength (Su~) of liquefied sand deposits are based on the correlations determined from liquefaction induced flow failures with SPT and CPT data. In this study, 44 lateral spread case histories are analyzed and a new relationship based on only lateral spread case histories is recommended, which estimates the residual shear strength ratio of the liquefiable soil layer from normalized shear wave velocity. The new proposed method is also utilized to estimate the residual lateral displacement of an example bridge problem in an area susceptible to lateral spreading in order to provide insight into how the proposed relationship can be used in geotechnical engineering practice.
基金supported by the Key Laboratory of Industrial Ecological and Environmental Engineering[KLIEEE-11-06]Fundamental Research Funds for the Central Universities[DUT11RC(3)83]
文摘Accurate crop residue resource estimation is important for bioenergy development.This is done by the ratio of residue to grain(R/G),which is usually regarded constant and is widely used for crop residue estimation though uncertainty is inevitable in practice.In this study,a Monte Carlo algorithm was applied to estimate national crop residue by R/G taken from published reports in China.The estimated result was further mapped in pixels by geographic information system.In2009,the amount of crop residue was found to be 802.32 million tons(Mt),with 679.36 and 947.28 Mt as the lower and upper limits for 95%confidence limits.Chinese crop residue was dominated by rice,wheat,and corn,accounting for74.57%(598.29 Mt).From 1949 to 2009,the amount of crop residue increased by four times,accompanied by component change.The spatial distribution of crop residue in China is markedly heterogeneous.Compared to the shortage of crop residue in northwest China,there is an abundant crop residue of about 334 Mt in eastern China,attracting 90%of the country's electricity or heat generation plants.
基金Supported by the Key Research Program Foundation, Ministry of Educational of China (Grant No.02021)the National Natural Science Foundation of China (Grant No. 30471351)
文摘To clarify liquefaction ratios and their construction variations of the main chemical compositions of wood in phenol using phosphoric acid as a catalyst, the chemical ingredients of wood such as holocellulose, cellulose and lignin, were measured and extracted according to GB methods. With Fourier transform infrared (FTIR), the product identification of reactant before and after liquefaction in phenol was investigated. The molecular weights and their distributions of the liquefaction results (acetone soluble parts) were studied by gel permeation chromatography (GPC). Results show that the molecular weights and their distributions of poplar and Chinese fir are almost the same. In poplar, the distribution of cellulose is the largest, and that ofholocellulose the smallest after liquefaction. For Chinese fir, the distribution of holocellulose is the largest, and that of cellulose the smallest. After liquefaction of poplar cellulose, the change bands of FTIR spectrum observed below 1 600 cm^-1, can be attributed to new substitute groups. The same is true for poplar lignin. For Chinese fir, the spectra of liquefaction results of all chemical compositions differ from that of wood meal. This reveals the more activity groups were produced because of the reactions between Chinese fir and phenol. The research shows that the liquefaction ratios of poplar decrease in the following order: holocellulose 〉 lignin 〉 cellulose, and those of Chinese fir in the order: lignin 〉 cellulose 〉 holocellulose.
文摘The Sinai Peninsula has been recognized as a subplate of the African Plate located at the triple junction of the Gulf of Suez rift,the Dead Sea Transform fault,and the Red Sea rift.The upper and lower crustal structures of this tectonically active,rapidly developing region are yet poorly understood because of many limitations.For this reason,a set of P- and S-wave travel times recorded at 14 seismic stations belonging to the Egyptian National Seismographic Network(ENSN) from 111 local and regional events are analyzed to investigate the crustal structures and the locations of the seismogenic zones beneath central and southern Sinai.Because the velocity model used for routine earthquake location by ENSN is one-dimensional,the travel-time residuals will show lateral heterogeneity of the velocity structures and unmodeled vertical structures.Seismic activity is strong along the eastern and southern borders of the study area but low to moderate along the northern boundary and the Gulf of Suez to the west.The crustal V_P/V_S ratio is 1.74 from shallow(depth≤10 km) earthquakes and 1.76 from deeper(depth 〉 10 km) crustal events.The majority of the regional and local travel-time residuals are positive relative to the Preliminary Reference Earth Model(PREM),implying that the seismic stations are located above widely distributed,tectonically-induced low-velocity zones.These low-velocity zones are mostly related to the local crustal faults affecting the sedimentary section and the basement complex as well as the rifting processes prevailing in the northern Red Sea region and the ascending of hot mantle materials along crustal fractures.The delineation of these low-velocity zones and the locations of big crustal earthquakes enable the identification of areas prone to intense seismotectonic activities,which should be excluded from major future development projects and large constructions in central and southern Sinai.
基金supported by the Scientific Technology Research and Development Program of Shandong,China (No.2010GZX20605)the Chinese National Foundation of Natural Sciences (No.21077066)+3 种基金the Natural Science Foundation of Shandong Province, China (No.ZR2010BM014)the Graduate Innovation Foundationof Shandong University (No.yyx10010, GIFSDU)the Shanghai Tongji Gao Tingyao Environmental Science &Technology Development Foundation (STGEF)the Scholarship Award for Excellent Doctoral Student granted by Ministry of Education
文摘An aluminum fractionation study was conducted for a surface reservoir water treatment to understand the performance of poly- aluminum-silicate-chloride (PASiC) in terms of the residual A1 fractions as a function of initial pH. The coagulation performance expressed as turbidity and organic matter removal was established as supporting data. Some extra data were evaluated in terms of the residual A1 ratio of the composite PASiC coagulant. The main residual A1 sources were the A1 fractions derived from the use of PASiC. The turbidity and organic matter removal ability was optimal at initial pH 6.00-7.00, while the concentrations of various residual A1 species and the residual A1 ratio of PASiC were minimal at an initial pH range of 7.00-8.00. Under the conditions of OH/AI molar ratio = 2.00 and Si/A1 molar ratio = 0.05, PASiC had superior coagulation performance and comparatively low residual A1 concentrations. The A1 fraction in the composite PASiC coagulant seldom remained under such conditions. Experimental data also indicated that the suspended (filterable) AI fraction was the dominant species, and organic-bound or organo-A1 complex A1 was considered to be the major species of dissolved A1 in water treated by PASiC coagulation. Additionally, the dissolved inorganic monomeric A1 species dominated the dissolved monomeric A1 fraction.
基金supported by the National Natural Science Foundations of China (Grants Nos 50425721 and 50737001)
文摘SnO2-based varistor samples doped with Co2O3,Nb2O5 and Cr2O3 were prepared by ball-mixed oxide method.The microstructure,nonlinear I-V characteristic and surge current performances of these samples were investigated.This paper mainly focused on the dependence of the residual voltage ratio behavior of SnO2-based varistors on Nb2O5 addition,different factors influencing the residual voltage ratio in different concentration of Nb2O5 were analyzed.The Nb2O5 addition influences its residual voltage ratio by changing the grain size,forming defects(especially the free electrons) and cumulative effect.The measured results indicated that the optimally obtained sample with 0.07mol% Nb2O5 possesses the lowest residual voltage ratio of 1.86,the corresponding nonlinear coefficient and the threshold electric field are 42.6 and 364.6 V/mm,respectively.
基金supported by the National Natural Science Foundations of China (Grant No. 50737001)
文摘The effects of manganese dioxide (MnO 2 ) additives on the electrical characteristics of the Al-doped ZnO varistors are investigated. The leakage current densities of the samples decrease first and then increase again with the increase of the amount of MnO 2 additives. Correspondingly, the nonlinear coefficients of the samples keep on increasing and then decrease. In addition, the donor densities increase monotonously with the amount of the doped MnO 2 increasing. The effects of MnO 2 additives on the electrical characteristics of the samples are different from the conclusion of previous literatures. The reasons of the distinct effects are supposed to be related with the donor and interface state densities of the samples.
基金financially supported by the National Natural Science Foundation of China (No. 41171235)Jiangsu Agriculture Science and Technology Innovation Fund, China (No. CX(13)3040)the Special Fund for Environmental Research in the Public Interest, China (No. 201309035-7)
文摘Split fertilization strategy is popularly adopted in rice to synchronize soil nitrogen(N) supply and crop N demand. Attention has been paid more on mid-season topdressing N, but limited on basal N. A clearer understanding of the basal N fate under split fertilization is crucial for determining rational basal N split ratio to improve the yield and reduce the loss to environment. A two-year field experiment with two N rates of 150 and 300 kg Nha^(-1), two split ratios of basal N, 40% and 25%, and two rice varieties,Wuyunjing 23(japonica) and Y-liangyou 2(super hybrid indica), was conducted. Labelled ^(15) N urea was supplied in micro-plots as basal fertilizer to determine the plant uptake, translocation, soil residual, and loss of basal N fertilizer. The results showed that basal N absorbed by rice was only 1.6%–11.5% before tillering fertilization(8–10 d after transplanting), 6.5%–21.4% from tillering fertilization to panicle fertilization, and little(0.1%–4.4%) after panicle fertilization. The recovery efficiency of basal N for the entire rice growth stage was low and ranged from 18.7% to 24.8%, not significantly affected by cultivars or N treatments. Soil residual basal N accounted for 10.3%–36.4% and decreased with increasing total N rate and basal N ratio, regardless of variety and year. 43.8%–70.4% of basal N was lost into the environment based on the N balance. Basal N loss was significantly linearly positive related with the basal N rate and obviously enhanced by the increasing basal N ratio for both varieties in both 2012 and 2013. The N use efficiency and yield was significantly improved when decreasing the basal N ratio from 40% to 25%. The results indicated that the basal N ratio should be reduced, especially with limited N inputs, to improve the yield and reduce the N loss to the environment.
文摘Purpose Recent researches of RF gun operated at cryogenic temperature have many advantages to serve as the technology to realize the future light source.In order to further improve the accelerating gradient of accelerators,the cryogenic acceleration structure is studied.Design/methodology/approach The cryogenic accelerating structure is studied by numerical analysis and simulation.Findings In this paper,the low-temperature characteristics of the material are analyzedfirstly,and then the preliminary design scheme of the cavity is proposed according to the analysis results.Furthermore,the prototype with RF coupler is designed and optimized systemically,and the modified Poynting vector distribution is calculated.Finally,the high-power test based on existed setup is also proposed.Originality/value The study of the cryogenic structure in this paper is helpful for improving the accelerating gradient and developing compact accelerators.