Robust architecture of 2D nano Mg-based borohydride on graphene with superior reversible hydrogen storage performance

Efficient technical strategies to synthesize hydrides with high capacity and favorable reversibility are significant for the development of novel energy materials.Herein,nano Mg-based borohydride,Mg(BH_(4))_(2),with robust architecture was designed and prepared by confining on graphene through a solution selfconfinement method.The Mg(BH_(4))_(2) confined on graphene displays a wrinkled 2D nano layer morphology within 8.8 nm thickness.Such 2D nano Mg(BH_(4))_(2) can start dehydrogenation at 67.9℃ with a high capacity of 12.0 wt.%,which is 190.5℃ lower than pristine Mg(BH_(4))_(2).The isothermal dehydrogenation tests and kinetics fitting results indicate the 2D nano Mg(BH_(4))_(2) possesses much-enhanced dehydrogenation kinetics of 31.3 kJ/mol activation energy,which is only half of pristine Mg(BH_(4))_(2).The thermodynamics of the 2D nano Mg(BH_(4))_(2) is also verified by PCT tests,of which Gibbs free energy value for the confined 2D nano Mg(BH_(4))_(2) is estimated to be-18.01 kJ/mol H_(2),lower than-16.36 kJ/mol H_(2) of pristine Mg(BH_(4))_(2).Importantly,the reversibility of the confined 2D nano Mg(BH_(4))_(2) is significantly enhanced to over 90%capacity retention with relatively kinetics stability during 10 cycles.The mechanism analyses manifest that Mg(BH_(4))_(2) exhibits stable 2D nano morphology during 10 cyclic tests,resulting in the greatly reduced H diffusion path and the improved de/rehydrogenation kinetics of the 2D nano Mg(BH_(4))_(2).Based on theoretical calculations of Mg(BH_(4))_(2) and the intermediate MgB12H12 confined on graphene,the charge transfer status of both samples is modified to facilitate de/rehydrogenation,thus leading to the significant thermodynamic improvements of the reversible hydrogen storage performances for 2D nano Mg(BH_(4))_(2).Such investigation of the Mg-based borohydride will illuminate prospective technical research of energy storage materials.

Temperature Dependence of Photoinduced Birefringence in an Azobenzene Polymer

The photoinduced birefringence in an azobenzene polymer is investigated at different temperatures between -20℃ to 50℃. It is found that there is a peak value of photoinduced birefringence in the temperature dependence of the photoinduced birefringence under a certain pumping intensity. With the pump light in 90mW/cm^2, the peak value of the photoinduced birefringence appeared at about 0℃ C. The effect of temperature on the photoinduced birefringence is discussed using the competition mechanism between the photoinduced reorientation and the thermal random motion.

Reversible storage of multiple light pulses in the EIT atomic medium

In this paper, we first present a full numerical simulation for the trapping and retrieval procedure of eight continuing '1' Guassian pulses (i.e., '11111111') in the electromagnetically induced transparency (BIT) medium. This simulation shows that an BIT medium has the ability to store multiple light pulses in a shape-preserving way. And we also, for the first time, give the formula evaluating the maximum number of pulses that can be stored by an EIT medium at one time. This work reveals a new possible way to the reversible storage of the photonic information.

Storage and Retrieval of a Weak Optical Signal Improved by Spontaneously Generated Coherence in an Atomic Assemble

We investigate the reversible storage of a weak single-mode light signal in a A-type three-level atomic system with spontaneously generated coherence （SGC） and pumped by an incoherent field. The scheme is phase-dependent. If the phase of the controlling field is set oppositely to that of the signal field, the combination of SGC with weak pump overcomes the drawback of incompletely retrieval in the conventional scheme, leading to 100% retrieval fidelity or even to the amplification of the retrieved signal with respect to its initial one.

Experimental investigations of a prototype reversible pump turbine in generating mode with water head variations

Influences of water head variations on the performances of a prototype reversible pump turbine are experimentally studied in generating mode within a wide range of load conditions(from 25% to 96% of the rated power). The pressure fluctuations of the reversible pump turbine at three different water heads(with non-dimensional values being 0.48, 0.71 and 0.90) are measured and compared based on the pressure data recorded in the whole flow passage of the turbine. Furthermore, effects of monitoring points and load variations on the impeller-induced unstable behavior(e.g. blade passing frequency and its harmonics) are quantitatively discussed. Our findings reveal that water head variations play a significant role on the pressure fluctuations and their propagation mechanisms inside the reversible pump turbine.