Assessment of Point and Nonpoint Sources Pollution in Songhua River Basin,Northeast China by Using Revised Water Quality Model

Individual participation of pollutants in the pollution load should be estimated even if roughly for the appropriate environmental management of a river basin.It is difficult to identify the sources and to quantify the load, especially in modeling nonpoint source.In this study a revised model was established by integrating point and nonpoint sources into one-dimensional Streeter-Phelps(S-P) model on the basis of real-time hydrologic data and surface water quality monitoring data in the Jilin Reach of the Songhua River Basin.Chemical oxygen demand(COD) and ammonia nitrogen(NH 3-N) loads were estimated.Results showed that COD loads of point source and nonpoint source were 134 958 t/yr and 86 209 t/yr, accounting for 61.02% and 38.98% of total loads, respectively.NH 3-N loads of point source and nonpoint source were 16 739 t/yr and 14 272 t/yr, accounting for 53.98% and 46.02%, respectively.Point source pollution was stronger than nonpoint source pollution in the study area at present.The water quality of upstream was better than that of downstream of the rivers and cities.It is indispensable to treat industrial wastewater and municipal sewage out of point sources, to adopt the best management practices to control diffuse pollutants from agricultural land and urban surface runoff in improving water quality of the Songhua River Basin.The revised S-P model can be successfully used to identify pollution source and quantify point source and nonpoint source loads by calibrating and validating.

Water Quality Evaluation and Analysis on the Causes of Pollution for Groundwater Sources in Yantai, China

Based on the investigation for the 14 groundwater sources, the water quality of the groundwater sources had been analyzed, using the evaluation method of the combination of inorganic and organic index instead of the traditional method which was only based on inorganic index. The results showed that the quality of 12 groundwater sources satisfied class III standard of groundwater quality and other two exceeded class III standard. There were one groundwater source, whose water quality reached class 1 standard, and five groundwater sources, whose water quality reached class II standard. There were seven groundwater sources, in which the fluorine, an organic pollutant, was detected. The results showed that the groundwater resources in Yantai City were less polluted and the main pollutant in groundwater was nitrate. According to the analytical data and the environmental conditions of groundwater sources, the conclusion was drawn that the agriculture and rural non-point pollution were the main reasons of groundwater pollution.

Integrating stable isotopes and factor analysis to delineate the groundwater provenance and pollution sources in the northwestern part of the Amman-Al Zarqa Basin, Jordan

Globally,groundwater contamination by nitrate is one of the most widespread environmental problems,particularly in arid and semiarid areas,which are characterized by low amounts of rainfall and groundwater recharge.The stable isotope composition of groundwater(δ2H-H2O andδ18O-H2O)and dissolved nitrate(δ15N-NO3–andδ18O-NO3–)and factor analysis(FA)were applied to explore groundwater provenance,pollution,and chemistry evolution in the northwestern part of the Amman-Al Zarqa Basin,Jordan.In this study,we collected 23 samples from the Lower Ajloun aquifer in 2021,including 1 sample from a groundwater well and 22 samples from springs.These samples were tested for electrical conductivity,total dissolved solids,pH,temperature,dissolved oxygen,the concentration of major ions(Ca2+,Mg2+,Na+,K+,HCO3–,Cl–,SO42–,and NO3–),and the stable isotope composition of groundwater and dissolved nitrate.The results revealed that groundwater in the study area is mainly Ca–Mg–HCO3 type and can be classified as fresh water,hard water,and very hard water.The range and average concentration of NO3–were 3.5–230.8 and 50.9 mg/L,respectively.Approximately 33%of the sampling points showed NO3–levels above the maximum allowable concentration of 50.0 mg/L set by the World Health Organization(WHO)guidelines for drinking water quality.The values ofδ18O-H2O andδ2H-H2O showed that groundwater in the study area is part of the current water cycle,originating in the Mediterranean Sea,with significant evaporation,orographic,and amount effects.The values of the stable isotope composition of NO3–corresponded toδ15N-NO3–andδ18O-NO3–values produced by the nitrification process of manure or septic waste and soil NH4+.The FA performed on the hydrochemical parameters and isotope data resulted in three main factors,with Factor 1,Factor 2,and Factor 3,accounting for 50%,21%,and 11%of the total variance,respectively.Factor 1 was considered human-induced factor,named"pollution factor",whereas Factor 2,named"conservative fingerprint factor",and Factor 3,named"hardness factor",were considered natural factors.This study will help local researchers manage groundwater sustainably in the study area and other similar arid and semiarid areas in the world.

Identification of coastal water quality by multivariate statistical techniques in two typical bays of northern Zhejiang Province,East China Sea

The Hangzhou Bay（HZB） and Xiangshan Bay（XSB）, in northern Zhejiang Province and connect to the East China Sea（ECS） were considerably affected by the consequence of water quality degradation. In this study, we analyzed physical and biogeochemical properties of water quality via multivariate statistical techniques. Hierarchical cluster analysis（HCA） grouped HZB and XSB into two subareas of different pollution sources based on similar physical and biogeochemical properties. Principal component analysis（PCA） identified three latent pollution sources in HZB and XSB respectively and emphasized the importance of terrestrial inputs, coastal industries as well as natural processes in determining the water quality of the two bays. Therefore, proper measurement for the protection of aquatic ecoenvironment in HZB and XSB were of great urgency.

Water Quality Assessment of the River Nile System:An Overview

Objectives The main objective of the present article is to assess and evaluate the characteristics of the Nile water system , and identify the major sources of pollution and its environmental and health consequences. The article is also aimed to highlight the importance of water management via re-use and recycle of treated effluents for industrial purpose and for cultivation of desert land. Method An intensive effort was made by the authors to collect, assess and compile the available data about the River Nile. Physico-chemical analyses were conducted to check the validity of the collected data. For the determination of micro-pollutants, Gas Chromatography (GC) and High Performance Liquid Chromatography (HPLC) were used. Heavy metals were also determined to investigate the level of industrial pollution in the river system. Results The available data revealed that the river receives a large quantity of industrial, agriculture and domestic wastewater. It is worth mentioning that the river is still able to recover in virtually all the locations, with very little exception. This is due to the high dilution ratio. The collected data confirmed the presence of high concentrations of chromium and manganese in all sediment samples. The residues of organo-chlorine insecticides were detected in virtually all locations. However, the levels of such residues are usually below the limit set by the WHO for use as drinking water. The most polluted lakes are Lake Maryut and Lake Manzala. Groundwater pollution is closely related to adjacent (polluted) surface waters. High concentrations of nutrients, E.coli, sulfur, heavy metals, etc. have been observed in the shallow groundwater, largely surpassing WHO standards for drinking water use. Conclusion A regular and continuous monitoring scheme shall be developed for the River Nile system. The environmental law shall be enforced to prohibit the discharge of wastewater (agricultural, domestic or industrial) to River Nile system.

Natural and Anthropogenic Influence in Water Quality:The Case of Linares City,NE Mexico

The aim of this research paper was to identify whether the water quality had been influenced either by the natural environment or by anthropogenic activities or both in the municipality of Linares, the second largest city of the State of Nuevo Leon, NE Mexico. The superficial water (Pablillo River) and the groundwater quality (from a fractured and a porous aquifers hydraulically interconnected) were determined by comparing their chemical composition with maximum permissible limits for water consumption and irrigation use. A hydrogeochemical modeling was performed to identify the distribution of aqueous species responsible for the presence of some dissolved or precipitated mineral species, as well as an identification of geochemical factors responsible of superficial and groundwater quality. A canonical correspondence analysis was allowed to determine if the natural environment and/or anthropogenic activities were responsible for water quality. The parameters analysed in both aquifers, as well as in the Pablillo River, were total solids, suspended solids, nitrate, and chloride;barium and mercury were present in both aquifers. As a natural influence, the predominant mineral species are as following: under-saturated anhydrite (porous aquifer), over-saturated aragonite, calcite, dolomite, and gypsum (both aquifers and Pablillo River), barite and whiterite (only in fractured aquifer). The geochemical factors responsible for natural contamination were rock dominance (fractured aquifer), and evaporation dominance (porous aquifer, Pablillo River). On the other hand, anthropogenic activities such as changes in soil use and the presence of point (old municipal landfill, pig farms, barite deposit), and diffuse (agricultural areas, septic tanks and latrines) pollution sources had influence in the presence of contaminants such as total and fecal coliforms, nitrates, chlorides, mercury and barium. Several control and remediation strategies should be taken into account to prevent this pollution in the future.

Application of Index Analysis to Evaluate the Water Quality of the Tuul River in Mongolia

A study of water pollution determinands of the Tuul River was carried out in surrounding area of Ulaanbaatar, the capital of Mongolia at 14 monitoring sites, using an extensive dataset between 1998 and 2008. An index method, developed by Ministry of Nature and Environment of Mongolia, applied for assessment and total, seven hydro-chemicals used in the index calculation. The research indicates that the Tuul River is not polluted until the Ulaanbaatar city and the contamination level spike appears when the river entering the city. The upper reaches of the river and tributaries have relatively good quality waters. Several pollution sources exist in the study area. Among them, the Central Wastewater Treatment Plant (CWTP) is a strongest point source in the downstream section of the river, recently. Pollutions at sites 7-10 are strongly dependant effluent treatment levels from the plant, and it contains a high amount of chemicals that can cause of major decrement of the water quality. This would definitely kill aquatic fauna in the stretch of the river affected. It certainly happened in 2007. The general trend of water quality gradually has been decreased in the study period. Clearly, there is a need to improve the water quality in the Tuul River in surrounding area of the Ulaanbaatar. In order to change this situation, operation enhancement of treatment plants, a water quality modeling and artificial increment of dissolved oxygen concentrations become crucial to improve the water quality significantly. Perhaps a new wastewater treatment plant is needed for Ulaanbaatar city.

A STUDY ON QUALITY OF AQUATIC ENVIRONMENT IN TUMEN RIVER AREA

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Indoor Air Quality in the United Arab Emirates

Air quality was measured inside 628 United Arab Emirates (UAE) personal residences. Weekly average concentrations of carbon monoxide (CO), formaldehyde (HCHO), hydrogen sulfide (H2S), nitrogen dioxide (NO2), sulfur dioxide (SO2), and three size fractions of particulate matter (PM2.5, PMc, and PM10) were determined in each home. In a subset of the homes, measurements of outdoor air quality, ultrafine PM concentrations, and elemental PM concentrations were also made. Questionnaires were administered to obtain information on housing demographics and lifestyle habits. Air measurements were performed using simple and cost effective passive samplers. The 90th percentiles of indoor CO, HCHO, H2S, NO2, and SO2 were 1.55 ppm, 0.05 ppm, 0.12 ppm, 0.01 ppm, and 0.05 ppm, respectively. Median indoor PM2.5, PMc, and PM10, concentrations were 5.73 μg/m3, 29.4 μg/m3, and 35.2 μg/m3, respectively. The median indoor concentration of ultrafine PM was 3.62 × 1010 particles/m3. Indoor/outdoor ratios for PM were 0.44, 0.41, and 0.38 for ultrafine PM, PM2.5, and PM10, respectively. These values fall within the range of other indoor air studies findings conducted in developing countries. Air conditioning, smoking, and attached kitchens were significantly correlated with indoor levels of carbon monoxide. In addition, indoor concentrations of PM2.5 and PM10 were significantly correlated with vehicles parked within five meters of the home, central air conditioning, and having attached kitchens. This is the first robust indoor air quality data set developed for the UAE. This study demonstrates that screening level tools are a good initial step for assessing air quality when logistical issues (distance, language, cultural, training) and intrusion into personal lives need to be minimized.

Assessment of Spring Water Quality in the Rural Watersheds of Western Nepal

A preliminary study was conducted to analyze the water quality of spring waters in rural watershed of Western Nepal. 155 spring water samples were collected from Jhimruk, Rangun, Bogtan-Lagam Karnali, Thuligad and Middle Karnali watershed. Collection and analysis occurred twice, once in pre-monsoon 2018 and post-monsoon 2018. Various physical and chemical parameters were analyzed by using standard water quality measurements and compared with the Nepal Drinking Water Quality Standard and the World Health Organization Standard Guideline. The results indicate that the turbidity was high during pre-monsoon season. The highest turbidity of 63.8 NTU was observed in the Bogtan-Lagam Karnali watershed. Two spring sources—one in Bogtan-Lagam Karnali and one in Middle Karnali exceeded the health standard for nitrate-N. The phosphate levels were high during the pre-monsoon season in Jhimruk and Rangun watershed in all the studied sites. Dissolved oxygen levels were relatively high during post-monsoon season. Results of the water quality index in all the studied sites revealed that the water quality ranges from being poor to good conditions in the spring sources. The results from this study suggested that the water bodies are relatively good and can be used for domestic purposes after suitable treatment.

Analysis of air quality characteristics of Beijing–Tianjin–Hebei and its surrounding air pollution transport channel cities in China

Beijing–Tianjin–Hebei(BTH)and its surrounding areas are very important to air pollution control in China.To analyze the characteristics of BTH and its surrounding areas of China,we collected 5,641,440 air quality data from 161 air monitoring stations and 37,123,000 continuous monitoring data from air polluting enterprises in BTH and surrounding cities to establish an indicator system for urban air quality portraits.The results showed that particulate matter with aerodynamic diameters of<2.5μm(PM2.5),particulate matter with aerodynamic diameters of<10μm(PM10)and SO2 improved significantly in 31 cities from2015 to 2018,but ozone deteriorated.Air quality in BTH and the surrounding areas showed obvious seasonal characteristics,among which PM2.5,PM10,SO2,and NO2 showed a"U"type distribution from January to December,while O3 had an"inverted U"distribution.The hourly changes in air quality revealed that peaks of PM2.5,PM10 and NO2 appeared from 8:00 to 10:00,while those for O3 appeared at 15:00–16:00.The exposure characteristics of the 31 cities showed that six districts in Beijing had the highest air quality population exposure,and that exposure levels in Zhengzhou,Puyang,Anyang,Jincheng were higher than the average of the 31 investigated cities.Additionally,multiple linear regression revealed a negative correlation between meteorological factors(especially wind and precipitation)and air quality,while a positive correlation existed between industrial pollution emissions and air quality in most of BTH and its surrounding cities.

Modeling the effects of constructed wetland on nonpoint source pollution control and reservoir water quality improvement

This article describes the integrated modeling approach for planning the size and the operation of constructed wetlands for maximizing retention of nonpoint source pollutant loads and reservoir water-quality improvement at a catchment scale. The experimental field-scale wetland systems （four sets, 0.88 ha each） have been in operation since 2002, where water depth was maintained at 30-50 cm and hydraulic loading rate was at 6.3-18.8 cm/day. The wetland system was found to be adequate for treating polluted stream water with stable removal efficiency even during the winter. The integrated modeling system （modified-BASINS） was applied to the Seokmoon estuarine reservoir watershed and calibrated with monitoring data from constructed wetland, stream, and reservoir. The calibrated integrated modeling system estimated that constructing wetlands on 0.5% （about 114 ha） of the watershed area at the mouth of reservoir could reduce 11.61% and 13.49% of total external nitrogen and phosphorus loads, respectively. It also might improve the nitrogen and phosphorus concentration of the reservoir by 9.69% and 16.48%, respectively. The study suggested that about 0.1%-1.0% of the watershed area should be allocated for constructed wetland to meet specified water-quality standards for the estuarine reservoir at the polder area where land use planning is relatively less complicated.

Analysis of Water Pollution Factors in the Downstream Water Functional Area of Songyuan City of the Songhua River

Jihei buffer zone of the Second Songhua River in lower reaches of Songyuan City of the Songhua River was taken as the research object,and the current water quality,point source and non-point source pollution,and regional social and economic conditions of the buffer zone and its upstream water functional area were investigated.According to pollution sources and pollutant carrying capacity of water functional areas,analysis on main pollution factors in buffer zone was completed.

An Improved Reverse Auction for Addressing Water Quality in Agricultural Watersheds Using Coupled Simulation-Optimization Models

As nutrients and sediment in agricultural watersheds continue to degrade water quality, attention is increasingly given to reverse auctions to cost-effectively address these pollutants. Typically, reverse auctions include a selection process which depends on both the monetary bid and a ranking of the environmental benefit, where the latter is often approximated using simple models, such as the Universal Soil Loss Equation （USLE）. When the environmental objective is to improve water quality, the cost-effectiveness of such ranking methods cannot always be assured since simple models may poorly approximate the effects on downstream water quality. In this paper, we introduce an alternative reverse auction approach that takes advantage of richer watershed process models and optimization tools that are now much more commonly available. This ＂improved＂ reverse auction allows decision-makers to better consider the cost-effective assignment of conservation practices and to address water quality or other environmental objectives. In a spatially detailed simulation, we demonstrate how this approach can improve the design of a reverse auction for the Raccoon River Watershed in Iowa, and estimate the potential gains from using the simulation-optimization approach relative to simpler ranking methods for selecting bids. We also point out that simple bid ranking schemes may not yield sufficient nutrient reductions to achieve water quality goals but bids areeasily selected to achieve any feasible water quality improvement in the ＂improved＂ auction process.

Research and Application of Pollution Control in the Middle Reach of Ashe River by Multi-Objective Optimization

Based on one-dimensional water quality model and nonlinear programming, the point source pollution reduction model with multi-objective optimization has been established. To achieve cost effective and best water quality, for us to optimize the process, we set pollutant concentration and total amount control as constraints and put forward the optimal pollution reduction control strategy by simulating and optimizing water quality monitoring data from the target section. Integrated with scenario analysis, COD and ammonia nitrogen pollution optimization wasstudiedin objective function area from Mountain Maan of Acheng to Fuerjia Bridge along Ashe River. The results showed that COD and NH3-N contribution has been greatly reduced to AsheRiverby 49.6% and 32.7% respectively. Therefore, multi-objective optimization by nonlinear programming for water pollution control can make source sewage optimization fairly and reasonably, and the optimal strategies of pollution emission are presented.

On the Limits to Manage Air-Quality in Glacier Bay

In Glacier Bay National Park, about 95% of the visitors come on board of cruise ships. The National Park Service has the mandate to manage park resources like air quality and visibility, while ensuring visitation. To understand the impact of cruise-ship emissions on the overall concentrations in Glacier Bay, emission-source contribution ratios (ESCR) and the interaction of pollutant from local and/or distant sources were determined using results from four WRF/Chem simulations of the 2008 tourist season (May 15 to September 15). These simulations only differed by the emissions considered: Biogenic emissions only (CLN), biogenic plus activity-based cruise-ship emissions (REF), biogenic plus all anthropogenic emissions except cruise-ship emissions (RETRO), and all aforementioned emissions (ALL). In general, ESCRs differed among pollutants. Interaction between pollutants from cruise-ship emissions and species from other sources including those advected into the bay decreased towards the top of the atmospheric boundary layer. Pollutants from different sources interacted strongest (lowest) in the west arm of the fjord where ships berthed for glacier viewing (in areas of the bay without cruise-ship travel). Pollutant interaction both enhanced/reduced NO2 concentrations by 10% (4 - 8 ppt absolute). Except for ozone, cruise-ship emissions on average governed air quality in the bay. On days with cruise-ship visits, they contributed between 60% and 80% of the bay-wide daily mean SO2 and NO2 concentrations below 1 km height. On days without visits, cruise-ship contributions still reached 40% due to previous visits. Highest cruise-ship ESCRs occurred during stagnant weather conditions. Despite the fact that all coarse particulate matter was due to anthropogenic sources, worst visibility conditions were due to meteorology. The results suggest limits as well as windows for managing air quality and visibility in Glacier Bay.

基于AquaCrop模型的水稻多目标灌溉制度优化研究

【目的】优化现有水稻灌溉制度,节约灌溉用水量,减少稻田氮磷流失量以降低面源污染风险。【方法】构建了基于AquaCrop模型和NSGA-Ⅱ算法的水稻灌溉制度模拟优化模型,利用水稻田间试验数据,开展以产量最大、氮磷流失量最小、灌水次数最少的3种目标组合(产量-氮磷流失量(Y-TNP)、产量-灌水次数(Y-N)、产量-氮磷流失量-灌水次数(Y-TNP-N))下的灌溉制度优化模型研究,提出适应不同生育期降水年型的稳产-控污-提效灌溉制度。【结果】(1)与常规灌溉相比,Y-TNP灌溉制度优化水稻产量下降2.14%,氮磷流失量减少23.09%;Y-N灌溉制度优化水稻产量下降1.76%,灌水次数减少53%;Y-TNP-N灌溉制度优化水稻产量下降2.64%,氮磷流失量减少22.83%,灌水次数减少2次。(2)不同典型年以Y-TNP-N为目标优化的稳产-控污-提效灌溉制度水稻产量介于7.74~7.78 t/hm^(2),同时大幅度减少灌水量进而降低氮磷流失量。【结论】AquaCrop模型可模拟试验区水稻的生长发育过程,本文构建的模拟-优化耦合模型可用于优化不同生育期降水年型下稳产-控污-提效的灌溉制度。

异龙湖流域水源污染调查及原位降氮关键技术研究

为确保颜洞、燕子洞提水回补异龙湖水体水质满足要求,对异龙湖流域泸江河团山—颜洞—燕子洞段水质状况和污染源开展了调查分析,结合该河段水质污染现状,设计了河道全方位的拦截、吸收、净化等措施组合的原位河流治理系统方案并开展了试验验证。结果表明:该河段污染严重,总氮质量浓度严重超标,岩溶污染突出,水质类别属于Ⅳ类及Ⅳ类以下;原位河流治理系统方案可使河道水质总氮污染得到明显改善,模拟河道上覆水、间隙水总氮质量浓度呈下降趋势,对上覆水总氮的实际平均削减率为49.99%。

水稻灌区面源污染治理研究进展

水稻生育期与雨热同期导致灌排机率高,也导致化肥中的氮磷伴随地表径流产生大量流失成为稻作区农业面源污染的主要来源。通过对水稻高效节水灌溉制度、农田退水污染迁移转化机理和灌区退水污染协同调控技术等方面国内外研究动态系统分析,并结合国家和学科发展需求,从退水污染机理解析、灌区水资源调配模拟、灌区面源水污协同调控等方面提出了稻作区面源污染治理研究中亟待解决的关键科学问题,以期为我国农业面源污染防控提供借鉴。

峡谷型水源水库蓄水过程水质变化特征及其影响要素

水源水库是城镇居民最主要的饮用水水源,新建水库选取引水水质一般较好,然而由于水库蓄水过程中水质受到降雨径流入库、水动力条件和分层结构变化的共同影响,库区水体水质仍可能呈恶化趋势.本研究重点探索水库蓄水过程中水质演变规律,解析水源水库污染特征.以固定频率取样检测的方法,跟踪监测陕西省汉中市三河口水库蓄水过程上游河道及库区水质,分析上游来水水质、库区水体分层结构及水动力条件等要素的改变对水库水质的影响.结果表明:①2021年6−7月三河口首次较大流量蓄水过程受来水温度影响,来流水体以底部潜流的形式进入库区,并在底部形成新的温度分层;双温跃层结构的形成导致在水体中部和底部各自形成厚度达15和10 m的厌氧水层.②9月初第二次特大流量径流入库彻底破坏水体热分层结构,水体在径流和气温的共同作用下实现完全混合.③水源水库蓄水过程水质受入库径流与水体分层结构共同影响:6−8月水库入库径流量小且污染负荷低,库区氮磷及有机物浓度有较小波动,而热分层结构阻碍了污染物的垂向传递,温跃层水体总氮浓度和高锰酸盐指数在垂向上呈较大值,分别为1.78和6.0 mg/L;8月至9月初入库径流量大且污染负荷较高,全库区氮磷及有机污染物浓度升高明显,总氮浓度由1.07 mg/L升至1.56 mg/L,总磷浓度由0.021 mg/L升至0.029 mg/L,高锰酸盐指数平均值由5.18 mg/L升至6.18 mg/L.水库蓄水过程中,上游径流入库是影响主库区水质的重要因素之一.