The ever-increasing demand for oil and gas has driven its exploration in rather extreme conditions. In Lamu offshore, which is hitherto underexplored, most of the wells already drilled turned out dry save for a few we...The ever-increasing demand for oil and gas has driven its exploration in rather extreme conditions. In Lamu offshore, which is hitherto underexplored, most of the wells already drilled turned out dry save for a few wells with hydrocarbon shows despite the promising reservoir properties and related geological structures. This, therefore, necessitated a source rock evaluation study in the area to ascertain the presence and potential of the source rock by integrating the geochemical data analysis and petroleum system modeling. The shallow Lamu offshore source rock quantity, quality, and maturity have been estimated through the determination of the total organic carbon (TOC) average values, Kerogen typing, and Rock-Eval pyrolysis measurements respectively. Geochemical data for Kubwa-1, Mbawa-1, Pomboo-1, and Simba-1 were evaluated for determining the source rock potential for hydrocarbon generation. Petroleum system modeling was applied in evaluating geological conditions necessary for a successful charge within a software that integrated geochemical and petrophysical characterization of the sedimentary formations in conjunction with boundary conditions that include basal heat flow, sediment-water interface temperature, and Paleo-water depth. The average TOC of 0.89 wt % in the study area suggests a fair organic richness which seems higher in the late cretaceous (0.98 wt %) than in the Paleocene (0.81 wt %). Vitrinite reflectance and T<sub>max</sub> values in the study area indicate the possible presence of both mature and immature source rocks. Type III Kerogen was the most dominant Kerogen type, and gas shows are the most frequent hydrocarbon encountered in the Lamu Basin with a few cases registering type II/III and type II. The charge properties (i.e. Temperature, transformation ratio, and Vitrinite reflectance) over geologic time at each of the wells have been estimated and their spatial variation mapped as seen from the burial history and depth curves overlaid with temperature, transformation ratio, and Vitrinite reflectance respectively. From the upper cretaceous maturity maps, the results seem to favor near coastal regions where average TOC is about 1.4 wt %, Vitrinite reflectance is more than 0.5%, transformation ratio is more than 10%, and temperatures range from 80°C to 160°C. The results postulate the absence of a definitive effective source rock with a likelihood of having cases of potential and possible source rocks. Moreover, greater uncertainty rests on the source rock’s presence and viability tending toward the deep offshore. Geochemical analysis and petroleum system modeling for hydrocarbon source rock evaluation improved the understanding of the occurrence of the possible and potential source rocks and processes necessary for hydrocarbon generation.展开更多
High-precision data on U and Th contents and Th/U ratios of zircon obtained using secondary ion mass spectrometry analysis have been collected from the literature. Zircon in the granitic rocks has median values of 350...High-precision data on U and Th contents and Th/U ratios of zircon obtained using secondary ion mass spectrometry analysis have been collected from the literature. Zircon in the granitic rocks has median values of 350 ppm U, 140 ppm Th, and Th/U=0.52; the recommended zircon-melt partition coefficients are 81 for Du and 8.2 for DTh. In zircon from mafic and intermediate rocks, the median values are 270 ppm U, 170 ppm Th, and Th/U=0.81, and the recommended zirconmelt partition coefficients are 169 for Du and 59 for DTh. The U and Th contents and Th/U ratios of magmatic zircon are low when zircon crystallizes in equilibrium with the melt. Increasing magma temperature should promote higher Th contents relative to U contents, resulting in higher Th/U ratios for zircon in mafic to intermediate rocks than in granitic rocks. However, when zircon crystallizes in disequilibrium with the melt, U and Th are more easily able to enter the zircon lattice, and their contents and Th/U ratios depend mainly on the degree of disequilibrium. The behavior of U and Th in magmatic zircon can be used as a geochemical indicator to determine the origins and crystallization environments of magmatic zircon.展开更多
The generalized mixture rule(GMR) is used to provide a unified framework for describing Young’s(E),shear(G) and bulk(K) moduli, Lame parameter(l), and P- and S-wave velocities(Vpand Vs) as a function of porosity in v...The generalized mixture rule(GMR) is used to provide a unified framework for describing Young’s(E),shear(G) and bulk(K) moduli, Lame parameter(l), and P- and S-wave velocities(Vpand Vs) as a function of porosity in various isotropic materials such as metals, ceramics and rocks. The characteristic J values of the GMR for E, G, K and l of each material are systematically different and display consistent correlations with the Poisson’s ratio of the nonporous material(v0). For the materials dominated by corner-shaped pores, the fixed point at which the effective Poisson’s ratio(n) remains constant is at v0=0.2, and J(G) > J(E) > J(K) > J(l) and J(G) < J(E) < J(K) < J(l) for materials with v0> 0.2 and v0< 0.2, respectively.J(Vs) > J(Vp) and J(Vs) < J(Vp) for the materials with v0> 0.2 and v0< 0.2, respectively. The effective n increases, decreases and remains unchanged with increasing porosity for the materials with v0< 0.2,v0> 0.2 and v0=0.2, respectively. For natural rocks containing thin-disk-shaped pores parallel to mineral cleavages, grain boundaries and foliation, however, the n fixed point decreases nonlinearly with decreasing pore aspect ratio(a: width/length). With increasing depth or pressure, cracks with smaller a values are progressively closed, making the n fixed point rise and finally reach to the point at v0=0.2.展开更多
The load/unload experiments on rock failure under pressure have been carried out in Material Test System (MTS) in the Laboratory for Non-linear Mechanics of Continuous Media (LNM), Institute of Mechanics, Chinese Acad...The load/unload experiments on rock failure under pressure have been carried out in Material Test System (MTS) in the Laboratory for Non-linear Mechanics of Continuous Media (LNM), Institute of Mechanics, Chinese Academy of Sciences, and load/unload response ratio (LURR) values with strain as response (i.e. inverse elastic constant as response rate) have been obtained. The experimental results are in accordance with theoretical results and those in real earthquakes: LURR rises just before rock failure. So LURR can be used as the precursor of rock failure and earthquake prediction.展开更多
The effect of structural discontinuities on the progressive failure process of anisotropic rocks should be paid particular attention.The crack damage stress σ_(cd),also considered as the yield strength,and the relati...The effect of structural discontinuities on the progressive failure process of anisotropic rocks should be paid particular attention.The crack damage stress σ_(cd),also considered as the yield strength,and the relationship between σ_(cd) and the uniaxial peak strength σ_(ucs) of anisotropic rocks for different orientations 8 of the isotropy planes with respect to the loading directions were investigated theoretically and experimentally.A theoretical relation of σ_(cd)/σ_(ucs) with the function of the shape parameter m was established.Additionally,uniaxial compression tests of shale samples were conducted for several inclinations θ.The test result of σ_(cd)/σ_(ucs) was close to the theoretical value for a given orientation.Furthermore,both experimental results and theoretical solutions of σ_(cd)/σ_(ucs) were independent of the inclination θ while σ_(cd) andσ_(ucs) were strongly affected by θ.The strength ratio σ_(cd)/σ_(ucs) may therefore be an intrinsic property of anisotropic rocks and could be used to predict the failure of rock samples.展开更多
There is a coupling of thermal, mechanical, chemical and fluidal processes in a continental shear zone. Both Xincheng - Xishui and Hetai shear zones are typical continental crust shear zones of greenschist facies envi...There is a coupling of thermal, mechanical, chemical and fluidal processes in a continental shear zone. Both Xincheng - Xishui and Hetai shear zones are typical continental crust shear zones of greenschist facies environment. The representative mylonite zones of the shear zones are studied with whole rock major and trace element analyses. The chemical compositional variation tendencies in both shear zones are very similar and the gain - loss ratios of various components in the mylonitic rocks are reflected in the mass balance equations. The enrichment of those immobile high - field- strengh elements is considered to be related to the volume loss of the mylonitic rocks in a shear zone. Based on the volume loss expression Cs /Co = 1/(1- V), the fractional volume losses (V) are 37.5% and 36.5%-42.3% respectively for mylonites and ultramylonites in the Xincheng-Xishui shear zone and 11 % and 28% respectively for mylonites and phyllonites in the Hetai shear zone. The high volume loss and large removal of SiO2 from the system imply that there is a large amount of percolating fluids in the shear zones. From the SiO2 loss, the fluid/rock ratios (N) are calculated as Nmyl = 113 - 563, Nultramyl= 133-664 for the Xincheng-Xishui shear zone and Nmyl=42-208, Nphyl=110-550 for the Hetai shear zone. Such a large amount of percolating fluid must have profoundly affected the rheological behavior, chemical behavior and metallogenesis of the shear zones.展开更多
文摘The ever-increasing demand for oil and gas has driven its exploration in rather extreme conditions. In Lamu offshore, which is hitherto underexplored, most of the wells already drilled turned out dry save for a few wells with hydrocarbon shows despite the promising reservoir properties and related geological structures. This, therefore, necessitated a source rock evaluation study in the area to ascertain the presence and potential of the source rock by integrating the geochemical data analysis and petroleum system modeling. The shallow Lamu offshore source rock quantity, quality, and maturity have been estimated through the determination of the total organic carbon (TOC) average values, Kerogen typing, and Rock-Eval pyrolysis measurements respectively. Geochemical data for Kubwa-1, Mbawa-1, Pomboo-1, and Simba-1 were evaluated for determining the source rock potential for hydrocarbon generation. Petroleum system modeling was applied in evaluating geological conditions necessary for a successful charge within a software that integrated geochemical and petrophysical characterization of the sedimentary formations in conjunction with boundary conditions that include basal heat flow, sediment-water interface temperature, and Paleo-water depth. The average TOC of 0.89 wt % in the study area suggests a fair organic richness which seems higher in the late cretaceous (0.98 wt %) than in the Paleocene (0.81 wt %). Vitrinite reflectance and T<sub>max</sub> values in the study area indicate the possible presence of both mature and immature source rocks. Type III Kerogen was the most dominant Kerogen type, and gas shows are the most frequent hydrocarbon encountered in the Lamu Basin with a few cases registering type II/III and type II. The charge properties (i.e. Temperature, transformation ratio, and Vitrinite reflectance) over geologic time at each of the wells have been estimated and their spatial variation mapped as seen from the burial history and depth curves overlaid with temperature, transformation ratio, and Vitrinite reflectance respectively. From the upper cretaceous maturity maps, the results seem to favor near coastal regions where average TOC is about 1.4 wt %, Vitrinite reflectance is more than 0.5%, transformation ratio is more than 10%, and temperatures range from 80°C to 160°C. The results postulate the absence of a definitive effective source rock with a likelihood of having cases of potential and possible source rocks. Moreover, greater uncertainty rests on the source rock’s presence and viability tending toward the deep offshore. Geochemical analysis and petroleum system modeling for hydrocarbon source rock evaluation improved the understanding of the occurrence of the possible and potential source rocks and processes necessary for hydrocarbon generation.
基金supported by the National Natural Science Foundation of China(Grant No. 40972058)the research grants(2008-Ⅰ-02 and 2008-Ⅱ-08)from the State Key Laboratory for Mineral Deposit Research,Nanjing University
文摘High-precision data on U and Th contents and Th/U ratios of zircon obtained using secondary ion mass spectrometry analysis have been collected from the literature. Zircon in the granitic rocks has median values of 350 ppm U, 140 ppm Th, and Th/U=0.52; the recommended zircon-melt partition coefficients are 81 for Du and 8.2 for DTh. In zircon from mafic and intermediate rocks, the median values are 270 ppm U, 170 ppm Th, and Th/U=0.81, and the recommended zirconmelt partition coefficients are 169 for Du and 59 for DTh. The U and Th contents and Th/U ratios of magmatic zircon are low when zircon crystallizes in equilibrium with the melt. Increasing magma temperature should promote higher Th contents relative to U contents, resulting in higher Th/U ratios for zircon in mafic to intermediate rocks than in granitic rocks. However, when zircon crystallizes in disequilibrium with the melt, U and Th are more easily able to enter the zircon lattice, and their contents and Th/U ratios depend mainly on the degree of disequilibrium. The behavior of U and Th in magmatic zircon can be used as a geochemical indicator to determine the origins and crystallization environments of magmatic zircon.
文摘The generalized mixture rule(GMR) is used to provide a unified framework for describing Young’s(E),shear(G) and bulk(K) moduli, Lame parameter(l), and P- and S-wave velocities(Vpand Vs) as a function of porosity in various isotropic materials such as metals, ceramics and rocks. The characteristic J values of the GMR for E, G, K and l of each material are systematically different and display consistent correlations with the Poisson’s ratio of the nonporous material(v0). For the materials dominated by corner-shaped pores, the fixed point at which the effective Poisson’s ratio(n) remains constant is at v0=0.2, and J(G) > J(E) > J(K) > J(l) and J(G) < J(E) < J(K) < J(l) for materials with v0> 0.2 and v0< 0.2, respectively.J(Vs) > J(Vp) and J(Vs) < J(Vp) for the materials with v0> 0.2 and v0< 0.2, respectively. The effective n increases, decreases and remains unchanged with increasing porosity for the materials with v0< 0.2,v0> 0.2 and v0=0.2, respectively. For natural rocks containing thin-disk-shaped pores parallel to mineral cleavages, grain boundaries and foliation, however, the n fixed point decreases nonlinearly with decreasing pore aspect ratio(a: width/length). With increasing depth or pressure, cracks with smaller a values are progressively closed, making the n fixed point rise and finally reach to the point at v0=0.2.
基金This project was sponsored by the National Natural Science Foundation (No. 19732006), China and Ninth Five-year Plan, China Seismological Bureau.
文摘The load/unload experiments on rock failure under pressure have been carried out in Material Test System (MTS) in the Laboratory for Non-linear Mechanics of Continuous Media (LNM), Institute of Mechanics, Chinese Academy of Sciences, and load/unload response ratio (LURR) values with strain as response (i.e. inverse elastic constant as response rate) have been obtained. The experimental results are in accordance with theoretical results and those in real earthquakes: LURR rises just before rock failure. So LURR can be used as the precursor of rock failure and earthquake prediction.
基金supported by the Strategic Priority Research Program of the Chinese Academy of Sciences (No.XDB10030302)the National Natural Science Foundation of China (No.41302233)the Project funded by China Postdoctoral Science Foundation (No.2014T70121)
文摘The effect of structural discontinuities on the progressive failure process of anisotropic rocks should be paid particular attention.The crack damage stress σ_(cd),also considered as the yield strength,and the relationship between σ_(cd) and the uniaxial peak strength σ_(ucs) of anisotropic rocks for different orientations 8 of the isotropy planes with respect to the loading directions were investigated theoretically and experimentally.A theoretical relation of σ_(cd)/σ_(ucs) with the function of the shape parameter m was established.Additionally,uniaxial compression tests of shale samples were conducted for several inclinations θ.The test result of σ_(cd)/σ_(ucs) was close to the theoretical value for a given orientation.Furthermore,both experimental results and theoretical solutions of σ_(cd)/σ_(ucs) were independent of the inclination θ while σ_(cd) andσ_(ucs) were strongly affected by θ.The strength ratio σ_(cd)/σ_(ucs) may therefore be an intrinsic property of anisotropic rocks and could be used to predict the failure of rock samples.
基金The study is sponsored by the National Natural Science Foundation of China (No.49172090 ) and supported by the Open Laboratory of Crust- Mantle Constitution, Recycling and Dynamics of Ministry of Geology and Mineral Resources
文摘There is a coupling of thermal, mechanical, chemical and fluidal processes in a continental shear zone. Both Xincheng - Xishui and Hetai shear zones are typical continental crust shear zones of greenschist facies environment. The representative mylonite zones of the shear zones are studied with whole rock major and trace element analyses. The chemical compositional variation tendencies in both shear zones are very similar and the gain - loss ratios of various components in the mylonitic rocks are reflected in the mass balance equations. The enrichment of those immobile high - field- strengh elements is considered to be related to the volume loss of the mylonitic rocks in a shear zone. Based on the volume loss expression Cs /Co = 1/(1- V), the fractional volume losses (V) are 37.5% and 36.5%-42.3% respectively for mylonites and ultramylonites in the Xincheng-Xishui shear zone and 11 % and 28% respectively for mylonites and phyllonites in the Hetai shear zone. The high volume loss and large removal of SiO2 from the system imply that there is a large amount of percolating fluids in the shear zones. From the SiO2 loss, the fluid/rock ratios (N) are calculated as Nmyl = 113 - 563, Nultramyl= 133-664 for the Xincheng-Xishui shear zone and Nmyl=42-208, Nphyl=110-550 for the Hetai shear zone. Such a large amount of percolating fluid must have profoundly affected the rheological behavior, chemical behavior and metallogenesis of the shear zones.
