后量子时代,基于格理论的公钥密码被认为是最有前途的抵抗量子计算机攻击的公钥密码体制.然而,相对于格上公钥加密体制和数字签名方案的快速发展,基于格上困难问题的密钥协商协议成果却较少.因此,现阶段如何构建格上安全的密钥协商协议...后量子时代,基于格理论的公钥密码被认为是最有前途的抵抗量子计算机攻击的公钥密码体制.然而,相对于格上公钥加密体制和数字签名方案的快速发展,基于格上困难问题的密钥协商协议成果却较少.因此,现阶段如何构建格上安全的密钥协商协议是密码学领域具有挑战性的问题之一.针对上述问题,基于环上带错误学习问题困难假设,采用调和技术构造了一种新的认证密钥协商协议RAKA(authenticated key agreement protocol based on reconciliation technique),该方案采用格上陷门函数技术提供了单向认证功能,并且在Ring-LWE假设下证明是安全的.与现有的基于LWE的密钥协商协议相比,该方案的共享会话密钥减小为2nlog q,效率更高;同时,由于该方案的安全性是基于格上困难问题,因此可以抵抗量子攻击.展开更多
From the general formula for calculating the efficiency of planetary geartrains, the efficiency of the double crank ring-plate-type pin-cycloidal gear planetary drive isderived. To prove the theory, an experimental st...From the general formula for calculating the efficiency of planetary geartrains, the efficiency of the double crank ring-plate-type pin-cycloidal gear planetary drive isderived. To prove the theory, an experimental study has been conducted. The tested value of theefficiency of a sample set of the new-type drive in the experiment agrees with the calculated one.It shows that the new-type drive is of not merely high bearing capacity, but also quite highefficiency.展开更多
In this paper,ring-opening polymerization of trimethylene carbonate(TMC)with rare earth(Nd,Y,La)ρ-tert- butylcalix[n]arene(n=4,6,and 8)complexes as catalysts has been studied.Poly(trimethylene carbonate)(PTMC)with M_...In this paper,ring-opening polymerization of trimethylene carbonate(TMC)with rare earth(Nd,Y,La)ρ-tert- butylcalix[n]arene(n=4,6,and 8)complexes as catalysts has been studied.Poly(trimethylene carbonate)(PTMC)with M_v of 21,400 was produced by bulk polymerization under the conditions as follows:[TMC]_0/[Nd](molar ratio)=1000,80℃, 8 h.Mechanism study reveals that the polymerization proceeds via a coordination mechanism.展开更多
Nano-ring-type magnetic tunnel junctions (NR-MTJs) with the layer structure of Ta(5)/Ir22Mn78(10)/ Co75Fe25(2)/Ru(0.75)/CoooFe20B20(3)/Al(0.6)-oxide/Co60Fe20B20(2.5)/Ta(3)/Ru(5) (thickness unit:...Nano-ring-type magnetic tunnel junctions (NR-MTJs) with the layer structure of Ta(5)/Ir22Mn78(10)/ Co75Fe25(2)/Ru(0.75)/CoooFe20B20(3)/Al(0.6)-oxide/Co60Fe20B20(2.5)/Ta(3)/Ru(5) (thickness unit: nm) were nano-fabricated on the Si(100)/SiO2 substrate using magnetron sputtering deposition combined with the optical lithography, electron beam lithography (EBL) and Ar ion-beam etching techniques. The smaller NR-MTJs with the inner- and outer-diameter of around 50 and 100 nm and also their corresponding NR-MTJ arrays were nano-patterned. The tunnelling magnetoresistance (TMR & R) versus driving current (I) loops for a spin-polarized current switching were measured, and the TMR ratio of around 35% at room temperature were observed. The critical values of switching current for the free Co60Fe20B20 layer relative to the reference Co6oFe2oB2o layer between parallel and anti-parallel magnetization states were between 0.50 and 0.75 mA in such NR-MTJs. It is suggested that the applicable MRAM fabrication with the density and capacity higher than 256 Mbit/inch2 even 6 Gbite/inch2 are possible using both I NR-MTJ+1 transistor structure and current switching mechanism based on based on our fabricated 4×4 MRAM demo devices.展开更多
The ring-opening polymerization of e-caprolactone (CL) initiated by novel single lanthanide tris(4-tert-butylphenolate)s [Ln(OTBP)3] is reported. Single-component La(OTBP)3 can effectively prepare polycaprolactone (PC...The ring-opening polymerization of e-caprolactone (CL) initiated by novel single lanthanide tris(4-tert-butylphenolate)s [Ln(OTBP)3] is reported. Single-component La(OTBP)3 can effectively prepare polycaprolactone (PCL) with over 90% yield and viscosity average molecular weight about 60 x 10 under quite mild conditions: molar ratio of CL to initiator is 1000, 60 C, 2 h in toluene. Mechanism study indicates that the monomer inserts into the growing chain via the break of acyl-oxygen bond of CL.展开更多
A series of cyclic (arylene phosphonate) oligomers were prepared by reaction of phenylphosphonic dichloride (PPD) with various bisphenols under pseudo-high dilution conditions via interfacial polycondensation. The yie...A series of cyclic (arylene phosphonate) oligomers were prepared by reaction of phenylphosphonic dichloride (PPD) with various bisphenols under pseudo-high dilution conditions via interfacial polycondensation. The yield of cyclic (arylene phosphonate) oligomers is over 85% by using hexadecyltrimethylammoniun bromide as phase transfer catalyst (PTC) at 0 'C . The structures of the cyclic oligomers were confirmed by a combination of matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF-MS) and IR analysis. These cyclic oligomers undergo facile ring-opening polymerization in the melt by using potassium 4,4'-biphenoxide as the initiator to give linear polyphosphonate. Free-radical ring-opening polymerization of cyclic(arylene phosphonate) oligomers containing sulfur linkages was also performed in the melt using 2,2'-dithiobis(benzothiazole) (DTB) as the initiator at 270 °C and the resulting polymer had a Mw, of 8 × 103 with a molecular weight distribution of 4. Ring-opening copolymerization of these cyclic oligomers with cyclic carbonate oligomers was also achieved. The average molecular weight of the resulting copolymer is higher than the corresponding homopolymer and the thermal stability of the copolymer is better than the corresponding homopolymer.展开更多
Ring-opening polymerization of ε-caprolactone has been carried out by using rare earth Schiff base complexes: lanthanide tris(N-phenyl-3,5-di-t-butylsalicylaldiminato)s [Ln(OPBS)3] as single component catalyst f...Ring-opening polymerization of ε-caprolactone has been carried out by using rare earth Schiff base complexes: lanthanide tris(N-phenyl-3,5-di-t-butylsalicylaldiminato)s [Ln(OPBS)3] as single component catalyst for the first time. The influences of different rare earth elements, monomer and catalyst concentration as well as reaction time on the polymerization were investigated. Mechanism studies showed that monomer inserts into the active site with the acyl-oxygen bond scission rather than the break of alkyl-oxygen bond.展开更多
An atmospheric-pressure argon plasma jet with screw ring-ring electrodes in surface dielectric barrier discharge is generated by a sinusoidal excitation voltage at 8 kHz. The discharge characteristics, such as rotatio...An atmospheric-pressure argon plasma jet with screw ring-ring electrodes in surface dielectric barrier discharge is generated by a sinusoidal excitation voltage at 8 kHz. The discharge characteristics, such as rotational and vibrational temperature of nitrogen, electronic excitation temperature, oxygen atomic density, nitrogen molecular density, and average electron density, are estimated. It is found that the rotational temperature of nitrogen is in the range of 352 ~ 392 K by comparing the simulated spectrum with the measured spectrum at the C3Πu → B3Πg (△ν = 2) band transition, the electronic excitation temperature is found to be in the range of 3127 ~ 3230 K by using the Boltzmann plot method, the oxygen atomic and nitrogen molecular density are of the order of magnitude of 1016 cm-3 by the actinometry method, and the average electron density is of the order of magnitude of 1012 cm-3 by the energy balance equation. Besides, the effective power, conduction, and displacement current are measured during the discharge.展开更多
The Donnell theory of shell is applied to describe shell motion and layer motion is described by means of three-dimensional Navier equations.Using deformation harmonious condi- tions of the interface,the effects of st...The Donnell theory of shell is applied to describe shell motion and layer motion is described by means of three-dimensional Navier equations.Using deformation harmonious condi- tions of the interface,the effects of stiffeners and layer are treated as reverse forces and moments acting on the cylindrical shell.In studying the acoustic field produced by vibration of the sub- merged ring-stiffened cylindrical coated shell,the structure dynamic equation,Helmholtz equation in the fluid field and the continuous conditions of the fluid-structure interface compose the cou- pling vibration equation of the sound-fluid-structure.The extract of sound pressure comes down to the extract of coupling vibration equation.By use of the solution of the equation,the influ- ences of hydrostatic pressure,physical characters and geometric parameters of the layer on sound radiation are discussed.展开更多
Exact analytical solutions of the Dirac equation are reported for the Poschl-Teller double-ring-shaped Coulomb potential.The radial,polar,and azimuthal parts of the Dirac equation are solved using the Nikiforov-Uvarov...Exact analytical solutions of the Dirac equation are reported for the Poschl-Teller double-ring-shaped Coulomb potential.The radial,polar,and azimuthal parts of the Dirac equation are solved using the Nikiforov-Uvarov method,and the exact bound-state energy eigenvalues and corresponding two-component spinor wavefunctions are reported.展开更多
Porcine pancreas lipase (PPL) and PPL immobilized on narrow distributed micron-sized glass beads wereemployed successfully for the ring-opening polymerization of 5, 5-dimethyl-1, 3-dioxan-2-one (DTC) for the first tim...Porcine pancreas lipase (PPL) and PPL immobilized on narrow distributed micron-sized glass beads wereemployed successfully for the ring-opening polymerization of 5, 5-dimethyl-1, 3-dioxan-2-one (DTC) for the first time.Different polymerization conditions such as enzyme concentration and reaction temperature were studied. Immobilized PPLexhibits higher activity than native PPL. Along wth the increasing enzyme concentration, the molecular weigh of resultingPDTC decreases. PPL immobilized on narrow distributed micron-sized glass beads has outstanding recyclability. For thethird recycle time, immobilized PPL exhibits the highest catalytic activity and with high activity even after the fifth recyletime for the synthesis of PDTC. The ~1H-NMR spectra indicate that decarboxylation does not occur during the ring-openingpolymerization.展开更多
Highly active calcium chloride(CaCl2) doped Zn-Co^Ⅲdouble metal-cyanide(Ca-DMC) catalysts were firstly reported.Ca-DMCs presented a very higher polymer yield(54 kg polymer/g catalyst) at relative low temperatur...Highly active calcium chloride(CaCl2) doped Zn-Co^Ⅲdouble metal-cyanide(Ca-DMC) catalysts were firstly reported.Ca-DMCs presented a very higher polymer yield(54 kg polymer/g catalyst) at relative low temperature(80-115℃) toward ringopening polymerization(ROP) of propylene oxide(PO) than did DMC catalysts without modification.展开更多
Following the principle of elastic floating compensation, this paper presents a new metal elastic ring for load equilibration and vibration reduction in 3-ring-gear reducer, and design and fabrivcation of a metal elas...Following the principle of elastic floating compensation, this paper presents a new metal elastic ring for load equilibration and vibration reduction in 3-ring-gear reducer, and design and fabrivcation of a metal elastic ring for SCH 3-ring-gear reducer. Comparison tests run with 3-ring-gear reducers without or with the metal elastic ring show satisfactory load equilibration and vibration reduction can be achieved with the metal elastic ring, and the metal elastic ring is a good solution for the problem of unequilibrated load and excessive vibration from which 3-ring-gear reducers suffered long.- This will further the improvement of design and application of 3-ring-gear reducers in both theory and practice.展开更多
Artemisinin resistance in Plasmodium falciparum threatens the remarkable efficacy of artemisininbased combination therapies worldwide. Thus, greater insight into the resistance mechanism using monitoring tools is esse...Artemisinin resistance in Plasmodium falciparum threatens the remarkable efficacy of artemisininbased combination therapies worldwide. Thus, greater insight into the resistance mechanism using monitoring tools is essential. The ring-stage survival assay is used for phenotyping artemisinin-resistance or decreased artemisinin sensitivity. Here, we review the progress of this measurement assay and explore its limitations and potential applications.展开更多
文摘后量子时代,基于格理论的公钥密码被认为是最有前途的抵抗量子计算机攻击的公钥密码体制.然而,相对于格上公钥加密体制和数字签名方案的快速发展,基于格上困难问题的密钥协商协议成果却较少.因此,现阶段如何构建格上安全的密钥协商协议是密码学领域具有挑战性的问题之一.针对上述问题,基于环上带错误学习问题困难假设,采用调和技术构造了一种新的认证密钥协商协议RAKA(authenticated key agreement protocol based on reconciliation technique),该方案采用格上陷门函数技术提供了单向认证功能,并且在Ring-LWE假设下证明是安全的.与现有的基于LWE的密钥协商协议相比,该方案的共享会话密钥减小为2nlog q,效率更高;同时,由于该方案的安全性是基于格上困难问题,因此可以抵抗量子攻击.
基金This project is supported by National Natural Science Foundation of China (No.50175011).
文摘From the general formula for calculating the efficiency of planetary geartrains, the efficiency of the double crank ring-plate-type pin-cycloidal gear planetary drive isderived. To prove the theory, an experimental study has been conducted. The tested value of theefficiency of a sample set of the new-type drive in the experiment agrees with the calculated one.It shows that the new-type drive is of not merely high bearing capacity, but also quite highefficiency.
基金This work was financially supported by the Special Fund for Major State Basic Research Project(G1999064801)the National Natural Science Foundation of China(Nos.20174033 and 20434020)
文摘In this paper,ring-opening polymerization of trimethylene carbonate(TMC)with rare earth(Nd,Y,La)ρ-tert- butylcalix[n]arene(n=4,6,and 8)complexes as catalysts has been studied.Poly(trimethylene carbonate)(PTMC)with M_v of 21,400 was produced by bulk polymerization under the conditions as follows:[TMC]_0/[Nd](molar ratio)=1000,80℃, 8 h.Mechanism study reveals that the polymerization proceeds via a coordination mechanism.
基金the State Key Project of Fundamental Research of Ministry of Science and Technology (No. 2006CB932200) the National Natural Science Foundation of China (NSFC, No. 10574156)+2 种基金 the Knowledge Innovation Program of Chinese Aca.demy of Sciencesthe protial support of 0utstanding Young Researcher Foundation (Nos. 50325104 and 50528101) K.C.Wong Education Foundation, Hong Kong.
文摘Nano-ring-type magnetic tunnel junctions (NR-MTJs) with the layer structure of Ta(5)/Ir22Mn78(10)/ Co75Fe25(2)/Ru(0.75)/CoooFe20B20(3)/Al(0.6)-oxide/Co60Fe20B20(2.5)/Ta(3)/Ru(5) (thickness unit: nm) were nano-fabricated on the Si(100)/SiO2 substrate using magnetron sputtering deposition combined with the optical lithography, electron beam lithography (EBL) and Ar ion-beam etching techniques. The smaller NR-MTJs with the inner- and outer-diameter of around 50 and 100 nm and also their corresponding NR-MTJ arrays were nano-patterned. The tunnelling magnetoresistance (TMR & R) versus driving current (I) loops for a spin-polarized current switching were measured, and the TMR ratio of around 35% at room temperature were observed. The critical values of switching current for the free Co60Fe20B20 layer relative to the reference Co6oFe2oB2o layer between parallel and anti-parallel magnetization states were between 0.50 and 0.75 mA in such NR-MTJs. It is suggested that the applicable MRAM fabrication with the density and capacity higher than 256 Mbit/inch2 even 6 Gbite/inch2 are possible using both I NR-MTJ+1 transistor structure and current switching mechanism based on based on our fabricated 4×4 MRAM demo devices.
基金supported by the National Natural Science Foundation of China.(Grant No.20174033 and 20254001)the Special Found for Major State Basic Research Project(Grant No.G1999064801)the Committee of Science and Technology of Zhejiang Province.
文摘The ring-opening polymerization of e-caprolactone (CL) initiated by novel single lanthanide tris(4-tert-butylphenolate)s [Ln(OTBP)3] is reported. Single-component La(OTBP)3 can effectively prepare polycaprolactone (PCL) with over 90% yield and viscosity average molecular weight about 60 x 10 under quite mild conditions: molar ratio of CL to initiator is 1000, 60 C, 2 h in toluene. Mechanism study indicates that the monomer inserts into the growing chain via the break of acyl-oxygen bond of CL.
基金This project was supported by the National Natural Science Foundation of China (No. 20084001).
文摘A series of cyclic (arylene phosphonate) oligomers were prepared by reaction of phenylphosphonic dichloride (PPD) with various bisphenols under pseudo-high dilution conditions via interfacial polycondensation. The yield of cyclic (arylene phosphonate) oligomers is over 85% by using hexadecyltrimethylammoniun bromide as phase transfer catalyst (PTC) at 0 'C . The structures of the cyclic oligomers were confirmed by a combination of matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF-MS) and IR analysis. These cyclic oligomers undergo facile ring-opening polymerization in the melt by using potassium 4,4'-biphenoxide as the initiator to give linear polyphosphonate. Free-radical ring-opening polymerization of cyclic(arylene phosphonate) oligomers containing sulfur linkages was also performed in the melt using 2,2'-dithiobis(benzothiazole) (DTB) as the initiator at 270 °C and the resulting polymer had a Mw, of 8 × 103 with a molecular weight distribution of 4. Ring-opening copolymerization of these cyclic oligomers with cyclic carbonate oligomers was also achieved. The average molecular weight of the resulting copolymer is higher than the corresponding homopolymer and the thermal stability of the copolymer is better than the corresponding homopolymer.
基金This work was financially supported by the Key Program of National Natural Science Foundation of China(No.G 20434020)the Special Funds for Major Basic Research Projects(No.G 2005 CB623802)the Committee of Science and Technology of Zhejiang Province.
文摘Ring-opening polymerization of ε-caprolactone has been carried out by using rare earth Schiff base complexes: lanthanide tris(N-phenyl-3,5-di-t-butylsalicylaldiminato)s [Ln(OPBS)3] as single component catalyst for the first time. The influences of different rare earth elements, monomer and catalyst concentration as well as reaction time on the polymerization were investigated. Mechanism studies showed that monomer inserts into the active site with the acyl-oxygen bond scission rather than the break of alkyl-oxygen bond.
基金supported by National Natural Science Foundation of China(No.51177007)Ministry of Science and Technology of China(No.2009AA064101-4)
文摘An atmospheric-pressure argon plasma jet with screw ring-ring electrodes in surface dielectric barrier discharge is generated by a sinusoidal excitation voltage at 8 kHz. The discharge characteristics, such as rotational and vibrational temperature of nitrogen, electronic excitation temperature, oxygen atomic density, nitrogen molecular density, and average electron density, are estimated. It is found that the rotational temperature of nitrogen is in the range of 352 ~ 392 K by comparing the simulated spectrum with the measured spectrum at the C3Πu → B3Πg (△ν = 2) band transition, the electronic excitation temperature is found to be in the range of 3127 ~ 3230 K by using the Boltzmann plot method, the oxygen atomic and nitrogen molecular density are of the order of magnitude of 1016 cm-3 by the actinometry method, and the average electron density is of the order of magnitude of 1012 cm-3 by the energy balance equation. Besides, the effective power, conduction, and displacement current are measured during the discharge.
基金Project supported by the National Defence Science and Technology Emphases Laboratory Foundation of China(No.99JS23.2.1.JWO506).
文摘The Donnell theory of shell is applied to describe shell motion and layer motion is described by means of three-dimensional Navier equations.Using deformation harmonious condi- tions of the interface,the effects of stiffeners and layer are treated as reverse forces and moments acting on the cylindrical shell.In studying the acoustic field produced by vibration of the sub- merged ring-stiffened cylindrical coated shell,the structure dynamic equation,Helmholtz equation in the fluid field and the continuous conditions of the fluid-structure interface compose the cou- pling vibration equation of the sound-fluid-structure.The extract of sound pressure comes down to the extract of coupling vibration equation.By use of the solution of the equation,the influ- ences of hydrostatic pressure,physical characters and geometric parameters of the layer on sound radiation are discussed.
文摘Exact analytical solutions of the Dirac equation are reported for the Poschl-Teller double-ring-shaped Coulomb potential.The radial,polar,and azimuthal parts of the Dirac equation are solved using the Nikiforov-Uvarov method,and the exact bound-state energy eigenvalues and corresponding two-component spinor wavefunctions are reported.
基金The authors are grateful for the financial support of the National Natural Science Foundation of China (No. 20104005) and Hubei Province Natural Science Foundation of China (No. 2001B053) and a grant from National Key Fundamental Research Program of Chin
文摘Porcine pancreas lipase (PPL) and PPL immobilized on narrow distributed micron-sized glass beads wereemployed successfully for the ring-opening polymerization of 5, 5-dimethyl-1, 3-dioxan-2-one (DTC) for the first time.Different polymerization conditions such as enzyme concentration and reaction temperature were studied. Immobilized PPLexhibits higher activity than native PPL. Along wth the increasing enzyme concentration, the molecular weigh of resultingPDTC decreases. PPL immobilized on narrow distributed micron-sized glass beads has outstanding recyclability. For thethird recycle time, immobilized PPL exhibits the highest catalytic activity and with high activity even after the fifth recyletime for the synthesis of PDTC. The ~1H-NMR spectra indicate that decarboxylation does not occur during the ring-openingpolymerization.
基金the financial supports of the National Science Foundation of the People's Republic of China(No.20704034)Provincial Natural Science Foundation of Zhejiang(No.Y4090047)
文摘Highly active calcium chloride(CaCl2) doped Zn-Co^Ⅲdouble metal-cyanide(Ca-DMC) catalysts were firstly reported.Ca-DMCs presented a very higher polymer yield(54 kg polymer/g catalyst) at relative low temperature(80-115℃) toward ringopening polymerization(ROP) of propylene oxide(PO) than did DMC catalysts without modification.
基金This project is sponsored by the National Natural Science Foundationthe National Key Laboratory of Mechanical Transmission of tfe Chongqing University
文摘Following the principle of elastic floating compensation, this paper presents a new metal elastic ring for load equilibration and vibration reduction in 3-ring-gear reducer, and design and fabrivcation of a metal elastic ring for SCH 3-ring-gear reducer. Comparison tests run with 3-ring-gear reducers without or with the metal elastic ring show satisfactory load equilibration and vibration reduction can be achieved with the metal elastic ring, and the metal elastic ring is a good solution for the problem of unequilibrated load and excessive vibration from which 3-ring-gear reducers suffered long.- This will further the improvement of design and application of 3-ring-gear reducers in both theory and practice.
基金funded by the National Natural Science Foundation of China(31260508,U1202226)grants of Doctor Newcomer Scholarship from Yunnan province
文摘Artemisinin resistance in Plasmodium falciparum threatens the remarkable efficacy of artemisininbased combination therapies worldwide. Thus, greater insight into the resistance mechanism using monitoring tools is essential. The ring-stage survival assay is used for phenotyping artemisinin-resistance or decreased artemisinin sensitivity. Here, we review the progress of this measurement assay and explore its limitations and potential applications.