As one of the regions most affected by global climate warming,the Tianshan mountains has experienced several ecological crises,including retreating glaciers and water deficits.Climate warming in these mountains is con...As one of the regions most affected by global climate warming,the Tianshan mountains has experienced several ecological crises,including retreating glaciers and water deficits.Climate warming in these mountains is considered mainly to be caused by increases in minimum temperatures and winter temperatures,while the influence of maximum temperatures is unclear.In this study,a 300-year tree-ring chronology developed from the Western Tianshan Mountains was used to reconstruct the summer(June-August)maximum temperature(Tmax6-8) variations from 1718 to2017.The reconstruction explained 53.1% of the variance in the observed Tmax6-8.Over the past 300 years,the Tmax6-8reconstruction showed clear interannual and decadal variabilities.There was a significant warming trend(0.18 ℃/decade) after the 1950s,which was close to the increasing rates of the minimum and mean temperatures.The increase in maximum temperature was also present over the whole Tianshan mountains and its impact on climate warming has increased.The Tmax6-8variations in the Western Tianshan mountains were influenced by frequent volcanic eruptions combined with the influence of solar activity and the summer North Atlantic Oscillation.This study reveals that climate warming is significantly influenced by the increase in maximum temperatures and clarifies possible driving mechanisms of temperature variations in the Western Tianshan mountains which should aid climate predictions.展开更多
As one of the regions most affected by global cli-mate warming,the Tianshan mountains has experienced sev-eral ecological crises,including retreating glaciers and water deficits.Climate warming in these mountains is c...As one of the regions most affected by global cli-mate warming,the Tianshan mountains has experienced sev-eral ecological crises,including retreating glaciers and water deficits.Climate warming in these mountains is considered mainly to be caused by increases in minimum temperatures and winter temperatures,while the influence of maximum temperatures is unclear.In this study,a 300-year tree-ring chronology developed from the Western Tianshan Moun-tains was used to reconstruct the summer(June-August)maximum temperature(T_(max6-8))variations from 1718 to 2017.The reconstruction explained 53.1% of the variance in the observed T_(max6-8).Over the past 300 years,the T_(max6-8)reconstruction showed clear interannual and decadal vari-abilities.There was a significant warming trend(0.18°C/decade)after the 1950s,which was close to the increasing rates of the minimum and mean temperatures.The increase in maximum temperature was also present over the whole Tianshan mountains and its impact on climate warming has increased.The T_(max6-8) variations in the Western Tianshan mountains were influenced by frequent volcanic eruptions combined with the influence of solar activity and the sum-mer North Atlantic Oscillation.This study reveals that cli-mate warming is significantly influenced by the increase in maximum temperatures and clarifies possible driving mech-anisms of temperature variations in the Western Tianshan mountains which should aid climate predictions.展开更多
A new temperature compensation technique for ring-oscillator-based ADCs is proposed. This technique employs a novelcfixed-number-based algorithm and CTAT current biasing technology to compensate the temperature-depend...A new temperature compensation technique for ring-oscillator-based ADCs is proposed. This technique employs a novelcfixed-number-based algorithm and CTAT current biasing technology to compensate the temperature-dependent variations of the output, thus eliminating the need for digital calibrations. Simulation results prove that, with the proposed technique,the resolution in the temperature range of 0 to 100℃ can reach a 2mV quantization bin size with an input voltage span of 120mV at the sampling frequency of fs = 100kHz.展开更多
Having analyzed the tree ring width and maximum latewood density of Pinus densata from west Sichuan, we obtained different climate information from tree-ring width and maximum latewood density chronology. The growth o...Having analyzed the tree ring width and maximum latewood density of Pinus densata from west Sichuan, we obtained different climate information from tree-ring width and maximum latewood density chronology. The growth of tree ring width was responded princi- pally to the precipitation in current May, which might be influenced by the activity of southwest monsoon, whereas the maximum latewood density reflected summer temperature (June-September). According to the correlation relationship, a transfer function had been used to reconstruct summer temperature for the study area. The explained variance of reconstruction is 51% (F=52.099, p〈0.0001). In the reconstruction series: before the 1930s, the climate was relatively cold, and relatively warm from 1930 to 1960, this trend was in accordance with the cold-warm period of the last 100 years, west Sichuan. Compared with Chengdu, the warming break point in west Sichuan is 3 years ahead of time, indicating that the Tibetan Plateau was more sensitive to temperature change. There was an evident summer warming signal after 1983. Although the last 100-year running average of summer temperature in the 1990s was the maximum, the running average of the early 1990s was below the average line and it was cold summer, but summer drought occurred in the late 1990s.展开更多
The search for two-dimensional(2D)nodal ring semimetallic materials is a current research hotspot in spintronics,and designing a 2D nodal ring(NR)material with high Curie temperature(TC)and strong robustness to spin-o...The search for two-dimensional(2D)nodal ring semimetallic materials is a current research hotspot in spintronics,and designing a 2D nodal ring(NR)material with high Curie temperature(TC)and strong robustness to spin-orbit coupling(SOC)is an even greater challenge.Here,based on the first-principles calculations and symmetry analysis,we predict that 2D Mn_(2)N_(3)is a nodal ring semimetal(NRSM)with three energy bands near the Fermi energy level consisting of electrons in the same spin channel.An electron-like energy band and two hole-like energy bands near the Fermi plane cross to form two NRs centered at the pointΓ.Symmetry analysis shows that the spin-polarized NR semimetal is robust to SOC due to the conservation of horizontal mirror symmetry.Monte-Carlo simulations further demonstrate that the TCof the 2D Mn_(2)N_(3)reaches 530 K,well above the room temperature.Notably,the 2D Mn_(2)N_(3)remains an NRSM on h-BN substrate.Our results not only reveal a general framework for designing 2D NR materials,but also promote further research in the direction of multifunctional quantum devices for spintronics.展开更多
The monthly mean temperature for October in the Fenglin National Natural Reserve of Wuying, in Heilongjiang province, was reconstructed for the period running from 1796 to 2004 using RES tree ring chronology. The expl...The monthly mean temperature for October in the Fenglin National Natural Reserve of Wuying, in Heilongjiang province, was reconstructed for the period running from 1796 to 2004 using RES tree ring chronology. The explained variance of the reconstruction is 34.8%. In the past 209 years, there are 4 colder and 4 warmer periods according to the reconstructed series. A period of 3.33-year is found significant based on the power spectrum method. Abrupt changes are also detected in the reconstructed series with 30-year time scale based on the smoothing t-test, smoothing F-test and Le Page test methods. Significant abrupt changes in mean value are observed for around 1871 and 1900, and a significant abrupt change in standard deviation is observed for around 1851.展开更多
Tree-ring standardized chronologies are developed by 78 cores collected from the eastern and western Helan Mountain. Statistical analysis shows that both the STD and RES chronologies correlate negatively with the temp...Tree-ring standardized chronologies are developed by 78 cores collected from the eastern and western Helan Mountain. Statistical analysis shows that both the STD and RES chronologies correlate negatively with the temperature of different periods of early half year, especially with January to August mean (JA) temperature, which means that JA temperature is one of the predominant limiting factors of tree growth in the Helan Mountain. Based on this analysis, we reconstructed JA temperature, and the explained variance is 43.3% (F=21.422, p〈0.001 ). The comparatively high temperature periods in the reconstruction were: 1805-1818 1828-1857, 1899-1907, 1919-1931 and 1968-1995; and the comparatively low temperatu re periods happened in 1858-1872, 1883-1895 and 1935-1953. Ten-year moving average curve shows three slow uplifting trends: 1766-1853, 1862-1931 and 1944-1995. Each temperature increase was followed by a sudden temperature decrease about 10 years, that is to say, the JA temperature in the Helan Mountain is characterized by slow increase and sudden decrease. The 70- and 10.77-year periodicities detected in the temperature series correspond to the Gleissberg (80-year) and Schwabe (11-year) periodicities of solar activity respectively, the 2.11-2.62 years cycles are considered to be influenced by QBO (Quasi-Biennial-Oscillation) and the local environmental change.展开更多
Long-term temperature variability has significant effects on runoff into the upper reaches of inland rivers. This paper developed a tree-ring chronology of Qilian juniper (Sabina przewalskii Kom.) from the upper tree-...Long-term temperature variability has significant effects on runoff into the upper reaches of inland rivers. This paper developed a tree-ring chronology of Qilian juniper (Sabina przewalskii Kom.) from the upper tree-line of the middle Qilian Mountains within the upper reaches of Heihe River Basin, Northwest China for a long-term reconstruction of temperature at the study site. In this paper, tree-ring chronology was used to examine climate-growth associations considering local climate data obtained from Qilian Meteorological Station. The results showed that temperatures correlated extremely well with standardized growth indices of trees (r=0.564, P<0.001). Tree-ring chronology was highest correlated with annual mean temperature (r=0.641, P<0.0001). Annual mean temperature which spans the period of 1445–2011 was reconstructed and explained 57.8% of the inter-annual to decadal temperature variance at the regional scale for the period 1961–2011. Spatial correlation patterns revealed that reconstructed temperature data and gridded temperature data had a significant correlation on a regional scale, indicating that the reconstruction represents climatic variations for an extended area surrounding the sampling sites. Analysis of the temperature reconstruction indicated that major cold periods occurred during the periods of 1450s–1480s, 1590s–1770s, 1810s–1890s, 1920s–1940s, and 1960s–1970s. Warm intervals occurred during 1490s–1580s, 1780s–1800s, 1900s–1910s, 1950s, and 1980s to present. The coldest 100-year and decadal periods occurred from 1490s–1580s and 1780s–1800s, respectively, while the warmest 100 years within the studied time period was the 20<sup>th</sup> century. Colder events and intervals coincided with wet or moist conditions in and near the study region. The reconstructed temperature agreed well with other temperature series reconstructed across the surrounding areas, demonstrating that this reconstructed temperature could be used to evaluate regional climate change. Compared to the tree-ring reconstructed temperature from nearby regions and records of glacier fluctuations from the surrounding high mountains, this reconstruction was reliable, and could aid in the evaluation of regional climate variability. Spectral analyses suggested that the reconstructed annual mean temperature variation may be related to large-scale atmospheric–oceanic variability such as the solar activity, Pacific Decadal Oscillation (PDO) and El Ni?o–Southern Oscillation (ENSO).展开更多
This work aimed at investigating the feasibility of surface modification of cellulose nanocrystals (CNCs) using <em>in situ</em> ring opening polymerization of <em>ε</em>-caprolactone (<em&...This work aimed at investigating the feasibility of surface modification of cellulose nanocrystals (CNCs) using <em>in situ</em> ring opening polymerization of <em>ε</em>-caprolactone (<em>ε</em>-CL) at room temperature. Residues of flax and milkweed (<em>Asclepias syriaca</em>) stem fibers were used as a source of cellulose to obtain and isolate CNCs. The cationic ring opening polymerization (CROP) of the monomer <em>ε</em>-CL was used to covalently graft polycaprolactone (PCL) chains at the CNCs surface. Silver hexafluoroantimonate (AgSbF<sub>6</sub>) was used in combination with the extracted CNCs to initiate, at room temperature, the polymerization and the grafting reactions with no other stimulus. Fourier-Transform InfraRed (FTIR), X-ray Photoelectron Spectrometry (XPS), UV/visible absorption and Gel Permeation Chromatography (GPC) analyses evidenced the presence of PCL chains covalently grafted at CNCs surface, the formation of Ag(0) particles as well as low or moderate molecular weight free PCL chains.展开更多
We have developed a 202-year tree-ring width chronology of Shensi fir(Abies chensiensis) growing in an open canopy forest at the treeline of the eastern Qinling Mountains. Climate response analyses revealed that the r...We have developed a 202-year tree-ring width chronology of Shensi fir(Abies chensiensis) growing in an open canopy forest at the treeline of the eastern Qinling Mountains. Climate response analyses revealed that the ring width of Shensi fir trees is primarily controlled by the range of temperature from February–June. The regression model that we used for statistical temperature reconstruction passed the leave-one-out cross-validation used in dendroclimatology, resulting in a quality-controlled February–June reconstruction for the eastern Qinling Mountains. The model accounts for 36.7% of the instrumental temperature variance during the period of 1960–2012. Warm springs and early summers occurred during AD 1870–1873, 1909–1914, 1927–1958 and 1997–2012, while the periods of AD 1874–1908, 1915–1926 and 1959–1996 were relatively cold. Spatial climate correlation analyses with gridded land surface data revealed that our temperature reconstruction contains a strong regional temperature signal for central China. The linkages of ourtemperature reconstruction with sea surface temperature in the Atlantic and Pacific oceans suggest the connection of regional temperature variations to large-scale ocean–atmosphere–land circulation. Preliminary analysis of links between large-scale climatic variation and the temperature reconstruction also shows that there is a relationship between extremes in spring and early summer temperature and anomalous atmospheric circulation in the Qinling Mountains. Overall, our study provides reliable information for the research of past temperature variability in the Qinling Mountains, China.展开更多
SiC/Cu composites were prepared by hot pressing. The high temperature tribological properties of the composites were investigated. XRD, SEM techniques were carried out to characterize the samples. It is found that the...SiC/Cu composites were prepared by hot pressing. The high temperature tribological properties of the composites were investigated. XRD, SEM techniques were carried out to characterize the samples. It is found that the friction coefficient of SiC/Cu composites increases with the increasing SiC content. The SiC reinforcement particles are worn down other than removed by pulling out during the wear test. Oxidation of Cu debris leads to the smooth contacting surface. Ring crack is formed under the cyclic wear test. The crack propagates through the damaged matrix and along the brittle interface between SiC particles and Cu matrix.展开更多
Based on two tree-ring maximum latewood density (MXD) chronologies of Picea schrenkiana from the Manas River Basin, Xinjiang, the response characteristics of MXD to climate variation was discussed. Correlation analy...Based on two tree-ring maximum latewood density (MXD) chronologies of Picea schrenkiana from the Manas River Basin, Xinjiang, the response characteristics of MXD to climate variation was discussed. Correlation analysis between MXD chronologies and instrumental records from Shihezi meteorological station showed that each chronology was significantly and positively correlated with the maximum monthly average temperature in July-August, and especially, the regional chronology (RC) was the most highly correlated variable (r=0.54, P〈0.001). Afterwards, the maximum average temperature in July-August was reconstructed using RC. Comparison among reconstructed temperature, observed values, and the drought index (Is) confirmed that precipitation would affect MXD when the absolute value of Is is greater than 1.5σ (|Is| 〉 2.5 during 1953-2008) or near to 1.5a over a 2-3 year period. The response characteristics are related to the semiarid climate of the study area. In dry years, lack of precipitation would limit the thickening of latewood cell walls and, as a result, impact MXD. Therefore, compared with relatively humid regions, the response of tree-ring MXD to air temperature similarly would be influenced by extreme moisture conditions in semiarid areas, and MXD, as a temperature proxy, should be used prudently on a limited scale.展开更多
基金supported by the Second Tibetan Plateau Scientific Expedition and Research(2019QZKK0101)the China Desert Meteorological Science Research Foundation(Sqj2022012)+3 种基金the Natural Science Basic Research Program of Shaanxi Province(2023-JC-QN-0307)the National Natural Science Foundation of China(42361144712)the Chinese Academy of Sciences(XDB40010300)the State Key Laboratory of Loess and Quaternary Geology,Institute of Earth Environment,CAS(SKLLQG2022).
文摘As one of the regions most affected by global climate warming,the Tianshan mountains has experienced several ecological crises,including retreating glaciers and water deficits.Climate warming in these mountains is considered mainly to be caused by increases in minimum temperatures and winter temperatures,while the influence of maximum temperatures is unclear.In this study,a 300-year tree-ring chronology developed from the Western Tianshan Mountains was used to reconstruct the summer(June-August)maximum temperature(Tmax6-8) variations from 1718 to2017.The reconstruction explained 53.1% of the variance in the observed Tmax6-8.Over the past 300 years,the Tmax6-8reconstruction showed clear interannual and decadal variabilities.There was a significant warming trend(0.18 ℃/decade) after the 1950s,which was close to the increasing rates of the minimum and mean temperatures.The increase in maximum temperature was also present over the whole Tianshan mountains and its impact on climate warming has increased.The Tmax6-8variations in the Western Tianshan mountains were influenced by frequent volcanic eruptions combined with the influence of solar activity and the summer North Atlantic Oscillation.This study reveals that climate warming is significantly influenced by the increase in maximum temperatures and clarifies possible driving mechanisms of temperature variations in the Western Tianshan mountains which should aid climate predictions.
基金This study was supported by the Second Tibetan Plateau Scientific Expedition and Research(2019QZKK0101)the China Desert Meteorological Science Research Foundation(Sqj2022012)+3 种基金the Natural Science Basic Research Program of Shaanxi Province(2023-JC-QN-0307)the National Natural Science Foundation of China(42361144712)the Chinese Academy of Sciences(XDB40010300)the State Key Laboratory of Loess and Quaternary Geology,Institute of Earth Environment,CAS(SKLLQG2022).
文摘As one of the regions most affected by global cli-mate warming,the Tianshan mountains has experienced sev-eral ecological crises,including retreating glaciers and water deficits.Climate warming in these mountains is considered mainly to be caused by increases in minimum temperatures and winter temperatures,while the influence of maximum temperatures is unclear.In this study,a 300-year tree-ring chronology developed from the Western Tianshan Moun-tains was used to reconstruct the summer(June-August)maximum temperature(T_(max6-8))variations from 1718 to 2017.The reconstruction explained 53.1% of the variance in the observed T_(max6-8).Over the past 300 years,the T_(max6-8)reconstruction showed clear interannual and decadal vari-abilities.There was a significant warming trend(0.18°C/decade)after the 1950s,which was close to the increasing rates of the minimum and mean temperatures.The increase in maximum temperature was also present over the whole Tianshan mountains and its impact on climate warming has increased.The T_(max6-8) variations in the Western Tianshan mountains were influenced by frequent volcanic eruptions combined with the influence of solar activity and the sum-mer North Atlantic Oscillation.This study reveals that cli-mate warming is significantly influenced by the increase in maximum temperatures and clarifies possible driving mech-anisms of temperature variations in the Western Tianshan mountains which should aid climate predictions.
文摘A new temperature compensation technique for ring-oscillator-based ADCs is proposed. This technique employs a novelcfixed-number-based algorithm and CTAT current biasing technology to compensate the temperature-dependent variations of the output, thus eliminating the need for digital calibrations. Simulation results prove that, with the proposed technique,the resolution in the temperature range of 0 to 100℃ can reach a 2mV quantization bin size with an input voltage span of 120mV at the sampling frequency of fs = 100kHz.
基金National Natural Science Foundation of China, No.30270227 No.90102005+1 种基金 Knowledge Innovation Project of the CAS, No.KZCX3-SW-321 No.KZCX 1-10-02
文摘Having analyzed the tree ring width and maximum latewood density of Pinus densata from west Sichuan, we obtained different climate information from tree-ring width and maximum latewood density chronology. The growth of tree ring width was responded princi- pally to the precipitation in current May, which might be influenced by the activity of southwest monsoon, whereas the maximum latewood density reflected summer temperature (June-September). According to the correlation relationship, a transfer function had been used to reconstruct summer temperature for the study area. The explained variance of reconstruction is 51% (F=52.099, p〈0.0001). In the reconstruction series: before the 1930s, the climate was relatively cold, and relatively warm from 1930 to 1960, this trend was in accordance with the cold-warm period of the last 100 years, west Sichuan. Compared with Chengdu, the warming break point in west Sichuan is 3 years ahead of time, indicating that the Tibetan Plateau was more sensitive to temperature change. There was an evident summer warming signal after 1983. Although the last 100-year running average of summer temperature in the 1990s was the maximum, the running average of the early 1990s was below the average line and it was cold summer, but summer drought occurred in the late 1990s.
基金Project supported by Taishan Scholar Program of Shandong Province,China(Grant No.ts20190939)Independent Cultivation Program of Innovation Team of Jinan City(Grant No.2021GXRC043)National Natural Science Foundation of China(Grant Nos.52173283 and 62071200)
文摘The search for two-dimensional(2D)nodal ring semimetallic materials is a current research hotspot in spintronics,and designing a 2D nodal ring(NR)material with high Curie temperature(TC)and strong robustness to spin-orbit coupling(SOC)is an even greater challenge.Here,based on the first-principles calculations and symmetry analysis,we predict that 2D Mn_(2)N_(3)is a nodal ring semimetal(NRSM)with three energy bands near the Fermi energy level consisting of electrons in the same spin channel.An electron-like energy band and two hole-like energy bands near the Fermi plane cross to form two NRs centered at the pointΓ.Symmetry analysis shows that the spin-polarized NR semimetal is robust to SOC due to the conservation of horizontal mirror symmetry.Monte-Carlo simulations further demonstrate that the TCof the 2D Mn_(2)N_(3)reaches 530 K,well above the room temperature.Notably,the 2D Mn_(2)N_(3)remains an NRSM on h-BN substrate.Our results not only reveal a general framework for designing 2D NR materials,but also promote further research in the direction of multifunctional quantum devices for spintronics.
基金supported by the Special Research Program for Public-welfare Forestry(No. 200804001)National Science and Technology Support Program(No.2007BAC29B01)the Natural Science Foundation of China(No.40705032)
文摘The monthly mean temperature for October in the Fenglin National Natural Reserve of Wuying, in Heilongjiang province, was reconstructed for the period running from 1796 to 2004 using RES tree ring chronology. The explained variance of the reconstruction is 34.8%. In the past 209 years, there are 4 colder and 4 warmer periods according to the reconstructed series. A period of 3.33-year is found significant based on the power spectrum method. Abrupt changes are also detected in the reconstructed series with 30-year time scale based on the smoothing t-test, smoothing F-test and Le Page test methods. Significant abrupt changes in mean value are observed for around 1871 and 1900, and a significant abrupt change in standard deviation is observed for around 1851.
基金National Natural Science Foundation of China, No.40525004 No.40599420+2 种基金 No.90211081 No.40531003 No.40121303
文摘Tree-ring standardized chronologies are developed by 78 cores collected from the eastern and western Helan Mountain. Statistical analysis shows that both the STD and RES chronologies correlate negatively with the temperature of different periods of early half year, especially with January to August mean (JA) temperature, which means that JA temperature is one of the predominant limiting factors of tree growth in the Helan Mountain. Based on this analysis, we reconstructed JA temperature, and the explained variance is 43.3% (F=21.422, p〈0.001 ). The comparatively high temperature periods in the reconstruction were: 1805-1818 1828-1857, 1899-1907, 1919-1931 and 1968-1995; and the comparatively low temperatu re periods happened in 1858-1872, 1883-1895 and 1935-1953. Ten-year moving average curve shows three slow uplifting trends: 1766-1853, 1862-1931 and 1944-1995. Each temperature increase was followed by a sudden temperature decrease about 10 years, that is to say, the JA temperature in the Helan Mountain is characterized by slow increase and sudden decrease. The 70- and 10.77-year periodicities detected in the temperature series correspond to the Gleissberg (80-year) and Schwabe (11-year) periodicities of solar activity respectively, the 2.11-2.62 years cycles are considered to be influenced by QBO (Quasi-Biennial-Oscillation) and the local environmental change.
基金The study was jointly funded by the NSFC(Grant No.90502009,40372085)the CAREERI of CAS(Grant No.2004106)Also this study is supported by the Alexander von Humboldt Foundation.
基金supported by the National Natural Science Foundation of China(91025002,30970492)the National Key Technology Research&Development Program(2012BAC08B05)the Key Project of the Chinese Academy of Sciences(KZZD-EW-04-05)
文摘Long-term temperature variability has significant effects on runoff into the upper reaches of inland rivers. This paper developed a tree-ring chronology of Qilian juniper (Sabina przewalskii Kom.) from the upper tree-line of the middle Qilian Mountains within the upper reaches of Heihe River Basin, Northwest China for a long-term reconstruction of temperature at the study site. In this paper, tree-ring chronology was used to examine climate-growth associations considering local climate data obtained from Qilian Meteorological Station. The results showed that temperatures correlated extremely well with standardized growth indices of trees (r=0.564, P<0.001). Tree-ring chronology was highest correlated with annual mean temperature (r=0.641, P<0.0001). Annual mean temperature which spans the period of 1445–2011 was reconstructed and explained 57.8% of the inter-annual to decadal temperature variance at the regional scale for the period 1961–2011. Spatial correlation patterns revealed that reconstructed temperature data and gridded temperature data had a significant correlation on a regional scale, indicating that the reconstruction represents climatic variations for an extended area surrounding the sampling sites. Analysis of the temperature reconstruction indicated that major cold periods occurred during the periods of 1450s–1480s, 1590s–1770s, 1810s–1890s, 1920s–1940s, and 1960s–1970s. Warm intervals occurred during 1490s–1580s, 1780s–1800s, 1900s–1910s, 1950s, and 1980s to present. The coldest 100-year and decadal periods occurred from 1490s–1580s and 1780s–1800s, respectively, while the warmest 100 years within the studied time period was the 20<sup>th</sup> century. Colder events and intervals coincided with wet or moist conditions in and near the study region. The reconstructed temperature agreed well with other temperature series reconstructed across the surrounding areas, demonstrating that this reconstructed temperature could be used to evaluate regional climate change. Compared to the tree-ring reconstructed temperature from nearby regions and records of glacier fluctuations from the surrounding high mountains, this reconstruction was reliable, and could aid in the evaluation of regional climate variability. Spectral analyses suggested that the reconstructed annual mean temperature variation may be related to large-scale atmospheric–oceanic variability such as the solar activity, Pacific Decadal Oscillation (PDO) and El Ni?o–Southern Oscillation (ENSO).
文摘This work aimed at investigating the feasibility of surface modification of cellulose nanocrystals (CNCs) using <em>in situ</em> ring opening polymerization of <em>ε</em>-caprolactone (<em>ε</em>-CL) at room temperature. Residues of flax and milkweed (<em>Asclepias syriaca</em>) stem fibers were used as a source of cellulose to obtain and isolate CNCs. The cationic ring opening polymerization (CROP) of the monomer <em>ε</em>-CL was used to covalently graft polycaprolactone (PCL) chains at the CNCs surface. Silver hexafluoroantimonate (AgSbF<sub>6</sub>) was used in combination with the extracted CNCs to initiate, at room temperature, the polymerization and the grafting reactions with no other stimulus. Fourier-Transform InfraRed (FTIR), X-ray Photoelectron Spectrometry (XPS), UV/visible absorption and Gel Permeation Chromatography (GPC) analyses evidenced the presence of PCL chains covalently grafted at CNCs surface, the formation of Ag(0) particles as well as low or moderate molecular weight free PCL chains.
基金supported by the Basic Research Operating Expenses of the Central-level Non-profit Research Institutes of China (IDM201105)the Open Foundation of MOE Key Laboratory of Western China's Environmental System, Lanzhou Universitythe Fundamental Research Funds for the Central Universities (lzujbky-2011-t02)
文摘We have developed a 202-year tree-ring width chronology of Shensi fir(Abies chensiensis) growing in an open canopy forest at the treeline of the eastern Qinling Mountains. Climate response analyses revealed that the ring width of Shensi fir trees is primarily controlled by the range of temperature from February–June. The regression model that we used for statistical temperature reconstruction passed the leave-one-out cross-validation used in dendroclimatology, resulting in a quality-controlled February–June reconstruction for the eastern Qinling Mountains. The model accounts for 36.7% of the instrumental temperature variance during the period of 1960–2012. Warm springs and early summers occurred during AD 1870–1873, 1909–1914, 1927–1958 and 1997–2012, while the periods of AD 1874–1908, 1915–1926 and 1959–1996 were relatively cold. Spatial climate correlation analyses with gridded land surface data revealed that our temperature reconstruction contains a strong regional temperature signal for central China. The linkages of ourtemperature reconstruction with sea surface temperature in the Atlantic and Pacific oceans suggest the connection of regional temperature variations to large-scale ocean–atmosphere–land circulation. Preliminary analysis of links between large-scale climatic variation and the temperature reconstruction also shows that there is a relationship between extremes in spring and early summer temperature and anomalous atmospheric circulation in the Qinling Mountains. Overall, our study provides reliable information for the research of past temperature variability in the Qinling Mountains, China.
基金Funded by the National Natural Scince Foundation of China (50972132)the Science Fund for Distinguished Young Scholars of Henan Province(512002200)
文摘SiC/Cu composites were prepared by hot pressing. The high temperature tribological properties of the composites were investigated. XRD, SEM techniques were carried out to characterize the samples. It is found that the friction coefficient of SiC/Cu composites increases with the increasing SiC content. The SiC reinforcement particles are worn down other than removed by pulling out during the wear test. Oxidation of Cu debris leads to the smooth contacting surface. Ring crack is formed under the cyclic wear test. The crack propagates through the damaged matrix and along the brittle interface between SiC particles and Cu matrix.
基金Supported by Natural Science Foundation of China(41275120,41271120,41301041)Strategic Science and Technology Planning Project of Institute of Geographic Sciences and Natural Resources Research of Chinese Academy of Sciences(2012ZD001)~~
文摘Based on two tree-ring maximum latewood density (MXD) chronologies of Picea schrenkiana from the Manas River Basin, Xinjiang, the response characteristics of MXD to climate variation was discussed. Correlation analysis between MXD chronologies and instrumental records from Shihezi meteorological station showed that each chronology was significantly and positively correlated with the maximum monthly average temperature in July-August, and especially, the regional chronology (RC) was the most highly correlated variable (r=0.54, P〈0.001). Afterwards, the maximum average temperature in July-August was reconstructed using RC. Comparison among reconstructed temperature, observed values, and the drought index (Is) confirmed that precipitation would affect MXD when the absolute value of Is is greater than 1.5σ (|Is| 〉 2.5 during 1953-2008) or near to 1.5a over a 2-3 year period. The response characteristics are related to the semiarid climate of the study area. In dry years, lack of precipitation would limit the thickening of latewood cell walls and, as a result, impact MXD. Therefore, compared with relatively humid regions, the response of tree-ring MXD to air temperature similarly would be influenced by extreme moisture conditions in semiarid areas, and MXD, as a temperature proxy, should be used prudently on a limited scale.