Similar to lithium-ion batteries(LIBs),during the first charge/discharge process of lithium-ion capacitors(LICs),lithium-intercalated anodes(e.g.,silicon,graphite,and hard carbon)also exhibit irreversible lithium inte...Similar to lithium-ion batteries(LIBs),during the first charge/discharge process of lithium-ion capacitors(LICs),lithium-intercalated anodes(e.g.,silicon,graphite,and hard carbon)also exhibit irreversible lithium intercalation behaviors,such as the formation of a solid electrolyte interface(SEI),which will consume Li^(+)in the electrolyte and significantly reduce the electrochemical performance of the system.Therefore,pre-lithiation is an indispensable procedure for LICs.At present,commercial LICs mostly use lithium metal as the lithium source to compensate for the irreversible capacity loss,which has the demerits of operational complexity and danger.However,the pre-lithiation strategy based on cathode sacrificial lithium salts(CSLSs)has been proposed,which has the advantages of low cost,simple operation,environmental protection,and safety.Therefore,there is an urgent need for a timely and comprehensive summary of the application of CSLSs to LICs.In this review,the important roles of pre-lithiation in LICs are detailed,and different pre-lithiation methods are reviewed and compared systematically and comprehensively.After that,we systematically discuss the pre-lithiation strategies based on CSLSs and mainly introduce the lithium extraction mechanism of CSLSs and the influence of intrinsic characteristics and doping amount of CSLSs on LICs performance.In addition,a summary and outlook are conducted,aiming to provide the essential basic knowledge and guidance for developing a new pre-lithiation technology.展开更多
The experiments focused on the influence of magnesium and titanium as additional alloying elements on the microstructure and electro-chemical behavior of Al-Zn-In sacrificial anodes. The electrochemical behavior of th...The experiments focused on the influence of magnesium and titanium as additional alloying elements on the microstructure and electro-chemical behavior of Al-Zn-In sacrificial anodes. The electrochemical behavior of the aluminum sacrificial anode with 3 wt.% sodium chloride solution was studied by electrochemical impedance spectroscopy (EIS) tests. It was found that a microstructure with few precipitates and refined grains could be achieved by adding 1 wt.% Mg and 0.05 wt.% Ti to the Al-Zn-In alloy,resulting...展开更多
Three-dimensional(3D)bioprinting is a powerful approach that enables the fabrication of 3D tissue constructs that retain complex biological functions.However,the dense hydrogel networks that form after the gelation of...Three-dimensional(3D)bioprinting is a powerful approach that enables the fabrication of 3D tissue constructs that retain complex biological functions.However,the dense hydrogel networks that form after the gelation of bioinks often restrict the migration and proliferation of encapsulated cells.Herein,a sacrificial microgel-laden bioink strategy was designed for directly bioprinting constructs with mesoscale pore networks(MPNs)for enhancing nutrient delivery and cell growth.The sacrificial microgel-laden bioink,which contains cell/gelatin methacryloyl(GelMA)mixture and gelled gelatin microgel,is first thermo-crosslinked to fabricate temporary predesigned cell-laden constructs by extrusion bioprinting onto a cold platform.Then,the construct is permanently stabilized through photo-crosslinking of GelMA.The MPNs inside the printed constructs are formed after subsequent dissolution of the gelatin microgel.These MPNs allowed for effective oxygen/nutrient diffusion,facilitating the generation of bioactive tissues.Specifically,osteoblast and human umbilical vein endothelial cells encapsulated in the bioprinted large-scale constructs(≥1 cm)with MPNs showed enhanced bioactivity during culture.The 3D bioprinting strategy based on the sacrificial microgel-laden bioink provided a facile method to facilitate formation of complex tissue constructs with MPNs and set a foundation for future optimization of MPN-based tissue constructs with applications in diverse areas of tissue engineering.展开更多
In this study, sacrificial components were incorporated into self-centering railway bridge piers to improve the lateral stiffness. The seismic response of this new detail was investigated. First, the method to compute...In this study, sacrificial components were incorporated into self-centering railway bridge piers to improve the lateral stiffness. The seismic response of this new detail was investigated. First, the method to compute the initial uplift moment of the self-centering pier is given. In addition, shaking table tests were conducted on a free-rocking pier without sacrificial components, which was used to validate a two-spring numerical model. Good agreement was obtained between the numerical results and experimental data. Furthermore, the validated model was employed to investigate the influence of sacrificial components on the seismic response of rocking piers. For this purpose, two models were developed, with and without sacrificial components. Nonlinear response history analysis was then performed on both models under three historical motions. The results showed that compared to the one without sacrificial components, the rocking pier with sacrificial components has comparable displacement at the top of the pier, and maximum uplift moment at high amplitude motion. Therefore, incorporating sacrificial components into the rocking pier can increase the lateral stiffness at service load and low amplitude frequent earthquakes but can produce comparable response at high seismic excitation. These results provide support for performance-based seismic design of self-centering rocking piers.展开更多
Oxide films are incorporated into melts by an entrainment process, and are expected to be present in most metals, but particularly cast Al alloys. The oxides are necessarily present as folded-over double films (bifi...Oxide films are incorporated into melts by an entrainment process, and are expected to be present in most metals, but particularly cast Al alloys. The oxides are necessarily present as folded-over double films (bifilms) that are effectively cracks. Their effect on the electrochemical behaviour of cast Al-SZn-0.021n sacrificial anodes was studied in 3 wt pct sodium chloride solution using the NACE efficiency evaluation. Three methods were employed to entrain progressive amounts of oxide in the alloy, including the addition of Al-Zn-ln maching chips to the charge, increasing the pouring height, and agitating the melt. The introduction of oxide bifilms in the cast alloy resulted in the deterioration of the electrochemical properties of the sacrificial anodes, such as current capacity and anode efficiency, and introduced increasing variability in these properties. The results suggest that corrosion behaviour is strongly related to the presence of bifilms suspended in the liquid alloy because bifilms provide crack paths allowing the corrodant to penetrate deeply into the metal matrix, and simultaneously provide localized galvanic cells because of the precipitation of Fe rich intermetallic compounds on their outer surfaces.展开更多
The sacrificial anode protection system for the steel pipe piles of the 3rd berth of Dandong; wharf at Dandong port has operated for eight years. In this paper, the program design and the protection effect of the sacr...The sacrificial anode protection system for the steel pipe piles of the 3rd berth of Dandong; wharf at Dandong port has operated for eight years. In this paper, the program design and the protection effect of the sacrificial anode protection system are presented. The results of various inspections show that the piles are protected very satisfactorily.展开更多
The microstructural properties and electrochemical performance of zinc(Zn)sacrificial anodes during strain-induced melt activation(SIMA)were investigated in this study.The samples were subjected to a compressive ratio...The microstructural properties and electrochemical performance of zinc(Zn)sacrificial anodes during strain-induced melt activation(SIMA)were investigated in this study.The samples were subjected to a compressive ratio of 20%-50% at various temperatures(425-435℃)and durations(5-30 min).Short-term electrochemical tests(anode tests)based on DNV-RP-B401 and potentiodynamic polarization tests were performed in 3.5wt%NaCl solution to evaluate the electrochemical efficiency and corrosion behavior of the samples,respectively.The electrochemical test results for the optimum sample confirmed that the corrosion current density declined by 90% and the anode efficiency slightly decreased relative to that of the raw sample.Energy-dispersive X-ray spectroscopy,scanning electron microscopy,metallographic images,and microhardness profiles showed the accumulation of alloying elements on the boundary and the conversion of uniform corrosion into localized corrosion,hence the decrease of the Zn sacrificial anode’s efficiency after the SIMA process.展开更多
In this work, the effect of zinc addition on the performance of aluminium-based sacrificial anode in seawater was investigated. The parameters used in assessing the performance of the cast anodes are anodic efficiency...In this work, the effect of zinc addition on the performance of aluminium-based sacrificial anode in seawater was investigated. The parameters used in assessing the performance of the cast anodes are anodic efficiency, protection efficiency and polarized potential. The percentages of Zn in the anodes were varied from 1 to 8%Zn. The alloys produced were tested as sacrificial anode for the protection of mild steel in seawater at room temperature. Current efficiency as high as 86.69% was achieved at 6%Zn in the alloys. The polarized potential obtained for the couples(steel/Al based alloys) are as given in the pourbaix diagrams with the steel lying within the immunity region/cathodic region ( S-0.5V SHE) and the sacrificial anodes within the anodic region. The protection offered by the sacrificial anodes to the steel after the 7th and 8th week were measured. Protection efficiency values as high as 99.26% and 99.13% were achieved after the 7th and 8th with Al-6%Zn. The microstructure showed the intermetallic structures of β-phase which breakdown the alumina passive film and thus enhancing the anode efficiency.展开更多
During the forming process of the free-standing structure or the functional cavity when releasing the high aspect ratio sacrificial layer, such structures tend to stick to the substrate due to capillary force. This pa...During the forming process of the free-standing structure or the functional cavity when releasing the high aspect ratio sacrificial layer, such structures tend to stick to the substrate due to capillary force. This paper describes the application of pull-in length conception as design rules to a novel 'dimpled' method in releasing sacrificial layer. Based on the conception of pull-in length in adhering Phenomenon, the fabrication and releasing sacrificial layer methods using micro bumps based on the silicon substrate were presented. According to the thermal isolation performances of one kind of micro electromechanical system device thermal shear stress sensor, the sacrificial layers were validated to be successfully released.展开更多
Freestanding membrane (FSM) of hydroxyapatite (HA) is a thin sheet of pure HA without any supporting substrates. Our original preparation process of FSM of HA had three steps: The first was the deposition of HA layer ...Freestanding membrane (FSM) of hydroxyapatite (HA) is a thin sheet of pure HA without any supporting substrates. Our original preparation process of FSM of HA had three steps: The first was the deposition of HA layer on sacrificial layer of solvent-soluble materials, the second was separation of FSM of HA by means of dissolution of sacrificial layer, and the third was post-annealing to crystallize FSM of HA. To date, the post-annealing process was a serious bottleneck of productivity owing to its too long time. In this short report, we proposed a novel sacrificial layer, heatproof and water-soluble Ba-compound, which makes the direct deposition of crystallized HA possible due to its heatproof property because the problem on the original process was that the previous sacrificial layers have no heatproof property and HA layer should be deposited as amorphous. We can deposit the Ba-compound sacrificial layer only in 1 hour followed with the direct deposition of crystallized HA layer, substituting the 20 hours of post-annealing. The FSM of HA was separated successfully from the substrate by means of dissolution of Ba-compound with water. Our novel process can shrink the process time by 19 hours.展开更多
Taiwan Strait is one of the potential wind farm in the world. Cooperate with the development of national policies, thousands of offshore wind turbines will be installed in Taiwan Strait. In order to enable offshore wi...Taiwan Strait is one of the potential wind farm in the world. Cooperate with the development of national policies, thousands of offshore wind turbines will be installed in Taiwan Strait. In order to enable offshore wind turbine foundation to be erected in the ocean for a long time, the offshore structure facilities are protected by sacrificial anode or impressed current of today. This study utilized the MIKE21 numerical model, combined with ocean parameters such as sea waves and tidal current to simulate the change of the diffusion concentration and diffusion range of the materials released by the aluminum sacrificial anode blocks by the Changhua offshore wind farm located on Taiwan Strait in winter and summer, thus to evaluate the impact on the marine environment.展开更多
We investigated the simulation of the cracking and ablation behavior of ferro-siliceous and siliceous nuclear sacrificial concretes. To this end, four type of sacrificial concretes were fabricated, i e, the ferro-sili...We investigated the simulation of the cracking and ablation behavior of ferro-siliceous and siliceous nuclear sacrificial concretes. To this end, four type of sacrificial concretes were fabricated, i e, the ferro-siliceous(F) and siliceous(S) plain concretes, and the polypropylene fiber reinforced concretes of the above two(FF, SF). The cracking and ablation behaviors of the sacrificial concretes were investigated by simulation tests, and the simulated elevated temperature was obtained by means of thermite powder. The number and the width of the cracks were compared and the pore size distribution of sacrificial concretes was measured. In addition, the interface and chemical composition of melt at different positions were analyzed, and the ablation depth of the sacrificial concrete crucibles was also measured. It was found that the siliceous concrete shows to be more prone to cracking than the ferro-siliceous concrete due to the higher content of fly ash and lower water to binder ratio; though the ablation depth of siliceous concrete is found to be slightly larger, no clear difference can be detected for the basemat ablation rate.展开更多
Most TibetanBuddhist ritualimplements andsacrificialobjects were cast in gold,silver or copper, in additionto those made of wood,bone,stone,shells,cloth,silks and brocade heyconstitute an important partof he treasure ...Most TibetanBuddhist ritualimplements andsacrificialobjects were cast in gold,silver or copper, in additionto those made of wood,bone,stone,shells,cloth,silks and brocade heyconstitute an important partof he treasure house ofTibetan Buddhism.展开更多
Sodium-ion capacitors(SICs)have attracted appreciable attention in virtue of the higher energy and power densities compared with their rivals,supercapacitors and sodium-ion batteries.Due to the lack of sodium resource...Sodium-ion capacitors(SICs)have attracted appreciable attention in virtue of the higher energy and power densities compared with their rivals,supercapacitors and sodium-ion batteries.Due to the lack of sodium resources in cathode,presodiation is critical for SICs to further augment performances.However,current presodiation strategy utilizes metallic sodium as the presodiation material.In this strategy,assembling/disassembling of half-cells is required,which is dangerous and in creases the time and cost of SIC leading to the restriction of their industrialization and commercialization.Herein we present a safe,low-cost and high-efficiency presodiation strategy by first employing Na_(2)C_(2)O_(4) as the sacrificial salt applied in SICs.Na_(2)C_(2)O_(4) is environmentally friendly and possesses considerably low expenditure.No additional residues remain after sodium extraction ascribed to its"zero dead mass"property.When paired with commercial activated carb on as the cathode and commercial hard carbon as the ano de,the constructed pouch-type SICs exhibit high energy and power densities of 91.7 Wh/kg and 13.1 kW/kg,respectively.This work shows a prospect of realizing the safe and low-cost manufacturing for high-performance SICs commercially.展开更多
Electrochemical fixation of atmospheric pressure of carbon dioxide to organic compounds is a useful and attractive method for synthesizing of various carboxylic acids. Electrochemical fixation of carbon dioxide, elect...Electrochemical fixation of atmospheric pressure of carbon dioxide to organic compounds is a useful and attractive method for synthesizing of various carboxylic acids. Electrochemical fixation of carbon dioxide, electrochemical carboxylation, organic halides, organic triflates, alkenes, aromatic compounds, and carbonyl compounds can readily occur in the presence of an atmospheric pressure of carbon dioxide to form the corresponding carboxylic acids with high yields, when a sacrificial anode such as magnesium or aluminum is used in the electrolysis. The electrochemical carboxylation of vinyl bromides was successfully applied for the synthesis of the precursor of nonsteroidal anti-inflammatory agents such as ibuprofen and naproxen. On the other hand, supercritical carbon dioxide (scCO2) has significant potential as an environmentally benign solvent in organic synthesis and it could be used both as a solvent and as a reagent in these electrochemical carboxylations by using a small amount of cosolvent.展开更多
The construction and surface modification of three-dimensional(3D) graphene structures have been recognized as effective ways to prepare high-performance graphene-based composites in energy-related applications. Herei...The construction and surface modification of three-dimensional(3D) graphene structures have been recognized as effective ways to prepare high-performance graphene-based composites in energy-related applications. Herein, on the basis of well-defined morphology and efficient electron conduction, the 3D highly-stable graphene hollow nanospheres have been synthesized by using sacrificial template method. The asprepared 3D graphene nanospheres exhibit superior mechanical stability, electrochemical stability, and strong hydrophobicity, which may accelerate the emission of H2O in acidic medium-based ORR. Accordingly, the 3D highly-stable graphene nanospheres are used to confine tiny Pt nanoparticles(3Dr-GO@Pt HNSs) for ORR in acidic medium, exhibiting superior activity with 4-electron-transfered pathway. Meanwhile,dramatically improved durability are achieved in terms of both ORR mass activity and electrochemically surface area compared to those of commercial Pt/C.展开更多
A free-standing paper-like three-dimensional graphene framework(3DGF) with orientated laminar structure and interconnected macropores, was obtained by the hard template-directed ordered assembly. As the sacrificial ...A free-standing paper-like three-dimensional graphene framework(3DGF) with orientated laminar structure and interconnected macropores, was obtained by the hard template-directed ordered assembly. As the sacrificial templates, polystyrene(PS) latex spheres were assembled with graphene oxide(GO) to build up a sandwich type composite film, followed by heat removal of which with a simultaneous reduction of GO. The 3DGF exhibited high specific surface area of 402.5 m2/g, controllable pores and mechanical flexibility, which was employed as the binder-free supercapacitor electrode and shows high specific gravimetric capacitance of 95 F/g at 0.5 A/g, with enhanced rate capability in 3 electrode KOH system.展开更多
A review of the literature published on topics interrelated to electrochemical treatment within wastewater by using sacrificial anodes was presented. Electrocoagulation (EC) is a technique used for water and has a gre...A review of the literature published on topics interrelated to electrochemical treatment within wastewater by using sacrificial anodes was presented. Electrocoagulation (EC) is a technique used for water and has a great ability on various wastewater treatments, industrial processed water, and medical treatment. It has potential in removing various pollutants such as chemical oxygen demand turbidity, ammonia, color, and suspended solid. One of the most necessities industries is Textile industries which release large volumes of wastewater that contains different dyes. Azo dyes contain strong N = N bond which is not easily broken by conventional methods. The discharge of this type of wastewater to natural watercourse can pose serious environmental impacts to aquatic life. Electrocoagulation (EC) method depends on several factors as electrode material, current density, operation time and PH. The review describes, discusses and compares the types of that electrode influencing the EC process in various wastewater and leachate. Both operating costs and electrical energy consumption values were found to vary greatly depending on the type of electrodes material and solution being treated.展开更多
Polyaniline(PANI)was effectively immobilized on the surface of ordered mesoporous carbon(OMC)by using Mn_2O_3 as sacrificial template.The observed microstructure and morphology indicate that a thin layer of PANI was c...Polyaniline(PANI)was effectively immobilized on the surface of ordered mesoporous carbon(OMC)by using Mn_2O_3 as sacrificial template.The observed microstructure and morphology indicate that a thin layer of PANI was coated on OMC uniformly.As a supercapacitor electrode material,the discharge capacity of the optimized PANI/OMC could reach 467 F/g,which is far higher than that of OMC,PANI and Mn_2O_3/OMC.Furthermore,PANI/OMC composites with different content of PANI are obtained by adjusting the amount of Mn_2O_3 on OMC and their properties are characterized.The results show that a thin layer of PANI can improve the capacity of PANI/OMC composites effectively and the further increase of PANI reduces the capacity of PANI/OMC composites.The sacrificial template method presented here is beneficial to coating a layer of polymer on carbon materials,and the content of polymer layer can be controlled by adjusting the amount of Mn_2O_3 in Mn_2O_3/OMC.展开更多
基金supported by the National Natural Science Foundation of China[grant number 22005318,22075303]the Western Young Scholars Foundations of Chinese Academy of Sciences,the Science Fund of Shandong Laboratory of Yantai Advanced Materials and Green Manufacturing(AMGM2022A02)the Provincial Youth Science and Technology Fund Program of Gansu Province[Project No.21JR7RA092].
文摘Similar to lithium-ion batteries(LIBs),during the first charge/discharge process of lithium-ion capacitors(LICs),lithium-intercalated anodes(e.g.,silicon,graphite,and hard carbon)also exhibit irreversible lithium intercalation behaviors,such as the formation of a solid electrolyte interface(SEI),which will consume Li^(+)in the electrolyte and significantly reduce the electrochemical performance of the system.Therefore,pre-lithiation is an indispensable procedure for LICs.At present,commercial LICs mostly use lithium metal as the lithium source to compensate for the irreversible capacity loss,which has the demerits of operational complexity and danger.However,the pre-lithiation strategy based on cathode sacrificial lithium salts(CSLSs)has been proposed,which has the advantages of low cost,simple operation,environmental protection,and safety.Therefore,there is an urgent need for a timely and comprehensive summary of the application of CSLSs to LICs.In this review,the important roles of pre-lithiation in LICs are detailed,and different pre-lithiation methods are reviewed and compared systematically and comprehensively.After that,we systematically discuss the pre-lithiation strategies based on CSLSs and mainly introduce the lithium extraction mechanism of CSLSs and the influence of intrinsic characteristics and doping amount of CSLSs on LICs performance.In addition,a summary and outlook are conducted,aiming to provide the essential basic knowledge and guidance for developing a new pre-lithiation technology.
文摘The experiments focused on the influence of magnesium and titanium as additional alloying elements on the microstructure and electro-chemical behavior of Al-Zn-In sacrificial anodes. The electrochemical behavior of the aluminum sacrificial anode with 3 wt.% sodium chloride solution was studied by electrochemical impedance spectroscopy (EIS) tests. It was found that a microstructure with few precipitates and refined grains could be achieved by adding 1 wt.% Mg and 0.05 wt.% Ti to the Al-Zn-In alloy,resulting...
基金sponsored by the National Nature Science Foundation of China(Nos.U1609207,81827804).
文摘Three-dimensional(3D)bioprinting is a powerful approach that enables the fabrication of 3D tissue constructs that retain complex biological functions.However,the dense hydrogel networks that form after the gelation of bioinks often restrict the migration and proliferation of encapsulated cells.Herein,a sacrificial microgel-laden bioink strategy was designed for directly bioprinting constructs with mesoscale pore networks(MPNs)for enhancing nutrient delivery and cell growth.The sacrificial microgel-laden bioink,which contains cell/gelatin methacryloyl(GelMA)mixture and gelled gelatin microgel,is first thermo-crosslinked to fabricate temporary predesigned cell-laden constructs by extrusion bioprinting onto a cold platform.Then,the construct is permanently stabilized through photo-crosslinking of GelMA.The MPNs inside the printed constructs are formed after subsequent dissolution of the gelatin microgel.These MPNs allowed for effective oxygen/nutrient diffusion,facilitating the generation of bioactive tissues.Specifically,osteoblast and human umbilical vein endothelial cells encapsulated in the bioprinted large-scale constructs(≥1 cm)with MPNs showed enhanced bioactivity during culture.The 3D bioprinting strategy based on the sacrificial microgel-laden bioink provided a facile method to facilitate formation of complex tissue constructs with MPNs and set a foundation for future optimization of MPN-based tissue constructs with applications in diverse areas of tissue engineering.
文摘In this study, sacrificial components were incorporated into self-centering railway bridge piers to improve the lateral stiffness. The seismic response of this new detail was investigated. First, the method to compute the initial uplift moment of the self-centering pier is given. In addition, shaking table tests were conducted on a free-rocking pier without sacrificial components, which was used to validate a two-spring numerical model. Good agreement was obtained between the numerical results and experimental data. Furthermore, the validated model was employed to investigate the influence of sacrificial components on the seismic response of rocking piers. For this purpose, two models were developed, with and without sacrificial components. Nonlinear response history analysis was then performed on both models under three historical motions. The results showed that compared to the one without sacrificial components, the rocking pier with sacrificial components has comparable displacement at the top of the pier, and maximum uplift moment at high amplitude motion. Therefore, incorporating sacrificial components into the rocking pier can increase the lateral stiffness at service load and low amplitude frequent earthquakes but can produce comparable response at high seismic excitation. These results provide support for performance-based seismic design of self-centering rocking piers.
文摘Oxide films are incorporated into melts by an entrainment process, and are expected to be present in most metals, but particularly cast Al alloys. The oxides are necessarily present as folded-over double films (bifilms) that are effectively cracks. Their effect on the electrochemical behaviour of cast Al-SZn-0.021n sacrificial anodes was studied in 3 wt pct sodium chloride solution using the NACE efficiency evaluation. Three methods were employed to entrain progressive amounts of oxide in the alloy, including the addition of Al-Zn-ln maching chips to the charge, increasing the pouring height, and agitating the melt. The introduction of oxide bifilms in the cast alloy resulted in the deterioration of the electrochemical properties of the sacrificial anodes, such as current capacity and anode efficiency, and introduced increasing variability in these properties. The results suggest that corrosion behaviour is strongly related to the presence of bifilms suspended in the liquid alloy because bifilms provide crack paths allowing the corrodant to penetrate deeply into the metal matrix, and simultaneously provide localized galvanic cells because of the precipitation of Fe rich intermetallic compounds on their outer surfaces.
文摘The sacrificial anode protection system for the steel pipe piles of the 3rd berth of Dandong; wharf at Dandong port has operated for eight years. In this paper, the program design and the protection effect of the sacrificial anode protection system are presented. The results of various inspections show that the piles are protected very satisfactorily.
文摘The microstructural properties and electrochemical performance of zinc(Zn)sacrificial anodes during strain-induced melt activation(SIMA)were investigated in this study.The samples were subjected to a compressive ratio of 20%-50% at various temperatures(425-435℃)and durations(5-30 min).Short-term electrochemical tests(anode tests)based on DNV-RP-B401 and potentiodynamic polarization tests were performed in 3.5wt%NaCl solution to evaluate the electrochemical efficiency and corrosion behavior of the samples,respectively.The electrochemical test results for the optimum sample confirmed that the corrosion current density declined by 90% and the anode efficiency slightly decreased relative to that of the raw sample.Energy-dispersive X-ray spectroscopy,scanning electron microscopy,metallographic images,and microhardness profiles showed the accumulation of alloying elements on the boundary and the conversion of uniform corrosion into localized corrosion,hence the decrease of the Zn sacrificial anode’s efficiency after the SIMA process.
文摘In this work, the effect of zinc addition on the performance of aluminium-based sacrificial anode in seawater was investigated. The parameters used in assessing the performance of the cast anodes are anodic efficiency, protection efficiency and polarized potential. The percentages of Zn in the anodes were varied from 1 to 8%Zn. The alloys produced were tested as sacrificial anode for the protection of mild steel in seawater at room temperature. Current efficiency as high as 86.69% was achieved at 6%Zn in the alloys. The polarized potential obtained for the couples(steel/Al based alloys) are as given in the pourbaix diagrams with the steel lying within the immunity region/cathodic region ( S-0.5V SHE) and the sacrificial anodes within the anodic region. The protection offered by the sacrificial anodes to the steel after the 7th and 8th week were measured. Protection efficiency values as high as 99.26% and 99.13% were achieved after the 7th and 8th with Al-6%Zn. The microstructure showed the intermetallic structures of β-phase which breakdown the alumina passive film and thus enhancing the anode efficiency.
文摘During the forming process of the free-standing structure or the functional cavity when releasing the high aspect ratio sacrificial layer, such structures tend to stick to the substrate due to capillary force. This paper describes the application of pull-in length conception as design rules to a novel 'dimpled' method in releasing sacrificial layer. Based on the conception of pull-in length in adhering Phenomenon, the fabrication and releasing sacrificial layer methods using micro bumps based on the silicon substrate were presented. According to the thermal isolation performances of one kind of micro electromechanical system device thermal shear stress sensor, the sacrificial layers were validated to be successfully released.
文摘Freestanding membrane (FSM) of hydroxyapatite (HA) is a thin sheet of pure HA without any supporting substrates. Our original preparation process of FSM of HA had three steps: The first was the deposition of HA layer on sacrificial layer of solvent-soluble materials, the second was separation of FSM of HA by means of dissolution of sacrificial layer, and the third was post-annealing to crystallize FSM of HA. To date, the post-annealing process was a serious bottleneck of productivity owing to its too long time. In this short report, we proposed a novel sacrificial layer, heatproof and water-soluble Ba-compound, which makes the direct deposition of crystallized HA possible due to its heatproof property because the problem on the original process was that the previous sacrificial layers have no heatproof property and HA layer should be deposited as amorphous. We can deposit the Ba-compound sacrificial layer only in 1 hour followed with the direct deposition of crystallized HA layer, substituting the 20 hours of post-annealing. The FSM of HA was separated successfully from the substrate by means of dissolution of Ba-compound with water. Our novel process can shrink the process time by 19 hours.
文摘Taiwan Strait is one of the potential wind farm in the world. Cooperate with the development of national policies, thousands of offshore wind turbines will be installed in Taiwan Strait. In order to enable offshore wind turbine foundation to be erected in the ocean for a long time, the offshore structure facilities are protected by sacrificial anode or impressed current of today. This study utilized the MIKE21 numerical model, combined with ocean parameters such as sea waves and tidal current to simulate the change of the diffusion concentration and diffusion range of the materials released by the aluminum sacrificial anode blocks by the Changhua offshore wind farm located on Taiwan Strait in winter and summer, thus to evaluate the impact on the marine environment.
基金Funded by National Natural Science Foundation of China(Nos.51378114 and 5161113020)National Basic Research Program of China(973 Program)(No.2015CB655105)
文摘We investigated the simulation of the cracking and ablation behavior of ferro-siliceous and siliceous nuclear sacrificial concretes. To this end, four type of sacrificial concretes were fabricated, i e, the ferro-siliceous(F) and siliceous(S) plain concretes, and the polypropylene fiber reinforced concretes of the above two(FF, SF). The cracking and ablation behaviors of the sacrificial concretes were investigated by simulation tests, and the simulated elevated temperature was obtained by means of thermite powder. The number and the width of the cracks were compared and the pore size distribution of sacrificial concretes was measured. In addition, the interface and chemical composition of melt at different positions were analyzed, and the ablation depth of the sacrificial concrete crucibles was also measured. It was found that the siliceous concrete shows to be more prone to cracking than the ferro-siliceous concrete due to the higher content of fly ash and lower water to binder ratio; though the ablation depth of siliceous concrete is found to be slightly larger, no clear difference can be detected for the basemat ablation rate.
文摘Most TibetanBuddhist ritualimplements andsacrificialobjects were cast in gold,silver or copper, in additionto those made of wood,bone,stone,shells,cloth,silks and brocade heyconstitute an important partof he treasure house ofTibetan Buddhism.
基金supported by the National Science Foundation of China(No.51907193,51822706 and 51777200)the Beijing Natural Science foundation(JQ19012)+2 种基金the Key Research Program of Frontier Sciences,CAS(No.ZDBS-LY-JSC047)the Youth Innovation Promotion Association,CAS(No.2020145)the Dalian National Laboratory for Clean Energy Cooperation Fund,the CAS(Nos.DNL201912,DNL201915).
文摘Sodium-ion capacitors(SICs)have attracted appreciable attention in virtue of the higher energy and power densities compared with their rivals,supercapacitors and sodium-ion batteries.Due to the lack of sodium resources in cathode,presodiation is critical for SICs to further augment performances.However,current presodiation strategy utilizes metallic sodium as the presodiation material.In this strategy,assembling/disassembling of half-cells is required,which is dangerous and in creases the time and cost of SIC leading to the restriction of their industrialization and commercialization.Herein we present a safe,low-cost and high-efficiency presodiation strategy by first employing Na_(2)C_(2)O_(4) as the sacrificial salt applied in SICs.Na_(2)C_(2)O_(4) is environmentally friendly and possesses considerably low expenditure.No additional residues remain after sodium extraction ascribed to its"zero dead mass"property.When paired with commercial activated carb on as the cathode and commercial hard carbon as the ano de,the constructed pouch-type SICs exhibit high energy and power densities of 91.7 Wh/kg and 13.1 kW/kg,respectively.This work shows a prospect of realizing the safe and low-cost manufacturing for high-performance SICs commercially.
文摘Electrochemical fixation of atmospheric pressure of carbon dioxide to organic compounds is a useful and attractive method for synthesizing of various carboxylic acids. Electrochemical fixation of carbon dioxide, electrochemical carboxylation, organic halides, organic triflates, alkenes, aromatic compounds, and carbonyl compounds can readily occur in the presence of an atmospheric pressure of carbon dioxide to form the corresponding carboxylic acids with high yields, when a sacrificial anode such as magnesium or aluminum is used in the electrolysis. The electrochemical carboxylation of vinyl bromides was successfully applied for the synthesis of the precursor of nonsteroidal anti-inflammatory agents such as ibuprofen and naproxen. On the other hand, supercritical carbon dioxide (scCO2) has significant potential as an environmentally benign solvent in organic synthesis and it could be used both as a solvent and as a reagent in these electrochemical carboxylations by using a small amount of cosolvent.
基金supported by the financial supports from National Natural Science Foundation of China (21503111, 51806110, 21875112 and 21576139)Natural Science Foundation of Jiangsu Higher Education Institutions of China (16KJB150020)+1 种基金Natural Science Foundation of Jiangsu Province (BK20171473)National and Local Joint Engineering Research Center of Biomedical Functional Materials and Priority Academic Program Development of Jiangsu Higher Education Institutions
文摘The construction and surface modification of three-dimensional(3D) graphene structures have been recognized as effective ways to prepare high-performance graphene-based composites in energy-related applications. Herein, on the basis of well-defined morphology and efficient electron conduction, the 3D highly-stable graphene hollow nanospheres have been synthesized by using sacrificial template method. The asprepared 3D graphene nanospheres exhibit superior mechanical stability, electrochemical stability, and strong hydrophobicity, which may accelerate the emission of H2O in acidic medium-based ORR. Accordingly, the 3D highly-stable graphene nanospheres are used to confine tiny Pt nanoparticles(3Dr-GO@Pt HNSs) for ORR in acidic medium, exhibiting superior activity with 4-electron-transfered pathway. Meanwhile,dramatically improved durability are achieved in terms of both ORR mass activity and electrochemically surface area compared to those of commercial Pt/C.
基金financial support from the Natural Science Foundation of China(51302281 and 51402324)Natural Science Foundation of Shanxi Province(2013011012–7)
文摘A free-standing paper-like three-dimensional graphene framework(3DGF) with orientated laminar structure and interconnected macropores, was obtained by the hard template-directed ordered assembly. As the sacrificial templates, polystyrene(PS) latex spheres were assembled with graphene oxide(GO) to build up a sandwich type composite film, followed by heat removal of which with a simultaneous reduction of GO. The 3DGF exhibited high specific surface area of 402.5 m2/g, controllable pores and mechanical flexibility, which was employed as the binder-free supercapacitor electrode and shows high specific gravimetric capacitance of 95 F/g at 0.5 A/g, with enhanced rate capability in 3 electrode KOH system.
文摘A review of the literature published on topics interrelated to electrochemical treatment within wastewater by using sacrificial anodes was presented. Electrocoagulation (EC) is a technique used for water and has a great ability on various wastewater treatments, industrial processed water, and medical treatment. It has potential in removing various pollutants such as chemical oxygen demand turbidity, ammonia, color, and suspended solid. One of the most necessities industries is Textile industries which release large volumes of wastewater that contains different dyes. Azo dyes contain strong N = N bond which is not easily broken by conventional methods. The discharge of this type of wastewater to natural watercourse can pose serious environmental impacts to aquatic life. Electrocoagulation (EC) method depends on several factors as electrode material, current density, operation time and PH. The review describes, discusses and compares the types of that electrode influencing the EC process in various wastewater and leachate. Both operating costs and electrical energy consumption values were found to vary greatly depending on the type of electrodes material and solution being treated.
基金financially supported by Chongqing Key Laboratory for Advanced Materials and Technologies of Clean Energies,Institute for Clean Energy & Advanced Materials (Southwest University)the Natural Science Foundation of Chongqing (No.cstc2013jcyjA5004)+2 种基金the Fundamental Research Funds for the Central Universities (No.XDJK2013B031)Program for Excellent Talents in Chongqing(No.102060-20600218)the National Natural Science Foundation of China(No.21163021)
文摘Polyaniline(PANI)was effectively immobilized on the surface of ordered mesoporous carbon(OMC)by using Mn_2O_3 as sacrificial template.The observed microstructure and morphology indicate that a thin layer of PANI was coated on OMC uniformly.As a supercapacitor electrode material,the discharge capacity of the optimized PANI/OMC could reach 467 F/g,which is far higher than that of OMC,PANI and Mn_2O_3/OMC.Furthermore,PANI/OMC composites with different content of PANI are obtained by adjusting the amount of Mn_2O_3 on OMC and their properties are characterized.The results show that a thin layer of PANI can improve the capacity of PANI/OMC composites effectively and the further increase of PANI reduces the capacity of PANI/OMC composites.The sacrificial template method presented here is beneficial to coating a layer of polymer on carbon materials,and the content of polymer layer can be controlled by adjusting the amount of Mn_2O_3 in Mn_2O_3/OMC.