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Bearing Fault Diagnosis Based on the Markov Transition Field and SE-IShufflenetV2 Model
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作者 Chaozhi Cai Tiexin Xu +1 位作者 Jianhua Ren Yingfang Xue 《Structural Durability & Health Monitoring》 EI 2025年第1期125-144,共20页
A bearing fault diagnosis method based on the Markov transitionfield(MTF)and SEnet(SE)-IShufflenetV2 model is proposed in this paper due to the problems of complex working conditions,low fault diagnosis accuracy,and poo... A bearing fault diagnosis method based on the Markov transitionfield(MTF)and SEnet(SE)-IShufflenetV2 model is proposed in this paper due to the problems of complex working conditions,low fault diagnosis accuracy,and poor generalization of rolling bearing.Firstly,MTF is used to encode one-dimensional time series vibration sig-nals and convert them into time-dependent and unique two-dimensional feature images.Then,the generated two-dimensional dataset is fed into the SE-IShufflenetV2 model for training to achieve fault feature extraction and classification.This paper selects the bearing fault datasets from Case Western Reserve University and Paderborn University to experimentally verify the effectiveness and superiority of the proposed method.The generalization performance of the proposed method is tested under the variable load condition and different signal-to-noise ratios(SNRs).The experimental results show that the average accuracy of the proposed method under different working conditions is 99.2%without adding noise.The accuracy under different working conditions from 0 to 1 HP is 100%.When the SNR is 0 dB,the average accuracy of the proposed method can still reach 98.7%under varying working conditions.Therefore,the bearing fault diagnosis method proposed in this paper is characterized by high accuracy,strong anti-noise ability,and generalization.Moreover,the proposed method can also overcome the influence of variable working conditions on diagnosis accuracy,providing method support for the accurate diagnosis of bearing faults under strong noise and variable working conditions. 展开更多
关键词 Bearings Markov transitionfield SE-IShufflenetV2
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FLIGHT CLASSIFICATION MODEL BASED ON TRANSITIVE CLOSURE ALGORITHM AND APPLICATION TO FLIGHT SEQUENCING PROBLEM 被引量:3
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作者 李雄 徐肖豪 李冬宾 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2007年第1期31-35,共5页
A new arrival and departure flight classification method based on the transitive closure algorithm (TCA) is proposed. Firstly, the fuzzy set theory and the transitive closure algorithm are introduced. Then four diff... A new arrival and departure flight classification method based on the transitive closure algorithm (TCA) is proposed. Firstly, the fuzzy set theory and the transitive closure algorithm are introduced. Then four different factors are selected to establish the flight classification model and a method is given to calculate the delay cost for each class. Finally, the proposed method is implemented in the sequencing problems of flights in a terminal area, and results are compared with that of the traditional classification method(TCM). Results show that the new classification model is effective in reducing the expenses of flight delays, thus optimizing the sequences of arrival and departure flights, and improving the efficiency of air traffic control. 展开更多
关键词 air traffic control transitive closure algorithm cost of flight delay classification model
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Practical Method for Determining All the Minimum Solutions of Fuzzy Matrix Equation and Transitive Closure of Fuzzy Relation 被引量:2
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作者 阎家杰 赵万忠 《Chinese Quarterly Journal of Mathematics》 CSCD 1993年第4期99-103,共5页
In this paper,the new theory frame and practical methhod for determining all the minimum solutions of Fuzzy matrix equation and transitive closure of Fuzzy relation is described,and it has been carried out on the mier... In this paper,the new theory frame and practical methhod for determining all the minimum solutions of Fuzzy matrix equation and transitive closure of Fuzzy relation is described,and it has been carried out on the miero-computer quickly and accurately. 展开更多
关键词 fuzzy matrix equation minimum solution fuzzy relation transitive closure
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The Properties of Transitive Bipartite Tournaments 被引量:1
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作者 谭尚旺 张德龙 《Chinese Quarterly Journal of Mathematics》 CSCD 2003年第4期358-363,共6页
Let Γm,n^* denote all m × n strongly connected bipartite tournaments and a(m, n) the maximal integer k such that every m × n bipartite tournament contains at least a k × k transitive bipartite subtour... Let Γm,n^* denote all m × n strongly connected bipartite tournaments and a(m, n) the maximal integer k such that every m × n bipartite tournament contains at least a k × k transitive bipartite subtournament. Let t ( m, n, k, l ) = max{t( Tm,n,k, l ) : Tm,n∈Γm,n^*}, where t ( Tm,n, k, l ) is the number of k × l(k≥2,l≥2) transitive bipartite subtournaments contained in Tm,n∈Γm,n^*. We obtain a method of graph theory for solving some integral programmings, investigate the upper bounds of a(m,n) and obtain t (m,n, k,l). 展开更多
关键词 reverse arc transitive bipartite tournament ENUMERATION
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Max-plus代数中analogy-transitive矩阵及其本征问题 被引量:1
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作者 王绘莉 舒乾宇 王学平 《四川师范大学学报(自然科学版)》 CAS CSCD 北大核心 2014年第3期293-297,共5页
定义一类analogy-transitive矩阵,讨论其基本性质,给出判定一个矩阵是否为analogytransitive矩阵的判定定理及算法,最后讨论关于analogy-transitive矩阵的本征问题.对于analogytransitive矩阵,存在一个O(n2)的算法计算其唯一本征值λ(A... 定义一类analogy-transitive矩阵,讨论其基本性质,给出判定一个矩阵是否为analogytransitive矩阵的判定定理及算法,最后讨论关于analogy-transitive矩阵的本征问题.对于analogytransitive矩阵,存在一个O(n2)的算法计算其唯一本征值λ(A)和所有本征向量x=(x1,…,xn)使得max j=1,…,n(aij+xj)=λ+xi(i=1,…,n).该结果较一般情况下O(n3)的算法有所改进. 展开更多
关键词 Max-plus代数 analogy-transitive矩阵 极大圈平均 本征问题 本征值 本征向量 本征空间
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Templated synthesis of transition metal phosphide electrocatalysts for oxygen and hydrogen evolution reactions 被引量:4
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作者 Rose Anne Acedera Alicia Theresse Dumlao +4 位作者 DJ Donn Matienzo Maricor Divinagracia Julie Anne del Rosario Paraggua Po-Ya Abel Chuang Joey Ocon 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期646-669,I0014,共25页
Transition metal phosphides(TMPs)have been regarded as alternative hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)catalysts owing to their comparable activity to those of noble metal-based catalysts... Transition metal phosphides(TMPs)have been regarded as alternative hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)catalysts owing to their comparable activity to those of noble metal-based catalysts.TMPs have been produced in various morphologies,including hollow and porous nanostructures,which are features deemed desirable for electrocatalytic materials.Templated synthesis routes are often responsible for such morphologies.This paper reviews the latest advances and existing challenges in the synthesis of TMP-based OER and HER catalysts through templated methods.A comprehensive review of the structure-property-performance of TMP-based HER and OER catalysts prepared using different templates is presented.The discussion proceeds according to application,first by HER and further divided among the types of templates used-from hard templates,sacrificial templates,and soft templates to the emerging dynamic hydrogen bubble template.OER catalysts are then reviewed and grouped according to their morphology.Finally,prospective research directions for the synthesis of hollow and porous TMP-based catalysts,such as improvements on both activity and stability of TMPs,design of environmentally benign templates and processes,and analysis of the reaction mechanism through advanced material characterization techniques and theoretical calculations,are suggested. 展开更多
关键词 OER HER transition metal phosphide Templated synthesis ELECTROCATALYSTS
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Graphs on which a group of order pq acts edge-transitively
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作者 CHEN Shang-di GUO Yan-hong 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2010年第4期489-495,共7页
Let F be a finite simple undirected graph with no isolated vertices. Let p, q be prime numbers with p≥q. We complete the classification of the graphs on which a group of order pq acts edge-transitively. The results a... Let F be a finite simple undirected graph with no isolated vertices. Let p, q be prime numbers with p≥q. We complete the classification of the graphs on which a group of order pq acts edge-transitively. The results are the following. If Aut(Г) contains a subgroup G of order pq that acts edge-transitively on F, then F is one of the following graphs: (1) pK1,1; (2) pqK1,1; (3) pgq,1; (4) qKp,1 (p 〉 q); (5) pCq (q 〉 2); (6) qCp (p 〉 q); (7) Cp (p 〉 q = 2); (8) Cpq; (9) (Zp, C) whereC={±r^μ |μ∈Zq} withq〉2, q|(p-1) and r≠1≡r^q (modp); (10) Kp,1 (p 〉 q); (11) a double Cayley graph B(G,C) with C = {1-r^μ | μ ∈ Zq} and r≠1≡r^q (modp); (12) Kpq,1;or (13) Kp,q. 展开更多
关键词 Graph EDGE-transitive vertex transitive.
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Transitive filtration of Lie superalgebras
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作者 王颖 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2000年第1期74-76,共3页
Let L be a finite dimensional simple Lie superalgebra, and a sufficient condition is obtained for the length of transitive filtration of L to be greater than zero.
关键词 LIE SUPERALGEBRA transitive FILTRATION FILTRATION LENGTH
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CLASSIFICATION OF PRIMITIVE (J_1,2)-ARC TRANSITIVE GRAPHS
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作者 Ding Shifeng 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2006年第3期361-368,共8页
In the author's Ph. D thesis, a non-quasiprimitive graph admitting a quasiprimitive automorphism group isomorphic to J1 was constructed ,where J1 is Janko simple group of order 175560. Is this the only one for J1? I... In the author's Ph. D thesis, a non-quasiprimitive graph admitting a quasiprimitive automorphism group isomorphic to J1 was constructed ,where J1 is Janko simple group of order 175560. Is this the only one for J1? In this paper all primitive (J1,2)-arc transitive graphs Г are given and that AutГ≌J1 is proved. 展开更多
关键词 2-arc transitive PRIMITIVE J1.
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Correction:Impact of Transition Metal Layer Vacancy on the Structure and Performance of P2 Type Layered Sodium Cathode Material 被引量:1
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作者 Orynbay Zhanadilov Sourav Baiju +7 位作者 Natalia Voronina Jun Ho Yu A-Yeon Kim Hun-Gi Jung Kyuwook Ihm Olivier Guillon Payam Kaghazchi Seung-Taek Myung 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第12期532-532,共1页
Following publication of the original article[1],the authors reported that the author Hun-Gi Jung should be affiliated as 3,4 and 5 instead of 4 and 5.The author’s name“A.-Yeon Kim”needed to be updated to“A-Yeon ... Following publication of the original article[1],the authors reported that the author Hun-Gi Jung should be affiliated as 3,4 and 5 instead of 4 and 5.The author’s name“A.-Yeon Kim”needed to be updated to“A-Yeon Kim”,removing the period.The correct author’s name and affiliation have been provided in this Correction.The original article[1]has been corrected. 展开更多
关键词 removing transition IMPACT
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Evolution of Superconducting-Transition Temperature with Superfluid Density and Conductivity in Pressurized Cuprate Superconductors 被引量:1
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作者 赵金瑜 蔡树 +15 位作者 陈逸雯 顾根大 闫宏涛 郭静 韩金宇 王鹏玉 周亚洲 李延春 李晓东 任治安 吴奇 周兴江 丁阳 向涛 毛河光 孙力玲 《Chinese Physics Letters》 SCIE EI CAS CSCD 2024年第4期110-117,共8页
What factors fundamentally determine the value of superconducting transition temperature Tc in high temperature superconductors has been the subject of intense debate.Following the establishment of an empirical law kn... What factors fundamentally determine the value of superconducting transition temperature Tc in high temperature superconductors has been the subject of intense debate.Following the establishment of an empirical law known as Homes'law,there is a growing consensus in the community that the Tc value of the cuprate superconductors is closely linked to the superfluid density(ρ_(s))of its ground state and the conductivity(σ)of its normal state.However,all the data supporting this empirical law(ρ_(s)=AσT_(c))have been obtained from the ambientpressure superconductors.In this study,we present the first high-pressure results about the connection of the quantities of ρ_(s) and σ with T_(c),through the studies on the Bi_(1.74)Pb_(0.38)Sr_(1.88)CuO_(6+δ)and Bi_(2)Sr_(2)CaCu_(2)O_(8+δ),in which the value of their high-pressure resistivity(ρ=1/σ)is achieved by adopting our newly established method,while the quantity ofρs is extracted using Homes'law.We highlight that the Tc values are strongly linked to the joint response factors of magnetic field and electric field,i.e.,ρ_(s) and σ,respectively,implying that the physics determining T_(c) is governed by the intrinsic electromagnetic fields of the system. 展开更多
关键词 SUPERCONDUCTORS transitION CONDUCTIVITY
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Super Cyclically Edge Connected Half Vertex Transitive Graphs
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作者 Haining Jiang Jixiang Meng Yingzhi Tian 《Applied Mathematics》 2013年第2期348-351,共4页
Tian and Meng in [Y. Tian and J. Meng, λc -Optimally half vertex transitive graphs with regularity k, Information Processing Letters 109 (2009) 683 - 686] shown that a connected half vertex transitive graph with regu... Tian and Meng in [Y. Tian and J. Meng, λc -Optimally half vertex transitive graphs with regularity k, Information Processing Letters 109 (2009) 683 - 686] shown that a connected half vertex transitive graph with regularity k and girth g(G) ≥ 6 is cyclically optimal. In this paper, we show that a connected half vertex transitive graph G is super cyclically edge-connected if minimum degree δ(G) ≥ 6 and girth g(G) ≥ 6. 展开更多
关键词 Cyclic EDGE-CONNECTIVITY Cyclically Optimal Super Cyclically Edge-Connected HALF VERTEX transitive Graph
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From VIB‑to VB‑Group Transition Metal Disulfides:Structure Engineering Modulation for Superior Electromagnetic Wave Absorption 被引量:2
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作者 Junye Cheng Yongheng Jin +10 位作者 Jinghan Zhao Qi Jing Bailong Gu Jialiang Wei Shenghui Yi Mingming Li Wanli Nie Qinghua Qin Deqing Zhang Guangping Zheng Renchao Che 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第2期218-257,共40页
The laminated transition metal disulfides(TMDs),which are well known as typical two-dimensional(2D)semiconductive materials,possess a unique layered structure,leading to their wide-spread applications in various field... The laminated transition metal disulfides(TMDs),which are well known as typical two-dimensional(2D)semiconductive materials,possess a unique layered structure,leading to their wide-spread applications in various fields,such as catalysis,energy storage,sensing,etc.In recent years,a lot of research work on TMDs based functional materials in the fields of electromagnetic wave absorption(EMA)has been carried out.Therefore,it is of great significance to elaborate the influence of TMDs on EMA in time to speed up the application.In this review,recent advances in the development of electromagnetic wave(EMW)absorbers based on TMDs,ranging from the VIB group to the VB group are summarized.Their compositions,microstructures,electronic properties,and synthesis methods are presented in detail.Particularly,the modulation of structure engineering from the aspects of heterostructures,defects,morphologies and phases are systematically summarized,focusing on optimizing impedance matching and increasing dielectric and magnetic losses in the EMA materials with tunable EMW absorption performance.Milestones as well as the challenges are also identified to guide the design of new TMDs based dielectric EMA materials with high performance. 展开更多
关键词 transition metal disulfides Electromagnetic wave absorption Impedance matching Structure engineering modulation
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Recent advances in transition metal phosphide materials:Synthesis and applications in supercapacitors 被引量:1
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作者 Ge Li Yu Feng +3 位作者 Yi Yang Xiaoliang Wu Xiumei Song Lichao Tan 《Nano Materials Science》 EI CAS CSCD 2024年第2期174-192,共19页
Supercapacitors(SCs)are considered promising energy storge systems because of their outstanding power density,fast charge and discharge rate and long-term cycling stability.The exploitation of cheap and efficient elec... Supercapacitors(SCs)are considered promising energy storge systems because of their outstanding power density,fast charge and discharge rate and long-term cycling stability.The exploitation of cheap and efficient electrode materials is the key to improve the performance of supercapacitors.As the battery-type materials,transition metal phosphides(TMPs)possess high theoretical specific capacity,good electrical conductivity and superior structural stability,which have been extensively studied to be electrode materials for supercapacitors.In this review,we summarize the up-to-date progress on TMPs materials from diversified synthetic methods,diverse nanostructures and several prominent TMPs and their composites in application of supercapacitors.In the end,we also propose the remaining challenges toward the rational discovery and synthesis of high-performance TMP electrodes materials for energy storage. 展开更多
关键词 transition metal phosphides Cobalt phosphide Nickel phosphides Electrode materials SUPERCAPACITOR
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Synthesis and Modulation of Low-Dimensional Transition Metal Chalcogenide Materials via Atomic Substitution 被引量:1
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作者 Xuan Wang Akang Chen +3 位作者 XinLei Wu Jiatao Zhang Jichen Dong Leining Zhang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第9期49-94,共46页
In recent years,low-dimensional transition metal chalcogenide(TMC)materials have garnered growing research attention due to their superior electronic,optical,and catalytic properties compared to their bulk counterpart... In recent years,low-dimensional transition metal chalcogenide(TMC)materials have garnered growing research attention due to their superior electronic,optical,and catalytic properties compared to their bulk counterparts.The controllable synthesis and manipulation of these materials are crucial for tailoring their properties and unlocking their full potential in various applications.In this context,the atomic substitution method has emerged as a favorable approach.It involves the replacement of specific atoms within TMC structures with other elements and possesses the capability to regulate the compositions finely,crystal structures,and inherent properties of the resulting materials.In this review,we present a comprehensive overview on various strategies of atomic substitution employed in the synthesis of zero-dimensional,one-dimensional and two-dimensional TMC materials.The effects of substituting elements,substitution ratios,and substitution positions on the structures and morphologies of resulting material are discussed.The enhanced electrocatalytic performance and photovoltaic properties of the obtained materials are also provided,emphasizing the role of atomic substitution in achieving these advancements.Finally,challenges and future prospects in the field of atomic substitution for fabricating low-dimensional TMC materials are summarized. 展开更多
关键词 transition metal chalcogenides Atomic substitution Ion exchange Low-dimensional materials Controllable synthesis
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Flag-transitive point-primitive 2-(v,k,4) symmetric designs and two dimensional classical groups 被引量:5
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作者 ZHOU Sheng-lin TIAN De-lu 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2011年第3期334-341,共8页
Let D be a 2-(v, k, 4) symmetric design and G be a flag-transitive point-primitive automorphism group of D with X ≥G ≤Aut(X) where X ≌ PSL2(q).Then D is a 2-(15,8,4) symmetric design with X = PSL2(9) and ... Let D be a 2-(v, k, 4) symmetric design and G be a flag-transitive point-primitive automorphism group of D with X ≥G ≤Aut(X) where X ≌ PSL2(q).Then D is a 2-(15,8,4) symmetric design with X = PSL2(9) and Xx = PGL2(3) where x is a point of D. 展开更多
关键词 Symmetric design FLAG-transitive point-primitive two dimensional classical group.
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Assessment of challenges and strategies for driving energy transitions in emerging markets:A socio-technological systems perspective 被引量:1
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作者 Nelson S.Chipangamate Glen T.Nwaila 《Energy Geoscience》 EI 2024年第2期81-100,共20页
The pursuit of improved quality of life standards has significantly influenced the contemporary mining model in the 21st century.This era is witnessing an unprecedented transformation driven by pressing concerns relat... The pursuit of improved quality of life standards has significantly influenced the contemporary mining model in the 21st century.This era is witnessing an unprecedented transformation driven by pressing concerns related to sustainability,climate change,the just energy transition,dynamic operating environments,and complex social challenges.Such transitions present both opportunities and obstacles.The aim of this study is to provide an extensive literature review on energy transition to identify the challenges and strategies associated with navigating transformations in energy systems.Understanding these transformations is particularly critical in the face of the severe consequences of global warming,where an accelerated energy transition is viewed as a universal remedy.Adopting a socio-technological systems perspective,specifically through the application of Actor Network Theory(ANT),this research provides a theoretical foundation while categorising challenges into five distinct domains and outlining strategies across these different dimensions.These insights are specifically tailored for emerging market countries to effectively navigate energy transition while fostering the development of resilient societies.Furthermore,our findings highlight that energy transition encompasses more than a mere technological shift;it entails fundamental changes in various systemic socio-economic imperatives.Through focusing on the role of social structures in transitions,this study makes a significant and innovative contribution to ANT,which has historically been criticised for its limited acknowledgement of social structures.Consequently,we propose an emerging market energy transition framework,which not only addresses technological aspects,but also integrates social considerations.This framework paves the way for future research and exploration of energy transition dynamics.The outcomes of this study offer valuable insights to policymakers,researchers,and practitioners engaged in the mining industry,enabling them to comprehend the multifaceted challenges involved and providing practical strategies for effective resolution.Through incorporating the social dimension into the analysis,we enhance the understanding of the complex nature of energy system transformations,facilitating a more holistic approach towards achieving sustainable and resilient energy transitions in emerging markets and beyond. 展开更多
关键词 Actor network theory Energy transition Social innovation Technology Actor inclusive policy
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Multistate transition and coupled solid-liquid modeling of motion process of long-runout landslide 被引量:1
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作者 Yang Gao Yueping Yin +3 位作者 Bin Li Han Zhang Weile Wu Haoyuan Gao 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第7期2694-2714,共21页
The recognition,repetition and prediction of the post-failure motion process of long-runout landslides are key scientific problems in the prevention and mitigation of geological disasters.In this study,a new numerical... The recognition,repetition and prediction of the post-failure motion process of long-runout landslides are key scientific problems in the prevention and mitigation of geological disasters.In this study,a new numerical method involving LPF3D based on a multialgorithm and multiconstitutive model was proposed to simulate long-runout landslides with high precision and efficiency.The following results were obtained:(a)The motion process of landslides showed a steric effect with mobility,including gradual disintegration and spreading.The sliding mass can be divided into three states(dense,dilute and ultradilute)in the motion process,which can be solved by three dynamic regimes(friction,collision,and inertial);(b)Coupling simulation between the solid grain and liquid phases was achieved,focusing on drag force influences;(c)Different algorithms and constitutive models were employed in phase-state simulations.The volume fraction is an important indicator to distinguish different state types and solid‒liquid ratios.The flume experimental results were favorably validated against long-runout landslide case data;and(d)In this method,matched dynamic numerical modeling was developed to better capture the realistic motion process of long-runout landslides,and the advantages of continuum media and discrete media were combined to improve the computational accuracy and efficiency.This new method can reflect the realistic physical and mechanical processes in long-runout landslide motion and provide a suitable method for risk assessment and pre-failure prediction. 展开更多
关键词 Long-runout landslide Multistate transition Mixed solid‒liquid flow Post-failure process Numerical simulation
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Crystal structure,phase transitions,and thermodynamic properties of magnesium metavanadate(MgV_(2)O_(6)) 被引量:1
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作者 Guishang Pei Cheng Pan +2 位作者 Dapeng Zhong Junyi Xiang Xuewei Lv 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第4期1449-1460,共12页
As a promising anode material for magnesium ion rechargeable batteries,magnesium metavanadate(MgV_(2)O_(6))has attracted considerable research interest in recent years.A MgV_(2)O_(6)sample was synthesized via a facile... As a promising anode material for magnesium ion rechargeable batteries,magnesium metavanadate(MgV_(2)O_(6))has attracted considerable research interest in recent years.A MgV_(2)O_(6)sample was synthesized via a facile solid-state reaction by multistep-firing stoichiometric mixtures of MgO and V2O5 powder under an air atmosphere.The solid-state phase transition fromα-MgV_(2)O_(6)toβ-MgV_(2)O_(6)occurred at 841 K and the enthalpy change was 4.37±0.04 kJ/mol.The endothermic effect at 1014 K and the enthalpy change was 26.54±0.26 kJ/mol,which is related to the incongruent melting ofβ-MgV_(2)O_(6).In situ XRD was performed to investigate phase transition of the as-prepared MgV_(2)O_(6)at high temperatures.The cell parameters obtained by Rietveld refinement indicated that it crystallizes in a monoclinic system with the C2/m space group,and the lattice parameters of a=9.280 A°,b=3.501 A°,c=6.731 A°,β=111.76°.The solid-state phase transition fromα-MgV_(2)O_(6)toβ-MgV_(2)O_(6)was further studied by thermal kinetics,indicating that this process is controlled first by a fibril-like mechanism and then by a spherulitic-type mechanism with an increasing heating rate.Additionally,the enthalpy change of MgV_(2)O_(6)at high temperatures was measured utilizing the drop calorimetry,heat capacity was calculated and given as:Cp=208.3+0.03583T-4809000T^(−2)(298-923 K)(J mol^(−1)K^(−1)),the high-temperature heat capacity can be used to calculate Gibbs free energy of MgV_(2)O_(6)at high temperatures. 展开更多
关键词 MgV_(2)O_(6) Crystal structure Phase transitions Thermodynamic functions
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Progress on Transition Metal Ions Dissolution Suppression Strategies in Prussian Blue Analogs for Aqueous Sodium-/Potassium-Ion Batteries 被引量:1
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作者 Wenli Shu Junxian Li +3 位作者 Guangwan Zhang Jiashen Meng Xuanpeng Wang Liqiang Mai 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第7期142-168,共27页
Aqueous sodium-ion batteries(ASIBs)and aqueous potassium-ion batteries(APIBs)present significant potential for large-scale energy storage due to their cost-effectiveness,safety,and environmental compatibility.Nonethel... Aqueous sodium-ion batteries(ASIBs)and aqueous potassium-ion batteries(APIBs)present significant potential for large-scale energy storage due to their cost-effectiveness,safety,and environmental compatibility.Nonetheless,the intricate energy storage mechanisms in aqueous electrolytes place stringent require-ments on the host materials.Prussian blue analogs(PBAs),with their open three-dimensional framework and facile synthesis,stand out as leading candidates for aqueous energy storage.However,PBAs possess a swift capacity fade and limited cycle longevity,for their structural integrity is compromised by the pronounced dis-solution of transition metal(TM)ions in the aqueous milieu.This manuscript provides an exhaustive review of the recent advancements concerning PBAs in ASIBs and APIBs.The dissolution mechanisms of TM ions in PBAs,informed by their structural attributes and redox processes,are thoroughly examined.Moreover,this study delves into innovative design tactics to alleviate the dissolution issue of TM ions.In conclusion,the paper consolidates various strategies for suppressing the dissolution of TM ions in PBAs and posits avenues for prospective exploration of high-safety aqueous sodium-/potassium-ion batteries. 展开更多
关键词 Prussian blue analogs transition metal ions dissolution Suppression strategies Aqueous sodium-ion batteries Aqueous potassium-ion batteries
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