3-d iam ino-6-(3,5-d im ethylpyrazol-1-yl)-1,2,4,5-tetrazine(ADMPT),3,6-d iam ino-1,2,4,5-tet-razine(DATZ),3,6-d ihydra-zino-1,2,4,5-tetrazine(DHT),3,3’-azob is(6-am ino-1,2,4,5-tetrazine)(DAAT) and som e h igh-n itr...3-d iam ino-6-(3,5-d im ethylpyrazol-1-yl)-1,2,4,5-tetrazine(ADMPT),3,6-d iam ino-1,2,4,5-tet-razine(DATZ),3,6-d ihydra-zino-1,2,4,5-tetrazine(DHT),3,3’-azob is(6-am ino-1,2,4,5-tetrazine)(DAAT) and som e h igh-n itrogen energetic compounds were synthesized.The structures of the compounds were confirm ed by elem ent analysis,IR,1H NMR and13C NMR spectra etc.展开更多
The crystal structure of the title compound N,N-bisphenyl-3,6-diethyl-1,4- dihydro-s-tetrazine-1,4-dicarbonamide (C20H22N6O2, Mr = 378.44) has been prepared and determi- ned by single-crystal X-ray diffraction. The cr...The crystal structure of the title compound N,N-bisphenyl-3,6-diethyl-1,4- dihydro-s-tetrazine-1,4-dicarbonamide (C20H22N6O2, Mr = 378.44) has been prepared and determi- ned by single-crystal X-ray diffraction. The crystal is of orthorhombic, space group Pbca with a = 16.287(2), b = 11.347(4), c = 20.975(4) ? V = 3876.4(16) ?, Z = 8, Dc = 1.297 g/cm3, F(000) = 1600, m = 0.088 mm-1, MoKa radiation (l = 0.71073 ?. The structure was refined to R = 0.0337 and wR = 0.1038 for 1952 observed reflections with I > 2s(I). X-ray diffraction analysis reveals that two amide groups are located at the 1 and 4 positions, and the tetrazine ring itself shows a boat conformation.展开更多
文摘3-d iam ino-6-(3,5-d im ethylpyrazol-1-yl)-1,2,4,5-tetrazine(ADMPT),3,6-d iam ino-1,2,4,5-tet-razine(DATZ),3,6-d ihydra-zino-1,2,4,5-tetrazine(DHT),3,3’-azob is(6-am ino-1,2,4,5-tetrazine)(DAAT) and som e h igh-n itrogen energetic compounds were synthesized.The structures of the compounds were confirm ed by elem ent analysis,IR,1H NMR and13C NMR spectra etc.
基金the NNSFC (No. 20272053) and Science and Technology Bureau (011101937) of Zhejiang province
文摘The crystal structure of the title compound N,N-bisphenyl-3,6-diethyl-1,4- dihydro-s-tetrazine-1,4-dicarbonamide (C20H22N6O2, Mr = 378.44) has been prepared and determi- ned by single-crystal X-ray diffraction. The crystal is of orthorhombic, space group Pbca with a = 16.287(2), b = 11.347(4), c = 20.975(4) ? V = 3876.4(16) ?, Z = 8, Dc = 1.297 g/cm3, F(000) = 1600, m = 0.088 mm-1, MoKa radiation (l = 0.71073 ?. The structure was refined to R = 0.0337 and wR = 0.1038 for 1952 observed reflections with I > 2s(I). X-ray diffraction analysis reveals that two amide groups are located at the 1 and 4 positions, and the tetrazine ring itself shows a boat conformation.
