The application of phthalate plasticizers has been restricted around the world due to their poor migration and potential harm to the human body.Hence,producing functional bio-based plasticizers via exploiting clean an...The application of phthalate plasticizers has been restricted around the world due to their poor migration and potential harm to the human body.Hence,producing functional bio-based plasticizers via exploiting clean and reusable resources meets the satisfaction of current demands.In this study,flame-retardant rubber seed oil-based plasticize(FRP)was prepared via epoxidation reaction and ring opening addition reactions,which was used as a flame-resistant plasticizer for polyvinyl chloride to replace petroleum-based phthalate plasticizer.When DOP was replaced with FRP,the torque of PVC blends increased from 11.4 to 18.4 N⋅m,the LOI value increased from 24.3%for PVC-FRP-0%to 33.1%for PVC-FRP-20.The THR value diminished from 39 MJ/m^(2)(pertaining to PVC-FRC-0)to 22 MJ/m^(2)Tg increased from 23°C to 47°C,the weight loss of plasticized PVC blends significantly reduced from 22.6%to 2.8%in leaching tests.The study provided a new way to prepare flame retardant plasticizer using rubber seed oil as raw material.展开更多
Shandong Gaomi Mida Rubber & Plastic Products Co., Ltd. (est. 1992) is a new high-technology enterprise that produces various kinds of parts for both washing machines and automobiles.
Calotropis procera(Aiton)W.T.Aiton,belonging to the family Apocynaceae,is C3 evergreen plant species in arid and semi-arid areas of the Punjab Province,Pakistan.It grows in a variety of habitats like salt affected and...Calotropis procera(Aiton)W.T.Aiton,belonging to the family Apocynaceae,is C3 evergreen plant species in arid and semi-arid areas of the Punjab Province,Pakistan.It grows in a variety of habitats like salt affected and waterlogged area,desert/semi-desert,roadside,wasteland,graveyard,forest,crop field,coastline,and river/canal bank.A total of 12 populations growing in different ecological regions were sampled to evaluate their growth,physio-biochemical,and anatomical responses to specific environmental condition.Population adapted to desert/semi-desert showed vigorous growth(plant height,shoot length,and number of leaves),enhanced photosynthetic level(chlorophyll a,chlorophyll b,carotenoids,and total chlorophyll),and apparent anatomical modifications such as increased stem radius,cuticle thickness,storage parenchyma tissues(cortex and pith),and vascular bundles in stems,while the maximum of midrib and lamina thickness,epidermal cells,cuticle thickness,cortical proportion,abaxial stomatal density,and its area in leaves.There was high plasticity in structural and functional features of these populations,which enable them to survive and tolerate under such hot and dry desert environment.Population of saline areas exhibited very critical modifications to sustain under salt prone environment.At physiological level,it possesses the maximum amount of organic osmolytes(glycine betaine and proline)and antioxidants(superoxide dismutase(SOD),catalase(CAT),and peroxidase(POD)),while at anatomical level,it showed intensive sclerification,large phloem region(inner and outer),pith parenchyma cells,and metaxylem vessels in stems and leaves.The population of dry mountains showed very distinctive features,such as increased shoot ionic contents(K+and Ca2+),collenchyma and sclerenchyma thickness in stems,trichomes size,and numerous small stomata on abaxial surface of leaves.It is concluded that no definite or precise single character can be taken as a yardstick for adjudging the biomass production in this rubber bush weed population.展开更多
The pyrolysis experiments were carried out in a continuous feeding rotary kiln pyrolyzer system and the influence of residence time and temperature on the pyrolysis of waste rubber and plastics has been investigated i...The pyrolysis experiments were carried out in a continuous feeding rotary kiln pyrolyzer system and the influence of residence time and temperature on the pyrolysis of waste rubber and plastics has been investigated in this paper.It shows that the extent of pyrolysis was maximum when the revolving speed was 1~2r/min and the temperature was 600℃.展开更多
In this study,microstructure and mechanical behavior of two types of Mg-based bimetal plates with a high formability sleeve were systematically studied,with a great emphasis on the effect of the interface characterist...In this study,microstructure and mechanical behavior of two types of Mg-based bimetal plates with a high formability sleeve were systematically studied,with a great emphasis on the effect of the interface characteristic and the sleeve fraction on the plasticity of composite plates.The rule of mixtures(ROM)for elongation was also addressed.The results show that when there is no or thin diffusion layer with thickness of about 3μm,Mg-based bimetal plates have a good plasticity with elongation of about 19-24%,and the ROM predicted elongations are very close to the experimental ones.In contrast,with a diffusion layer about 95-155μm thick,Mg-based bimetal plates exhibit a poor plasticity with elongation of about 11-17%,and the experimental elongations largely deviate from the ROM predictions.The plasticity of Mg-based bimetal plates increases with increasing sleeve fraction.This study provides new insights on the plastic deformation of Mg-based bimetal composites with a high formability sleeve.展开更多
基金funded by the Science and Technology Project of Henan Province(202102310593)and Science and Technology Project of Kaifeng City(2002003).
文摘The application of phthalate plasticizers has been restricted around the world due to their poor migration and potential harm to the human body.Hence,producing functional bio-based plasticizers via exploiting clean and reusable resources meets the satisfaction of current demands.In this study,flame-retardant rubber seed oil-based plasticize(FRP)was prepared via epoxidation reaction and ring opening addition reactions,which was used as a flame-resistant plasticizer for polyvinyl chloride to replace petroleum-based phthalate plasticizer.When DOP was replaced with FRP,the torque of PVC blends increased from 11.4 to 18.4 N⋅m,the LOI value increased from 24.3%for PVC-FRP-0%to 33.1%for PVC-FRP-20.The THR value diminished from 39 MJ/m^(2)(pertaining to PVC-FRC-0)to 22 MJ/m^(2)Tg increased from 23°C to 47°C,the weight loss of plasticized PVC blends significantly reduced from 22.6%to 2.8%in leaching tests.The study provided a new way to prepare flame retardant plasticizer using rubber seed oil as raw material.
文摘Shandong Gaomi Mida Rubber & Plastic Products Co., Ltd. (est. 1992) is a new high-technology enterprise that produces various kinds of parts for both washing machines and automobiles.
文摘Calotropis procera(Aiton)W.T.Aiton,belonging to the family Apocynaceae,is C3 evergreen plant species in arid and semi-arid areas of the Punjab Province,Pakistan.It grows in a variety of habitats like salt affected and waterlogged area,desert/semi-desert,roadside,wasteland,graveyard,forest,crop field,coastline,and river/canal bank.A total of 12 populations growing in different ecological regions were sampled to evaluate their growth,physio-biochemical,and anatomical responses to specific environmental condition.Population adapted to desert/semi-desert showed vigorous growth(plant height,shoot length,and number of leaves),enhanced photosynthetic level(chlorophyll a,chlorophyll b,carotenoids,and total chlorophyll),and apparent anatomical modifications such as increased stem radius,cuticle thickness,storage parenchyma tissues(cortex and pith),and vascular bundles in stems,while the maximum of midrib and lamina thickness,epidermal cells,cuticle thickness,cortical proportion,abaxial stomatal density,and its area in leaves.There was high plasticity in structural and functional features of these populations,which enable them to survive and tolerate under such hot and dry desert environment.Population of saline areas exhibited very critical modifications to sustain under salt prone environment.At physiological level,it possesses the maximum amount of organic osmolytes(glycine betaine and proline)and antioxidants(superoxide dismutase(SOD),catalase(CAT),and peroxidase(POD)),while at anatomical level,it showed intensive sclerification,large phloem region(inner and outer),pith parenchyma cells,and metaxylem vessels in stems and leaves.The population of dry mountains showed very distinctive features,such as increased shoot ionic contents(K+and Ca2+),collenchyma and sclerenchyma thickness in stems,trichomes size,and numerous small stomata on abaxial surface of leaves.It is concluded that no definite or precise single character can be taken as a yardstick for adjudging the biomass production in this rubber bush weed population.
文摘The pyrolysis experiments were carried out in a continuous feeding rotary kiln pyrolyzer system and the influence of residence time and temperature on the pyrolysis of waste rubber and plastics has been investigated in this paper.It shows that the extent of pyrolysis was maximum when the revolving speed was 1~2r/min and the temperature was 600℃.
基金supported by the National Key Research and Development Program of China (No.2022YFB3708400)the Guangdong Major Project of Basic and Applied Basic Research (No.2020B0301030006)+3 种基金the Guangdong Academy of Science Fund (No.2020GDASYL-20200101001,2021GDASYL-20210102002,2021GDASYL-20210103103)the National Natural Science Foundation of China (Nos.51905111 and 12002092)the Youth Talent Support Programme of Guangdong Provincial Association for Science and Technology (No.SKXRC202301)the Natural Science Foundation of Guangdong Province (Nos.2021A1515011730 and 2019A1515012096).
文摘In this study,microstructure and mechanical behavior of two types of Mg-based bimetal plates with a high formability sleeve were systematically studied,with a great emphasis on the effect of the interface characteristic and the sleeve fraction on the plasticity of composite plates.The rule of mixtures(ROM)for elongation was also addressed.The results show that when there is no or thin diffusion layer with thickness of about 3μm,Mg-based bimetal plates have a good plasticity with elongation of about 19-24%,and the ROM predicted elongations are very close to the experimental ones.In contrast,with a diffusion layer about 95-155μm thick,Mg-based bimetal plates exhibit a poor plasticity with elongation of about 11-17%,and the experimental elongations largely deviate from the ROM predictions.The plasticity of Mg-based bimetal plates increases with increasing sleeve fraction.This study provides new insights on the plastic deformation of Mg-based bimetal composites with a high formability sleeve.
