A Preliminary Study on Paleomagnetism and Rock Magnetism of Eclogite from the Maobei Area

A preliminary study of paleomagnetism and rock magnetism has been done on 55 eclogite samples collected from the Chinese Continental Scientific Drilling （CCSD） site at the Maobei （毛北） area, Donghai （东海） County, Jiangsu （江苏） Province. Also the isothermal remanence, hysteresis loop, magnetic fabric, thermal susceptibility were measured, and analyses were made by electron-probe and scanning electric microscope on some samples synchronously. The result indicates that there are two groups of stable remanence, the normal and reversed magnetization. The remanence orientations are： D=94.3°, I=-29.1° and D=273.7°, I=15.4°, respectively. The magnetization intensity and the density of the samples which carry the normal magnetization are very different from those bearing reversed magnetization. The magnetic anisotropy is weak, and the minimum axis is hardly determined. The isothermal remanence and the hysteresis loop show that the magnetic carriers of the eclogite are likely SD （single domain） and PSD （pseudo.single domain） magnetite. According to the magnetic property, the cause of formation of magnetic carriers, the mechanism of the remanence, and the significance for the tectonics are discussed.

A Study of Rock Magnetism of High-Grade Hematite Ores

Rock magnetism is useful in various applications. Hematite is one of the two most important carriers of magnetism in the natural world and its magnetic features were mostly studied through laboratory experiments using synthetic hematite samples. A gap exists between the magnetic behaviors of hematite contained in the natural rocks and ores and those of synthetic hematite samples. This paper presents the results of a rock magnetism study on the natural hematite ores from the Whaleback mine in the Hamersley Province in the northwest of Western Australia. It was found that high-grade hematite ores carry a much higher remanent magnetization than induced magnetization. Hematite ores with less than 0.1% magnetite appear to have an exponential correlation between the bulk susceptibility and hematite content in weight percentage, different from the commonly accepted linear relationship between the bulk susceptibility and hematite content obtained from synthetic hematite samples. The new knowledge gained from this study contributes to a better understanding of magnetic behaviors of hematite, particularly natural hematite, and hence applications to other relevant disciplines.

Sedimentary sources and processes in the eastern Arabian Sea:Insights from environmental magnetism,geochemistry and clay mineralogy

The spatial distribution patterns of surficial sediment samples from different sedimentary domains （shallow to deep-sea regions） of the eastern Arabian Sea were studied using sediment proxies viz. environmental magnetism, geochemistry, particle size and clay mineralogy. Higher concentrations of magnetic minerals （high Xlf） were recorded in the deep-water sediments when compared with the shallow water sediments. The magnetic mineralogy of one of the shallow water samples is influenced by the presence of bacterial magnetite as evidenced from the XARM/Xlf VS. XARM/Xfd biplot. However, the other samples are catchment-derived. The high correlation documented for Xlf, anhysteretic remanent mag- netisation （XARM） and isothermal remanent magnetisation （IRM） with Al indicates that the deep-sea surflcial sediments are influenced by terrigenous fluxes which have been probably derived from the southern Indian rivers, the Sindhu （the Indus） and the Narmada-Tapti rivers. A lower Mn concentration is recorded in the upper slope sediments from the oxygen minimum zone （OMZ） but a higher Mn/AI ratio is documented in the lower slope and deep-sea sediments. Clay minerals such as illite （24-48.5%）, chlorite （14.1-34.9%）, smectite （10.6-28.7%） and kaolinite （11.9-27.5%） dominate the sediments of shallow and deep-sea regions and may have been derived from different sources and transported by fluvial and aeolian agents. Organic carbon （OC） data indicate a low concentration in the shallow/shelf region （well oxygenated water conditions） and deeper basins （increased bottom-water oxygen concentration and low sedimentation rate）. High OC concentrations were documented in the OMZ （very low bottom-water oxygen concentration with high sedimentation rate）. The calcium carbonate concentration of the surface sediments from the continental shelf and slope regions （〈 1800 m） up to the Chagos-Laccadive Ridge show higher concentrations （average - 58%） when compared to deep basin sediments （average - 44%）. Our study demonstrates that particle size as well as magnetic grain size, magnetic minerals and elemental variations are good indicators to distinguish terrigenous from biogenic sediments and to identify sediment provenance.

The Effect of Rock Rheology on Rock Magnetism: A Possible Mechanism of Seismomagnetism

An experiment of uniaxial compression was carried out on samples of 8 representative rock types.The temporal variations of the remanent magnetization,strain and acoustic emission of samples were recorded and investigated,especially when the samples were under constant load and when they had just been unloaded.It was found that most samples still showed changes of their remanent magnetization under constant load and the tendency of these changes remained the same as that before the load had been kept constant.In the meantime,similar changes of strains were observed as well.However,in a short time period immediately after the sample had been completely unloaded,the variations of remanent magnetization and strains were still observed.The above phenomena seem to be the reflection of rheological properties of rocks.It is interesting to note that some similar phenomena were also found in field observations,such as aseismic geomagnetic changes and secular variation in local geomagnetic field before and after

Composition and Assemblage Characteristics of Magnetic Minerals in Layer S_(5-1) of Xifeng and Duanjiapo Sections

Relatively strongly magnetic fine components (<30μm, XS-4J and DS-4J) which are most environmentally sensitive were separated from layer S-{5-1} in the Xifeng and Duanjiapo loess sections and analyzed by MPV-3 for their morphometric characteristics and reflectance, SEM-ESD for their element contents and XRD for their mineral phases, respectively. The results showed that minerals in both samples are dominated by detrial Fe-Ti oxides of aeolian origin. In sample XS-4J the reflectance and iron contents of magnetic minerals are usually high. In addition to magnetite (Fe-3O-4), maghemite (γFe-2O-3) and hematite (Fe-2O-3), some Fe-high oxide ({72.25 wt%}-{86.67 wt%}), ilmenite (FeTiO-3), and magnetite-ulvspinel were also detected. In sample DS-4J obvious negative linear correlations were found between Ti and Fe, and the contents of Mn, Si, Al and Ca are usually high and the minerals are dominated by magnetite (maghemite), goethite (FeOOH) and limonite (containing Si and OH). In addition, the signs of corrosion of magnetic minerals and newly crystallized magnetite (maghemite) were recognized. Differences in the composition and assemblage characteristics of magnetite minerals between XS and DS reflect significant differences in source rocks and preserving conditions.

ROCK MAGNETISM OF LOW TEMPERATURE AND CHARACTER OF MAGNETIC PARTICLES IN LOESS

Ⅰ. INTRODUCTIONLoess strata in China consist of alternating loess and palaeosol layers; the loess represents the dust deposition in dry-cold climatic condition while the palaeosol is the product developed in warm-humid environment. The magnetic susceptibility of loess stratigraphy as a palaeoclimate indicator is a significant physical parameter, which was first put forward

MSSBAUER STUDY OF MAGNETISM AND CONTENT OF KRASNOZEM MAGNETIC MINERALS

The magnetism and content of soil magnetic minerals are the foundation of the soil magnetic genesis research and the application of the soil magnetism to the applied geophysics, archaeology and the environmental science. According to Mssbauer spectra

Rock magnetism and magnetic anisotropy in folded sills and basaltic flows:A case study of volcanics from the Taimyr Peninsula, Northern Russia

Magnetic measurements were performed on apparently deformed igneous rocks of 23 sites from the southeastern part of the Taimyr Peninsula. Rock magnetism and reflected light microscopy analyses reveal that fine-grained titanomagnetites up to pure magnetites mainly carry the majority of magnetic fabrics in the sills, and that the slightly coarser Ti-poor or -medium titanomagnetites carry most mag-netic fabrics in the basaltic flows. Magnetic anisotropies were determined by applying anisotropy of low-field magnetic susceptibility (AMS) on 180 unheated samples and 128 samples that had been pre-viously heated to 600°C during a paleomagnetic study to detect heating effects on the anisotropy of magnetic susceptibility (AMS) properties of volcanic rocks. Laboratory heating significantly affects anisotropy variations of these igneous rocks corresponding to the mineralogical changes during the heat treatment.

Mid-Late Quaternary loess-paleosol sequence in Lantian's Yushan,China:An environmental magnetism approach and its paleoclimatic significance

The application of rock magnetism methods to investigating the variations of magnetic minerals in the sediments is an important approach to the reestablishment of paleoclimate evolution. Thus we performed fine magnetic measurements on the loess-paleosol sequence (from L15 upwards to S5, in which L is short for Loess, S is short for Paleosol, the same hereinafter) of Yushan strati-graphic section, which is on the southeastern margin of Chinese Loess Plateau, in Lantian County of China's Shaanxi Province, and the thickness of which is ca. 40 m. Our study shows that the primary magnetic carriers of loess and paleosol in this section are magnetite, maghemite, hematite and goethite. Thermomagnetic analyses on the samples of representative horizons show that the higher pedogenesis degree of the sediments, the smaller variations of magnetization there will be before and after heating, probably related to the pedogenic alteration of loess sediments. Analyses of several magnetic parameters show a significant discrepancy between the paleoclimatic conditions recorded in the strata from the loess unit L15 upward to the paleosol unit S5 in the study area and those recorded in the relative strata of other sections on the Chinese Loess Plateau, and those recorded in marine sediments, indicating the great impact of regional geological background. Similarly, the rapid and intensive change recorded in the segment from L15 to S9-1, and the significant difference between the paleoclimate evolutions of the two periods before and after the change (from L15 to S9-1, and from L9 to the base of S6) indicate the strong alteration of magnetic carriers in the study area as a result of the alternations of summer and winter monsoons in East Asia.

Preliminary study on environmental magnetism of modern sediments in Kunming Lake and its implication

The study on global changes is an important international scientific program of IGBP organized by ICSU. It is also one of the most active programs in the area of natural sciences.Obviously, the study of global climate change in the past should be a focus of the modern scientific research. Its first task is to reconstruct historical sequences of climate. The research is not only the basis of knowing the climatic change in the past, but also the key to predict the climatic change trend in the coming 21st century. In the past two years, we have carried out some preliminary study of environmental magnetism by systematical sampling of modern sediments at a section in the Kunming Lake in the Sum-

Rock Magnetic Characterization of Fine Particles from Car Engines, Brake Pads and Tobacco: An Environmental Pilot Study on Oahu, Hawaii, USA

Today, it is well known that small airborne particles are very harmful to human health. For the first time in Hawaii we have conducted an environmental pilot study of fine magnetic particles on the island of Oahu, Hawaii, of particulate matter (PM) PM = 60, PM = 10, and PM = 2.5. In order to do a rock magnetic characterization we have performed low field susceptibility vs. temperature [k-T] experiments to determine the Curie points of small particles collected from exhaust pipes, as well as from brake pads of four different types of car engines using gasoline octane ratings of 87, 89, and 92. The Curie point determinations are very well defined and range from 292°C through 393°C and up to 660°C. In addition, we have conducted magnetic granulometry experiments on raw tobacco, burnt tobacco ashes, as well as on automotive engine exhaust, and brake pads in question. The results of the experiments show ferro and ferrimagnetic hysteresis loops with magnetic grain sizes ranging from superparamagnetic-multidomain [SP-MD], multidomain [MD] and pseudo-single domain [PSD] shown on the modified Day et al., diagram of Dunlop (2002). Thus far, the results we have obtained from this pilot study are in agreement with other studies conducted from cigarette ashes from Bulgaria. Our results could be correlated to the traffic-related PM in Rome, Italy where the SP fraction mainly occurs as coating of MD particles originated by localized stress in the oxidized outer shell surrounding the un-oxidized core of magnetite-like grains. All these magnetic particles have been reported to be very harmful to our human bodies (i.e. brain, lungs, heart, liver etc.).

Gravity and magnetic anomalies field characteristics in the South China Sea and its application for interpretation of igneous rocks

Igneous rocks in the South China Sea have broad prospects for oil and gas exploration.Integrated geophysical methods are important approaches to study the distribution of igneous rocks and to determine and identify igneous rock bodies.Aimed at the characteristics of gravity and magnetic fields in the South China Sea,several potential field processing methods are preferentially selected.Reduction to the pole by variable inclinations in the area of low magnetic latitudes is used to perform reduction processing on magnetic anomalies.The preferential continuation method is used to separate gravity and magnetic anomalies and extract the gravity and magnetic anomaly information of igneous rocks in the shallow part of the South China Sea.The 3D spatial equivalent distribution of igneous rocks in South China Sea is illustrated by the 3 D correlation imaging of magnetic anomalies.Since the local anomaly boundaries are highlighted gravity and magnetic gradients,the distribution characters of different igneous rocks are roughly outlined by gravity and magnetic correlation analysis weighted by gradient.The results show the distribution of igneous rocks is controlled and influenced by deep crustal structure and faulting.

Environmental magnetic measurements of marine sediments from Antarctica: implications to paleoclimate changes during the past 15 ka

In this paper, authors report some results obtained from systematic rock magnetic measurements on Core NP95 1 and Core NG93 1 , which were collected from the Prydz Bay, Eastern Antarctica and Great Wall Bay (Maxwell Bay), Western Antarctica respectively during the 11th and 9th CHINARE and a sequence of paleoclimate variations is well established based on sediment rock magnetic properties. In Antarctica, the magnetic properties show a close linkage to paleoenvironmental variations. The Core NP95 1 well recorded several paleoclimatic events, such as Heinrich event 1, Bolling Allerod warm period and Younger Dryas cold event. The Heinrich event 1 occurred at about 14 2 ka B.P., Younger Dryas cold event occurred between 11 7 ka B.P. and 10 3 ka B.P., and the boundary of Pleistocene and Holocene in Antarctica is 10 3 ka B.P.. In Holocene, two warm periods were recorded at about 10 0 ka B.P. and 6 0 ka B.P. with a little cold period between them. After 6 0 ka B.P. , two cores both recorded a cold climatic oscillation. Paleoclimate described by two cores rock magnetic measurements was simultaneously changed in Eastern and Western Antarctica during the same period two cores commonly covered.

Transformation relationship among different magnetic minerals within loess-paleosol sediments of the Chinese Loess Plateau

The dominant magnetic minerals and carriers of magnetic signals within the Chinese Loess Plateau are magnetite, maghemite, hematite, and goethite. In this study, we investigated the provenance and evo- lution of magnetic minerals during loess pedogenesis, using X-ray diffraction (XRD) and optical and electron microscopy, including field emission scanning electron microscopy (FESEM) and high- resolution transmission electron microscopy (HRTEM). Our results reveal that single- and multiphase mineral assemblages among magnetic minerals in the loess-paleosol sequence have been formed. Partial oxidation of coarse eolian magnetite has occurred in the desert source area and the oxidation degree is enhanced after deposition of the dust upon the Chinese Loess Plateau. This mode of origin resulted in a microtexture consisting of an inner magnetite core surrounded by a hematite rim, and strongly affected the magnetic characteristics of the loess. Goethite coexists with hematite in the loess and paleosol, and nanometer-scale hematite is formed upon goethite rims via dehydration. Our study provides direct mineralogical evidence of the magnetic record and paleoclimatic implications of the loess–paleosol sequence of the Chinese Loess Plateau.

ULF electric and magnetic anomalies accompanying the cracking of rock sample

The anomalies of electric-magnetic field and self-potential before earthquakes are important precursory phenom-ena. A simulating experiment study on the variations in ultra-low frequency (ULF) magnetic field and self-poten-tial during rock cracking was carried out in a magnetic field-free space. The results revealing in detail the whole process of the occurrences of electric and magnetic anomalies are significant for understanding the microscopic mechanism of ULF electric and magnetic signals. The experiment indicated that at the initial stage the slow changes in strain, self-potential and magnetic field with small amounts appeared firstly near the source of initial cracking, and then extended as the crack developed on. In the time domain, the self-potential anomaly emerged first and ULF magnetic field changes arose then. The shape of the ULF electric and magnetic anomaly varied ob-viously in early-, mid- and late-term of the test. The authors attributed the pulse-like changes of self-potential to the generation and movement of the accumulated electric charges during the cracking caused by charge separation on the crack tips within the sample. While the magnetic pulses of shorter-period at the last stage of the test, may be induced by instantaneous electric current of the accumulated charge during the cracking acceleration. The technical method and the observational results of this experiment are given in detail and the microscopic mechanism of elec-tric and magnetic precursors before earthquake are discussed in the present paper as well.

Magnetic Solid-Phase Extraction of Phthalate Esters from Environmental Water Samples using Fibrous Phenyl-functionalized Fe3O4@SiO2@KCC-1

A new kind of phenyl-functionalized magnetic fibrous mesoporous silica(Fe3 O4@Si O2@KCC-1-phenyl) was prepared by copolymerization as an efficient adsorbent for the magnetic extraction of phthalate esters from environmental water samples. The obtained Fe3 O4@Si O2@KCC-1-phenyl showed monodisperse fibrous spherical morphology, fairly strong magnetic response(29 emu/g), and an abundant π-electron system, which allowed rapid isolation of the Fe3 O4@Si O2@KCC-1-phenyl from solutions upon applying an appropriate magnetic field. Several variables that affect the extraction efficiency of the analytes,including the type of the elution solvent, amount of adsorbent, extraction time and reusability, were investigated and optimized. Under optimum conditions, the Fe3 O4@Si O2@KCC-1-phenyl was used for the extraction of four phthalate esters from environmental water samples followed by high-performance liquid chromatographic analysis. Validation experiments indicated that the developed method presented good linearity(0.1-20 ng/m L), low limit of detection(7.5-29 μg/L, S/N =3). The proposed method was applied to the determination of phthalate esters in different real water samples, with relative recoveries of 93%-103.4%and relative standard deviation of 0.8%-8.3%.

Rock magnetic property of gravity core CSH1 from the northern Okinawa Trough and the effect of early diagenesis

Detailed rock magnetic investigations were undertaken at 2 -4 cm interval for the gravity core CSHI （with a length of 17.36 m） from the northern Okinawa Trough. Time-scale of the core was constructed by two characteristic tephras and foraminferal assemblages, indicating an age of 50 ka for the bottom of the core. Except for three tephras and abrupt decrease in surface, there are little changes in all kinds of rock magnetic parameters that can be correlated to the climate change for the last 50 ka. Different from the common sediments, most S-ratios （S equals the negative ratio of IRM-0.3T to SIRM, which is an indicator of low coercivity content） of the sediments are smaller than 0. 9, which implies a substantial amount of magnetic minerals with high coercivity. The existence of iron sulphide （ greigite or pyrrhotite） is revealed by representative susceptibility - temperature curves showing 200 350 ℃ Curie temperature in addition to 580 ℃ of magnetite, and also by awful smell during heating and dark heating products. Both the occurrence of authigenic iron sulphide and quick decrease of magnetic parameters near the surface clearly show that sediments from Core CSHI have undergone early diagenesis. The featureless magnetic changes of the whole core except for three tephras mean that the post-depositonal alteration is so strong that most original signals have been destroyed. For the same reason, the organic matter in sediment and sulphate in pore water must have been consumed along with dissolution, precipitation of iron and manganese happening sequencially during the redox reaction series. Great caution must be taken when using these altered chemical parameters for the interpretation of climatic changes.

Paleoenvironmental significance investigation of loess magnetic fabric in a semiarid region

Here we report our recent magnetic fabric investigation of loess deposition in Shagou section, located at the northeastern Qilian Mountains, the northeastern rim of the Tibetan Plateau. On the basis of environmental magnetism data, we indicate that the variation of anisotropy of magnetic susceptibility (AMS) parameters, especially the foliation (F) and degree of anisotropy (P), might be more sensitive to the environmental change in the arid and semiarid regions than the magnetic susceptibility fluctuation. During the investigated interval, from 0.83 to 0.128 Ma, most of the middle to late Pleistocene significant climate change can be unraveled by the AMS parameters, such as the strengthening of cold/dry climate, the step drying event occurred nearly 250 ka, and the severe environmental change in MIS16. Our results also suggest that there is strong correlation between median diameter (Md) of grain size, F, and P. We propose that the AMS parameters can act as an important paleoenvironmental change indicator in the arid and semiarid regions.

Relationship between the Extent of Igneous Rocks and Deep Structures as Determined by Gravitational and Magnetic Data in the South China Sea

The distribution of oil and gas resources in the South China Sea and adjacent areas is closely related to the structural pattern that helped to define the controlling effect of deep processes on oil-bearing basins.Igneous rocks can record important information from deep processes.Deep structures such as faults,basin uplift and depression,Cenozoic basement and magnetic basement are all the results of energy exchange within the earth.The study of the relationship between igneous rocks and deep structures is of great significance for the study of the South China Sea.By using the minimum curvature potential field separation technique and the correlation analysis technique of gravitational and magnetic anomalies,the fusion of gravitational and magnetic data reflecting igneous rocks can be obtained,through which the igneous rocks with high susceptibility/high density or high susceptibility/low density can be identified.In this study area,igneous rocks do not develop in the Yinggehai basin,Qiongdongnan basin,Zengmu basin and Brunei-Sabah basin whilst igneous rocks with high susceptibility/high density or high susceptibility/low density are widely-developed in other basins.In undeveloped igneous areas,faults are also undeveloped the Cenozoic thickness is greater,the magnetic basement depth is greater and the Cenozoic thickness is highly positively correlated with the magnetic basement depth.In igneously developed regions,the distribution pattern of the Qiongtai block is mainly controlled by primary faults,while the distribution of the Zhongxisha block,Xunta block and Yongshu-Taiping block is mainly controlled by secondary faults,the Cenozoic thickness having a low correlation with the depth of the magnetic basement.

Ferrimagnetic Minerals in Red Paleosols of Pleistocene Epoch, Eastern China

The type, grain size and origin of ferrimagnetic minerals separated from red paleosols of Pleistocene Epoch (Q\-2) in eastern China, were studied by using mineral magnetic measurement, X\|ray powder diffraction and electron microscopy. Results showed that the iron oxides in red paleosols were composed of hematite (α\|Fe\-2O\-3), maghemite (γ\|Fe\-2O\-3) and goethite(α\|FeOOH). Mineral magnetic parameters and X\|ray diffraction patterns indicated that maghemite was the dominant remanence carrier in red paleosols, which is characterized by superparamagnetic (SP) and stable single domain (SSD) grains. The variations of magnetic susceptibility (χ), anhysteretic magnetic susceptibility (χ\-\{ARM\}) and saturation isothermal remanent magnetization (SIRM) for red paleosols following heating to various temperatures showed two peak values at 700℃ and 900℃. The spherulitic magnetic particles measuring \{250-1000\}μm in diameter in red paleosols were separated by the magnetic separation method, indicating that these magnetic particles were an assemblage of superparamagnetic and stable single domain ferrimagnetic grains. It is suggested that the ferrimagnetic minerals of red paleosols be a pedogenic ferrimagnetic component under high temperature and high humid conditions in the Pleistocene Epoch (Q\-2). It is concluded that the magnetism characteristics of red paleosols can be used to evaluate the environmental changes of Quaternary in eastern China.