Polar components play a very important role toward light stability of hydrotreated naphthenic rubber process oil. Polar components in hydrotreated naphthenic rubber process oil are analyzed in detail. Polar components...Polar components play a very important role toward light stability of hydrotreated naphthenic rubber process oil. Polar components in hydrotreated naphthenic rubber process oil are analyzed in detail. Polar components are firstly isolated from rubber process oil by column chromatography of silica gel, and then characterized by a series of instrument technology including elemental analysis, infrared spectroscopy, APCI/MS and XPS. The results show that the polar components comprise some hetero atoms compounds of sulfur, nitrogen and oxygen. Oxygen-containing compounds such as hydroxyl, carbonyl, and carboxyl groups constitute the main body of polar components. Nitrogen-containing compounds （NH2, NH, or NO2 and-N=N-） and sulfur-containing compounds (SO42- and PHSSPH) only account for minor percent of polar components. The molecular weight distribution of polar components mainly concentrates between 300 and 500 and a minor portion distributes from 180 to 300.展开更多
The curing process of rubber fender was investigated. A parabola model was put forward for the first time, which described variation of rubber thermal properties such as heat conduction and specific heat. Based on Kam...The curing process of rubber fender was investigated. A parabola model was put forward for the first time, which described variation of rubber thermal properties such as heat conduction and specific heat. Based on Kamal and Sourour model, a modified Rafei kinetic model was used to predict the rubber curing kinetics. To compare with experimental data, the fender curing process was simulated by parabola model and linear model respectively. Additionally, the curing craft and structure of the fender were modified and evaluated based on finite element analysis （FEA）. As a result, the curing uniformity and efficiency of the fender was highly improved. It was investigated that, the parabola model correlated the rubber thermal behavior more precisely. The numerical prediction was in good agreement with the experimental evaluation.展开更多
Based on the analysis of the preparation of metal rubber （MR） and two pivotal hypotheses, the uniform distribution and the unaltered topological structure of wires in the radial direction of columns in the punch pro...Based on the analysis of the preparation of metal rubber （MR） and two pivotal hypotheses, the uniform distribution and the unaltered topological structure of wires in the radial direction of columns in the punch process, a 3D parametrical model was established based on four approaches： helix-making, planar roughcast-weaving, planar roughcast-rolling, and 3D roughcast punching. In the modeling process, 5 lattice types of weave patterns in planar roughcast were put forward, and 10 quantificational modeling parameters were picked up to exclusively define the column MR component structure. The wire distribution was visualized by CAD techniques. The important performance parameter of column MR components （relative density ρ^- ） can be forecasted by modeling computing, which provides the necessary foundation for the design and optimization of MR materials.展开更多
To overcome the large time-delay in measuring the hardness of mixed rubber, rheological parameters were used to predict the hardness. A novel Q-based model updating strategy was proposed as a universal platform to tra...To overcome the large time-delay in measuring the hardness of mixed rubber, rheological parameters were used to predict the hardness. A novel Q-based model updating strategy was proposed as a universal platform to track time-varying properties. Using a few selected support samples to update the model, the strategy could dramat- ically save the storage cost and overcome the adverse influence of low signal-to-noise ratio samples. Moreover, it could be applied to any statistical process monitoring system without drastic changes to them, which is practical for industrial practices. As examples, the Q-based strategy was integrated with three popular algorithms （partial least squares （PIE）, recursive PIE （RPLS）, and kernel PIE （KPIE）） to form novel regression ones, QPLS, QRPIE and QKPLS, respectively. The applications for predicting mixed rubber hardness on a large-scale tire plant in east China prove the theoretical considerations.展开更多
The mix designs and specimen preparation for the dry process and wet process of sulfur rubber conerete （ SRC ） were investigated. The compressive strength, corrosion-resistance and toughness were studied and discuss...The mix designs and specimen preparation for the dry process and wet process of sulfur rubber conerete （ SRC ） were investigated. The compressive strength, corrosion-resistance and toughness were studied and discussed. The results show that SRC is corrosion-resistanet. Although the compressive strength of SRC decreases with inereasing rubber content, the toughness increases instead . Adding micro-filler will improve the compressive strength of SRC . There is a threshold value for the sulfur content, at which the compressive strength and the workability of SRC reach an optimum balance . The bond between rubber particles and surrounding sulfur is strong due to the vulcanization process that generates cross-link through S-C bonds.展开更多
文摘Polar components play a very important role toward light stability of hydrotreated naphthenic rubber process oil. Polar components in hydrotreated naphthenic rubber process oil are analyzed in detail. Polar components are firstly isolated from rubber process oil by column chromatography of silica gel, and then characterized by a series of instrument technology including elemental analysis, infrared spectroscopy, APCI/MS and XPS. The results show that the polar components comprise some hetero atoms compounds of sulfur, nitrogen and oxygen. Oxygen-containing compounds such as hydroxyl, carbonyl, and carboxyl groups constitute the main body of polar components. Nitrogen-containing compounds （NH2, NH, or NO2 and-N=N-） and sulfur-containing compounds (SO42- and PHSSPH) only account for minor percent of polar components. The molecular weight distribution of polar components mainly concentrates between 300 and 500 and a minor portion distributes from 180 to 300.
基金Funded by the National Natural Science Foundation of China(No. 51005108)Natural Science Research Project of Jiangsu Province Colleges and Universities(No.12KJB430006)Graduate Students' Scientific Research Innovation Project of Jiangsu Province Ordinary University (No.CXZZ12_0666)
文摘The curing process of rubber fender was investigated. A parabola model was put forward for the first time, which described variation of rubber thermal properties such as heat conduction and specific heat. Based on Kamal and Sourour model, a modified Rafei kinetic model was used to predict the rubber curing kinetics. To compare with experimental data, the fender curing process was simulated by parabola model and linear model respectively. Additionally, the curing craft and structure of the fender were modified and evaluated based on finite element analysis （FEA）. As a result, the curing uniformity and efficiency of the fender was highly improved. It was investigated that, the parabola model correlated the rubber thermal behavior more precisely. The numerical prediction was in good agreement with the experimental evaluation.
文摘Based on the analysis of the preparation of metal rubber （MR） and two pivotal hypotheses, the uniform distribution and the unaltered topological structure of wires in the radial direction of columns in the punch process, a 3D parametrical model was established based on four approaches： helix-making, planar roughcast-weaving, planar roughcast-rolling, and 3D roughcast punching. In the modeling process, 5 lattice types of weave patterns in planar roughcast were put forward, and 10 quantificational modeling parameters were picked up to exclusively define the column MR component structure. The wire distribution was visualized by CAD techniques. The important performance parameter of column MR components （relative density ρ^- ） can be forecasted by modeling computing, which provides the necessary foundation for the design and optimization of MR materials.
文摘To overcome the large time-delay in measuring the hardness of mixed rubber, rheological parameters were used to predict the hardness. A novel Q-based model updating strategy was proposed as a universal platform to track time-varying properties. Using a few selected support samples to update the model, the strategy could dramat- ically save the storage cost and overcome the adverse influence of low signal-to-noise ratio samples. Moreover, it could be applied to any statistical process monitoring system without drastic changes to them, which is practical for industrial practices. As examples, the Q-based strategy was integrated with three popular algorithms （partial least squares （PIE）, recursive PIE （RPLS）, and kernel PIE （KPIE）） to form novel regression ones, QPLS, QRPIE and QKPLS, respectively. The applications for predicting mixed rubber hardness on a large-scale tire plant in east China prove the theoretical considerations.
基金Funded by the Natural Science Foundation of China ( No.50408004)
文摘The mix designs and specimen preparation for the dry process and wet process of sulfur rubber conerete （ SRC ） were investigated. The compressive strength, corrosion-resistance and toughness were studied and discussed. The results show that SRC is corrosion-resistanet. Although the compressive strength of SRC decreases with inereasing rubber content, the toughness increases instead . Adding micro-filler will improve the compressive strength of SRC . There is a threshold value for the sulfur content, at which the compressive strength and the workability of SRC reach an optimum balance . The bond between rubber particles and surrounding sulfur is strong due to the vulcanization process that generates cross-link through S-C bonds.
