Shear-type structures are common structural forms in industrial and civil buildings,such as concrete and steel frame structures.Fault diagnosis of shear-type structures is an important topic to ensure the normal use o...Shear-type structures are common structural forms in industrial and civil buildings,such as concrete and steel frame structures.Fault diagnosis of shear-type structures is an important topic to ensure the normal use of structures.The main drawback of existing damage assessment methods is that they require accurate structural finite element models for damage assessment.However,for many shear-type structures,it is difficult to obtain accurate FEM.In order to avoid finite elementmodeling,amodel-freemethod for diagnosing shear structure defects is developed in this paper.This method only needs to measure a few low-order vibration modes of the structure.The proposed defect diagnosis method is divided into two stages.In the first stage,the location of defects in the structure is determined based on the difference between the virtual displacements derived from the dynamic flexibility matrices before and after damage.In the second stage,damage severity is evaluated based on an improved frequency sensitivity equation.Themain innovations of this method lie in two aspects.The first innovation is the development of a virtual displacement difference method for determining the location of damage in the shear structure.The second is to improve the existing frequency sensitivity equation to calculate the damage degree without constructing the finite elementmodel.Thismethod has been verified on a numerical example of a 22-story shear frame structure and an experimental example of a three-story steel shear structure.Based on numerical analysis and experimental data validation,it is shown that this method only needs to use the low-order modes of structural vibration to diagnose the defect location and damage degree,and does not require finite element modeling.The proposed method should be a very simple and practical defect diagnosis technique in engineering practice.展开更多
To improve the damage efficiency of compact terminal sensitive projectile with EFP warhead,it is vital to understand how the embedded structure(ES)affects the EFP forming performance.In this paper,the corresponding nu...To improve the damage efficiency of compact terminal sensitive projectile with EFP warhead,it is vital to understand how the embedded structure(ES)affects the EFP forming performance.In this paper,the corresponding numerical investigation is focused on,in which the fluid-structure interaction(FSI)method and the experimental verification are used.Based on the obtained quantitative relations between the forming performance and a(the ratio of height to maximum radius of ES),an optimal design is further provided.The results indicate that:when the embedded structural length and width range 0.1e0.3D and 0.1e0.2D(D:diameter of EFP warhead)at a fixed volume,respectively,EFP forming velocity nearly keeps as a constant,1760 m/s;the height of ES has a dramatical effect on the propagating range of detonation wave,resulting in significant influence on the aerodynamic shape and length-to-diameter ratio of EFP;under the given constraints,the EFP length-diameter ratio can reach the optimal value2.76,when the height of ES is 0.22D.展开更多
A new coordination complex [Cu(IMI)4](PA)2 had been synthesized with imidazole(IMI) as ligands and picrate(PA-) groups as outer anions,and characterized by Fourier transform infrared(FTIR) spectrum and eleme...A new coordination complex [Cu(IMI)4](PA)2 had been synthesized with imidazole(IMI) as ligands and picrate(PA-) groups as outer anions,and characterized by Fourier transform infrared(FTIR) spectrum and elemental analysis.Its crystal structure was determined by single crystal X-ray diffraction(XRD) analysis.The crystallographic data show that the crystal belongs to monoclinic,C2/c space group,a=2.542(5) nm,b=0.91773(18) nm,c=1.3778(3) nm,β=107.854(3)° and Z=4.Furthermore,the central copper(II) ion is coordinated by four N atoms from four imidazole ligands.All the molecular units are linked into a zigzag pattern along a-axis by the hydrogen bonds,and extended to the distance regularly.Thermal decomposition mechanisms were determined based on differential scanning calorimetry(DSC) and thermogravimetry-differential thermogravimetry(TG-DTG) analysis,and kinetic parameters of the first exothermic process were studied using Kissinger's and Ozawa-Doyle's method,respectively.Sensitivity tests show that the title complex has low sensitivity to external stimulus,but it has a higher energy of combustion of 14.2 kJ/g due to which it may be used as the additives of energetic materials to improve the explosive performance.展开更多
Using the three-dimensional reticular nickel foam as experimental material, the sound absorption performance was investigated for several various multilayer structures in the frequency range of 2000-4000 Hz, which is ...Using the three-dimensional reticular nickel foam as experimental material, the sound absorption performance was investigated for several various multilayer structures in the frequency range of 2000-4000 Hz, which is aurally sensitive for human ears. The results showed that the 7.5 mm-thick foam sample, which was formed by piling of 5-layer foam plate(thickness: 1.5 mm; porosity: 96%; average pore-diameter: 0.65 mm) could exhibit an excellent sound absorption effect at 4000 Hz, with the absorption coefficient about 0.8. Constituting alternate air gap with the total thickness of about 18.5 mm can greatly improve the absorption performance at relatively low frequencies of 2000-3150 Hz, with the absorption coefficient up to about 0.5 or more. In addition, the research showed that alternate piling up the perforated plate inside the foam plates can also achieve a quite good effect of sound absorption at relatively low frequencies.展开更多
The sensitive area of targeted observations for short-term(7 d)prediction of vertical thermal structure(VTS)in summer in the Yellow Sea was investigated.We applied the Conditional Nonlinear Optimal Perturbation(CNOP)m...The sensitive area of targeted observations for short-term(7 d)prediction of vertical thermal structure(VTS)in summer in the Yellow Sea was investigated.We applied the Conditional Nonlinear Optimal Perturbation(CNOP)method and an adjoint-free algorithm with the Regional Ocean Modeling System(ROMS).We used vertical integration of CNOP-type temperature errors to locate the sensitive areas,where reduction of initial errors is expected to yield the greatest improvement in VTS prediction for the selected verification area.The identified sensitive areas were northeast−southwest orientated northeast to the verification area,which were possibly related to the southwestward background currents.Then,we performed a series of sensitivity experiments to evaluate the effectiveness of the identified sensitive areas.Results show that initial errors in the identified sensitive areas had the greatest negative effect on VTS prediction in the verification area compared to errors in other areas(e.g.,the verification area and areas to its east and northeast).Moreover,removal of initial errors through deploying simulated observations in the identified sensitive areas led to more refined prediction than correction of initial conditions in the verification area itself.Our results suggest that implementation of targeted observation in the CNOP-based sensitive areas is an effective method to improve short-term prediction of VTS in summer in the Yellow Sea.展开更多
The effect of grain structure on quench sensitivity of an Al-Zn-Mg-Cu-Cr alloy was investigated by hardness testing, optical microscopy, X-ray diffraction, scanning electron microscopy, transmission electron microscop...The effect of grain structure on quench sensitivity of an Al-Zn-Mg-Cu-Cr alloy was investigated by hardness testing, optical microscopy, X-ray diffraction, scanning electron microscopy, transmission electron microscopy and scanning transmission electron microscopy. The results show that with the decrease of quenching rate from 960 ℃/s to 2 ℃/s, the hardness after aging is decreased by about 33% for the homogenized and solution heat treated alloy(H-alloy) with large equiaxed grains and about 43% for the extruded and solution heat treated alloy(E-alloy) with elongated grains and subgrains. Cr-containing dispersoids make contribution to about 33% decrement in hardness of the H-alloy due to slow quenching; while in the E-alloy, the amount of(sub) grain boundaries is increased by about one order of magnitude, which leads to a further 10% decrement in hardness due to slow quenching and therefore higher quench sensitivity.展开更多
Spiky spherical nickel powder with sharp nano-tips on its surface is a kind of excellent fillers for developing pressure-sensitive cement-based composites/sensors for traffic detection,structural health monitoring,and...Spiky spherical nickel powder with sharp nano-tips on its surface is a kind of excellent fillers for developing pressure-sensitive cement-based composites/sensors for traffic detection,structural health monitoring,and border and military security.The sharp nano-tips on the surface of spiky spherical nickel particles can induce field emission and tunneling effects,which leads to the ultrahigh pressure-sensitive responses of the cement-based composites.In this paper,we systematically introduce research on nanotip-induced ultrahigh pressure-sensitive cement-based composites/sensors,with attentions to their pressure-sensitive property and sensing mechanism,pressure-sensitive characteristic model,and smart structure system for traffic detection.展开更多
The characterisation of the pore-fracture structure(PFS)and its evolution in coal during mining are essential for preventing gas outbursts and improving gas extraction efficiency.In this study,the evolution of the PFS...The characterisation of the pore-fracture structure(PFS)and its evolution in coal during mining are essential for preventing gas outbursts and improving gas extraction efficiency.In this study,the evolution of the PFS in coal samples under the condition of mining stress was directly captured in situ by combination of the mechanical testing system with high-precision visualisation nuclear magnetic resonance equipment.A fractional derivative model was established to describe the relationship between stress and porosity based on experimental results of the PFS under different stress states.The results showed that with an increase in the deviatoric stress,the adsorption pore content increases rapidly initially and then increases slowly or remains unchanged;the seepage pore and fracture(SPF)content decreases initially and then increases.The SPF compressibility coefficient decreases with an increase in the deviatoric stress.The fractional derivative model can accurately describe the stress sensitivity of the SPFs at the pre-peak stage,thus providing a new approach for accurately characterising the seepage characteristics of coal reservoirs.展开更多
The dynamic characteristics of bridge structures, such as the natural frequencies, mode shapes and model damping ratio, are the basis of structural dynamic computation, seismic analysis, vibration control and structur...The dynamic characteristics of bridge structures, such as the natural frequencies, mode shapes and model damping ratio, are the basis of structural dynamic computation, seismic analysis, vibration control and structural health condition monitoring. In this paper, a three-dimensional finite-element model is established for a highway bridge over a railway on No.312 National Highway and the ambient test is carried out in site, the dynamic characteristics of the bridge are studied using the finite-element analysis and ambient vibration measurements. Comparison between the theoretical and experimental results shows that the frequency differences of the modes range between 0.44% and 8.77%. If the measurement is more reliable, the finite element model updating is necessary. Thus, a set of design variables is selected based on sensitivity analysis, then the finite element model of the bridge is updated based on optimization algorithm. The results of model updating show that the proposed updating method in this paper is more simple and effective, the updated finite element model can reflect the dynamic characteristics of the bridge better, the analytical results can provide the theoretical basis for damage identification and health condition monitoring of the bridge.展开更多
With the development of satellite structure technology, more and more design parameters will affect its structural performance. It is desirable to obtain an optimal structure design with a minimum weight, including op...With the development of satellite structure technology, more and more design parameters will affect its structural performance. It is desirable to obtain an optimal structure design with a minimum weight, including optimal configuration and sizes. The present paper aims to describe an optimization analysis for a satellite structure, including topology optimization and size optimization. Based on the homogenization method, the topology optimization is carried out for the main supporting frame of service module under given constraints and load conditions, and then the sensitivity analysis is made of 15 structural size parameters of the whole satellite and the optimal sizes are obtained. The numerical result shows that the present optimization design method is very effective.展开更多
High-performance connection frames are of great significance for ultra-high acceleration and ultra-precision positioning in macro-micro motion platforms. This paper first takes the connection frame as a research objec...High-performance connection frames are of great significance for ultra-high acceleration and ultra-precision positioning in macro-micro motion platforms. This paper first takes the connection frame as a research object,builds a finite element model(FEM) of the natural frequency of the frame, and then verifies the correctness of this model. The frequency sensitivity method is then used to perturb the structural parameters of the FEM of the connection frame, and the sensitivities of the first-order natural frequency and mass of the corresponding structural parameters are obtained by calculation and analysis. The design variables are also determined. The natural frequency is used as the optimization objective, and the design parameters and mass of the connection frame are constrained. The structural parameters of the connecting frame are obtained through optimization, and the model is built and verified by experiments. The results show that the first-order natural frequency of the connecting frame is effectively improved by the frequency sensitivity method, avoids resonance between the connecting frame and the voice coil motor, and realizes the lightweight design of the connection frame. This research provides a reliable basis for the stable operation and ultra-precision positioning of ultra-high acceleration macro-motion platforms.展开更多
The structural response of a single-layer reticulated dome to external explosions is shaped by many variables,and the associated uncertainties imply non-deterministic results.Existing deterministic methods for predict...The structural response of a single-layer reticulated dome to external explosions is shaped by many variables,and the associated uncertainties imply non-deterministic results.Existing deterministic methods for predicting the consequences of specific explosions do not account for these uncertainties.Therefore,the impact of the uncertainties associated with these input variables on the structures’response needs to be studied and quantified.In this study,a parametric uncertainty analysis was conducted first.Then,local and global sensitivity analyses were carried out to identify the drivers of the structural dynamic response.A probabilistic structural response model was established based on sensitive variables and a reasonable sample size.Furthermore,some deterministic empirical methods for explosion-resistance design,including the plane blast load model of CONWEP,the curved blast load model under the 50%assurance level,and the 20%mass-increased method,were used for evaluating their reliability.The results of the analyses revealed that the structural response of a single-layer reticulated dome to an external blast loading is lognormally distributed.Evidently,the MB0.5 method based on the curved reflector load model yielded results with a relatively stable assurance rate and reliability,but CONWEP did not;thus,the 1.2MB0.5 method can be used for making high-confidence simple predictions.In addition,the results indicated that the structural response is very sensitive to the explosion parameters.Based on these results,it is suggested that for explosion proofing,setting up a defensive barrier is more effective than structural strengthening.展开更多
The nonlinear finite element(FE) analysis has been widely used in the design and analysis of structural or geotechnical systems.The response sensitivities(or gradients) to the model parameters are of significant i...The nonlinear finite element(FE) analysis has been widely used in the design and analysis of structural or geotechnical systems.The response sensitivities(or gradients) to the model parameters are of significant importance in these realistic engineering problems.However the sensitivity calculation has lagged behind,leaving a gap between advanced FE response analysis and other research hotspots using the response gradient.The response sensitivity analysis is crucial for any gradient-based algorithms,such as reliability analysis,system identification and structural optimization.Among various sensitivity analysis methods,the direct differential method(DDM) has advantages of computing efficiency and accuracy,providing an ideal tool for the response gradient calculation.This paper extended the DDM framework to realistic complicated soil-foundation-structure interaction(SFSI) models by developing the response gradients for various constraints,element and materials involved.The enhanced framework is applied to three-dimensional SFSI system prototypes for a pilesupported bridge pier and a pile-supported reinforced concrete building frame structure,subjected to earthquake loading conditions.The DDM results are verified by forward finite difference method(FFD).The relative importance(RI) of the various material parameters on the responses of SFSI system are investigated based on the DDM response sensitivity results.The FFD converges asymptotically toward the DDM results,demonstrating the advantages of DDM(e.g.,accurate,efficient,insensitive to numerical noise).Furthermore,the RI and effects of the model parameters of structure,foundation and soil materials on the responses of SFSI systems are investigated by taking advantage of the sensitivity analysis results.The extension of DDM to SFSI systems greatly broaden the application areas of the d gradient-based algorithms,e.g.FE model updating and nonlinear system identification of complicated SFSI systems.展开更多
A systematic study on the structure sensitivity,host effect,and the deactivation mechanism of Ircatalyzed selective hydrogenation of 1,3-butadiene,a key process in the purification of alkadiene for the upgrading of C4...A systematic study on the structure sensitivity,host effect,and the deactivation mechanism of Ircatalyzed selective hydrogenation of 1,3-butadiene,a key process in the purification of alkadiene for the upgrading of C4 cut,is presented by coupling steady-state catalytic testing,in-depth characterization,kinetic evaluation,and density functional theory calculations.We reveal that:(i) 1,3-Butadiene hydrogenation on iridium is structure-sensitive with the optimal particle size of about 2 nm,and the H_(2) dissociation energy is a reliable activity descriptor;(ii) The nature of the NC hosts exerts a critical impact on the catalytic performance,and balanced nitrogen content and speciation seem key for the optimized performance;and (iii) Different deactivation mechanisms occur:fouling by coke deposition on the catalysts with a high N:C ratio (>1),and site blockage due to the competitive adsorption between 1-butene/cis-2-butene and 1,3-butadiene.These molecular insights provide valuable guidelines for the catalyst design in selective hydrogenations.展开更多
The geometry, electronic structure, polarizability and hyperpolarizability of dye sensitizer 3,4-bis[1-(carboxymethyl)-3-indolyl]-1H-pyrrole-2,5-dione (BIMCOOH) were studied using density functional theory (DFT)...The geometry, electronic structure, polarizability and hyperpolarizability of dye sensitizer 3,4-bis[1-(carboxymethyl)-3-indolyl]-1H-pyrrole-2,5-dione (BIMCOOH) were studied using density functional theory (DFT) with hybrid functional B3LYP, and the electronic absorption spectra were investigated using semi-empirical quantum chemical method ZINDO-1 and time-dependent DFT (TDDFT). The results of natural bond orbital suggest that the natural charges of the dione, indole, and acetic groups are about 0.15e, -0.29e, and 0.44e, respectively. The calculated isotropic polarizability, polarizability anisotropy invariant and hyperpolarizability are 305.4, 188.3, and 1155.4 a.u., respectively. The electronic absorption spectral features in visible and near-UV region were assigned to the π→π^* transition due to the qualitative agreement between the experiment and the TDDFT calculations, and the transitions of the excited states 9-11 related to photoinduced intramolecular charge transfer processes. The analysis of electronic structure and UV-Vis absorption indicates that the indole groups primarily contributed sensitization of photo-to-currency conversion processes, and the interracial electron transfer between semiconductor TiO2 electrode and dye sensitizer BIMCOOH are electron injection processes from excited states of the dyes to the semiconductor conduction band.展开更多
In order to study the influence of parameters on durability of marine concrete structures, the parameter's sensitivity analysis was studied in this paper. With the Fick's 2nd law of diffusion and the deterministic s...In order to study the influence of parameters on durability of marine concrete structures, the parameter's sensitivity analysis was studied in this paper. With the Fick's 2nd law of diffusion and the deterministic sensitivity analysis method (DSA), the sensitivity factors of apparent surface chloride content, apparent chloride diffusion coefficient and its time dependent attenuation factor were analyzed. The results of the analysis show that the impact of design variables on concrete durability was different. The values of sensitivity factor of chloride diffusion coefficient and its time dependent attenuation factor were higher than others. Relative less error in chloride diffusion coefficient and its time dependent attenuation coefficient induces a bigger error in concrete durability design and life prediction. According to probability sensitivity analysis (PSA), the influence of mean value and variance of concrete durability design variables on the durability failure probability was studied. The results of the study provide quantitative measures of the importance of concrete durability design and life prediction variables. It was concluded that the chloride diffusion coefficient and its time dependent attenuation factor have more influence on the reliability of marine concrete structural durability. In durability design and life prediction of marine concrete structures, it was very important to reduce the measure and statistic error of durability design variables.展开更多
This paper presents methods for computing a second-order sensitivity matrix and the Hessian matrix of eigenvalues and eigenvectors of multiple parameter structures. Second-order perturbations of eigenvalues and eigenv...This paper presents methods for computing a second-order sensitivity matrix and the Hessian matrix of eigenvalues and eigenvectors of multiple parameter structures. Second-order perturbations of eigenvalues and eigenvectors are transformed into multiple parameter forms,and the second-order perturbation sensitivity matrices of eigenvalues and eigenvectors are developed.With these formulations,the efficient methods based on the second-order Taylor expansion and second-order perturbation are obtained to estimate changes of eigenvalues and eigenvectors when the design parameters are changed. The presented method avoids direct differential operation,and thus reduces difficulty for computing the second-order sensitivity matrices of eigenpairs.A numerical example is given to demonstrate application and accuracy of the proposed method.展开更多
The expanded ammonium nitrate (EAN) samples with different states were prepared by using a vacuum crystallizing technology. The structure characters,such as porosity,pore structure,specific surface area,particle surfa...The expanded ammonium nitrate (EAN) samples with different states were prepared by using a vacuum crystallizing technology. The structure characters,such as porosity,pore structure,specific surface area,particle surface shape and surface defects,and detonator initiation sensitivity and explosion power,of common ammonium nitrate (AN) and EAN were tested using density measuring,N2 adsorbing,scanning electron microscope (SEM) and plate trace test methods. The tested results show that the particle surface of common AN is smoother,denser,lower porosity and specific surface area than those tested of EAN. The particle surface of EAN is irregular,which has edges,protuberance and severely distorted crystal form,and its specific surface area and porosity are larger than those of un-expanded AN. EAN has typical self-sensitization structure characters. The detonator initiation sensitivity and explosion power of ammonium nitrate-fuel oil(ANFO) made of different states of EAN are related to the self-sensitization structures of EAN,and expanded ANFO sample has higher detonator initiation sensitivity and explosion power compared with un-expanded ANFO sample. The characterization techniques can be used to reveal the self-sensitization structure of EAN.展开更多
Recent progress in dye-sensitized solar cells (DSC) research is reviewed, focusing on atomic-scale investigations of the interface electronic structures and dynamical processes, including the structure of dye adsorp...Recent progress in dye-sensitized solar cells (DSC) research is reviewed, focusing on atomic-scale investigations of the interface electronic structures and dynamical processes, including the structure of dye adsorption onto Ti02, ultrafast electron injection, hot-electron injection, multiple-exciton generation, and electron-hole recombination. Advanced exper- imental techniques and theoretical approaches are briefly summarized, and then progressive achievements in photovoltaic device optimization based on insights from atomic scale investigations are introduced. Finally, some challenges and oppor- tunities for further improvement of dye solar cells are presented.展开更多
In many practical structures, physical parameters of material and applied loads have random property.To optimize this kind of structures,an optimum mathematical model was built.This model has reliability constraints o...In many practical structures, physical parameters of material and applied loads have random property.To optimize this kind of structures,an optimum mathematical model was built.This model has reliability constraints on dynamic stress and displacement and upper & lower limits of the design variables. The numerical characteristic of dynamic response and sensitivity of dynamic response based on probability of structure were deduced respectively. By equivalent disposing, the reliability constraints were changed into conventional forms. The SUMT method was used in the optimization process.Two examples illustrate the correctness and practicability of the optimum model and solving approach.展开更多
基金the Zhejiang Public Welfare Technology Application Research Project(LGF22E080021)Ningbo Natural Science Foundation Project(202003N4169)+2 种基金Natural Science Foundation of China(11202138,52008215)the Natural Science Foundation of Zhejiang Province,China(LQ20E080013)the Major Special Science and Technology Project(2019B10076)of“Ningbo Science and Technology Innovation 2025”.
文摘Shear-type structures are common structural forms in industrial and civil buildings,such as concrete and steel frame structures.Fault diagnosis of shear-type structures is an important topic to ensure the normal use of structures.The main drawback of existing damage assessment methods is that they require accurate structural finite element models for damage assessment.However,for many shear-type structures,it is difficult to obtain accurate FEM.In order to avoid finite elementmodeling,amodel-freemethod for diagnosing shear structure defects is developed in this paper.This method only needs to measure a few low-order vibration modes of the structure.The proposed defect diagnosis method is divided into two stages.In the first stage,the location of defects in the structure is determined based on the difference between the virtual displacements derived from the dynamic flexibility matrices before and after damage.In the second stage,damage severity is evaluated based on an improved frequency sensitivity equation.Themain innovations of this method lie in two aspects.The first innovation is the development of a virtual displacement difference method for determining the location of damage in the shear structure.The second is to improve the existing frequency sensitivity equation to calculate the damage degree without constructing the finite elementmodel.Thismethod has been verified on a numerical example of a 22-story shear frame structure and an experimental example of a three-story steel shear structure.Based on numerical analysis and experimental data validation,it is shown that this method only needs to use the low-order modes of structural vibration to diagnose the defect location and damage degree,and does not require finite element modeling.The proposed method should be a very simple and practical defect diagnosis technique in engineering practice.
基金funded by the National Natural Science Foundation of China under No. 11102088Fundamental Research Funds for the Central Universities under No. 30915118821funded by the Specialized Research Fund for the Doctoral Program of Higher Education of China under No. 20133219110019
文摘To improve the damage efficiency of compact terminal sensitive projectile with EFP warhead,it is vital to understand how the embedded structure(ES)affects the EFP forming performance.In this paper,the corresponding numerical investigation is focused on,in which the fluid-structure interaction(FSI)method and the experimental verification are used.Based on the obtained quantitative relations between the forming performance and a(the ratio of height to maximum radius of ES),an optimal design is further provided.The results indicate that:when the embedded structural length and width range 0.1e0.3D and 0.1e0.2D(D:diameter of EFP warhead)at a fixed volume,respectively,EFP forming velocity nearly keeps as a constant,1760 m/s;the height of ES has a dramatical effect on the propagating range of detonation wave,resulting in significant influence on the aerodynamic shape and length-to-diameter ratio of EFP;under the given constraints,the EFP length-diameter ratio can reach the optimal value2.76,when the height of ES is 0.22D.
基金Supported by the Project of Science and Technology of Applied Physical Chemistry Laboratory of China(No.9140C3703051105)the Project of State Key Laboratory of Explosion Science and Technology,China(Nos. QNKT12-02,ZDKT10-01b)
文摘A new coordination complex [Cu(IMI)4](PA)2 had been synthesized with imidazole(IMI) as ligands and picrate(PA-) groups as outer anions,and characterized by Fourier transform infrared(FTIR) spectrum and elemental analysis.Its crystal structure was determined by single crystal X-ray diffraction(XRD) analysis.The crystallographic data show that the crystal belongs to monoclinic,C2/c space group,a=2.542(5) nm,b=0.91773(18) nm,c=1.3778(3) nm,β=107.854(3)° and Z=4.Furthermore,the central copper(II) ion is coordinated by four N atoms from four imidazole ligands.All the molecular units are linked into a zigzag pattern along a-axis by the hydrogen bonds,and extended to the distance regularly.Thermal decomposition mechanisms were determined based on differential scanning calorimetry(DSC) and thermogravimetry-differential thermogravimetry(TG-DTG) analysis,and kinetic parameters of the first exothermic process were studied using Kissinger's and Ozawa-Doyle's method,respectively.Sensitivity tests show that the title complex has low sensitivity to external stimulus,but it has a higher energy of combustion of 14.2 kJ/g due to which it may be used as the additives of energetic materials to improve the explosive performance.
基金Project(C16) supported by the Testing Foundation of Beijing Normal University,China
文摘Using the three-dimensional reticular nickel foam as experimental material, the sound absorption performance was investigated for several various multilayer structures in the frequency range of 2000-4000 Hz, which is aurally sensitive for human ears. The results showed that the 7.5 mm-thick foam sample, which was formed by piling of 5-layer foam plate(thickness: 1.5 mm; porosity: 96%; average pore-diameter: 0.65 mm) could exhibit an excellent sound absorption effect at 4000 Hz, with the absorption coefficient about 0.8. Constituting alternate air gap with the total thickness of about 18.5 mm can greatly improve the absorption performance at relatively low frequencies of 2000-3150 Hz, with the absorption coefficient up to about 0.5 or more. In addition, the research showed that alternate piling up the perforated plate inside the foam plates can also achieve a quite good effect of sound absorption at relatively low frequencies.
基金The National Natural Science Foundation of China under contract Nos 41705081 and 41906005the Innovation Special Zone Project under contract No.18-H863-05-ZT-001-012-06the Open Project Fund of the Laboratory for Regional Oceanography and Numerical Modeling,Pilot National Laboratory for Marine Science and Technology(Qingdao)under contract No.2019A05.
文摘The sensitive area of targeted observations for short-term(7 d)prediction of vertical thermal structure(VTS)in summer in the Yellow Sea was investigated.We applied the Conditional Nonlinear Optimal Perturbation(CNOP)method and an adjoint-free algorithm with the Regional Ocean Modeling System(ROMS).We used vertical integration of CNOP-type temperature errors to locate the sensitive areas,where reduction of initial errors is expected to yield the greatest improvement in VTS prediction for the selected verification area.The identified sensitive areas were northeast−southwest orientated northeast to the verification area,which were possibly related to the southwestward background currents.Then,we performed a series of sensitivity experiments to evaluate the effectiveness of the identified sensitive areas.Results show that initial errors in the identified sensitive areas had the greatest negative effect on VTS prediction in the verification area compared to errors in other areas(e.g.,the verification area and areas to its east and northeast).Moreover,removal of initial errors through deploying simulated observations in the identified sensitive areas led to more refined prediction than correction of initial conditions in the verification area itself.Our results suggest that implementation of targeted observation in the CNOP-based sensitive areas is an effective method to improve short-term prediction of VTS in summer in the Yellow Sea.
基金Project(2012CB619500)supported by the National Basic Research Program of ChinaProject supported by Shenghua Yuying Project of Central South University,China
文摘The effect of grain structure on quench sensitivity of an Al-Zn-Mg-Cu-Cr alloy was investigated by hardness testing, optical microscopy, X-ray diffraction, scanning electron microscopy, transmission electron microscopy and scanning transmission electron microscopy. The results show that with the decrease of quenching rate from 960 ℃/s to 2 ℃/s, the hardness after aging is decreased by about 33% for the homogenized and solution heat treated alloy(H-alloy) with large equiaxed grains and about 43% for the extruded and solution heat treated alloy(E-alloy) with elongated grains and subgrains. Cr-containing dispersoids make contribution to about 33% decrement in hardness of the H-alloy due to slow quenching; while in the E-alloy, the amount of(sub) grain boundaries is increased by about one order of magnitude, which leads to a further 10% decrement in hardness due to slow quenching and therefore higher quench sensitivity.
文摘Spiky spherical nickel powder with sharp nano-tips on its surface is a kind of excellent fillers for developing pressure-sensitive cement-based composites/sensors for traffic detection,structural health monitoring,and border and military security.The sharp nano-tips on the surface of spiky spherical nickel particles can induce field emission and tunneling effects,which leads to the ultrahigh pressure-sensitive responses of the cement-based composites.In this paper,we systematically introduce research on nanotip-induced ultrahigh pressure-sensitive cement-based composites/sensors,with attentions to their pressure-sensitive property and sensing mechanism,pressure-sensitive characteristic model,and smart structure system for traffic detection.
基金This work was supported by the National Natural Science Foundation of China(Nos.51827901,52121003,52142302,and 51904309)the 111 Project(No.B14006)the Yueqi Outstanding Scholar Program of CUMTB(No.2017A03).
文摘The characterisation of the pore-fracture structure(PFS)and its evolution in coal during mining are essential for preventing gas outbursts and improving gas extraction efficiency.In this study,the evolution of the PFS in coal samples under the condition of mining stress was directly captured in situ by combination of the mechanical testing system with high-precision visualisation nuclear magnetic resonance equipment.A fractional derivative model was established to describe the relationship between stress and porosity based on experimental results of the PFS under different stress states.The results showed that with an increase in the deviatoric stress,the adsorption pore content increases rapidly initially and then increases slowly or remains unchanged;the seepage pore and fracture(SPF)content decreases initially and then increases.The SPF compressibility coefficient decreases with an increase in the deviatoric stress.The fractional derivative model can accurately describe the stress sensitivity of the SPFs at the pre-peak stage,thus providing a new approach for accurately characterising the seepage characteristics of coal reservoirs.
基金Supported by the National Natural Science Foundation of China(50378041)the Program for New Century Excellent Talents of Ministry of Educationof China (2004)
文摘The dynamic characteristics of bridge structures, such as the natural frequencies, mode shapes and model damping ratio, are the basis of structural dynamic computation, seismic analysis, vibration control and structural health condition monitoring. In this paper, a three-dimensional finite-element model is established for a highway bridge over a railway on No.312 National Highway and the ambient test is carried out in site, the dynamic characteristics of the bridge are studied using the finite-element analysis and ambient vibration measurements. Comparison between the theoretical and experimental results shows that the frequency differences of the modes range between 0.44% and 8.77%. If the measurement is more reliable, the finite element model updating is necessary. Thus, a set of design variables is selected based on sensitivity analysis, then the finite element model of the bridge is updated based on optimization algorithm. The results of model updating show that the proposed updating method in this paper is more simple and effective, the updated finite element model can reflect the dynamic characteristics of the bridge better, the analytical results can provide the theoretical basis for damage identification and health condition monitoring of the bridge.
文摘With the development of satellite structure technology, more and more design parameters will affect its structural performance. It is desirable to obtain an optimal structure design with a minimum weight, including optimal configuration and sizes. The present paper aims to describe an optimization analysis for a satellite structure, including topology optimization and size optimization. Based on the homogenization method, the topology optimization is carried out for the main supporting frame of service module under given constraints and load conditions, and then the sensitivity analysis is made of 15 structural size parameters of the whole satellite and the optimal sizes are obtained. The numerical result shows that the present optimization design method is very effective.
基金financially supported by the National Natural Science Foundation of China (Grant No. 51705132)the Science and Technology Department of Henan Province Natural Science Project (Grant No. 172102210215)+1 种基金Henan Postdoctoral Foundation, doctoral Foundation (2016BS008)the Education Department of Henan Province Natural Science Project (Grant No. 17A460008)
文摘High-performance connection frames are of great significance for ultra-high acceleration and ultra-precision positioning in macro-micro motion platforms. This paper first takes the connection frame as a research object,builds a finite element model(FEM) of the natural frequency of the frame, and then verifies the correctness of this model. The frequency sensitivity method is then used to perturb the structural parameters of the FEM of the connection frame, and the sensitivities of the first-order natural frequency and mass of the corresponding structural parameters are obtained by calculation and analysis. The design variables are also determined. The natural frequency is used as the optimization objective, and the design parameters and mass of the connection frame are constrained. The structural parameters of the connecting frame are obtained through optimization, and the model is built and verified by experiments. The results show that the first-order natural frequency of the connecting frame is effectively improved by the frequency sensitivity method, avoids resonance between the connecting frame and the voice coil motor, and realizes the lightweight design of the connection frame. This research provides a reliable basis for the stable operation and ultra-precision positioning of ultra-high acceleration macro-motion platforms.
基金the financial support from the China Postdoctora Science Foundation (project No. 2021M690406)the financial supports from the National Natural Science Foundation of China (project Nos. 51708521, 51778183)
文摘The structural response of a single-layer reticulated dome to external explosions is shaped by many variables,and the associated uncertainties imply non-deterministic results.Existing deterministic methods for predicting the consequences of specific explosions do not account for these uncertainties.Therefore,the impact of the uncertainties associated with these input variables on the structures’response needs to be studied and quantified.In this study,a parametric uncertainty analysis was conducted first.Then,local and global sensitivity analyses were carried out to identify the drivers of the structural dynamic response.A probabilistic structural response model was established based on sensitive variables and a reasonable sample size.Furthermore,some deterministic empirical methods for explosion-resistance design,including the plane blast load model of CONWEP,the curved blast load model under the 50%assurance level,and the 20%mass-increased method,were used for evaluating their reliability.The results of the analyses revealed that the structural response of a single-layer reticulated dome to an external blast loading is lognormally distributed.Evidently,the MB0.5 method based on the curved reflector load model yielded results with a relatively stable assurance rate and reliability,but CONWEP did not;thus,the 1.2MB0.5 method can be used for making high-confidence simple predictions.In addition,the results indicated that the structural response is very sensitive to the explosion parameters.Based on these results,it is suggested that for explosion proofing,setting up a defensive barrier is more effective than structural strengthening.
基金National Key Research and Development Program of China under Grant No.2016YFC0701106Natural Sciences and Engineering Research Council of Canada via Discovery under Grant No.NSERC RGPIN-2017-05556 Li
文摘The nonlinear finite element(FE) analysis has been widely used in the design and analysis of structural or geotechnical systems.The response sensitivities(or gradients) to the model parameters are of significant importance in these realistic engineering problems.However the sensitivity calculation has lagged behind,leaving a gap between advanced FE response analysis and other research hotspots using the response gradient.The response sensitivity analysis is crucial for any gradient-based algorithms,such as reliability analysis,system identification and structural optimization.Among various sensitivity analysis methods,the direct differential method(DDM) has advantages of computing efficiency and accuracy,providing an ideal tool for the response gradient calculation.This paper extended the DDM framework to realistic complicated soil-foundation-structure interaction(SFSI) models by developing the response gradients for various constraints,element and materials involved.The enhanced framework is applied to three-dimensional SFSI system prototypes for a pilesupported bridge pier and a pile-supported reinforced concrete building frame structure,subjected to earthquake loading conditions.The DDM results are verified by forward finite difference method(FFD).The relative importance(RI) of the various material parameters on the responses of SFSI system are investigated based on the DDM response sensitivity results.The FFD converges asymptotically toward the DDM results,demonstrating the advantages of DDM(e.g.,accurate,efficient,insensitive to numerical noise).Furthermore,the RI and effects of the model parameters of structure,foundation and soil materials on the responses of SFSI systems are investigated by taking advantage of the sensitivity analysis results.The extension of DDM to SFSI systems greatly broaden the application areas of the d gradient-based algorithms,e.g.FE model updating and nonlinear system identification of complicated SFSI systems.
基金Zhejiang Normal University for providing the financial support (YS304320035, YS304320036, ZZ323205020521005039)Financial support from the National Natural Science Foundation of China (NSFC, 21606199)+1 种基金the Science and Technology Department of Zhejiang Province (LGG20B060004)the National Key Research and Development Program of China (2021YFA1501800, 2021YFA1501801, 2021YFA1501802) are also gratefully acknowledged。
文摘A systematic study on the structure sensitivity,host effect,and the deactivation mechanism of Ircatalyzed selective hydrogenation of 1,3-butadiene,a key process in the purification of alkadiene for the upgrading of C4 cut,is presented by coupling steady-state catalytic testing,in-depth characterization,kinetic evaluation,and density functional theory calculations.We reveal that:(i) 1,3-Butadiene hydrogenation on iridium is structure-sensitive with the optimal particle size of about 2 nm,and the H_(2) dissociation energy is a reliable activity descriptor;(ii) The nature of the NC hosts exerts a critical impact on the catalytic performance,and balanced nitrogen content and speciation seem key for the optimized performance;and (iii) Different deactivation mechanisms occur:fouling by coke deposition on the catalysts with a high N:C ratio (>1),and site blockage due to the competitive adsorption between 1-butene/cis-2-butene and 1,3-butadiene.These molecular insights provide valuable guidelines for the catalyst design in selective hydrogenations.
基金ACKNOWLEDGMENTS This work was supported by the NationM NaturM Science Foundation of China (No. 10647006), the Prominent Youth Foundation (No.Q200704) and the Scientific Developmental Foundation of Lanzhou University of Technology. Cai-rong Zhang would like to thank Professor Wan-zhen Liang (USTC), and the Gansu Supercomputer Center is also appreciated.
文摘The geometry, electronic structure, polarizability and hyperpolarizability of dye sensitizer 3,4-bis[1-(carboxymethyl)-3-indolyl]-1H-pyrrole-2,5-dione (BIMCOOH) were studied using density functional theory (DFT) with hybrid functional B3LYP, and the electronic absorption spectra were investigated using semi-empirical quantum chemical method ZINDO-1 and time-dependent DFT (TDDFT). The results of natural bond orbital suggest that the natural charges of the dione, indole, and acetic groups are about 0.15e, -0.29e, and 0.44e, respectively. The calculated isotropic polarizability, polarizability anisotropy invariant and hyperpolarizability are 305.4, 188.3, and 1155.4 a.u., respectively. The electronic absorption spectral features in visible and near-UV region were assigned to the π→π^* transition due to the qualitative agreement between the experiment and the TDDFT calculations, and the transitions of the excited states 9-11 related to photoinduced intramolecular charge transfer processes. The analysis of electronic structure and UV-Vis absorption indicates that the indole groups primarily contributed sensitization of photo-to-currency conversion processes, and the interracial electron transfer between semiconductor TiO2 electrode and dye sensitizer BIMCOOH are electron injection processes from excited states of the dyes to the semiconductor conduction band.
文摘In order to study the influence of parameters on durability of marine concrete structures, the parameter's sensitivity analysis was studied in this paper. With the Fick's 2nd law of diffusion and the deterministic sensitivity analysis method (DSA), the sensitivity factors of apparent surface chloride content, apparent chloride diffusion coefficient and its time dependent attenuation factor were analyzed. The results of the analysis show that the impact of design variables on concrete durability was different. The values of sensitivity factor of chloride diffusion coefficient and its time dependent attenuation factor were higher than others. Relative less error in chloride diffusion coefficient and its time dependent attenuation coefficient induces a bigger error in concrete durability design and life prediction. According to probability sensitivity analysis (PSA), the influence of mean value and variance of concrete durability design variables on the durability failure probability was studied. The results of the study provide quantitative measures of the importance of concrete durability design and life prediction variables. It was concluded that the chloride diffusion coefficient and its time dependent attenuation factor have more influence on the reliability of marine concrete structural durability. In durability design and life prediction of marine concrete structures, it was very important to reduce the measure and statistic error of durability design variables.
基金Project supported by the 985-Engineering Innovation of Graduate Students of Jilin Universitythe Science and Technology Development Foundation of Jilin Province(20070541)
文摘This paper presents methods for computing a second-order sensitivity matrix and the Hessian matrix of eigenvalues and eigenvectors of multiple parameter structures. Second-order perturbations of eigenvalues and eigenvectors are transformed into multiple parameter forms,and the second-order perturbation sensitivity matrices of eigenvalues and eigenvectors are developed.With these formulations,the efficient methods based on the second-order Taylor expansion and second-order perturbation are obtained to estimate changes of eigenvalues and eigenvectors when the design parameters are changed. The presented method avoids direct differential operation,and thus reduces difficulty for computing the second-order sensitivity matrices of eigenpairs.A numerical example is given to demonstrate application and accuracy of the proposed method.
文摘The expanded ammonium nitrate (EAN) samples with different states were prepared by using a vacuum crystallizing technology. The structure characters,such as porosity,pore structure,specific surface area,particle surface shape and surface defects,and detonator initiation sensitivity and explosion power,of common ammonium nitrate (AN) and EAN were tested using density measuring,N2 adsorbing,scanning electron microscope (SEM) and plate trace test methods. The tested results show that the particle surface of common AN is smoother,denser,lower porosity and specific surface area than those tested of EAN. The particle surface of EAN is irregular,which has edges,protuberance and severely distorted crystal form,and its specific surface area and porosity are larger than those of un-expanded AN. EAN has typical self-sensitization structure characters. The detonator initiation sensitivity and explosion power of ammonium nitrate-fuel oil(ANFO) made of different states of EAN are related to the self-sensitization structures of EAN,and expanded ANFO sample has higher detonator initiation sensitivity and explosion power compared with un-expanded ANFO sample. The characterization techniques can be used to reveal the self-sensitization structure of EAN.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11222431 and 11074287)the National Basic Key Research Program of China(Grant No.2012CB921403)the Hundred-Talent Program of the Chinese Academy of Sciences
文摘Recent progress in dye-sensitized solar cells (DSC) research is reviewed, focusing on atomic-scale investigations of the interface electronic structures and dynamical processes, including the structure of dye adsorption onto Ti02, ultrafast electron injection, hot-electron injection, multiple-exciton generation, and electron-hole recombination. Advanced exper- imental techniques and theoretical approaches are briefly summarized, and then progressive achievements in photovoltaic device optimization based on insights from atomic scale investigations are introduced. Finally, some challenges and oppor- tunities for further improvement of dye solar cells are presented.
文摘In many practical structures, physical parameters of material and applied loads have random property.To optimize this kind of structures,an optimum mathematical model was built.This model has reliability constraints on dynamic stress and displacement and upper & lower limits of the design variables. The numerical characteristic of dynamic response and sensitivity of dynamic response based on probability of structure were deduced respectively. By equivalent disposing, the reliability constraints were changed into conventional forms. The SUMT method was used in the optimization process.Two examples illustrate the correctness and practicability of the optimum model and solving approach.