Strength Model of Soda Residue Soil Considering Consolidation Stress and Structural Influence

Soda residue(SR)is a type of industrial waste produced in the soda process with the ammonia-soda method.Applying SR to backfilling solves the land occupation and environmental pollution problems in coastal areas and saves material costs for foundation engineering.The strength characteristics of soda residue soil(SRS)under different consolidation conditions are the key points to be solved in the engineering application of SRS.Triaxial compression tests were performed on the undisturbed SRS of Tianjin Port.The shear properties of SRS under different consolidation conditions were then discussed.Meanwhile,a structural strength model(SSM)based on Mohr-Coulomb theory was proposed.SSM reflects the influence of soil structure on undrained strength(Cu)and divides the Cu into the following two parts:friction strength(C_(uf))and original structural strength(C_(u0)).C_(uf)characterizes the magnitude of friction between soil particles,which is related to the consolidation stress.Meanwhile,C_(u0)represents the structural effect on soil strength,which is related to the soil deposition and consolidation processes.SSM was validated by the test data of undisturbed soils.Results reveal that the undisturbed soil generally had a certain C_(u0).Therefore,the SRS strength model was established by combining the experimental law of SRS with SSM.Error analysis shows that the SRS strength model can effectively predict the Cu of undisturbed SRS in Tianjin Port under different consolidation conditions.

Field testing of shear strength of granite residual soils

The characteristics of residual soils are very different from those of sedimentary soils.Although the strength characteristics of sedimentary soils have been studied extensively,the shear strength characteristics of granitic residual soils(GRS)subjected to the weathering of parent rocks have rarely been investigated.In this study,the shear strength characteristics of GRS in the Taishan area of southeast China(TSGRS)were studied by field and laboratory tests.The field tests consisted of a cone penetration test(CPT),borehole shear test(BST),self-boring pressuremeter test(SBPT),and seismic dilatometer Marchetti test(SDMT).The shortcomings of laboratory testing are obvious,with potential disturbances arising through the sampling,transportation,and preparation of soil samples.Due to the special structure of GRS samples and the ease of disturbance,the results obtained from laboratory tests were generally lower than those obtained from situ tests.The CPT and scanning electron microscopy(SEM)results indicated significant weathering and crustal hardening in the shallow TSGRS.This resulted in significant differences in the strength and strength parameters of shallow soil obtained by the BST.Based on the SDMT and SBPT results,a comprehensive evaluation method of shear strength for TSGRS was proposed.The SBPT was suitable for evaluating the strength of shallow GRS.The material index(ID)and horizontal stress index(KD)values obtained by the SDMT satisfied the empirical relationship proposed by Marchetti based on the ID index,and were therefore considered suitable for the evaluation of the shear strength of deep GRS.

Discussion of“Site observations of weathered granitic soils subjected to cementation and partial drainage using SCPTU”[J Rock Mech Geotech Eng 15(2023)984e996]

Comprehensive data from in situ and laboratory tests in residual soil have been presented by Zhang et al.(2023).A number of issues addressed in the paper have been the interest of the discussers,namely the characterisation and behaviour of residual soils,limitation of piezocone testing due to the capacity of the entire system,measurement of shear wave velocity,rate effect of piezocone(CPTU)testing and piezocone testing with dual pore pressure penetrometers.Clarification and complementation of these issues are required with regard to both the execution and interpretation of the tests.

Effects of soil crust on the collapsing erosion of colluvial deposits with granite residual soil

Collapsing erosion is a unique phenomenon commonly observed on the granite residue hillslopes in the tropical and subtropical regions of southern China,characterized by its abrupt occurrence and significant erosion volumes.However,the impacts of soil crust conditions on the erosion of colluvial deposits with granite residual soils have only been studied to a limited extent.To address this issue,this study investigates the impacts of three soil crust conditions(i.e.,without crust,10-minute crust,and 20-minute crust)on gully morphology,rainfall infiltration,and runoff and sediment yield during slope erosion of colluvial deposits with granite residues(classified as Acrisols)in Yudu County,Ganzhou City,Jiangxi Province,China,using simulated rainfall tests and photographic methods.The results showed that as the strength of the soil crust increased,the capacity of moisture infiltration and the width and depth of the gully as well as the sediment concentration and yield ratio decreased;at the same time,the runoff ratio increased.The sediment yield in the without-crust test was found to be 1.24 and 1.43 times higher than that observed in the 10-minute crust and 20-minute crust tests,respectively.These results indicate that soil crusts can effectively prevent slope erosion and moisture infiltration,while providing valuable insights for the management of soil erosion in natural environments.

Water retention behavior and shear strength of artificially cemented granite residual soil subjected to free drying

Artificially cemented soils have been widely used as filling materials in highway and railway construction.The shear strength evolution of filling materials upon moist variation can determine the stability of subgrade and embankments.This study conducted water retention tests,MIP tests,and multi-stage triaxial shear tests on cement-treated granite residual soil(GRS)to determine its water retention curve(WRC)upon free drying,pore structure,and peak shear strength qf,respectively.The water retention behavior and shear strength evolution upon free drying were modeled based on the dual-porosity structure of cement-treated GRS and the effective stress principle,respectively.Results show that the drying-WRC is bimodal and higher cement dosage yields a more severe decrease in the water retention capacity within a specific suction range.For a given confining pressure,the peak shear strength qf increased with increasing cement dosage or suction value s.The peak shear strength qf also solely depends on the suction value in the peak stress state.In addition,the cement-treated GRS has a bimodal pore size distribution curve,and its macro-and micro-void ratios remain almost unchanged after free drying.The bimodal drying-WRC of the cement-treated GRS can be modeled by differentiating the water retention mechanisms in macro-and micro-pores.Moreover,using the macro-pore degree of saturation as the effective stress parameterχ=S_(rM),the q_(f)–p′_(f)relationship(where p′_(f)is the effective mean pressure at failure)under various suction and stress conditions can be unified,and the q_(f)–s relationships at various net confining pressuresσ_(3),net can be well reproduced.These findings can help design subgrade and embankments constructed by artificially cemented GRS and assess their safe operation upon climate change.

Effect of integration of mechanical ball milling and flue gas desulfurization gypsum on dealkalization of bauxite residue

The synergistic impact of mechanical ball milling and flue gas desulfurization(FGD)gypsum on the dealkalization of bauxite residue was investigated through integrated analyses of solution chemistry,mineralogy,and microtopography.The results showed a significant decrease in Na_(2)O content(>30 wt.%)of FGD gypsum-treated bauxite residue after 30 min of mechanical ball milling.Mechanical ball milling resulted in differentiation of the elemental distribution,modification of the minerals in crystalline structure,and promotion in the dissolution of alkaline minerals,thus enhancing the acid neutralization capacity of bauxite residue.5 wt.%FGD gypsum combined with 30 min mechanical ball milling was optimal for the dealkalization of bauxite residue.

Residue and Degradation Dynamic of Buprofezin in Citrus and Soil

[Objective] The paper was to detect the residue of buprofezin in citrus and soil.[Method] Gas chromatography（GC）method was used to measure the residue of buprofezin in citrus and soil.[Result] The average recovery rate of buprofezin in entire citrus fruit was 96.17%-97.38%,and the variation coefficient was 6.10%-9.07%;the average recovery rate in pulp was 95.24%-105.46%,and the variation coefficient was 3.30%-6.01%;the average recovery rate in peel was 88.76%-93.64%,and the variation coefficient was 5.12%-6.27%;the average recovery rate in soil was 97.79%-104.3%,and the variation coefficient was 2.45%-9.21%.The degradation dynamics and the final residue results of buprofezin in citrus and soil showed that the degradation half-lives in citrus in Changsha（Hunan）,Hangzhou（Zhejiang）and Guiyang（Guizhou）were 7.65,7.64 and 8.40 d,and the degradation half-lives in soil in three places were 13.75,9.97 and 10.18 d,respectively.[Conclusion] When 25% buprofezin SC watered agent were sprayed in citrus fruits for 2-3 times according to the recommended dose of 166.7-250.0 mg/L,the safe period of buprofezin in citrus could be set as 14 d.

Rehabilitation of bauxite residue to support soil development and grassland establishment

Rehabilitation(amendment and vegetation establishment)on bauxite residue is viewed as a promising strategy to stabilize the surface and initiate soil development.However,such approaches are inhibited by high pH,high exchangeable sodium(ESP)and poor nutrient status.Amendment with gypsum is effective in improving residue physical and chemical properties and promoting seed establishment and growth.Application of organics(e.g.compost)can address nutrient deficiencies but supplemental fertilizer additions may be required.A series of germination bioassays were performed on residue to determine candidate species and optimum rehabilitation application rates.Subsequent field trials assessed establishment of grassland species Holcus lanatus and Trifolium pratense as well as physical and chemical properties of amended residue.Follow up monitoring over five years assessed elemental content in grassland and species dynamics.With co-application of the amendments several grassland species can grow on the residue.Over time other plant species can invade the restored area and fast growing nutrient demanding grasses are replaced.Scrub species can establish within a 5 Yr period and there is evidence of nutrient cycling.High pH,sodicity and nutrient deficiencies are the major limiting factors to establishing grassland on residue.Following restoration several plant species can grow on amended residue.

Effects of Different Sowing Dates on Weed Suppression and Pesticide Residue in Soil

[Objective] To effectively suppress weeds and degrade pesticide residues in soil, pollution-free agricultural production is a very important way. [Method] In regions where high residual pesticides had been applied for a long term, 2-3 consecutive years of shallow ploughing after the autumn harvest, early shallow ploughing and sowing later in the next spring, and late ploughing and sowing were conducted,and the effects of the three measures on weed suppression and reduction of pesticide residue in soil were analyzed by measuring the length and fresh weight of crop radicles. [Result] Trifluralin applied in the A. membranaceus field for a long term limited the growth of the alfalfa seedlings. That is, the radicle length of each plant was 2.1-2.9 cm shorter than that of the control, and the fresh weight of each plant reduced by 0.19-0.20 g. Metsulfuron methyl applied in the alfalfa field for a long term also limited the growth of the alfalfa seedlings, that is, the radicle length of each plant was 1.9-2.0 cm shorter than that of the control, and the fresh weight of each plant reduced by 0.13-0.15 g. Shallow ploughing was conducted within two days after the autumn harvest, and all weed seeds on the ground were plowed into the plough layer 0-10 cm instead of deep soil. Early shallow ploughing in the next spring could make most seeds of weeds in surface soil sprout early, and sowing was conducted after 10 d, so that about 40% of weeds sprouting early were killed off. However, after shallow ploughing and sowing were conducted 10 d later than the normal sowing period, and around 30% of weeds were killed off. In addition,the weeds left in soil should be removed manually at the seedling stage or in late period. These measures had no adverse impact on the growth and development of crop radicles and yield. [Conclusion] In regions where pesticides with long-term residue had been applied for a long term, 2-3 consecutive years of shallow ploughing after the autumn harvest, different farming and sowing measures and artificia weeding could suppress weeds in the crop fields effectively, did not pollute soil environment, and promoted the degradation of pesticides left in soil.

Mesoscopic measurement of damage and shear bands of granite residual soil using Micro-CT and digital volume correlation

The mesomechanics of geotechnical materials are closely related to the macromechanical properties,especially the mesoscale evolution of shear bands,which is helpful for understanding the failure mechanism of geotechnical materials.However,there is lack of effective quantitative analysis method for the complex evolution mechanism of threedimensional shear bands.In this work,we used X-ray computed tomography(CT)to reconstruct volume images and used the digital volume correlation(DVC)method to calculate the three-dimensional strain fields of granite residual soil samples at different loading stages.The trend of the failure surface of the shear bands was obtained by the planar fitting method,and the connectivity index was constructed according to the projection characteristics of the shear bands on the failure trend surface.The results support the following findings:the connectivity index of the shear band increases rapidly and then slowly with increasing axial strain,which is characterized by a near'S'curve.As the stress reaches the peak value,the connectivity index of the shear bands almost exceeds 0.7.The contribution of the new shear band volume to the connectivity of the shear bands becomes increasingly small with increasing axial loading.Affected by quartz grains and stress at the initial stage,the dip angle gradually and finally approaches the included angle of the maximum shear stress from the discrete state with increasing axial loading.The tendency and dip angle of the resulting shear bands are dynamic,and the tendency slightly deflects with increasing loading.

Evaluating the Effects of Aquaculture Wastewater Irrigation with Fertilizer Reduction on Greenhouse Tomato Production,Economic Benefits and Soil Nitrogen Characteristics

The utilization of aquaculture wastewater as irrigation is an effective way to recycle and reuse water and nitrogen fertilizer resources because it contains numerous nutrients.However,it is still unclear that the pattern of substituting aquaculture wastewater irrigation for fertilizer supplementing is conducive to improving the soil nitrogen status,fruit yield and water-fertilizer use efficiency for tomato production.In this context,the experiment was intended to establish the appropriate irrigation regime of aquaculture wastewater in tomato production for freshwater replacement and fertilizer reduction to ensure good yields.Pot experiments were conducted with treatments as farmers accustomed to irrigation and fertilization used as control(CK),1.75 L aquaculture wastewater with base fertilizer(W1),2 L aquaculture wastewater with base fertilizer;and 2.25 L aquaculture wastewater with base fertilizer(W3).We examined the effects of aquaculture wastewater irrigation on soil nitrogen distribution,Nrelated hydrolases,tomato yield,and economic benefits.The results showed that the control treatment had the highest N input,about 24.68%higher than the W3 treatment,while the yield was only about 7.81%higher than W3.This indicated that the overuse of chemical fertilizer was present in the current tomato production.Although the reduction of fertilizer in aquaculture wastewater irrigation caused a decrease in tomato production,this economic loss can be compensated by cost savings in the wastewater disposal.Among aquaculture wastewater treatments,the W3 treatment had the highest overall benefit,achieving 62.63%freshwater savings,37.50%fertilizer input reduction,and an economic return of approximately 19,466 Yuan per hectare higher than the control.Additionally,increasing the irrigation volume of aquaculture wastewater could provide more available nutrients to the soil,which were more prevalent in the form of organic nitrogen.The lower soil nitrate reductase activities(NR)under aquaculture wastewater treatments after harvesting also proved that this pattern was beneficial to reduce soil nitrate nitrogen residues.Overall,the results demonstrate that aquaculture wastewater irrigation alleviates the soil nitrate residues,improves nutrient availability,and results in more economic returns with water and fertilizer conservation for the greenhouse production of tomatoes.

Effects of Agro-Ecological Practices on the Productivity of Orange-Fleshed Sweet Potato (Ipomoea batatas (L.) Lam) and Soil Fertility in the Sudano-Sahelian Zone of Burkina Faso

This study consisted to evaluate the effects of ecological practices on the yield performance of the JEWEL of orange-fleshed sweet potato (Ipomoea batatas (L.) Lam). The study was conducted in a Sudano-Sahelian cropping system (Lantargou, eastern region of Burkina Faso). Agro-ecological practices consisted of the inputs of 3.20 t/ha of compost + 2.45 t/ha of wood ash (CO + WA);4.90 t/ha of wood ash (WA);6.40 t/ha of compost (CO) were compared to control with no inputs (T0). Each treatment was repeated four times. The crop management consisted of plowing, harrowing, raising of ridges with 40 cm height, burying of treatments, transplanting of cuttings, two weeding’s, and using of biopesticide called PIOL for crop protection. Composite soil samples per treatment were also collected at tuber harvest and analyzed to determine the effects of treatments on residual soil fertility. Results showed that the plant heights and diameters under the CO were significantly (P < 0.001) improved by 16% and 12% compared to T0. The WA treatment significantly increased the number of large tubers by 43% (P ≤ 0.01) compared to T0. Total tuber numbers, large tuber numbers and tuber yields of sweet potato under CO + WA were significantly (P < 0.001) and respectively improved by 27%, 50% and 31% compared to T0. All treatments increased soil organic matter, N, P and K contents, and reduced soil acidity compared with those obtained under T0. Soil K content was improved by 39% under CO + WA, and soil N content by 34% under WA compared to T0. Soil C/N ratio under CO + WA was reduced by 20% compared others treatments. But, the CO + WA treatment outperformed by improving residual soil N content by 38%, and the WA treatment by increasing soil K content by 50% compared to T0. In addition, soil pHH2O increased by 1.2 units under WA treatment compared to T0. As conclusion, the application of 6.4 t/ha of compost performed well to improve the vegetative growth of orange-fleshed sweet potato while the inputs of 3.2 t/ha of compost + 2.45 t/ha of wood ash were efficacy to significantly increase the tuber yields and improve the residual fertility of soil.

Use of X-ray computed tomography to study structures and particle contacts of granite residual soil

A small problem about soil particle regularization and contacts but essential to geotechnical engineering was studied.The soils sourced from Guangzhou and Xiamen were sieved into five different particle scale ranges(d<0.075 mm,0.075 mm≤d<0.1 mm,0.1 mm≤d<0.2 mm,0.2 mm≤d<0.5 mm and 0.5 mm≤d<1.0 mm)to study the structures and particle contacts of granite residual soil.The X-ray micro computed tomography method was used to reconstruct the microstructure of granite residual soil.The particle was identified and regularized using principal component analysis(PCA).The particle contacts and geometrical characteristics in 3D space were analyzed and summarized using statistical analyses.The results demonstrate that the main types of contact among the particles are face-face,face-angle,face-edge,edge-edge,edge-angle and angle-angle contacts for particle sizes less than 0.2 mm.When the particle sizes are greater than 0.2 mm,the contacts are effectively summarized as face-face,face-angle,face-edge,edge-edge,edge-angle,angle-angle,sphere-sphere,sphere-face,sphere-edge and sphere-angle contacts.The differences in porosity among the original sample,reconstructed sample and regularized sample are closely related to the water-swelling and water-disintegrable characteristics of granite residual soil.

Effects of dry-wet cycles on three-dimensional pore structure and permeability characteristics of granite residual soil using X-ray micro computed tomography

Due to seasonal climate alterations,the microstructure and permeability of granite residual soil are easily affected by multiple dry-wet cycles.The X-ray micro computed tomography(micro-CT)acted as a nondestructive tool for characterizing the microstructure of soil samples exposed to a range of damage levels induced by dry-wet cycles.Subsequently,the variations of pore distribution and permeability due to drywet cycling effects were revealed based on three-dimensional(3D)pore distribution analysis and seepage simulations.According to the results,granite residual soils could be separated into four different components,namely,pores,clay,quartz,and hematite,from micro-CT images.The reconstructed 3D pore models dynamically demonstrated the expanding and connecting patterns of pore structures during drywet cycles.The values of porosity and connectivity are positively correlated with the number of dry-wet cycles,which were expressed by exponential and linear functions,respectively.The pore volume probability distribution curves of granite residual soil coincide with the χ^(2)distribution curve,which verifies the effectiveness of the assumption of χ^(2)distribution probability.The pore volume distribution curves suggest that the pores in soils were divided into four types based on their volumes,i.e.micropores,mesopores,macropores,and cracks.From a quantitative and visual perspective,considerable small pores are gradually transformed into cracks with a large volume and a high connectivity.Under the action of dry-wet cycles,the number of seepage flow streamlines which contribute to water permeation in seepage simulation increases distinctly,as well as the permeability and hydraulic conductivity.The calculated hydraulic conductivity is comparable with measured ones with an acceptable error margin in general,verifying the accuracy of seepage simulations based on micro-CT results.

Influence of groundwater drawdown on excavation responses e A case history in Bukit Timah granitic residual soils

Performances of a braced cut-and-cover excavation system for mass rapid transit （MRT） stations of the Downtown Line Stage 2 in Singapore are presented. The excavation was carried out in the Bukit Timah granitic （BTG） residual soils and characterized by significant groundwater drawdown, due to dewatering work in complex site conditions, insufficient effective waterproof measures and more permeable soils. A two-dimensional numerical model was developed for back analysis of retaining wall movement and ground surface settlement. Comparisons of these measured excavation responses with the calculated performances were carried out, upon which the numerical simulation procedures were calibrated. In addition, the influences of groundwater drawdown on the wall deflection and ground surface settlement were numerically investigated and summarized. The performances were also compared with some commonly used empirical charts, and the results indicated that these charts are less applicable for cases with significant groundwater drawdowns. It is expected that these general behaviors will provide useful references and insights for future projects involving excavation in BTG residual soils under significant groundwater drawdowns.

Influences of different modifiers on the disintegration of improved granite residual soil under wet and dry cycles

The disintegration of granite residual soil is especially affected by variations in physical and chemical properties. Serious geologic hazards or engineering problems are closely related to the disintegration of granite residual soil in certain areas. Research on the mechanical properties and controlling mechanisms of disintegration has become a hot issue in practical engineering. In this paper, the disintegration characteristics of improved granite residual soil are studied by using a wet and dry cycle disintegration instrument, and the improvement mechanism is analyzed. The results show that the disintegration amounts and disintegration ratios of soil samples treated with different curing agents are obviously different. The disintegration process of improved granite residual soil can be roughly divided into 5 stages:the forcible water intrusion stage, microcrack and fissure development stage, curing and strengthening stage, stable stage, and sudden disintegration stage. The disintegration of granite residual soil is caused by the weakening of the cementation between soil particles under the action of water. When the disintegration force is greater than the anti-disintegration force of soil, the soil will disintegrate. Cement and lime mainly rely on ion exchange agglomeration, the inclusion effect of curing agents on soil particles, the hard coagulation reaction and carbonation to strengthen granite residual soil. Kaolinite mainly depends on the reversibility of its own cementation to improve and strengthen granite residual soil. The reversibility of kaolinite cementation is verified by investigating pure kaolinite with a tensile, soaking, drying and tensile test cycle. Research on the disintegration characteristics and disintegration mechanism of improved granite residual soil is of certain reference value for soil modification.

Evolution of cracks in the shear bands of granite residual soil

The evolution of shear bands and cracks plays an important role in landslides.However,there is no systematic method for classification of the cracks,which can be used to analyze the evolution of cracks in shear bands.In this study,X-ray computed tomography(CT)is used to observe the behavior of granite residual soil during a triaxial shear process.Based on the digital volume correlation(DVC)method,a crack classification method is established according to the connectivity characteristics of cracks before and after loading.Cracks are then divided into six classes:obsolete,brand-new,isolated,split,combined,and compound.With evolution of the shear bands,a large number of brand-new cracks accelerate the damages of materials at the mesoscale,resulting in a sharp decrease in strength.The volume of brandnew cracks increases rapidly with increasing axial strain,and their volume is greater than 50%when the strain reaches 12%,while the volume of compound cracks decreases from 54%to 21%.As cracks are the weakest areas in a material,brand-new cracks accelerate the development of shear bands.Finally,the coupling effect of shear bands and cracks destroys the soil strength.

Flow-slide characteristics and failure mechanism of shallow landslides in granite residual soil under heavy rainfall

Affected by typhoons over years, Fujian Province in Southeast China has developed a large number of shallow landslides, causing a long-term concern for the local government. The study on shallow landslide is not only helpful to the local government in disaster prevention, but also the theoretical basis of regional early warning technology. To determine the whole-process characteristics and failure mechanisms of flow-slide failure of granite residual soil slopes, we conducted a detailed hazard investigation in Minqing County, Fujian Province, which was impacted by Typhoon Lupit-induced heavy rainfall in August 2021. Based on the investigation and preliminary analysis results, we conducted indoor artificial rainfall physical model tests and obtained the whole-process characteristics of flow-slide failure of granite residual soil landslides. Under the action of heavy rainfall, a granite residual soil slope experiences initial deformation at the slope toe and exhibits development characteristics of continuous traction deformation toward the middle and upper parts of the slope. The critical volumetric water content during slope failure is approximately 53%. Granite residual soil is in a state of high volumetric water content under heavy rainfall conditions, and the shear strength decreases, resulting in a decrease in stability and finally failure occurrence. The new free face generated after failure constitutes an adverse condition for continued traction deformation and failure. As the soil permeability(cm/h) is less than the rainfall intensity(mm/h), and it is difficult for rainwater to continuously infiltrate in short-term rainfall, the influence depth of heavy rainfall is limited. The load of loose deposits at the slope foot also limits the development of deep deformation and failure. With the continuous effect of heavy rainfall, the surface runoff increases gradually, and the influence mode changes from instability failure caused by rainfall infiltration to erosion and scouring of surface runoff on slope surface. Transportation of loose materials by surface runoff is an important reason for prominent siltation in disaster-prone areas.

Industrial wastes applications for alkalinity regulation in bauxite residue: A comprehensive review

Bauxite residue is a highly alkaline material generated from the production of alumina in which bauxite is dissolved in caustic soda.Approximately 4.4 billion tons of bauxite residues are either stockpiled or landfilled,creating environmental risks either from the generation of dust or migration of filtrates.High alkalinity is the critical factor restricting complete utilization of bauxite residues,whilst the application of alkaline regulation agents is costly and difficult to apply widely.For now,current industrial wastes,such as waste acid,ammonia nitrogen wastewater,waste gypsum and biomass,have become major problems restricting the development of the social economy.Regulation of bauxite residues alkalinity by industrial waste was proposed to achieve‘waste control by waste’with good economic and ecological benefits.This review will focus on the origin and transformation of alkalinity in bauxite residues using typical industrial waste.It will propose key research directions with an emphasis on alkaline regulation by industrial waste,whilst also providing a scientific reference point for their potential use as amendments to enhance soil formation and establish vegetation on bauxite residue disposal areas(BRDAs)following large-scale disposal.

Variation of alkaline characteristics in bauxite residue under phosphogypsum amendment

Aiming at alkaline problem of bauxite residue,this work focused variation of alkaline characteristics in bauxite residue through phosphogypsum treatment.The results demonstrated that the pH of bauxite residue reduced from initial 10.83 to 8.70 when 1.50 wt%phosphogypsum was added for 91 d.The removal rates of free alkali and exchangeable sodium were 97.94%and 75.87%,respectively.Meanwhile,significant positive correlations(P<0.05)existed between pH and free alkali,exchangeable sodium.The effect of free alkali composition was CO3^2–>OH^–>AlO2^–>HCO3^–.In addition,alkaline phase decreased from 52.81%to 48.58%and gypsum stably presented in bauxite residue which continuously provided Ca^2+to inhibit dissolution of combined alkali.Furthermore,phosphogypsum promoted formation of macroaggregate structure,increased Ca^2+,decreased Na+and Al^3+on the surface of bauxite residue significantly,ultimately promoting soil formation in bauxite residue.