The Ti fire found in high performance engines promotes the development of burn resistant Ti alloys. The burn resistant mechanism of Ti40 alloy is investigated. Ti40 alloy reveals good burn resistance. Its interfacial ...The Ti fire found in high performance engines promotes the development of burn resistant Ti alloys. The burn resistant mechanism of Ti40 alloy is investigated. Ti40 alloy reveals good burn resistance. Its interfacial products between burning products and the matrix are tenacious, which retard the diffusion of oxygen into the matrix. Two burn resistant mechanisms, that is, fast scatter dispersion of heat and suppression of oxygen diffusion, are proposed.展开更多
Organic dust flames deal with a field of science in which many complicated phenomena like pyrolysis or devolatization of solid particles and combustion of volatile particles take place. One-dimensional flame propagati...Organic dust flames deal with a field of science in which many complicated phenomena like pyrolysis or devolatization of solid particles and combustion of volatile particles take place. One-dimensional flame propagation in cloud of fuel mixture is analyzed in which flame structure is divided into three zones. The first zone is preheat zone in which rate of the chemical reaction is small and transfer phenomena play significant role in temperature and mass distributions. In this model, it is assumed that particles pyrolyze first to yield a gaseous fuel mixture. The second zone is reaction zone where convection and vaporization rates of the particles are small. The third zone is convection zone where diffusive terms are negligible in comparison of other terms. Non-zero Biot number is used in order to study effect of particles thermal resistance on flame characteristics. Also, effect of particle size on combustion of micro organic dust is investigated. According to obtained results, it is understood that both flame temperature and burning velocity decrease with rise in the Biot number and particle size.展开更多
Dynamic recrystallization (DRX) behavior in β phase region for the burn resistant titanium alloy Ti?25V?15Cr?0.2Si was investigated with a compression test in the temperature range of 950?1100 °C and the strain ...Dynamic recrystallization (DRX) behavior in β phase region for the burn resistant titanium alloy Ti?25V?15Cr?0.2Si was investigated with a compression test in the temperature range of 950?1100 °C and the strain rate of 0.001?1 s?1. The results show that deformation mechanism of this alloy in hot deformation is dominated by DRX, and new grains of DRX are evolved by bulging nucleation mechanism as a predominant mechanism. DRX occurs more easily with the decrease of strain rate and the increase of deformation temperature. Grain refinement is achieved due to DRX during the hot deformation at strain rate range of 0.01?0.1 s?1 and temperature range of 950?1050 °C. DRX grain coarsening is observed for the alloy deformed at the higher temperatures of 1100 °C and the lower strain rates of 0.001 s?1. Finally, in order to determine the recrystallized fraction and DRX grain size under different deformation conditions, the prediction models of recrystallization kinetics and recrystallized grain sizes were established.展开更多
Ti 40 alloy is a single β phase burn resistant titanium alloy. Its high temperature deformation mechanism and stress strain ( σ ε ) curves were studied by Gleeble 1500 thermal simulator. The results sugg...Ti 40 alloy is a single β phase burn resistant titanium alloy. Its high temperature deformation mechanism and stress strain ( σ ε ) curves were studied by Gleeble 1500 thermal simulator. The results suggest that there are a bit abrupt flow stress drops followed by steady state in Ti 40 alloy as annealing. The magnitude of the flow stress drop increases with strain rate and decreases with temperature. Its deformation activation energies are 174 kJ/mol for 650~850℃ and 276.7 kJ/mol for 950~1000℃, which are close to or bigger than the values for self and solute lattice diffusion in pure β titanium, thereby, the deformation mechanism at temperature range is controlled by lattice diffusion for 650~850℃, or mainly controlled by dynamic recrystallization for 950~1000℃.展开更多
The direct-current simulation burning method was used to investigate the burn-resistant behavior of Ti14 titanium alloy.The results show that Ti14 alloy exhibits a better burn resistance than TC4 alloy(Ti-6A1-4V).Cu...The direct-current simulation burning method was used to investigate the burn-resistant behavior of Ti14 titanium alloy.The results show that Ti14 alloy exhibits a better burn resistance than TC4 alloy(Ti-6A1-4V).Cu is observed to preferentially migrate to the surface of Ti14 alloy during the burning reaction,and the burned product contains Cu,Cu2O,and TiO2.An oxide layer mainly comprising loose TiO2 is observed beneath the burned product.Meanwhile,Ti2Cu precipitates at grain boundaries near the interface of the oxide layer,preventing the contact between O2 and Ti and forming a rapid diffusion layer near the matrix interface.Consequently,a multiple-layer structure with a Cu-enriched layer(burned product)/Cu-lean layer(oxide layer)/Cu-enriched layer(rapid diffusion layer) configuration is formed in the burn heat-affected zone of Ti14 alloy;this multiple-layer structure is beneficial for preventing O2 diffusion.Furthermore,although A1 can migrate to form A12O3 on the surface of TC4 alloy,the burn-resistant ability of TC4 is unimproved because the Al2O3 is discontinuous and not present in sufficient quantity.展开更多
Ti - 40 alloy is a single β phase burn resistant titanium alloy.Its high temperature deformation mech- anism is studied and its stress - strain curves are examined he use of Gleeble - 1500 thermal -simulator. The r...Ti - 40 alloy is a single β phase burn resistant titanium alloy.Its high temperature deformation mech- anism is studied and its stress - strain curves are examined he use of Gleeble - 1500 thermal -simulator. The results reveal that there are abrupt flow stress drops followed b steady state.The magnitude of the flow stress drop increases with strain rote and decreases with temperature.Deformation activation energy, Q, is 247. 5 KJ/mol. The deformation mechanism of Ti - 40 alloy is controlled by the lattice diffusion Its constitutive equation is set up, i. e.展开更多
Burning resistivities of the Ti Cr V Mo alloys were investigated by means of their adiabatic flame temperatures. Calculated results show that the adiabatic flame temperature of the Ti Cr V Mo alloys is lower tha...Burning resistivities of the Ti Cr V Mo alloys were investigated by means of their adiabatic flame temperatures. Calculated results show that the adiabatic flame temperature of the Ti Cr V Mo alloys is lower than that of the Ti Cr V alloys, most probably due to that the gas products of molybdenum oxide can be easily formed and the sublimation of more oxides leads to the reduction of T af . Therefore, the Ti Cr V Mo alloys would have better burning resistivity and their optimal composition is presented.展开更多
This study investigates the feasibility of using electrochemical machining(ECM) to produce critical aeroengine components from a new burn-resistant titanium alloy(Ti40), thereby reducing costs and improving effici...This study investigates the feasibility of using electrochemical machining(ECM) to produce critical aeroengine components from a new burn-resistant titanium alloy(Ti40), thereby reducing costs and improving efficiency relative to conventional mechanical machining.Through this, it is found that an aqueous mix of sodium chloride and potassium bromide provides the optimal electrolyte and that the surface quality of the Ti40 workpiece is improved by using a pulsed current of1 k Hz rather than a direct current.Furthermore, the quality of cavities produced by ECM and the overall material removal rate are determined to be dependent on a combination of operating voltage, electrolyte inlet pressure, cathode feeding rate and electrolyte concentration.By optimizing these parameters, a surface roughness of 0.371 lm has been achieved in conjunction with a specific removal rate of more than 3.1 mm3/A?min.展开更多
文摘The Ti fire found in high performance engines promotes the development of burn resistant Ti alloys. The burn resistant mechanism of Ti40 alloy is investigated. Ti40 alloy reveals good burn resistance. Its interfacial products between burning products and the matrix are tenacious, which retard the diffusion of oxygen into the matrix. Two burn resistant mechanisms, that is, fast scatter dispersion of heat and suppression of oxygen diffusion, are proposed.
文摘Organic dust flames deal with a field of science in which many complicated phenomena like pyrolysis or devolatization of solid particles and combustion of volatile particles take place. One-dimensional flame propagation in cloud of fuel mixture is analyzed in which flame structure is divided into three zones. The first zone is preheat zone in which rate of the chemical reaction is small and transfer phenomena play significant role in temperature and mass distributions. In this model, it is assumed that particles pyrolyze first to yield a gaseous fuel mixture. The second zone is reaction zone where convection and vaporization rates of the particles are small. The third zone is convection zone where diffusive terms are negligible in comparison of other terms. Non-zero Biot number is used in order to study effect of particles thermal resistance on flame characteristics. Also, effect of particle size on combustion of micro organic dust is investigated. According to obtained results, it is understood that both flame temperature and burning velocity decrease with rise in the Biot number and particle size.
基金Projects(51261020,51164030)supported by the National Natural Science Foundation of ChinaProject(GF201401007)supported by the Open Fund of National Defense Key Disciplines Laboratory of Light Alloy Processing Science and Technology,China
文摘Dynamic recrystallization (DRX) behavior in β phase region for the burn resistant titanium alloy Ti?25V?15Cr?0.2Si was investigated with a compression test in the temperature range of 950?1100 °C and the strain rate of 0.001?1 s?1. The results show that deformation mechanism of this alloy in hot deformation is dominated by DRX, and new grains of DRX are evolved by bulging nucleation mechanism as a predominant mechanism. DRX occurs more easily with the decrease of strain rate and the increase of deformation temperature. Grain refinement is achieved due to DRX during the hot deformation at strain rate range of 0.01?0.1 s?1 and temperature range of 950?1050 °C. DRX grain coarsening is observed for the alloy deformed at the higher temperatures of 1100 °C and the lower strain rates of 0.001 s?1. Finally, in order to determine the recrystallized fraction and DRX grain size under different deformation conditions, the prediction models of recrystallization kinetics and recrystallized grain sizes were established.
文摘Ti 40 alloy is a single β phase burn resistant titanium alloy. Its high temperature deformation mechanism and stress strain ( σ ε ) curves were studied by Gleeble 1500 thermal simulator. The results suggest that there are a bit abrupt flow stress drops followed by steady state in Ti 40 alloy as annealing. The magnitude of the flow stress drop increases with strain rate and decreases with temperature. Its deformation activation energies are 174 kJ/mol for 650~850℃ and 276.7 kJ/mol for 950~1000℃, which are close to or bigger than the values for self and solute lattice diffusion in pure β titanium, thereby, the deformation mechanism at temperature range is controlled by lattice diffusion for 650~850℃, or mainly controlled by dynamic recrystallization for 950~1000℃.
基金supported by the Major State Basic Research Development Program of China(No.2007CB613807)the National Natural Science Foundation of China(Nos.51201019 and 51401033)
文摘The direct-current simulation burning method was used to investigate the burn-resistant behavior of Ti14 titanium alloy.The results show that Ti14 alloy exhibits a better burn resistance than TC4 alloy(Ti-6A1-4V).Cu is observed to preferentially migrate to the surface of Ti14 alloy during the burning reaction,and the burned product contains Cu,Cu2O,and TiO2.An oxide layer mainly comprising loose TiO2 is observed beneath the burned product.Meanwhile,Ti2Cu precipitates at grain boundaries near the interface of the oxide layer,preventing the contact between O2 and Ti and forming a rapid diffusion layer near the matrix interface.Consequently,a multiple-layer structure with a Cu-enriched layer(burned product)/Cu-lean layer(oxide layer)/Cu-enriched layer(rapid diffusion layer) configuration is formed in the burn heat-affected zone of Ti14 alloy;this multiple-layer structure is beneficial for preventing O2 diffusion.Furthermore,although A1 can migrate to form A12O3 on the surface of TC4 alloy,the burn-resistant ability of TC4 is unimproved because the Al2O3 is discontinuous and not present in sufficient quantity.
文摘Ti - 40 alloy is a single β phase burn resistant titanium alloy.Its high temperature deformation mech- anism is studied and its stress - strain curves are examined he use of Gleeble - 1500 thermal -simulator. The results reveal that there are abrupt flow stress drops followed b steady state.The magnitude of the flow stress drop increases with strain rote and decreases with temperature.Deformation activation energy, Q, is 247. 5 KJ/mol. The deformation mechanism of Ti - 40 alloy is controlled by the lattice diffusion Its constitutive equation is set up, i. e.
文摘Burning resistivities of the Ti Cr V Mo alloys were investigated by means of their adiabatic flame temperatures. Calculated results show that the adiabatic flame temperature of the Ti Cr V Mo alloys is lower than that of the Ti Cr V alloys, most probably due to that the gas products of molybdenum oxide can be easily formed and the sublimation of more oxides leads to the reduction of T af . Therefore, the Ti Cr V Mo alloys would have better burning resistivity and their optimal composition is presented.
基金sponsored by the National Natural Science Foundation of China the Program for New Century Excellent Talents in University (NCET-12-0627) of Chinathe Fundamental Research Funds for the Central Universities of China
文摘This study investigates the feasibility of using electrochemical machining(ECM) to produce critical aeroengine components from a new burn-resistant titanium alloy(Ti40), thereby reducing costs and improving efficiency relative to conventional mechanical machining.Through this, it is found that an aqueous mix of sodium chloride and potassium bromide provides the optimal electrolyte and that the surface quality of the Ti40 workpiece is improved by using a pulsed current of1 k Hz rather than a direct current.Furthermore, the quality of cavities produced by ECM and the overall material removal rate are determined to be dependent on a combination of operating voltage, electrolyte inlet pressure, cathode feeding rate and electrolyte concentration.By optimizing these parameters, a surface roughness of 0.371 lm has been achieved in conjunction with a specific removal rate of more than 3.1 mm3/A?min.