期刊文献+
共找到2,412篇文章
< 1 2 121 >
每页显示 20 50 100
Elastic wave insulation and propagation control based on the programmable curved-beam periodic structure
1
作者 Jiajia MAO Hong CHENG Tianxue MA 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第10期1791-1806,共16页
Curved-beams can be used to design modular multistable metamaterials(MMMs)with reprogrammable material properties,i.e.,programmable curved-beam periodic structure(PCBPS),which is promising for controlling the elastic ... Curved-beams can be used to design modular multistable metamaterials(MMMs)with reprogrammable material properties,i.e.,programmable curved-beam periodic structure(PCBPS),which is promising for controlling the elastic wave propagation.The PCBPS is theoretically equivalent to a spring-oscillator system to investigate the mechanism of bandgap,analyze the wave propagation mechanisms,and further form its geometrical and physical criteria for tuning the elastic wave propagation.With the equivalent model,we calculate the analytical solutions of the dispersion relations to demonstrate its adjustability,and investigate the wave propagation characteristics through the PCBPS.To validate the equivalent system,the finite element method(FEM)is employed.It is revealed that the bandgaps of the PCBPS can be turned on-and-off and shifted by varying its physical and geometrical characteristics.The findings are highly promising for advancing the practical application of periodic structures in wave insulation and propagation control. 展开更多
关键词 curved-beam based periodic structure equivalent stiffness spring-oscillator system dispersion relation wave propagation
下载PDF
Noether's theorem for non-conservative Hamilton system based on El-Nabulsi dynamical model extended by periodic laws 被引量:5
2
作者 龙梓轩 张毅 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第11期359-367,共9页
This paper focuses on the Noether symmetries and the conserved quantities for both holonomic and nonholonomic systems based on a new non-conservative dynamical model introduced by E1-Nabulsi. First, the E1-Nabulsi dyn... This paper focuses on the Noether symmetries and the conserved quantities for both holonomic and nonholonomic systems based on a new non-conservative dynamical model introduced by E1-Nabulsi. First, the E1-Nabulsi dynamical model which is based on a fractional integral extended by periodic laws is introduced, and E1-Nabulsi-Hamilton's canoni- cal equations for non-conservative Hamilton system with holonomic or nonholonomic constraints are established. Second, the definitions and criteria of E1-Nabulsi-Noether symmetrical transformations and quasi-symmetrical transformations are presented in terms of the invariance of E1-Nabulsi-Hamilton action under the infinitesimal transformations of the group. Fi- nally, Noether's theorems for the non-conservative Hamilton system under the E1-Nabulsi dynamical system are established, which reveal the relationship between the Noether symmetry and the conserved quantity of the system. 展开更多
关键词 Noether's theorem non-conservative Hamilton system E1-Nabulsi dynamical model fractionalintegral extended by periodic laws
下载PDF
Geographic Drone-based Route Optimization Approach for Emergency Area Ad-Hoc Network
3
作者 V.Krishnakumar R.Asokan 《Computer Systems Science & Engineering》 SCIE EI 2023年第4期985-1000,共16页
Wireless sensor Mobile ad hoc networks have excellent potential in moving and monitoring disaster area networks on real-time basis.The recent challenges faced in Mobile Ad Hoc Networks(MANETs)include scalability,local... Wireless sensor Mobile ad hoc networks have excellent potential in moving and monitoring disaster area networks on real-time basis.The recent challenges faced in Mobile Ad Hoc Networks(MANETs)include scalability,localization,heterogeneous network,self-organization,and self-sufficient operation.In this background,the current study focuses on specially-designed communication link establishment for high connection stability of wireless mobile sensor networks,especially in disaster area network.Existing protocols focus on location-dependent communications and use networks based on typically-used Internet Protocol(IP)architecture.However,IP-based communications have a few limitations such as inefficient bandwidth utilization,high processing,less transfer speeds,and excessive memory intake.To overcome these challenges,the number of neighbors(Node Density)is minimized and high Mobility Nodes(Node Speed)are avoided.The proposed Geographic Drone Based Route Optimization(GDRO)method reduces the entire overhead to a considerable level in an efficient manner and significantly improves the overall performance by identifying the disaster region.This drone communicates with anchor node periodically and shares the information to it so as to introduce a drone-based disaster network in an area.Geographic routing is a promising approach to enhance the routing efficiency in MANET.This algorithm helps in reaching the anchor(target)node with the help of Geographical Graph-Based Mapping(GGM).Global Positioning System(GPS)is enabled on mobile network of the anchor node which regularly broadcasts its location information that helps in finding the location.In first step,the node searches for local and remote anticipated Expected Transmission Count(ETX),thereby calculating the estimated distance.Received Signal Strength Indicator(RSSI)results are stored in the local memory of the node.Then,the node calculates the least remote anticipated ETX,Link Loss Rate,and information to the new location.Freeway Heuristic algorithm improves the data speed,efficiency and determines the path and optimization problem.In comparison with other models,the proposed method yielded an efficient communication,increased the throughput,and reduced the end-to-end delay,energy consumption and packet loss performance in disaster area networks. 展开更多
关键词 Mobile ad hoc networks(MANETs) geographical graph-based mapping(GGM) geographic drone based route optimization data speed anchor node’s
下载PDF
简易烈度计记录的噪声水平评价:以泸定M_(S)6.8级地震为例
4
作者 郭文轩 任叶飞 +4 位作者 姚鑫鑫 岸田忠大 江鹏 王宏伟 温瑞智 《振动与冲击》 EI CSCD 北大核心 2024年第18期313-320,共8页
在我国地震预警和烈度速报系统中,烈度计被广泛使用。烈度计的频谱特征主要是通过检定实验室进行标定,但在破坏性地震中,烈度计响应特点缺少必要的研究分析。该文以2022年四川泸定M_(S)6.8级地震为例,对比分析了烈度计记录和强震仪记录... 在我国地震预警和烈度速报系统中,烈度计被广泛使用。烈度计的频谱特征主要是通过检定实验室进行标定,但在破坏性地震中,烈度计响应特点缺少必要的研究分析。该文以2022年四川泸定M_(S)6.8级地震为例,对比分析了烈度计记录和强震仪记录在噪声水平、信噪比(signal-to-noise ratio,SNR)、高通滤波截止频率(f_(HP))取值以及有效周期范围(T_(max))方面的特点,综合评价了烈度计记录的频谱特征,分析了噪声影响。得到以下结论:在整个频域范围内,烈度计记录的SNR要比强震仪记录平均意义上低一个数量级,可以估计烈度计动态范围较强震仪大致低20 dB;烈度计记录的最佳f_(HP)取值相较于强震仪记录存在更大的不确定性,尤其是在竖直方向上;烈度计记录的最佳f_(HP)取值更大,反应谱T_(max)较传统强震仪记录在水平方向小1~2 s,在竖直方向小3 s左右。该研究结果有助于合理应用烈度计记录,服务地震学和地震工程学相关研究。 展开更多
关键词 烈度计记录 信噪比(sNR) 高通滤波截止频率 有效周期范围 泸定6.8级地震
下载PDF
基于潮汐附加构造应力的2013年灯塔M_(S)5.1地震射出长波辐射变化分析
5
作者 荆涛 Boonphor Phetphouthongdy +4 位作者 Chansouk Sioudom 刘洋洋 李继庚 康春丽 马未宇 《地震》 CSCD 北大核心 2024年第2期52-62,共11页
针对2013年1月23日辽宁灯塔M_(S)5.1地震,利用引潮力附加构造应力(Additional Tectonic Stress Caused By Tidal Force,ATSCTF)计算模型,计算得到震中位置(41.5°N,123.2°E)在地震前5周以及震后3周(2012年12月16日—2013年2月1... 针对2013年1月23日辽宁灯塔M_(S)5.1地震,利用引潮力附加构造应力(Additional Tectonic Stress Caused By Tidal Force,ATSCTF)计算模型,计算得到震中位置(41.5°N,123.2°E)在地震前5周以及震后3周(2012年12月16日—2013年2月15日)的ATSCTF变化。地震发生时,ATSCTF垂直方向分量处于高相位点附近,显示引潮力对本次正断层走滑型地震具有诱发作用。以ATSCTF变化周期的各低相位点时间(2012年12月19日、2013年1月4日、2013年1月18日、2013年2月2日)数据分别为背景,各周期期后数据分别与背景逐日相减,计算研究区(36°N~46°N,118°E~128°E)范围内,National Oceanic and Atmospheric Administration(NOAA)卫星射出长波辐射数据(Outgoing Long Wave Radiation,OLR)在各ATSCTF周期时段分布及其变化。结果显示,无震的ATSCTF变化的A、B、D周期,震中附近OLR无变化;发震的ATSCTF变化的C周期,在空间上,该地区震前OLR仅震中及其南侧区域发生了显著连续升高变化过程,在时间上经历了初始微异常→异常加强→高峰→衰减→发震→平静的演化过程,与岩石应力加载—破裂经历:初始微动破裂→扩张破裂→应力闭锁→地震爆发→平静的力学演化过程中各阶段红外辐射特征一致;显示引潮力对处于临界状态的活动断层具有诱发作用,而OLR是地震构造应力应变过程辐射表征。 展开更多
关键词 2013年灯塔M_(s)5.1地震 长波辐射 潮汐附加构造应力 震前ATsCTF周期异常
下载PDF
BIODRILL S合成基钻井液在垦利区块首次应用
6
作者 彭三兵 李斌 +3 位作者 韩东东 徐磊 程龙生 黄贤斌 《钻井液与完井液》 CAS 北大核心 2024年第1期60-67,共8页
渤海油田垦利9-1区块地层岩性复杂,且存在断层带,钻井过程中易发生泥岩水化分散和砂岩层井眼缩径等问题,井壁垮塌风险极大。针对该区块地层岩性特点和技术难题并结合环保要求,制备了一种复合型封堵材料PFMOSHIELD,构建了BIODRILL S合成... 渤海油田垦利9-1区块地层岩性复杂,且存在断层带,钻井过程中易发生泥岩水化分散和砂岩层井眼缩径等问题,井壁垮塌风险极大。针对该区块地层岩性特点和技术难题并结合环保要求,制备了一种复合型封堵材料PFMOSHIELD,构建了BIODRILL S合成基钻井液体系。该体系流变性能良好,抗钙、抗岩屑污染达26%和15%,封堵性、沉降稳定性、润滑性优异,高温高压砂盘滤失量3.2 mL,静置7 d沉降因子为0.53,极压润滑系数0.082。BIODRILL S首次在渤海湾垦利9-1区块进行了现场应用,结果表明:该体系解决了垦利9-1区块泥页岩水化和砂岩层井眼缩径问题,垦利9-1北-3定向探井三开井段上部地层钻屑完整,钻屑达4~7 cm;井眼清洁性能良好,钻井液动塑比超过0.59 Pa/mPa·s,φ6和φ3读数均超过9,剪切稀释性强,提高了井眼净化效率,有效避免形成“岩屑床”;润滑性能优异,在大井斜段(55°、70°、67°)可实现直接起钻。 展开更多
关键词 合成基钻井液 BIODRILL s 渤海油田 垦利区块
下载PDF
Application of periodic orbit theory in chaos-based security analysis 被引量:3
7
作者 龙敏 丘水生 《Chinese Physics B》 SCIE EI CAS CSCD 2007年第8期2254-2258,共5页
Chaos-based encryption schemes have been studied extensively, while the security analysis methods for them are still problems to be resolved. Based on the periodic orbit theory, this paper proposes a novel security an... Chaos-based encryption schemes have been studied extensively, while the security analysis methods for them are still problems to be resolved. Based on the periodic orbit theory, this paper proposes a novel security analysis method. The periodic orbits theory indicates that the fundamental frequency of the spiraling orbits is the natural frequency of associated linearized system, which is decided by the parameters of the chaotic system. Thus, it is possible to recover the plaintext of secure communication systems based on chaotic shift keying by getting the average time on the spiraling orbits. Analysis and simulation results show that the security analysis method can break chaos shift keying secure communication systems, which use the parameters as keys. 展开更多
关键词 periodic orbit theory secure communication chaos-based security analysis
下载PDF
Risk assessment of water security in Haihe River Basin during drought periods based on D-S evidence theory 被引量:7
8
作者 Qian-jin DONG Xia LIU 《Water Science and Engineering》 EI CAS CSCD 2014年第2期119-132,共14页
The weights of the drought risk index (DRI), which linearly combines the reliability, resiliency, and vulnerability, are difficult to obtain due to complexities in water security during drought periods. Therefore, d... The weights of the drought risk index (DRI), which linearly combines the reliability, resiliency, and vulnerability, are difficult to obtain due to complexities in water security during drought periods. Therefore, drought entropy was used to determine the weights of the three critical indices. Conventional simulation results regarding the risk load of water security during drought periods were often regarded as precise. However, neither the simulation process nor the DRI gives any consideration to uncertainties in drought events. Therefore, the Dempster-Shafer (D-S) evidence theory and the evidential reasoning algorithm were introduced, and the DRI values were calculated with consideration of uncertainties of the three indices. The drought entropy and evidential reasoning algorithm were used in a case study of the Haihe River Basin to assess water security risks during drought periods. The results of the new DRI values in two scenarios were compared and analyzed. It is shown that the values of the DRI in the D-S evidence algorithm increase slightly from the original results of Zhang et al. (2005), and the results of risk assessment of water security during drought periods are reasonable according to the situation in the study area. This study can serve as a reference for further practical application and planning in the Haihe River Basin, and other relevant or similar studies. 展开更多
关键词 risk assessment water security drought periods entropy D-s evidence theory "evidential reasoning algorithm Haihe River Basin
下载PDF
水性抗氧剂组成以及含量对ASA树脂性能的影响
9
作者 刘孟恩 汤千熠 +1 位作者 张明耀 刘伯军 《中国塑料》 CAS CSCD 北大核心 2024年第3期73-78,共6页
采用乳液聚合法制备了核壳比为6/4的ASA核壳接枝共聚物胶乳,系统地研究了水性抗氧剂的组成以及含量对ASA接枝共聚物热氧老化性能的影响,并采用熔融共混法制备ASA树脂,探究了水性抗氧剂的组成以及含量对ASA树脂力学性能、表观性能的影响... 采用乳液聚合法制备了核壳比为6/4的ASA核壳接枝共聚物胶乳,系统地研究了水性抗氧剂的组成以及含量对ASA接枝共聚物热氧老化性能的影响,并采用熔融共混法制备ASA树脂,探究了水性抗氧剂的组成以及含量对ASA树脂力学性能、表观性能的影响。结果表明,水性抗氧剂的组成CPL/DLTP为2/3时,其ASA接枝共聚物的热氧老化性能最优;随着水性抗氧剂含量的增加,ASA接枝共聚物的氧化诱导期显著增长;水性抗氧剂的加入量超过1%以后,ASA接枝共聚物的氧化诱导期增长不显著;在230℃空气条件下,添加1%水性抗氧剂的ASA接枝共聚物的氧化诱导期可达73.1 min,其抗热氧老化能力是相同条件下不添加水性抗氧剂ASA接枝共聚物的80倍以上;水性抗氧剂的组成及含量对ASA树脂的力学性能无明显影响,对其表观性能如白度影响明显。 展开更多
关键词 丙烯腈-苯乙烯-丙烯酸丁酯 核壳接枝共聚物 水性抗氧剂 氧化诱导期 抗热氧老化能力
下载PDF
Accounting for Quadratic and Cubic Invariants in Continuum Mechanics–An Overview
10
作者 Artur V.Dmitrenko Vladislav M.Ovsyannikov 《Fluid Dynamics & Materials Processing》 EI 2024年第9期1925-1939,共15页
The differential equations of continuum mechanics are the basis of an uncountable variety of phenomena and technological processes in fluid-dynamics and related fields.These equations contain derivatives of the first ... The differential equations of continuum mechanics are the basis of an uncountable variety of phenomena and technological processes in fluid-dynamics and related fields.These equations contain derivatives of the first order with respect to time.The derivation of the equations of continuum mechanics uses the limit transitions of the tendency of the volume increment and the time increment to zero.Derivatives are used to derive the wave equation.The differential wave equation is second order in time.Therefore,increments of volume and increments of time in continuum mechanics should be considered as small but finite quantities for problems of wave formation.This is important for calculating the generation of sound waves and water hammer waves.Therefore,the Euler continuity equation with finite time increments is of interest.The finiteness of the time increment makes it possible to take into account the quadratic and cubic invariants of the strain rate tensor.This is a new branch in hydrodynamics.Quadratic and cubic invariants will be used in differential wave equations of the second and third order in time. 展开更多
关键词 Quadratic invariant cubic invariant continuity equation generation of periodic waves N.E.Zhukovsky’s hydraulic shock TURBULENCE
下载PDF
COVID-19 mortality paradox(United States vs Africa):Mass vaccination vs early treatment
11
作者 Mina Thabet Kelleni 《World Journal of Experimental Medicine》 2024年第1期6-12,共7页
The coronavirus disease 2019(COVID-19)mortality rate in 55 African countries is almost 4.5 times lower than in the coronavirus disease 2019(COVID-19)despite Africa having over 4.2 times more people.This mortality para... The coronavirus disease 2019(COVID-19)mortality rate in 55 African countries is almost 4.5 times lower than in the coronavirus disease 2019(COVID-19)despite Africa having over 4.2 times more people.This mortality paradox is also evident when comparing Nigeria,a heavily populated,poorly vaccinated and weakly mandated country to Israel,a small,highly vaccinated and strictly mandated country.Nigeria has almost 4 times lower COVID mortality than Israel.In this Field of Vision perspective,I explain how this paradox has evolved drawing upon my academic,clinical and social experience.Since April 2020,I’ve developed and been using the Egyptian immune-modulatory Kelleni’s protocol to manage COVID-19 patients including pediatric,geriatric,pregnant,immune-compromised and other individuals suffering from multiple comorbidities.It’s unfortunate that severe acute respiratory syndrome coronavirus 2 is still evolving accompanied by more deaths.However in Africa,we’ve been able to live without anxiety or mandates throughout the pandemic because we trust science and adopted early treatment using safe,and effective repurposed drugs that have saved the majority of COVID-19 patients.This article represents an African and Egyptian tale of honor. 展开更多
关键词 COVID-19 Early treatment Kelleni’s Protocol Mandates Mortality Paradox sARs-CoV-2 Nucleic acid based vaccines
下载PDF
Effect of Base Width and Stiffness of the Structure on Period of Vibration of RC Framed Buildings in Seismic Analysis
12
作者 Prakash Sangamnerkar Sheo Kumar Dubey 《Open Journal of Earthquake Research》 2015年第2期65-73,共9页
Fundamental natural period of vibration T of the building is an important parameter for evaluation of seismic base shear. Empirical equations given in the Indian seismic code for the calculation of the fundamental per... Fundamental natural period of vibration T of the building is an important parameter for evaluation of seismic base shear. Empirical equations given in the Indian seismic code for the calculation of the fundamental period of a framed structure, primarily as a function of height, do not consider the effect of stiffness of the structure, base dimensions of the structure, number of panels in both the directions, amount of infill and properties of the infill. The fundamental period can be evaluated using simplified expressions found in codes, which are based on earthquake recordings in existing buildings, laboratory tests, numerical or analytical computations. These technical codes provide expressions which depend on basic parameters such as building height or number of stories. Building periods predicted by these expressions are widely used in practice although it has been observed that there is scope for further improvement in these equations since the height alone is inadequate to explain period variability. It is also known that the period of a RC frame structure differs depending on whether the longitudinal or transverse direction of the structure is considered. The aim of this study is to find the effects of building base width in both the directions, stiffness of the structure etc. and to predict the fundamental period of vibration of reinforced concrete buildings with moment resisting frames (MRF). A few examples of dynamic analysis are presented in this study to show the effect of base dimensions and stiffness of the structure in calculating the time period of the structure. And it is recommended to be incorporated in the formula for evaluating the natural period of vibration of structures. 展开更多
关键词 base DIMENsIONs Dynamic Analysis NATURAL period of VIBRATION sTIFFNEss
下载PDF
观察基于Watson人性照顾理论的干预对重症肺炎合并呼吸衰竭患者的应用效果
13
作者 王宝玉 《世界睡眠医学杂志》 2024年第5期1173-1176,共4页
目的:观察基于Watson人性照顾理论的干预对重症肺炎合并呼吸衰竭患者的应用效果。方法:选取2021年6月至2023年6月泉州市第一医院呼吸与危重症医学科收治的重症肺炎合并呼吸衰竭患者94例作为研究对象,按照随机数字表法分为对照组和观察组... 目的:观察基于Watson人性照顾理论的干预对重症肺炎合并呼吸衰竭患者的应用效果。方法:选取2021年6月至2023年6月泉州市第一医院呼吸与危重症医学科收治的重症肺炎合并呼吸衰竭患者94例作为研究对象,按照随机数字表法分为对照组和观察组,每组47例。对照组给予常规护理干预,观察组在对照组基础上给予Watson人性照顾理论的干预。采用匹兹堡睡眠质量指数量表(PSQI)比较2组患者干预前后睡眠质量的变化,采用阿森斯失眠量表(AIS)评估2组患者干预前后失眠的改善效果,并通过2组患者护理后的呼吸困难缓解时间、机械通气时间、重症监护室住院时间,以判断恢复情况。结果:干预后,观察组患者PSQI评分、AIS评分均显著低于对照组,观察组呼吸困难缓解时间、机械通气时间及重症监护室住院时间均显著短于对照组,差异均有统计学意义(均P<0.05)。结论:对重症肺炎合并呼吸衰竭患者应用基于Watson人性照顾理论的护理干预可有效改善其睡眠质量,促进病情恢复,值得临床推广应用。 展开更多
关键词 基于Watson人性照顾理论的干预 重症肺炎 呼吸衰竭 睡眠质量 重症护理
下载PDF
载铜地质聚合物微球的制备及其催化降解双酚S的性能
14
作者 张政 刘琳 +3 位作者 李子晨 王梦琦 黄春燕 葛圆圆 《化工进展》 EI CAS CSCD 北大核心 2024年第9期5290-5301,共12页
传统的芬顿反应因在废水处理过程中会产生大量富含金属污泥而应用受限。本研究采用悬浮固化法得到了一种低成本、易回收、绿色的多孔地质聚合物微球(GM),将其作为载体通过浸渍法制备了载铜地质聚合物微球(Cu-GM),作为类芬顿反应催化剂,... 传统的芬顿反应因在废水处理过程中会产生大量富含金属污泥而应用受限。本研究采用悬浮固化法得到了一种低成本、易回收、绿色的多孔地质聚合物微球(GM),将其作为载体通过浸渍法制备了载铜地质聚合物微球(Cu-GM),作为类芬顿反应催化剂,催化H_(2)O_(2)降解水中的双酚S(BPS)。SEM、XRD、BET和XPS等一系列表征结果表明,Cu^(+/2+)被稳定固定在GM表面。进一步探究了Cu-GM用量、H_(2)O_(2)用量、BPS浓度和溶液初始p H对催化降解的影响。结果表明,在优化条件下,Cu-GM在480min内对BPS的去除率可达99.3%,催化降解过程符合一级反应动力学。通过自由基淬灭实验发现,在催化降解过程中·OH和^(1)O_(2)是主要活性物质。循环实验表明Cu-GM具有良好的重复利用性,在去除水中有机污染物方面有着极大的应用潜力。 展开更多
关键词 地质聚合物微球 铜基类芬顿 双酚s 催化降解 降解机理
下载PDF
业绩型股权激励、行权条件与企业ESG表现
15
作者 王欣桐 王雷 《管理会计研究》 2024年第3期22-35,共14页
企业ESG表现颇受投资者关注,提升企业ESG表现以提高竞争力也逐渐形成共识。作为一种长期激励方式,股权激励如何促使高管提升企业ESG表现?为了研究这一问题,本文选取2008—2021年沪深A股上市公司作为研究对象,探究业绩型股权激励及其行... 企业ESG表现颇受投资者关注,提升企业ESG表现以提高竞争力也逐渐形成共识。作为一种长期激励方式,股权激励如何促使高管提升企业ESG表现?为了研究这一问题,本文选取2008—2021年沪深A股上市公司作为研究对象,探究业绩型股权激励及其行权条件对企业ESG表现的影响。实证结果表明,业绩型股权激励显著提升企业ESG表现。当高管任期较长时,这一关系更为显著。进一步研究发现,行权业绩考核越难、行权等待期越长越有助于提升企业ESG表现,但行权有效期不影响企业ESG表现。上述研究结论有助于企业完善高管股权激励的契约结构,促进企业ESG表现的提升。 展开更多
关键词 业绩型股权激励 行权时间限制 行权业绩考核 企业EsG表现
下载PDF
基于NaIO_(3)转化NaIO_(4)回用合成S-甘油醛缩丙酮及其寡聚研究
16
作者 张珍明 季姜钰 +3 位作者 彭晓含 张疏航 刘若雨 李润莱 《化学世界》 CAS 2024年第3期177-183,共7页
S-甘油醛缩丙酮是合成手性药物的重要中间体。以L-抗坏血酸为原料,经缩酮化,硼氢化钠还原,高碘酸钠氧化制得S-甘油醛缩丙酮,收率为46.8%;探讨了含碘酸钠母液转化成高碘酸钠以循环套用,回收率为83.90%;初步考察了S-甘油醛缩丙酮的聚合度... S-甘油醛缩丙酮是合成手性药物的重要中间体。以L-抗坏血酸为原料,经缩酮化,硼氢化钠还原,高碘酸钠氧化制得S-甘油醛缩丙酮,收率为46.8%;探讨了含碘酸钠母液转化成高碘酸钠以循环套用,回收率为83.90%;初步考察了S-甘油醛缩丙酮的聚合度与时间的关系,并推测其寡聚化合物的结构和反应机理;用^(1)H NMR、IR和LC-MS等对化合物结构进行表征。 展开更多
关键词 s-甘油醛缩丙酮 L-抗坏血酸 高碘酸钠 循环利用 合成 寡聚
下载PDF
Analysis on Rules of Investment Decision Based on Payback Period of Dynamic Investment
17
作者 Guojie Zhao Gang Lu 《Chinese Business Review》 2005年第10期53-55,共3页
The index of payback period of dynamic investment is an improvement on index of payback period of static investment, which is the problem that the rules to evaluate the project are feasible or not. This paper proves t... The index of payback period of dynamic investment is an improvement on index of payback period of static investment, which is the problem that the rules to evaluate the project are feasible or not. This paper proves that rules shall be apt when using payback period of dynamic investment to evaluate the project feasibility under the condition of keeping the dynamic evaluation index to evaluate the same scheme and the consistent feasibility. 展开更多
关键词 rules on project evaluation payback period of dynamic investment base earnings ratio life length of project
下载PDF
基于密度泛函理论的S掺杂碳载体负载Pt催化剂对氧还原反应的影响
18
作者 叶蔚甄 任强 +1 位作者 王春璐 曲亚坤 《石油学报(石油加工)》 EI CAS CSCD 北大核心 2024年第4期931-941,共11页
采用密度泛函方法对比研究了Pt/C催化剂中碳载体掺S前后对氧还原反应(ORR)的影响。从电荷分布、态密度及d带中心等性质出发,分析了金属-载体间相互作用,研究了ORR各物种在催化剂上的吸附并计算了ORR过电势。结果表明:S掺杂使得碳载体表... 采用密度泛函方法对比研究了Pt/C催化剂中碳载体掺S前后对氧还原反应(ORR)的影响。从电荷分布、态密度及d带中心等性质出发,分析了金属-载体间相互作用,研究了ORR各物种在催化剂上的吸附并计算了ORR过电势。结果表明:S掺杂使得碳载体表面发生了电子转移,S上的电子转移到邻近的C原子上,负载Pt纳米颗粒后,Pt金属上的电子转移给了碳载体;Pt在S掺杂碳载体上的吸附更强,形成了Pt—C键和Pt—S键,Pt纳米颗粒的分散度和稳定性得到了提升;掺S使得催化剂d带中心下降,对ORR各中间体的吸附减弱,ORR过电势降低,表明掺S能提高催化剂的催化活性。 展开更多
关键词 s掺杂 Pt基催化剂 氧还原反应 密度泛函理论 态密度 d带中心 过电势
下载PDF
1例藏族完全型Shone综合征患者的围术期护理
19
作者 贾二歌 王小芳 《中国临床护理》 2024年第1期61-65,共5页
文章总结了1例藏族完全型Shone综合征患者的围术期护理经验。护理要点包括术前密切监测患者四肢血压,做好安全护理,预防晕厥、猝死等意外事件发生,术后加强肺康复护理,做好阶段性运动干预、疼痛护理、个体化饮食护理,同时全程做好多方... 文章总结了1例藏族完全型Shone综合征患者的围术期护理经验。护理要点包括术前密切监测患者四肢血压,做好安全护理,预防晕厥、猝死等意外事件发生,术后加强肺康复护理,做好阶段性运动干预、疼痛护理、个体化饮食护理,同时全程做好多方位跨文化护理。经过精心治疗和护理,患者术后恢复良好,痊愈出院。 展开更多
关键词 完全型shone综合征 藏族 围术期 跨文化护理
下载PDF
CO_(2)和H_(2)S对镍基合金028点蚀敏感性及点蚀生长动力学的影响
20
作者 席文强 孙冲 +2 位作者 樊学华 林学强 孙建波 《表面技术》 EI CAS CSCD 北大核心 2024年第16期78-88,102,共12页
目的探明CO_(2)和H_(2)S对镍基合金028钝化膜性能和点蚀敏感性的影响。方法采用循环动电位极化(CPP)、电化学阻抗谱(EIS)、莫特-肖特基(M-S)等测试方法,研究Cl-环境、CO_(2)-Cl-环境和H_(2)S-Cl-环境中镍基合金028的钝化膜性能。通过制... 目的探明CO_(2)和H_(2)S对镍基合金028钝化膜性能和点蚀敏感性的影响。方法采用循环动电位极化(CPP)、电化学阻抗谱(EIS)、莫特-肖特基(M-S)等测试方法,研究Cl-环境、CO_(2)-Cl-环境和H_(2)S-Cl-环境中镍基合金028的钝化膜性能。通过制备一维人工凹坑电极模拟点蚀坑的稳态生长,采用向负向电位扫描法,研究镍基合金028在局部点蚀环境中的金属溶解动力学,明确CO_(2)和H_(2)S对点蚀生长动力学的影响。结果CO_(2)和H_(2)S都会使镍基合金028钝化膜性能变差,而H_(2)S的影响更为显著,具体表现为:在H_(2)S-Cl-环境中具有更高的钝化电流密度jp、更低的点蚀电位Eb和再钝化电位Erp。H_(2)S-Cl-环境中的钝化膜电阻Rf、电荷转移电阻Rt和钝化膜厚度均低于CO_(2)-Cl-环境中的,此外,钝化膜在H_(2)S-Cl-环境中具有更高的点缺陷密度。在最大点蚀坑溶解电流密度jdiss,max相同的条件下,H_(2)S-Cl-环境中点蚀稳态生长所需的驱动力Emax明显低于CO_(2)-Cl-环境中的;在相同Emax下,H_(2)S-Cl-环境中的jdiss,max高于CO_(2)-Cl-环境中的。结论CO_(2)和H_(2)S通过增加钝化膜溶解速率、降低钝化膜电阻和增加点缺陷密度,不同程度地增加了镍基合金028的点蚀敏感性,而H_(2)S更容易造成钝化膜损伤。在点蚀稳态生长阶段,镍基合金028点蚀的稳态生长遵循塔菲尔规律,相比于CO_(2),H_(2)S更容易促进点蚀从亚稳态向稳态发展,并且在H_(2)S环境中具有更高的点蚀生长稳定性。 展开更多
关键词 镍基合金 CO_(2) H_(2)s 点蚀敏感性 一维人工凹坑电极 点蚀生长动力学
下载PDF
上一页 1 2 121 下一页 到第
使用帮助 返回顶部