The safety valve is an important component to ensure the safe operation of lithium-ion batteries(LIBs).However,the effect of safety valve type on the thermal runaway(TR)and gas venting behavior of LIBs,as well as the ...The safety valve is an important component to ensure the safe operation of lithium-ion batteries(LIBs).However,the effect of safety valve type on the thermal runaway(TR)and gas venting behavior of LIBs,as well as the TR hazard severity of LIBs,are not known.In this paper,the TR and gas venting behavior of three 100 A h lithium iron phosphate(LFP)batteries with different safety valves are investigated under overheating.Compared to previous studies,the main contribution of this work is in studying and evaluating the effect of gas venting behavior and TR hazard severity of LFP batteries with three safety valve types.Two significant results are obtained:(Ⅰ)the safety valve type dominates over gas venting pressure of battery during safety venting,the maximum gas venting pressure of LFP batteries with a round safety valve is 3320 Pa,which is one order of magnitude higher than other batteries with oval or cavity safety valve;(Ⅱ)the LFP battery with oval safety valve has the lowest TR hazard as shown by the TR hazard assessment model based on gray-fuzzy analytic hierarchy process.This study reveals the effect of safety valve type on TR and gas venting,providing a clear direction for the safety valve design.展开更多
The possibility of pressure control with the structural change of a safety valve is investigated Safety valve is commonly used as safety devices for numerous applications which include boilers,ships,industrial plant...The possibility of pressure control with the structural change of a safety valve is investigated Safety valve is commonly used as safety devices for numerous applications which include boilers,ships,industrial plants,and piping Setting and stopping pressures of a safety valve, p set and p sto ,are traditionally adjusted with a fine tuning of seat ring and valve ring heights, h sr and h vr However, it is not easy to achieve the proper setting and stopping pressures of a safety valve in practice The depth of inside and outside grooves in a valve, d i and d o are modified and their effects on setting and stopping pressures of a safety vlave are tested The most appropriate values appear 1 0 mm in d i and 0 5~1 0 mm in d o,respectively The valve ring height, h vr ,shows that the best results can be achieved at 2 3 mm for setting pressures of 0 1~0 4 MPa and 1 0 mm for setting pressures of 0 5~1 0 MPa The stopping pressures increases with the increase of seat ring height, h sr , upto certain h sr value and then becomes independent to the seat ring height This implies that there exists the optimum h sr ,which provides the largest flow rate and the proper stopping pressure Stopping pressures of a safety valve are adjusted with the seat ring and valve ring heights This study,however,demonstrated that the modification of value grooves also changes setting and stopping pressures of a safety valve Therefore,the proper selection in dimensions of the inside and outside grooves should be considered for the safety valve design展开更多
基金supported by the National Key R&D Program of China(No.2021YFB2402001)the Postgraduate Innovation and Entrepreneurship Practice Project of Anhui Province(No.2022cxcysj013)+2 种基金the China Postdoctoral Science Foundation(No.2022T150615)the Fundamental Research Funds for the Central Universities(No.WK5290000002)supported by Youth Innovation Promotion Association CAS(No.Y201768)。
文摘The safety valve is an important component to ensure the safe operation of lithium-ion batteries(LIBs).However,the effect of safety valve type on the thermal runaway(TR)and gas venting behavior of LIBs,as well as the TR hazard severity of LIBs,are not known.In this paper,the TR and gas venting behavior of three 100 A h lithium iron phosphate(LFP)batteries with different safety valves are investigated under overheating.Compared to previous studies,the main contribution of this work is in studying and evaluating the effect of gas venting behavior and TR hazard severity of LFP batteries with three safety valve types.Two significant results are obtained:(Ⅰ)the safety valve type dominates over gas venting pressure of battery during safety venting,the maximum gas venting pressure of LFP batteries with a round safety valve is 3320 Pa,which is one order of magnitude higher than other batteries with oval or cavity safety valve;(Ⅱ)the LFP battery with oval safety valve has the lowest TR hazard as shown by the TR hazard assessment model based on gray-fuzzy analytic hierarchy process.This study reveals the effect of safety valve type on TR and gas venting,providing a clear direction for the safety valve design.
文摘The possibility of pressure control with the structural change of a safety valve is investigated Safety valve is commonly used as safety devices for numerous applications which include boilers,ships,industrial plants,and piping Setting and stopping pressures of a safety valve, p set and p sto ,are traditionally adjusted with a fine tuning of seat ring and valve ring heights, h sr and h vr However, it is not easy to achieve the proper setting and stopping pressures of a safety valve in practice The depth of inside and outside grooves in a valve, d i and d o are modified and their effects on setting and stopping pressures of a safety vlave are tested The most appropriate values appear 1 0 mm in d i and 0 5~1 0 mm in d o,respectively The valve ring height, h vr ,shows that the best results can be achieved at 2 3 mm for setting pressures of 0 1~0 4 MPa and 1 0 mm for setting pressures of 0 5~1 0 MPa The stopping pressures increases with the increase of seat ring height, h sr , upto certain h sr value and then becomes independent to the seat ring height This implies that there exists the optimum h sr ,which provides the largest flow rate and the proper stopping pressure Stopping pressures of a safety valve are adjusted with the seat ring and valve ring heights This study,however,demonstrated that the modification of value grooves also changes setting and stopping pressures of a safety valve Therefore,the proper selection in dimensions of the inside and outside grooves should be considered for the safety valve design