Based on the biological prototype characteristics of shark’s gill jet orifice,the flexible driving characteristics of ionic exchange polymer metal composites(IPMC)artificial muscle materials and the use of sleeve fle...Based on the biological prototype characteristics of shark’s gill jet orifice,the flexible driving characteristics of ionic exchange polymer metal composites(IPMC)artificial muscle materials and the use of sleeve flexible connector,the IPMC linear driving unit simulation model is built and the IPMC material-driving dynamic control structure of bionic gill unit is developed.Meanwhile,through the stress analysis of bionic gill plate and the motion simulation of bionic gill unit,it is verified that various dynamic control and active control of the jet orifice under the condition of different mainstream field velocities will be taken by using IPMC material-driving.Moreover,the large-deflection deformation of bionic gill plate under dynamic pressure and the comparative analysis with that of a rigid gill plate is studied,leading to the achievement of approximate revised modifier from real value to theoretical value of the displacement control of IPMC.展开更多
Poly(aryl ether ketone)s (PAEKs) were successfully synthesized via nucleophilic aromatic substitution (SNAR) mechanism, using ionic liquids as green reaction media. The influence of various reaction parameters includi...Poly(aryl ether ketone)s (PAEKs) were successfully synthesized via nucleophilic aromatic substitution (SNAR) mechanism, using ionic liquids as green reaction media. The influence of various reaction parameters including monomer concentration, dehydration time, polymerization temperature and duration, IL's cations and anions nature, upon PAEKs molecular weight was investigated. In addition, the peculiarities of hydrogen-bonding ability of ILs were investigated. The interaction of 2,2-bis(4-hydroxyphenyl) propane (bisphenol A) with ILs has a strong influence on PAEKs synthesis. Various moderate molecular weight PAEKs have been obtained in high yields with molecular weights ranging from 10000 to 18000g mol-1.展开更多
Poly(ionic liquid)s(PILs)refer to a polymeric architecture with repeating ionic liquid species in each unit.They are attracting rapidly increasing interest because of their diverse structures and facial processability...Poly(ionic liquid)s(PILs)refer to a polymeric architecture with repeating ionic liquid species in each unit.They are attracting rapidly increasing interest because of their diverse structures and facial processability.Our group focused on the design and synthesis of PILs for various applications in the past decade,including polyelectrolytes,biomedical materials,and other related fields.In this review,we briefly summarized our recent studies on the application of PiLs for energy and electronic devices,emphasizing the controllable synthesis and regulation of specific structures and functions.The unique properties and designable structures of PILs will inspire further investigation in an extensive variety of potential applications.展开更多
Poly(vinylidene fluoride-hexafluropropylene)(PVDF-HFP)and poly(methyl methacrylate)(PMMA)-based gel polymer electrolytes(GPEs)comprising propylene carbonate and diethyl carbonate mixed plasticizer with variation of li...Poly(vinylidene fluoride-hexafluropropylene)(PVDF-HFP)and poly(methyl methacrylate)(PMMA)-based gel polymer electrolytes(GPEs)comprising propylene carbonate and diethyl carbonate mixed plasticizer with variation of lithium perchlorate(LiClO_(4))salt concentrations have been prepared using a solvent casting technique.Structural characterization has been carried out using XRD wherein diffraction pattern reveals the amorphous nature of sample up to 7.5 wt.%salt and complexation of polymers and salt have been studied by FTIR analysis.Surface morphology of the samples has been studied using scanning electron microscope.Electrochemical impedance spectroscopy in the temperature range 303-363K has been carried out for electrical conductivity.The maximum room temperature conductivity of 2.83×10^(-4) S cm^(-1) has been observed for the GPE incorporating 7.5 wt.%LiClO_(4).The temperature dependence of ionic conductivity obeys the Arrhenius relation.The increase in ionic conductivity with change in temperatures and salt content is observed.Transport number measurement is carried out by Wagner’s DC polarization method.Loss tangent(tanδ)and imaginary part of modulus(M″)corresponding to dielectric relaxation and conductivity relaxation respectively show faster relaxation process with increasing salt content up to optimum value of 7.5 wt.%LiClO_(4).The modulus(M″)shows that the conductivity relaxation is of non-Debye type(broader than Debye peak).展开更多
基金Project(51275102)supported by the National Natural Science Foundation of ChinaProject(HEUCF140713)supported by the Fundamental Research Funds for the Central Universities,China
文摘Based on the biological prototype characteristics of shark’s gill jet orifice,the flexible driving characteristics of ionic exchange polymer metal composites(IPMC)artificial muscle materials and the use of sleeve flexible connector,the IPMC linear driving unit simulation model is built and the IPMC material-driving dynamic control structure of bionic gill unit is developed.Meanwhile,through the stress analysis of bionic gill plate and the motion simulation of bionic gill unit,it is verified that various dynamic control and active control of the jet orifice under the condition of different mainstream field velocities will be taken by using IPMC material-driving.Moreover,the large-deflection deformation of bionic gill plate under dynamic pressure and the comparative analysis with that of a rigid gill plate is studied,leading to the achievement of approximate revised modifier from real value to theoretical value of the displacement control of IPMC.
基金supported by the National Natural Science Foundation of China (21274014)Beijing Municipal Commission of Education+1 种基金the Fundamental Research Funds for the Central UniversitiesMeasuring Fund of Large Apparatus of Beijing Normal University
文摘Poly(aryl ether ketone)s (PAEKs) were successfully synthesized via nucleophilic aromatic substitution (SNAR) mechanism, using ionic liquids as green reaction media. The influence of various reaction parameters including monomer concentration, dehydration time, polymerization temperature and duration, IL's cations and anions nature, upon PAEKs molecular weight was investigated. In addition, the peculiarities of hydrogen-bonding ability of ILs were investigated. The interaction of 2,2-bis(4-hydroxyphenyl) propane (bisphenol A) with ILs has a strong influence on PAEKs synthesis. Various moderate molecular weight PAEKs have been obtained in high yields with molecular weights ranging from 10000 to 18000g mol-1.
基金This work was financially supported by the National Natural Science Foundation of China(21835005,U1862109,22005045)Collaborative Innovation Center of Suzhou Nano Science and Technology,the Priority Academic Program,Development of Jiangsu Higher Education Institutions,the Fundamental Research Funds for the Central Universities(2232020D-07)the Initial Research Funds for Young Teachers of Donghua University.
文摘Poly(ionic liquid)s(PILs)refer to a polymeric architecture with repeating ionic liquid species in each unit.They are attracting rapidly increasing interest because of their diverse structures and facial processability.Our group focused on the design and synthesis of PILs for various applications in the past decade,including polyelectrolytes,biomedical materials,and other related fields.In this review,we briefly summarized our recent studies on the application of PiLs for energy and electronic devices,emphasizing the controllable synthesis and regulation of specific structures and functions.The unique properties and designable structures of PILs will inspire further investigation in an extensive variety of potential applications.
文摘Poly(vinylidene fluoride-hexafluropropylene)(PVDF-HFP)and poly(methyl methacrylate)(PMMA)-based gel polymer electrolytes(GPEs)comprising propylene carbonate and diethyl carbonate mixed plasticizer with variation of lithium perchlorate(LiClO_(4))salt concentrations have been prepared using a solvent casting technique.Structural characterization has been carried out using XRD wherein diffraction pattern reveals the amorphous nature of sample up to 7.5 wt.%salt and complexation of polymers and salt have been studied by FTIR analysis.Surface morphology of the samples has been studied using scanning electron microscope.Electrochemical impedance spectroscopy in the temperature range 303-363K has been carried out for electrical conductivity.The maximum room temperature conductivity of 2.83×10^(-4) S cm^(-1) has been observed for the GPE incorporating 7.5 wt.%LiClO_(4).The temperature dependence of ionic conductivity obeys the Arrhenius relation.The increase in ionic conductivity with change in temperatures and salt content is observed.Transport number measurement is carried out by Wagner’s DC polarization method.Loss tangent(tanδ)and imaginary part of modulus(M″)corresponding to dielectric relaxation and conductivity relaxation respectively show faster relaxation process with increasing salt content up to optimum value of 7.5 wt.%LiClO_(4).The modulus(M″)shows that the conductivity relaxation is of non-Debye type(broader than Debye peak).
