Curtailing Carbon Usage with Addition of Functionalized NiFe2O4 Quantum Dots:Toward More Practical S Cathodes for Li-S Cells

Smartcombination of manifold carbonaceous materials with admirable functionalities(like full of pores/functional groups,high specific surface area) is still a mainstream/preferential way to address knotty issues of polysulfides dissolution/shuttling and poor electrical conductivity for S-based cathodes.However,extensive use of conductive carbon fillers in cell designs/technology would induce electrolytic overconsumption and thereby shelve high-energy-density promise of Li-S cells.To cut down carbon usage,we propose the incorporation of multi-functionalized NiFe2O4 quantum dots(QDs) as affordable additive substitutes.The total carbon content can be greatly curtailed from 26%(in traditional S/C cathodes) to a low/commercial mass ratio(~5%).Particularly,note that NiFe2O4 QDs additives own superb chemisorption interactions with soluble Li2Sn molecules and proper catalytic features facilitating polysulfide phase conversions and can also strengthen charge-transfer capability/redox kinetics of overall cathode systems.Benefiting from these intrinsic properties,such hybrid cathodes demonstrate prominent rate behaviors(decent capacity retention with ~526 mAh g^-1 even at 5 A g^-1) and stable cyclic performance in LiNO3-free electrolytes(only ~0.08% capacity decay per cycle in 500 cycles at 0.2 A g^-1).This work may arouse tremendous research interest in seeking other alternative QDs and offer an economical/more applicable methodology to construct low-carbon-content electrodes for practical usage.

LPS'S CRITERION FOR INCOMPRESSIBLE NEMATIC LIQUID CRYSTAL FLOWS

In this paper we derive LPS＇s criterion for the breakdown of classical solutions to the incompressible nematic liquid crystal flow, a simplified version of Ericksen-Leslie system modeling the hydrodynamic evolution of nematic liquid crystals in R^3. We show that if 0 〈 T 〈 ＋∞ is the maximal time interval for the unique smooth solution u ∈ C^∞（[0, T）,R^3）,then ｜u｜＋｜△d｜∈L^q（[0,T],L^p（R^3））,where p and q satisfy the Ladyzhenskaya-Prodi-Serrin＇s condition：3/p＋2/q=1 and p∈（3,＋∞].

Numerical analyses of pillar behavior with variation in yield criterion,dilatancy, rock heterogeneity and length to width ratio

With recent advances in numerical modeling, design of underground structures increasingly relies on numerical modeling-based analysis approaches. While modeling tools like the discrete element method(DEM) and the combined finite-discrete element method(FDEM) are useful for investigating small-scale damage processes, continuum models remain the primary practical tool for most field-scale problems.The results obtained from such models are significantly dependent on the selection of an appropriate yield criterion and dilation angle. Towards improving its capabilities in handling mining-related problems, the authors have previously developed a new yield criterion(called progressive S-shaped criterion). The focus of the current study is to demonstrate its use in modeling rock pillars through a comparative analysis against four other yield criteria. In addition to the progressive S-shaped criterion,only one out of the four other criteria predicted a trend in strength consistent with an empirical pillar strength database compiled from the literature. Given the closely-knit relationship between yield criteria and dilation angle in controlling the overall damage process, a separate comparison was conducted using a mobilized dilation model, a zero degree dilation angle and a constant non-zero dilation angle. This study also investigates the impact of meso-scale heterogeneity in mechanical properties on the overall model response by assigning probability distributions to the input parameters. The comparisons revealed that an isotropic model using a combination of progressive S-shaped criterion and mobilized dilation angle model is sufficient in capturing the behaviors of rock pillars. Subsequently, the pillar model was used to assess the effect of L/W(length/width) ratio on the peak strength.

联合GNSS与GRACE/GRACE-FO数据反演中国西南地区陆地水储量变化

GNSS和重力恢复与气候试验(GRACE)及其后续任务(GRACE-FO)给陆地水储量变化(TWSC)研究带来了技术革新,但这两种技术估计的区域TWSC具有不同的时空尺度和精度特性。因此,有必要融合两种观测数据,以获得同一尺度且高精度的TWSC。本文基于GNSS独立反演模型,使用求和算子对喷气推进实验室(JPL)的GRACE/GRACE-FO Mascon数据进行求和运算来构建约束,通过赤池贝叶斯准则选择最优模型参数,构建了一种联合GNSS与GRACE/GRACE-FO数据的区域TWSC反演模型。随后,本文设计数值模拟试验,以验证利用该模型反演中国西南地区TWSC的可行性。结果显示,1000次试验中联合反演估算的均方根误差均值为10 mm,比GNSS独立反演结果低47%。基于此方法,本文联合GNSS与JPL Mascon数据反演了中国西南地区2011年1月—2022年6月的时变TWSC。对比联合反演、GNSS独立反演、GRACE/GRACE-FO和高分辨率全球陆地数据同化系统(GLDAS)的结果,发现联合反演与GLDAS的TWSC周年振幅空间分布特征最吻合,表明联合反演估计的TWSC空间分辨率优于GNSS独立反演和GRACE的结果。最后,结合水平衡方程估算的区域水文收支情况,并通过广义三角帽方法评估陆地水储量等效水柱高的变化率(d(EWH)/d t)的不确定性。结果显示,联合反演估计的d(EWH)/d t不确定性为8 mm/月,较GRACE/GRACE-FO、GNSS独立反演和水平衡方程结果分别低33%、68%和62%。研究结果表明,与GNSS和GRACE/GRACE-FO独立反演方法相比,联合反演能够改善TWSC估值的精度,可为水资源管理决策及水文气候学研究提供更可靠的数据支撑。

Strength criterion of porous media: Application of homogenization techniques

The present paper aims at giving some general ideas concerning the micromechanical approach of the strength of a porous material. It is shown that its determination theoretically amounts to solving a nonlinear boundary value problem defined on a representative elementary volume(REV). The principle of nonlinear homogenization is illustrated based on the case of a solid phase having a Green’s strength criterion. An original refinement of the so-called secant method(based on two reference strains) is also provided. The paper also describes the main feature of the Gurson’s model which implements the principle of limit analysis on a conceptual model of hollow sphere. The last part of the paper gives some ideas concerning poromechanical couplings.

Absolutely Stable of Takagi-Sugeno Fuzzy Control System by Using Popov’s Criterion

In this paper, we presented a sufficient condition on the frequency domain for the absolutely stable analysis of the Takagi-Sugeno (T-S)fuzzy control system, based on the Popov’s criterion. we use some numerical examples to illustrate the efficiency of frequency domain-based condition.

Relations between cubic equation, stress tensor decomposition, and von Mises yield criterion

Inspired by Cardano＇s method for solving cubic scalar equations, the addi- tive decomposition of spherical/deviatoric tensor （DSDT） is revisited from a new view- point. This decomposition simplifies the cubic tensor equation, decouples the spher- ical/deviatoric strain energy density, and lays the foundation for the von Mises yield criterion. Besides, it is verified that under the precondition of energy decoupling and the simplest form, the DSDT is the only possible form of the additive decomposition with physical meanings.

Stability analysis of the simplest Takagi-Sugeno fuzzy control system using circle criterion

A frequency-domain-based sufficient condition is derived to guarantee the globally asymptotic stability of the simplest Takagi-Sugeno （T-S） fuzzy control system by using the circle criterion. The analysis is performed in the frequency domain, and hence the condition is of great significance when the frequency-response method, which is widely used in the linear control theory and practice, is employed to synthesize the simplest T-S fuzzy controller. Besides, this sufficient condition is featured by a graphical interpretation, which makes the condition straightforward to be used. Comparisons are drawn between the performance of the simplest T-S fuzzy controller and that of the linear compensator. Two numerical examples are presented to demonstrate how this sufficient condition can be applied to both stable and unstable plants.

Strengthening People-to-people Exchanges and Practical Cooperation for Win-Win Situation——Sidelights on CAFIU Vice-President Qi Xuchun's Visit to New Zealand and Australia

At the invitation of Asia New Zealand Foundation and Australian Institute of International Affairs(ANA),a CAFIU delegation headed by Mr.Qi Xuchun,Vice-Chairman of the CPPCC National Committee,Executive Vice-Chairman of the Central Committee of Revolutionary Committee of the Chinese Kuomintang and

Awareness, Practice and Intention to Practice Testicular Self-Examination among Professional Working Males in Ghana

Background: The aetiology of Testicular Cancer (TC) is still unknown to researchers but many of the associated risk factors have been identified. These include family history, age, racial origin, cryptorchidism, urogenital malformations, testicular atrophy, and infertility. Given the lack of scientific data on the causes of the disease, it has been asserted in previous studies that the promotion of awareness and early detection are prerequisites to mitigating risks of metastasis as well as improving survival. This study is to assess the awareness, practice, and intention to practice testicular self-examination among professional working males in Accra. Methods: A quantitative cross-sectional design with a structured research instrument was used to collect data from respondants. The purposive and convenience sampling techniques were used to collect data from 300 men at Accra in Ghana. The study was conducted at two (2) Universities and a Senior High school at Accra in Ghana. The data was then analysed using descriptive statistics, logistic regression, multiple linear regression, and structural equation modeling. Results: From the study findings, 37% of male participants rated their knowledge of testicular self-examination and related symptoms as good, 28% of participants practised testicular self-examination monthly, while 65% of respondents expressed their intention to practice monthly testicular self-examination. The findings from logistic regression demonstrated that level of education, age, and marital status of participants had a significant influence on testicular self-examination. Additionally, the multiple linear regression results revealed knowledge and self-efficacy significantly predict testicular self-examination intention. The path coefficient results from the structural equation model are consistent with results from the regression models. Conclusion: This research is the first to investigate testicular self-examination among men in Ghana. The findings revealed awareness and practice of TSE are low among participants. Therefore, the research findings would improve the expertise of physicians and nurses in providing counsel, intervention, and support for patients at risk of testicular cancer.

Digital Disparities:How Artificial Intelligence Can Facilitate Anti-Black Racism in the U.S.Healthcare Sector

This paper delves into the intricate interplay between artificial intelligence(AI)systems and the perpetuation of Anti-Black racism within the United States medical industry.Despite the promising potential of AI to enhance healthcare outcomes and reduce disparities,there is a growing concern that these technologies may inadvertently/advertently exacerbate existing racial inequalities.Focusing specifically on the experiences of Black patients,this research investigates how the following AI components:medical algorithms,machine learning,and natural learning processes are contributing to the unequal distribution of medical resources,diagnosis,and health care treatment of those classified as Black.Furthermore,this review employs a multidisciplinary approach,combining insights from computer science,medical ethics,and social justice theory to analyze the mechanisms through which AI systems may encode and reinforce racial biases.By dissecting the three primary components of AI,this paper aims to present a clear understanding of how these technologies work,how they intersect,and how they may inherently perpetuate harmful stereotypes resulting in negligent outcomes for Black patients.Furthermore,this paper explores the ethical implications of deploying AI in healthcare settings and calls for increased transparency,accountability,and diversity in the development and implementation of these technologies.Finally,it is important that I prefer the following paper with a clear and concise definition of what I refer to as Anti-Black racism throughout the text.Therefore,I assert the following:Anti-Black racism refers to prejudice,discrimination,or antagonism directed against individuals or communities of African descent based on their race.It involves the belief in the inherent superiority of one race over another and the systemic and institutional practices that perpetuate inequality and disadvantage for Black people.Furthermore,I proclaim that this form of racism can be manifested in various ways,such as unequal access to opportunities,resources,education,employment,and fair treatment within social,economic,and political systems.It is also pertinent to acknowledge that Anti-Black racism is deeply rooted in historical and societal structures throughout the U.S.borders and beyond,leading to systemic disadvantages and disparities that impact the well-being and life chances of Black individuals and communities.Addressing Anti-Black racism involves recognizing and challenging both individual attitudes and systemic structures that contribute to discrimination and inequality.Efforts to combat Anti-Black racism include promoting awareness,education,advocacy for policy changes,and fostering a culture of inclusivity and equality.

Critical care nurses and their clinical reasoning for customizing monitor alarms:a mixed-method study

Objective:To explore the clinical rationale of critical care nurses for personalizing monitor alarms.One of the most crucial jobs assigned to critical care nurses is monitoring patients'physiological indicators and carrying out the necessary associated interventions.Successful use of equipment in the nursing practice environment will be improved by a thorough understanding of the nurse's approach to alarm configuration.Methods:A mixed-method design integrating quantitative and qualitative components was used.The sample of this study recruited a convenience sample of 60 nurses who have worked in critical care areas.This study took place at Lebanese American University Medical Center Rizk Hospital,utilizing a semi-structured interview with participants.Results:The study demonstrated the high incidence of nuisance alarms and the desensitization of critical care nurses to vital ones.According to the nurses,frequent false alarms and a shortage of staff are the 2 main causes of alarm desensitization.Age was significantly associated with the perception of Smart alarms,according to the data(P=0.03).Four interconnected themes and subcategories that reflect the clinical reasoning process for alarm customization were developed as a result of the study's qualitative component:(1)unit alarm environment;(2)nursing style;(3)motivation to customize;and(4)clinical and technological customization.Conclusions:According to this study,nurses believe that alarms are valuable.However,a qualitative analysis of the experiences revealed that customization has been severely limited since the healthcare team depends on nurses to complete these tasks independently.Additionally,a staffing shortage and lack of technical training at the start of placement have also hindered customization.

海上S油田硫化氢抑制剂优选研究及应用

海上S油田硫化氢(H_(2)S)产出浓度高,影响油田安全开发生产。为解决此问题,通过综合分析S油田储层、流体及其菌群性质,确定油田H_(2)S成因,并开展了H_(2)S抑制剂优选试验。研究结果表明,H_(2)S抑制剂TS-762室内评价呈现良好的脱硫效果,且TS-762与油田水处理系统使用的化学药剂具有良好的配伍性。试验区块应用结果表明,TS-762能够有效发挥生物竞争排斥作用,区块中采油井产出的H_(2)S浓度显著降低。

PIC/S技术标准指南体系分析

国家药品监督管理局已于2023年9月正式提交了加入药品检查合作计划(PIC/S)申请并已成为正式申请者。当前,PIC/S针对申请加入机构和制药行业颁发了大量的技术标准与指南,熟悉并掌握这些技术标准指南,有助于药品监管机构和制药行业更有效地推进和应对加入PIC/S工作。参考PIC/S网站,本文按照GMP标准、机构指南、指导文件、备忘录和其他文件的分类原则,对PIC/S发布的现行技术标准与指南进行了系统分析与梳理,从体系层面对其进行了研究,以期为业内机构和人员更好地理解PIC/S标准指南体系提供参考。

PIC/S GMP草药药品生产附录与我国GMP中药饮片、中药制剂附录及相关法规的对比与思考

目的:通过对药品检查合作计划(PIC/S)GMP草药药品生产附录进行对比研究,查找我国中药生产相关法规的优势及不足,为顺利加入PIC/S提供理论依据。方法:对我国GMP中药饮片、中药制剂附录及相关法规与PIC/S GMP草药药品生产附录的内容进行全面对比,并就一些优势和差异问题进行分析讨论。结果:我国GMP中药饮片、中药制剂附录及相关法规与PIC/S GMP草药药品生产附录在各个方面要求基本一致,且我国中药监管法规在厂房与设施设备、人员、确认与验证、生产管理、质量控制等方面的要求较PIC/S GMP草药药品生产附录更全面、更具体。结论:我国中药生产相关法规具备良好基础,已满足PIC/S GMP草药药品生产附录的要求,后续应坚定信心,明确方向,进一步完善我国中药生产相关法规要求。

利用Yabuki & Matsu′ura反演方法计算2011年日本东北地区太平洋海域M_w9.0级地震同震滑动分布

Yabuki&Matsu′ura反演方法是利用ABIC最佳模型参数选取方法和平滑的滑动分布作为约束条件,由形变观测数据计算发震断层滑动分布.本文基于日本列岛同震GPS观测数据和发震断层曲面构造模型,利用Yabuki&Matsu′ura反演方法计算2011年日本东北地区太平洋海域Mw9.0级地震的发震断层同震滑动分布.反演结果表明,断层面上的最大滑动量为35m,较大滑动分布在浅于30km的震源中心上部,最大破裂集中在20km深度的地方.其地震矩约为3.63×1022 N.m,对应的矩震级为Mw9.0.模拟结果显示Yabuki&Matsu′ura反演方法更适用于倾角低于40°的断层模型反演.最后,本文基于上述方法获得的发震断层滑动模型,利用地球体位错理论正演计算该地震在中国及其邻区产生的远场形变,正演计算结果基本可以解释由中国GPS陆态网络观测到的同震形变.

基于多重映射的安全S盒构造方法

将构造S盒的问题转化为寻找满足一定条件的映射的问题。利用Tent映射的混沌特性,提出初始映射算法,并使用该算法得到可作为初始S盒的初始映射。为了提高S盒的安全性,提出了使用多个初始映射对初始S盒做非线性操作的多重映射算法,经安全性准则检验,该算法能够获得安全性更高的S盒。最后通过设定一个安全指标统计了该算法能够生成的优良S盒的个数,表明优良S盒的个数随着算法采用初始映射个数的增加而增加,并且实现算法所需的时间与算法中采用的初始映射的个数成正比。

应用Sheard准则评估集合不足患者的临床研究

目的:运用Sheard准则对集合不足的屈光不正患者的双眼视失平衡症状进行评估和诊治。方法:对2009-06以来18例集合不足的患者进行眼屈光检查,同时检测远近分离性隐斜,远近辐辏,正相对调节,调节状态,负相对调节,辐辏近点,调节幅度等眼动参数。计算AC/A参数,检测其对Sheard准则符合性,并利用该准则计算所需的棱镜处方。结果:近距棱镜不符合Sheard准则有14例(78%),其所需的基底朝内棱镜度数为(3.47±2.83)△。结论:临床上运用Sheard准则可有效地评估和诊治近距离用眼不适的集合不足患者。

基于Delta-s的高速果奶装箱机器人工程示范

研究Delta-S机器人在果奶装箱机上的工程示范应用,包括其系统布局及功能要求及Delta-S机器人的抓取器设计、软件设计和工程实践等问题。在基本设计分析的基础上,选取装填工位做具体分析。分析结果表明,Delta-S机器人在高速果奶装箱机上的应用使得装箱自动化水平和速度都大幅提高,进一步说明Delta-S机器人在工业生产线上的应用具有很好的应用前景。

采用B/S架构的半导体TCAD网络实验教学平台构建研究

基于B/S(浏览器/服务器)架构,开发了一款适用于高校微电子专业实验教学的半导体TCAD网络实验教学平台。该平台的核心是一台运行于Linux系统的高性能服务器,TCAD软件运行在服务器端,教学平台管理者(教师)拥有利用telnet、SSH等终端登录工具登录服务器的资格和权力,而学生则通过指定端口利用浏览器来使用该平台。该平台的优点是由于学生只需通过基于Windows系统的浏览器访问服务器,不必熟悉Unix或Linux等类Unix操作系统,极大地方便了学生的使用,并且无需在服务器端为每个学生建立账户,可节省服务器硬件成本和网络管理成本,并大大地提高了系统的安全性。同时,采用该方式降低了服务器的负载,初步实验结果显示采用该方式比采用传统的图形界面登录服务器时的负荷降低了约58%。