Scaling of reverse osmosis (RO) membrane surface is one of the main problems in desalination proc- esses. To mitigate scales, organic anti-scalants are often used. If the dosages of anti-scalants are reduced, by using...Scaling of reverse osmosis (RO) membrane surface is one of the main problems in desalination proc- esses. To mitigate scales, organic anti-scalants are often used. If the dosages of anti-scalants are reduced, by using other much cheaper scale inhibitors, RO running cost will decrease greatly. The present paper investigated the inhi- bition of CaCO3 precipitation by zinc ions in RO system. The results show that the zinc ion concentration of 2mg?L-1 was able to exert a marked suppression effect on both bulk precipitation of CaCO3 and on membrane scaling on waters of moderate hardness.展开更多
Fouling phenomenon is considered among the major reasons that cause significant increase of operating cost of desalination plants equipped with reverse osmosis(RO)membranes.This phenomenon is studied in the present wo...Fouling phenomenon is considered among the major reasons that cause significant increase of operating cost of desalination plants equipped with reverse osmosis(RO)membranes.This phenomenon is studied in the present work in the case of RO polyamide aromatic membranes using model seawater containing inorganic salts and colloidal compounds.Different solubility conditions of CaCO3 and CaSO4 were applied to study RO performances with and without colloid presence.During experiments,the membrane permeate fluxes were continuously monitored.Moreover,studies of chemical composition,structure,and morphology of the materials deposited on the membrane surface were conducted using energy dispersive microanalysis(EDS)X-ray diffraction and scanning electronic microscopy(SEM).Results show that in conditions of calcium carbonate oversaturation there is a reduction in the permeate flow of 11.2%due to fouling of the membrane by the precipitation of this compound.While in the same conditions of calcium sulphate oversaturation the reduction of the flow is 5%,so we can conclude that in conditions of oversaturation of both salts,calcium carbonate produces a greater fouling of the membrane that in its view causes greater decrease in the flow of permeate.All this based on the results of the test with both salts in oversaturated conditions.Resulting in the formation of calcite and gypsum crystals onto the membranes as XRD analyses stated.Additional presence of colloidal silica in those conditions intensifies strongly the fouling,leading until to 24.1%of permeate flux decrease.展开更多
基金Supported by the National Natural Science Foundation of China (No.20306015) and the Scientific Research Foundation of theState Education Ministry for Returned Overseas Chinese Scholars (No.[2003]406).
文摘Scaling of reverse osmosis (RO) membrane surface is one of the main problems in desalination proc- esses. To mitigate scales, organic anti-scalants are often used. If the dosages of anti-scalants are reduced, by using other much cheaper scale inhibitors, RO running cost will decrease greatly. The present paper investigated the inhi- bition of CaCO3 precipitation by zinc ions in RO system. The results show that the zinc ion concentration of 2mg?L-1 was able to exert a marked suppression effect on both bulk precipitation of CaCO3 and on membrane scaling on waters of moderate hardness.
基金funded by the Project AM11/04 of the Junta de Andalucía(Spain)。
文摘Fouling phenomenon is considered among the major reasons that cause significant increase of operating cost of desalination plants equipped with reverse osmosis(RO)membranes.This phenomenon is studied in the present work in the case of RO polyamide aromatic membranes using model seawater containing inorganic salts and colloidal compounds.Different solubility conditions of CaCO3 and CaSO4 were applied to study RO performances with and without colloid presence.During experiments,the membrane permeate fluxes were continuously monitored.Moreover,studies of chemical composition,structure,and morphology of the materials deposited on the membrane surface were conducted using energy dispersive microanalysis(EDS)X-ray diffraction and scanning electronic microscopy(SEM).Results show that in conditions of calcium carbonate oversaturation there is a reduction in the permeate flow of 11.2%due to fouling of the membrane by the precipitation of this compound.While in the same conditions of calcium sulphate oversaturation the reduction of the flow is 5%,so we can conclude that in conditions of oversaturation of both salts,calcium carbonate produces a greater fouling of the membrane that in its view causes greater decrease in the flow of permeate.All this based on the results of the test with both salts in oversaturated conditions.Resulting in the formation of calcite and gypsum crystals onto the membranes as XRD analyses stated.Additional presence of colloidal silica in those conditions intensifies strongly the fouling,leading until to 24.1%of permeate flux decrease.
